CN110629361A - Moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton-nylon blended fabric and preparation method thereof - Google Patents

Moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton-nylon blended fabric and preparation method thereof Download PDF

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Publication number
CN110629361A
CN110629361A CN201910932593.8A CN201910932593A CN110629361A CN 110629361 A CN110629361 A CN 110629361A CN 201910932593 A CN201910932593 A CN 201910932593A CN 110629361 A CN110629361 A CN 110629361A
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ultraviolet
cotton
sweat
static
releasing
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侯连书
林晓康
王红卫
罗保龙
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Shaanxi Jin Lan Science And Technology Ltd
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Shaanxi Jin Lan Science And Technology Ltd
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    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/26Yarns or threads characterised by constructional features, e.g. blending, filament/fibre with characteristics dependent on the amount or direction of twist
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44Yarns or threads characterised by the purpose for which they are designed
    • D02G3/441Yarns or threads with antistatic, conductive or radiation-shielding properties
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00Woven fabrics designed to make specified articles
    • D03D1/0035Protective fabrics
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/47Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/533Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads antistatic; electrically conductive
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34Polyamides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10Repellency against liquids
    • D06M2200/11Oleophobic properties
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10Repellency against liquids
    • D06M2200/12Hydrophobic properties
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/25Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/10Inorganic fibres based on non-oxides other than metals
    • D10B2101/12Carbon; Pitch
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/20Metallic fibres
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/02Cotton
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/16Physical properties antistatic; conductive
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    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/22Physical properties protective against sunlight or UV radiation

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Woven Fabrics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The invention discloses a moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton-nylon blended fabric which comprises the following components in percentage by mass: 55-65% of cotton fiber, 34.5-44.5% of polyester fiber and 0.5% of conductive fiber, wherein the sum of the mass percentages of the above three fibers is 100%. The invention also specifically discloses a preparation method of the cotton-nylon blended fabric, which comprises the steps of carrying out ultraviolet ray finishing on the semi-finished product of the antistatic colored cloth and then carrying out moisture absorption and sweat releasing finishing to prepare the multifunctional fabric, and the multifunctional fabric has excellent performance, meets the relevant national standard regulation, can meet the requirements of industrial production and use, breaks through the limitation that the traditional cotton/nylon blended fabric only has a single function, and has strong market competitiveness and huge social and economic benefits.

Description

Moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton-nylon blended fabric and preparation method thereof
Technical Field
The invention belongs to the technical field of functional textiles, and particularly relates to a moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton-nylon blended fabric and a preparation method thereof.
Background
In recent years, with the rapid development of the industry in China, the production scale of the petrochemical industry is also expanding. The petrochemical industry uses petroleum, refined petroleum products, oil fields and natural gas which exist in large quantities in nature as raw materials, and adopts various chemical processing to prepare a series of important basic organic chemical products, but because of the special properties of the petrochemical industry: the system is inflammable, explosive, poisoned easily, corroded at high temperature and high pressure, so active and effective countermeasures are needed in the aspects of safety protection and management to ensure the engineering progress and the safety of all workers.
The method provides guarantee for safety protection in the labor protection industry and industrial individual safety, promotes improvement of the individual safety protection level in China, and provides higher requirements for the functionality of textiles in China. In order to solve the above problems, the antistatic performance of textiles is a widely studied function at present. However, for high altitude and strong ultraviolet areas like Xinjiang, Tibet and the like, only a single antistatic functional fabric in the market cannot meet the safety protection of the areas. In order to avoid injury to workers and enhance labor protection, the protective performance of the work clothes tends to be developed from single protective performance to composite protective performance. Therefore, the fabric with multiple protective performances such as the anti-static moisture-absorbing sweat-discharging ultraviolet-proof fabric has wider market prospect.
Disclosure of Invention
The invention aims to provide a moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton-nylon blended fabric which can prevent static electricity and ultraviolet rays.
The invention also aims to provide a preparation method of the cotton-nylon blended fabric.
The first technical scheme adopted by the invention is as follows: the moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton polyester blended fabric comprises the following components in percentage by mass: 55-65% of cotton fiber, 34.5-44.5% of polyester fiber and 0.5% of conductive fiber, wherein the sum of the mass percentages of the above three fibers is 100%.
The first technical solution adopted by the present invention is further characterized in that,
the conductive fiber may be any one of a metal fiber, a carbon black fiber, a conductive metal compound fiber, and a conductive polymer fiber.
The conductive fiber is nylon-based 20D/3F conductive yarn.
