A kind of absorbing sweat hydrofuge open air UV resistance fabric and preparation method thereof
Technical field
The present invention relates to a kind of absorbing sweat hydrofuge open air UV resistance fabrics and preparation method thereof, belong to micro- field of textiles.
Background technique
With the continuous raising of summer temperature, the volume of perspiration of people increases, thus to the ventilative of clothing fabric, moisture absorption, row
The requirement of sweat function is higher and higher.But the moisture absorption of existing fabric is less desirable;Moreover, the row of being not easy after fabric moisture absorption
Out, it is poor to perspire effect.In addition, the clothing fabric of especially outdoor type, to the more demanding of uvioresistant, and existing fabric
It cannot be provided simultaneously with absorbing sweat hydrofuge and uv resistance energy mostly.
The absorbing sweat hydrofuge performance of fabric depends primarily on the fibre structure of fabric.Fiber currently on the market mainly passes through
Three kinds of modes obtain the performance of hydroscopic fast-drying, first is that by forming hollow microporous structure, the construction of fiber is doughnut
Shape, and have micro- porous be connected to hollow space in fiber side;Using this slightly it is porous can sweat absorption to hollow space store up
It deposits, or by the sweat stored by hollow space, is evaporated using body temperature, then by this slightly porous discharge fabric;This fiber
The absorbing sweat speed of fabric is 1.3 times of cotton fabric, outclass conventional polyester fabric;Second is that by a kind of silk egg of highly hygroscopic property
It is white, it is coated in above hygroscopicity fibre, to obtain better moisture pick-up properties;Third is that using special spinning processing procedure, fiber is allowed
Inside and outside tube wall all has elongated groove, and is distributed between the hole of the similar neural network form of formation, and sweat can rapidly enter
The groove of fiber, and evaporated rapidly through groove with hole, allow human body to have dry and comfortable refrigerant comfort, cardinal principle is fortune
Improve the water imbibition of synthetic fibers with the siphonage of physics, that is, by fiber surface roughening, heteromorphosis, pore,
And achieve the purpose that dress material absorbing sweat, quick-drying to increase the surface area of fiber.
Compared with conventional fibre fabric, porous ultra-high molecular weight polyethylene prepared by the present invention/composite fabric structure is complicated
But preparation method is simple, is a kind of high technology content, high value-added product, and product has good market prospects.Meanwhile
Absorbing sweat hydrofuge open air UV resistance fabric of the invention has moisture absorbing and sweat releasing and antiultraviolet dual function, is being alleviated or avoided too
While ultraviolet light in sunlight is to the injury of human body, moisture absorption ability of sweat absorption can increase the comfort level of human body dress.
Summary of the invention
The purpose of the present invention is to provide a kind of absorbing sweat hydrofuge open air UV resistance fabrics, by preparing poly-dopamine/superelevation
Poly-dopamine/ultra-high molecular weight polyethylene/parafilm is completely immersed in and is knitted by package hot pressing by molecular weight polyethylene/parafilm
In object, the paraffin in fabric is dissolved by solvent, porous ultra-high molecular weight polyethylene/compound fabric is prepared;It is porous super
High molecular weight polyethylene/compound fabric pads by fabric finishing agent, dry and obtains one kind and have excellent absorbing sweat hydrofuge and prevent
Ultraviolet fabric.
Its technical solution includes:
A kind of preparation method of absorbing sweat hydrofuge open air UV resistance fabric, includes the following steps:
S1 presses mass volume ratio (1~4): dopamine hydrochloride is added in alkaline ethanol aqueous solution 1000g/mL,
20~30h is stirred under conditions of 100~300 revs/min, centrifugation takes lower sediment, and deionized water is washed, after vacuum freeze drying
Obtain poly-dopamine particle;
S2 is by mass volume ratio (3~6): it is 0.8~1.0g/L that methoxy poly (ethylene glycol) amine is added to concentration by 1mg/mL
Poly-dopamine aqueous dispersions in, under conditions of 300~500 revs/min stir 20~30h, centrifugation, take lower sediment, go from
Sub- water washing obtains modified poly-dopamine particle after vacuum freeze drying;
S3 is by ultra-high molecular weight polyethylene, modified poly-dopamine particle, paraffin oil at 40~80 revs/min, 190~210 DEG C
Under conditions of stir 15~30min;Then heating pressurization, is cooled to room temperature, and it is poly- to obtain modified poly-dopamine/super high molecular weight
Ethylene/parafilm;
S4 will be modified poly-dopamine/ultra-high molecular weight polyethylene/parafilm tiling, then stack one layer of fabric, then again
It is secondary to stack one layer of modified poly-dopamine/ultra-high molecular weight polyethylene/parafilm, heating pressurization, it is ensured that modified poly-dopamine/super
High molecular weight polyethylene/paraffin fully penetrates into fabric;It is cooled to room temperature, by mass volume ratio 1:(12~20) g/mL will be warm
Treated that fabric submerges in a solvent for pressure, pulls out, naturally dry;It repeats immersion step 1~3 time;It obtains after natural drying more
Hole ultra-high molecular weight polyethylene/compound fabric;
S5 UV resistance arranges: porous ultra-high molecular weight polyethylene/compound fabric padded using fabric finishing agent,
75~100wt% of pick-up, by the fabric after padding at 170~180 DEG C 25~35min of forced air drying to get absorbing sweat hydrofuge
Outdoor UV resistance fabric.
Preferably, the alkaline ethanol aqueous solution is by dehydrated alcohol: water: one is hydrated ammonia by volume (30~50): (80
~100): (0.5~0.7) mixes.
Preferably, the condition of the vacuum freeze drying is control 6~9mm of material thickness, sets pre-freezing temperature as -22
~-18 DEG C, 1.0~3.0h is kept after sample temperature drops to -22~-18 DEG C, is