The warp and weft yarn structure of the blended fabric is single yarn, and the density of the warp and weft single yarn is 18 tex-18.5 tex; the fabric weave structure of the blended fabric is as follows: 2/1 twill with the mass per unit area of 150-170 g/m2And the twist of the warp and weft single yarns is 90-110 twist/10 cm.
The second technical scheme adopted by the invention is a preparation method of the cotton-nylon blended fabric with moisture absorption, sweat releasing, static resistance and ultraviolet resistance, which is specifically implemented according to the following steps:
step 1, weaving antistatic grey cloth
Respectively weighing 55-65% of cotton fiber, 34.5-44.5% of polyester fiber and 0.5% of conductive fiber according to the mass percentage, wherein the sum of the mass percentages of the above three components is 100%; firstly, preparing cotton fibers and polyester fibers into cotton/nylon blended yarns, then doubling and twisting the conductive yarns and a proper amount of cotton/nylon blended yarns into conductive yarns, weaving grey cloth by taking the residual cotton/nylon blended yarns as warp yarns and weft yarns, and preparing anti-static grey cloth;
step 2, dyeing
And (3) pretreating the antistatic grey cloth obtained in the step (1), soaking and rolling the antistatic grey cloth in a dyeing machine, drying and soaping the antistatic grey cloth to obtain an antistatic dyed cloth semi-finished product.
Step 3, moisture absorption, sweat releasing and ultraviolet finishing
Step 3.1, preparing and preparing ultraviolet-proof finishing liquid
Respectively weighing an anti-ultraviolet finishing agent, a fixing agent and a color fixing agent, dissolving the anti-ultraviolet finishing agent, the fixing agent and the color fixing agent in water, mixing and stirring uniformly to obtain an oil-resistant water-repellent finishing liquid, wherein the concentration of the anti-ultraviolet finishing agent in the oil-resistant water-repellent finishing liquid is 35-45 g/L;
step 3.2, ultraviolet-proof finishing
And (3) adding the anti-ultraviolet finishing liquid obtained in the step (3.1) into a padding bath, immersing the semi-finished anti-static colored cloth obtained in the step (2) into the anti-ultraviolet finishing liquid, padding by adopting a one-padding-one-rolling process, and drying to obtain the anti-static anti-ultraviolet cotton/nylon blended fabric.
Step 3.3, preparing moisture absorption and sweat releasing finishing liquid
The method comprises the steps of weighing a moisture absorption and sweat releasing auxiliary agent, a hydrophilic softening agent and citric acid respectively, dissolving the moisture absorption and sweat releasing auxiliary agent, the hydrophilic softening agent and the citric acid in water, mixing and stirring uniformly to prepare a moisture absorption and sweat releasing finishing liquid, wherein the concentration of the moisture absorption and sweat releasing agent in the moisture absorption and sweat releasing finishing liquid is 40-60 g/L.
Step 3.4, moisture absorption and sweat releasing finishing
And (3) adding the moisture absorption and sweat releasing finishing liquid obtained in the step (3.3) into a padding tank, soaking the ultraviolet-proof and anti-static cotton/nylon blended fabric obtained in the step (3.2) into the moisture absorption and sweat releasing finishing liquid, padding by adopting a one-padding and one-rolling process, and drying to obtain the anti-static and anti-ultraviolet cotton/nylon blended fabric.
The second technical solution adopted by the present invention is further characterized in that,
in the step 1, the twist of the conductive yarns is 25-55 twists/10 cm, the mass ratio of the conductive yarns to the residual cotton-polyester blended yarns is 1: 75-85, the conductive yarns are woven at intervals of 0.9cm in the warp direction and 0.8cm in the weft direction in the weaving process, the distance between every two adjacent conductive yarns in the warp direction is 0.5-2 cm, and the distance between every two adjacent conductive yarns in the weft direction is 0.5-2 cm.
In the step 2, the drying temperature is 80-100 ℃, the soaping agent is an anti-sticking soaping agent ZJ-R305, the bath ratio in the soaping process is 1:20, and the cleaning is carried out for 10min at normal temperature after the soaping is finished.
In the step 3.1, the ultraviolet finishing agent is a Jieershuang ultraviolet-proof finishing agent SCJ-966, the fixing agent is a Jieershuang SCJ-939, and the color fixing agent is a Liangsheng TF-234B; the padding in the step 3.2 has the vehicle speed of 30-40 m/min, the rolling residual rate of 60-65% and the drying temperature of 130-140 ℃.
In the step 3.3, the moisture absorption and sweat releasing auxiliary agent is a Hensman moisture absorption and sweat releasing agent HSD-S, the hydrophilic softening agent is DT-6400, and the mass ratio of the moisture absorption and sweat releasing auxiliary agent to the hydrophilic softening agent to the citric acid is 4:1: 0.5-6: 1: 0.5.
The padding in the step 3.4 has the vehicle speed of 40-50 m/min, the rolling residual rate of 60-70% and the drying temperature of 110-130 ℃.
The invention has the beneficial effects that:
(1) the moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton-nylon blended fabric has the functions of static resistance, oil resistance and water repellency, is a multifunctional fabric, has excellent performance, meets the relevant national standard regulations, can meet the requirements of industrial production and use, breaks through the limitation that the traditional special fabric only has a single function, and has strong market competitiveness and huge social and economic benefits.
(2) According to the moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton-nylon blended fabric, the multi-protection functional fabric which has good anti-static performance, durability, oil resistance and water resistance and good air permeability is developed by adjusting the using amount of the oil-resistant and water-resistant auxiliary agent for multiple times. After multiple tests, the method is suitable for batch production, can be used in various occasions, and is particularly suitable for being used as special work clothes, such as coal washery, petroleum and petrochemical oil extraction, mining industry, fuel gas and other industrial departments, artillery, missile, satellite launching and other troops, so as to avoid or reduce fire loss and personal safety accidents caused by static electricity, human errors, environmental factors and the like.
Detailed Description
The present invention will be described in detail with reference to the following embodiments.
The moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton polyester blended fabric comprises the following components in percentage by mass: 55-65% of cotton fiber, 34.5-44.5% of polyester fiber (Yilun) and 0.5% of conductive fiber, wherein the sum of the mass percentages of the three fibers is 100%.
The conductive fiber is any one of a metal fiber, a carbon black fiber, a conductive metal compound fiber, and a conductive polymer fiber.
Preferably, the conductive fiber is nylon-based 20D/3F conductive yarn.
The warp and weft yarn structure of the blended fabric is single yarn, and the density of the warp and weft single yarn is as follows: 18tex to 18.5 tex; the fabric weave structure of the blended fabric is as follows: 2/1 twill, the mass per unit area is: 150 to 170g/m2The twist of the warp and weft single yarns is as follows: 90-110 twist/10 cm.
The preparation method of the moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton and nylon blended fabric is specifically implemented according to the following steps:
step 1, weaving antistatic grey cloth
Respectively weighing 55-65% of cotton fiber, 34.5-44.5% of polyester fiber (Yilun) and 0.5% of conductive fiber according to the mass percentage, wherein the sum of the mass percentages of the above three components is 100%; firstly, preparing cotton fibers and polyester fibers into cotton/nylon blended yarns, and then doubling and twisting the conductive fibers and a proper amount of the cotton/nylon blended yarns into conductive yarns, wherein the twist of the conductive yarns is 25-55 twists/10 cm; and weaving grey cloth by using the residual cotton/nylon blended yarns as warp yarns and weft yarns, and weaving the conductive yarns in the warp direction and the weft direction at intervals in the weaving process to manufacture the anti-static grey cloth. The mass ratio of the conductive yarns to the residual cotton-polyester blended yarns is 1: 75-85, the distance between every two adjacent conductive yarns in the warp direction is 0.5-2 cm, and the distance between every two adjacent conductive yarns in the weft direction is 0.5-2 cm.
Step 2, dyeing
And (3) pretreating the antistatic grey cloth obtained in the step (1), soaking and rolling the antistatic grey cloth in a dyeing machine, drying the antistatic grey cloth at 80-100 ℃, and soaping the antistatic grey cloth to obtain an antistatic dyed cloth semi-finished product.
The soaping agent is an anti-sticking soaping agent ZJ-R305, the concentration of the soaping agent is 2-3 g/L, the bath ratio in the soaping process is 1:20, and after soaping, normal-temperature washing is carried out for 10 min.
Step 3, moisture absorption, sweat releasing and ultraviolet finishing
Because the moisture absorption and sweat releasing finishing agent can not be used together with the ultraviolet-proof finishing agent, the ultraviolet-proof finishing agent is needed to be firstly carried out.
Step 3.1, preparing and preparing ultraviolet-proof finishing liquid
Weighing the ultraviolet-proof finishing agent, the fixing agent and the color fixing agent according to the mass ratio of 3-5: 1-2: 1, dissolving the ultraviolet-proof finishing agent, the fixing agent and the color fixing agent in water, and uniformly mixing to obtain an ultraviolet-proof finishing liquid, wherein the concentration of the ultraviolet-proof finishing agent in the ultraviolet-proof finishing liquid is 35-45 g/L.
The ultraviolet finishing agent is a Jieershuang ultraviolet-proof finishing agent SCJ-966, the fixing agent is a Jieershuang SCJ-939, and the color fixing agent is a Liangheng TF-234B.
Step 3.2, ultraviolet-proof finishing
And (3) adding the anti-ultraviolet finishing liquid obtained in the step (3.1) into a padding tank, immersing the anti-static colored cloth semi-finished product obtained in the step (2) into the anti-ultraviolet finishing liquid, padding by adopting a one-padding one-rolling process, wherein the padding speed is 30-40 m/min, the padding residual rate is 60-65%, and then drying at 130-140 ℃ in sequence to obtain the anti-static anti-ultraviolet cotton/nylon blended fabric.
Step 3.3, preparing moisture absorption and sweat releasing finishing liquid
The moisture absorption and sweat release auxiliary agent, the hydrophilic softening agent and the citric acid are respectively weighed according to the mass ratio of 4:1: 0.5-6: 1:0.5, dissolved in water, and uniformly mixed and stirred to prepare the moisture absorption and sweat release finishing liquid, wherein the concentration of the moisture absorption and sweat release agent in the moisture absorption and sweat release finishing liquid is 40-60 g/L.
The moisture absorption and sweat releasing additive is a Hensman moisture absorption and sweat releasing agent HSD-S, the hydrophilic softening agent is DT-6400, and the citric acid is a penetrating agent and a pH regulator.
Step 3.4, moisture absorption and sweat releasing finishing
And (3) adding the moisture absorption and sweat releasing finishing liquid obtained in the step (3.3) into a padding tank, soaking the ultraviolet-proof and anti-static cotton/nylon blended fabric obtained in the step (3.2) into the moisture absorption and sweat releasing finishing liquid, padding by adopting a one-padding and one-rolling process, wherein the padding speed is 40-50 m/min, the rolling residual rate is 60-70%, and then drying at 110-130 ℃ in sequence to obtain the moisture absorption, sweat releasing and anti-static ultraviolet-proof cotton/nylon blended fabric.
The ultraviolet-proof finishing agent in the step 3.1 mainly contains an ultraviolet absorbent (benzophenone compound), does not contain harmful substances such as formaldehyde, heavy metal ions and the like, and meets the requirement of environmental protection. The color, strength, moisture absorption and air permeability of the fabric are not affected. The benzophenone compound is light brown liquid in appearance, is easy to solidify at low temperature (heated in water bath and used after being stirred), has the effective component content of 33 percent, the pH value of about 7, and is nonionic in ionicity and miscible with water. The ultraviolet-proof finishing agent is mainly suitable for ultraviolet-proof finishing of cotton, hemp, silk, wool, polyester cotton, nylon and other fabrics, the treated fabrics have absorption, conversion, reflection and scattering effects on ultraviolet rays (especially UV-A and UV-B) with the wave band of 180-400 nm, the UPF value is as high as 50+, and the UPF value is still 50+ after 40 times of washing.
In the step 3.3, the moisture absorption and sweat discharge agent is a compound emulsion of a hydrophilic polymer and polysiloxane, and the compounding ratio of the hydrophilic polymer to the polysiloxane is 2: 1-3: 1. Appearance low viscosity white dispersion. The fabric is used for moisture absorption and sweat releasing finishing of synthetic fibers and blended fabrics thereof, has obvious moisture absorption and sweat releasing effects, particularly has good washing fastness for terylene and blended fabrics thereof, gives warm and gorgeous appearance and soft hand feeling to the fabrics, has good antistatic effect, and can be used for after finishing together with most products.
Compared with the prior art, the invention has the advantages that: the moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton-nylon blended fabric simultaneously has the functions of static resistance, moisture absorption, sweat releasing and ultraviolet resistance, adopts the relationship between the content of different fibers and the protective performance of textiles, solves the technical problems of multi-component fiber blended spinning technology, fabric pretreatment, dyeing and finishing, develops the protective fabric with good static resistance, moisture absorption, sweat releasing performance, ultraviolet resistance, wear resistance, comfort performance and high strength, is suitable for batch production, can be used in various occasions, is particularly suitable for being used as special working clothes, such as industrial departments of coal, petrifaction, mining industry, gas industry and the like, troops such as artillery, missile, satellite launching and the like, and avoids or reduces fire loss and personal safety accidents caused by static electricity, human errors, environmental factors and the like.
Example 1
The moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton nylon blended fabric is prepared by the following method:
step 1, anti-static grey cloth weaving
Selecting cotton/nylon blended yarns with the specification of 32S JC70/Y30 as prepared raw materials, respectively weighing 0.5 percent of nylon-based 20D/3F conductive wires and 99.5 percent of cotton/nylon blended yarns of 32S JC70/Y30 according to the mass percent, wherein the sum of the mass percent of the above fibers is 100 percent, and doubling and twisting the nylon-based 20D/3F conductive wires and a proper amount of the cotton/nylon blended yarns of 32S JC70/Y30 into conductive yarns, wherein the twist degrees of the conductive yarns are respectively woven into the conductive yarns at intervals of 0.5cm in the warp direction and at intervals of 0.5cm in the weft direction in the weaving process to prepare the anti-static grey cloth.
The mass ratio of the conductive yarn to the rest of the 32S JC70/Y30 cotton/nylon blended yarn is 1: 75.
Step 2, dyeing
And (3) carrying out dyeing pretreatment on the anti-static gray fabric obtained in the step (1), soaking and rolling on a dyeing machine, drying at 80 ℃ and soaping to obtain the anti-static cotton/nylon blended colored fabric.
Step 3, moisture absorption, sweat releasing and ultraviolet finishing
Step 3.1, preparing and preparing ultraviolet-proof finishing liquid
And 3.1, respectively weighing 30kg of Beijing Jieershuang ultraviolet-proof finishing agent SCJ-966, 20kg of Beijing Jieershuang SCJ-939 and 10kg of Liangsheng TF-234B, sequentially dissolving in water to ensure that the concentration of the Beijing Jieershuang ultraviolet-proof finishing agent is 35g/L, mixing and uniformly stirring to prepare the ultraviolet-proof finishing liquid.
Step 3.2, ultraviolet-proof finishing
And (3) adding the anti-ultraviolet finishing liquid obtained in the step (3.1) into a padding tank, immersing the semi-finished anti-static colored cloth obtained in the step (2) into the anti-ultraviolet finishing liquid, padding by adopting a one-padding one-rolling process, wherein the padding speed is 40m/min, the padding rate is 60%, and then drying at 130 ℃ in sequence to obtain the anti-static anti-ultraviolet cotton/nylon blended fabric.
Step 3.3, preparing moisture absorption and sweat releasing finishing liquid
Respectively weighing 24kg of a Hounsfield moisture and sweat absorbing and removing agent HSD-S, 6kg of a hydrophilic softening agent DT-6400 and 3kg of citric acid, dissolving the 24kg of the Hounsfield moisture and sweat absorbing and removing agent HSD-S in water to enable the concentration of the Hounsfield moisture and sweat absorbing and removing agent HSD-S to be 40g/L, mixing and stirring uniformly to obtain the moisture absorbing and sweat removing finishing liquid.
Step 3.4, moisture absorption and sweat releasing finishing
Adding the moisture absorption and sweat releasing finishing liquid obtained in the step 3.3 into a padding tank, soaking the ultraviolet-proof and anti-static cotton/nylon blended fabric obtained in the step 3.2 into the moisture absorption and sweat releasing finishing liquid, padding by adopting a one-padding and one-rolling process, wherein the padding speed is 40m/min, the padding rate is 60%, and then drying at 110 ℃ in sequence to obtain the moisture absorption, sweat releasing and anti-static ultraviolet-proof cotton/nylon blended fabric
Example 2
The moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton nylon blended fabric is prepared by the following method:
step 1, anti-static grey cloth weaving
Selecting cotton/vinylon blended yarns with specification of 32S JC60/Y40 as prepared raw materials, respectively weighing 0.5% of nylon-based 20D/3F conductive wires and 99.5% of 32S JC60/Y40 cotton/vinylon blended yarns according to the mass percentage, wherein the sum of the mass percentages of the above fibers is 100%, doubling and twisting the nylon-based 20D/3F conductive wires and a proper amount of 32S JC60/Y40 cotton/vinylon blended yarns into conductive yarns, wherein the twist degree of the conductive yarns is 40 twist/10 cm, weaving grey cloth by using the rest 32S JC 38 60/Y40 cotton/vinylon blended yarns as warp yarns and weft yarns, and weaving the conductive yarns into the anti-static grey cloth by using interval of 0.9cm in the warp direction and interval of 0.8cm in the weft direction respectively in the weaving process.
The mass ratio of the conductive yarn to the residual 32/2S JC60/T40 cotton/nylon blended yarn is 1: 80.
Step 2, dyeing
And (3) carrying out dyeing pretreatment on the anti-static gray fabric obtained in the step (1), soaking and rolling on a dyeing machine, drying at 90 ℃ and soaping to obtain the anti-static cotton/nylon blended colored fabric.
Step 3, moisture absorption, sweat releasing and ultraviolet finishing
Step 3.1, preparing and preparing ultraviolet-proof finishing liquid
And 3.1, respectively weighing 50kg of Beijing Jieershuang ultraviolet-proof finishing agent SCJ-966, 22kg of Beijing Jieershuang SCJ-939 and 11kg of Liangsheng TF-234B, sequentially dissolving in water to ensure that the concentration of the Beijing Jieershuang ultraviolet-proof finishing agent is 40g/L, mixing and uniformly stirring to prepare the ultraviolet-proof finishing liquid.
Step 3.2, ultraviolet-proof finishing
And (3) adding the anti-ultraviolet finishing liquid obtained in the step (3.1) into a padding tank, immersing the semi-finished anti-static colored cloth obtained in the step (2) into the anti-ultraviolet finishing liquid, padding by adopting a one-padding one-rolling process, wherein the padding speed is 45m/min, the padding rate is 65%, and then drying at 135 ℃ in sequence to obtain the anti-static anti-ultraviolet cotton/nylon blended fabric.
Step 3.3, preparing moisture absorption and sweat releasing finishing liquid
Respectively weighing 30kg of a Hounsfield moisture absorption and perspiration agent HSD-S, 6kg of a hydrophilic softening agent and 3kg of citric acid, dissolving the materials in water to enable the concentration of the Hounsfield moisture absorption and perspiration agent HSD-S to be 45g/L, mixing and uniformly stirring to obtain the moisture absorption and perspiration finishing liquid.
Step 3.4, moisture absorption and sweat releasing finishing
Adding the moisture absorption and sweat releasing finishing liquid obtained in the step 3.3 into a padding tank, soaking the ultraviolet-proof and anti-static cotton/nylon blended fabric obtained in the step 3.2 into the moisture absorption and sweat releasing finishing liquid, padding by adopting a one-padding and one-rolling process, wherein the padding speed is 45m/min, the padding rate is 65%, and then drying at 120 ℃ in sequence to obtain the moisture absorption, sweat releasing and anti-static ultraviolet-proof cotton/nylon blended fabric
Example 3
The moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton nylon blended fabric is prepared by the following method:
step 1, anti-static grey cloth weaving
Selecting a cotton/vinylon blended yarn with the specification of 32S JC55/Y45 as a prepared raw material, respectively weighing 0.5% of nylon-based 20D/3F conductive wires and 99.5% of 32S JC55/Y45 cotton/vinylon blended yarns according to the mass percentage, wherein the sum of the mass percentages of the above fibers is 100%, doubling and twisting the nylon-based 20D/3F conductive wires and a proper amount of 32S JC55/Y45 cotton/vinylon blended yarns into conductive yarns, wherein the twist of the conductive yarns is 55 twists/10 cm, weaving grey cloth by taking the rest 32S JC55/Y45 cotton/vinylon blended yarns as warp yarns and weft yarns, and weaving the conductive yarns into the grey cloth at intervals of 2cm in the warp direction and at intervals of 2cm in the weft direction in the weaving process to prepare the anti-static grey cloth.
The mass ratio of the conductive yarn to the rest of the 32S JC55/Y45 cotton/nylon blended yarn is 1: 85.
Step 2, dyeing
And (3) carrying out dyeing pretreatment on the anti-static gray fabric obtained in the step (1), soaking and rolling on a dyeing machine, drying at 100 ℃ and soaping to obtain the anti-static cotton/nylon blended colored fabric.
Step 3, moisture absorption and sweat releasing finishing
Step 3.1, preparing and preparing ultraviolet-proof finishing liquid
Respectively weighing 50kg of Beijing Jieershuang ultraviolet-proof finishing agent SCJ-966, 10kg of Beijing Jieershuang SCJ-939 and 10kg of Liangsheng TF-234B, sequentially dissolving in water to ensure that the concentration of the Beijing Jieershuang ultraviolet-proof finishing agent is 45g/L, mixing and uniformly stirring to prepare the ultraviolet-proof finishing liquid.
Step 3.2, ultraviolet-proof finishing
And (3) adding the anti-ultraviolet finishing liquid obtained in the step (3.1) into a padding tank, immersing the anti-static cotton/nylon blended colored fabric obtained in the step (2) into the anti-ultraviolet finishing liquid, padding by adopting a one-padding one-rolling process, adjusting the machine speed to be 50m/min, adjusting the rolling residual rate to be 70%, and drying at 140 ℃ to obtain the anti-static anti-ultraviolet cotton/nylon blended fabric.
Step 3.3, preparing moisture absorption and sweat releasing finishing liquid
Respectively weighing 36kg of Hounsfield moisture absorption and sweat releasing agent HSD-S, 6kg of hydrophilic softener and 38kg of citric acid, dissolving the materials in water to enable the concentration of the Hounsfield moisture absorption and sweat releasing agent HSD-S to be 50g/L, mixing and uniformly stirring to obtain the moisture absorption and sweat releasing finishing liquid.
Step 3.4, moisture absorption and sweat releasing finishing
And (3) adding the moisture absorption and sweat releasing finishing liquid obtained in the step (3.3) into a padding tank, immersing the anti-static anti-ultraviolet cotton/nylon blended fabric obtained in the step (3.2) into the moisture absorption and sweat releasing finishing liquid, padding by adopting a one-padding and one-rolling process, adjusting the machine speed to be 50m/min, and adjusting the rolling residual rate to be 70%, and then drying at 130 ℃ to obtain the moisture absorption, sweat releasing, anti-static and anti-ultraviolet cotton/nylon blended fabric.
The moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton-nylon blended fabric obtained in the embodiment 1-3 is subjected to fabric point-to-point resistance detection, moisture-absorbing, sweat-releasing and anti-ultraviolet detection according to the national standard, and the results are shown in table 1.
TABLE 1 Performance testing of cotton-nylon blended fabric with moisture absorption, sweat releasing, antistatic and ultraviolet resistance
According to the test result, the antistatic, moisture-absorbing, sweat-discharging and ultraviolet-preventing cotton/nylon blended fabric has the antistatic performance reaching the B-level requirement of the national standard, the index is close to or reaches the A-level standard requirement, and the soaking time, the water absorption rate, the maximum soaking radius, the liquid water diffusion speed, the single transmission index and the liquid water dynamic transmission comprehensive index are all larger than the national standard of moisture-absorbing and sweat-discharging performance; the test results of the UPF ultraviolet protection coefficient and the UVA average transmittance (%) also accord with the national standard, so the anti-static moisture-absorption sweat-discharge ultraviolet-proof cotton/nylon blended fabric material has excellent anti-static function, moisture-absorption sweat-discharge performance and ultraviolet-proof performance, accords with the national standard regulation, greatly exceeds the grade of the existing fabric in the market, and can meet the requirements of industrial production and use.

Claims (10)

1. The moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton-nylon blended fabric is characterized by comprising the following components in percentage by mass: 55-65% of cotton fiber, 34.5-44.5% of polyester fiber and 0.5% of conductive fiber, wherein the sum of the mass percentages of the above three fibers is 100%.
2. The moisture-absorbing, sweat-releasing, antistatic and ultraviolet ray-proof cotton and nylon blended fabric according to claim 1, wherein the conductive fiber is any one of a metal fiber, a carbon black fiber, a conductive metal compound fiber and a conductive polymer fiber.
3. The moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton and nylon blended fabric according to claim 2, wherein the conductive fibers are nylon-based 20D/3F conductive filaments.
4. The moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton nylon blended fabric according to claim 1, wherein the warp and weft yarn structure of the blended fabric is single yarn, and the density of the warp and weft single yarn is 18tex to 18.5 tex; the fabric weave structure of the blended fabric is as follows: 2/1 twill with the mass per unit area of 150-170 g/m2And the twist of the warp and weft single yarns is 90-110 twist/10 cm.
5. The preparation method of the moisture-absorbing sweat-releasing antistatic ultraviolet-proof cotton-nylon blended fabric according to claim 1 is characterized by comprising the following steps:
step 1, weaving antistatic grey cloth
Respectively weighing 55-65% of cotton fiber, 34.5-44.5% of polyester fiber and 0.5% of conductive fiber according to the mass percentage, wherein the sum of the mass percentages of the above three components is 100%; firstly, preparing cotton fibers and polyester fibers into cotton/nylon blended yarns, then doubling and twisting the conductive yarns and a proper amount of cotton/nylon blended yarns into conductive yarns, weaving grey cloth by taking the residual cotton/nylon blended yarns as warp yarns and weft yarns, and weaving the conductive yarns in the warp direction and the weft direction at intervals respectively in the weaving process to prepare anti-static grey cloth;
step 2, dyeing
Pre-treating the anti-static grey cloth obtained in the step 1, soaking and rolling the grey cloth in a dyeing machine, drying and soaping the grey cloth to obtain an anti-static dyed cloth semi-finished product;
step 3, moisture absorption, sweat releasing and ultraviolet finishing
Step 3.1, preparing and preparing ultraviolet-proof finishing liquid
Respectively weighing an anti-ultraviolet finishing agent, a fixing agent and a color fixing agent, dissolving the anti-ultraviolet finishing agent, the fixing agent and the color fixing agent in water, mixing and stirring uniformly to obtain an oil-resistant water-repellent finishing liquid, wherein the concentration of the anti-ultraviolet finishing agent in the oil-resistant water-repellent finishing liquid is 35-45 g/L;
step 3.2, ultraviolet-proof finishing
Adding the anti-ultraviolet finishing liquid obtained in the step 3.1 into a padding bath, immersing the semi-finished anti-static colored cloth obtained in the step 2 into the anti-ultraviolet finishing liquid, padding by adopting a one-padding one-rolling process, and drying to obtain the anti-static anti-ultraviolet cotton/nylon blended fabric;
step 3.3, preparing moisture absorption and sweat releasing finishing liquid
Respectively weighing a moisture absorption and sweat releasing auxiliary agent, a hydrophilic softening agent and citric acid, dissolving the moisture absorption and sweat releasing auxiliary agent, the hydrophilic softening agent and the citric acid in water, mixing and stirring uniformly to prepare a moisture absorption and sweat releasing finishing liquid, wherein the concentration of the moisture absorption and sweat releasing agent in the moisture absorption and sweat releasing finishing liquid is 40-60 g/L;
step 3.4, moisture absorption and sweat releasing finishing
And (3) adding the moisture absorption and sweat releasing finishing liquid obtained in the step (3.3) into a padding tank, soaking the ultraviolet-proof and anti-static cotton/nylon blended fabric obtained in the step (3.2) into the moisture absorption and sweat releasing finishing liquid, padding by adopting a one-padding and one-rolling process, and drying to obtain the anti-static and anti-ultraviolet cotton/nylon blended fabric.
6. The method for preparing the moisture-absorbing, sweat-releasing, antistatic and ultraviolet-proof cotton-polyester blended fabric according to claim 5, wherein the twist of the conductive yarn in the step 1 is 25-55 twists/10 cm, the mass ratio of the conductive yarn to the remaining cotton-polyester blended yarn is 1: 75-85, the distance between two adjacent conductive yarns in the warp direction is 0.5-2 cm, and the distance between two adjacent conductive yarns in the weft direction is 0.5-2 cm.
7. The method for preparing the moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton and instrumental nylon blended fabric according to claim 5, wherein the drying temperature in the step 2 is 80-100 ℃, the soaping agent is an anti-sticking soaping agent ZJ-R305, the bath ratio in the soaping process is 1:20, and after the soaping process, the fabric is cleaned at normal temperature for 10 min.
8. The method for preparing the moisture absorption, sweat releasing, anti-static and anti-ultraviolet cotton and nylon blended fabric according to claim 5, wherein in the step 3.1, the ultraviolet finishing agent is a Jieershuang ultraviolet-proof finishing agent SCJ-966, the fixing agent is a Jieershuang SCJ-939, and the fixing agent is Cantonese TF-234B; the padding in the step 3.2 has the vehicle speed of 30-40 m/min, the rolling residual rate of 60-65% and the drying temperature of 130-140 ℃.
9. The method for preparing the moisture-absorbing sweat-discharging antistatic ultraviolet-proof cotton instrumental fiber blended fabric according to claim 5, wherein in the step 3.3, the moisture-absorbing sweat-discharging auxiliary agent is a Hunsmy moisture-absorbing sweat-discharging agent HSD-S, the hydrophilic softening agent is DT-6400, and the mass ratio of the moisture-absorbing sweat-discharging auxiliary agent to the hydrophilic softening agent to the citric acid is 4:1: 0.5-6: 1: 0.5.
10. The method for preparing the moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton and nylon blended fabric according to claim 5, wherein the padding in the step 3.4 is performed at a speed of 40-50 m/min, a residual rolling rate of 60-70% and a drying temperature of 110-130 ℃.
CN201910932593.8A 2019-09-29 2019-09-29 Moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton-nylon blended fabric and preparation method thereof Pending CN110629361A (en)

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Application publication date: 20191231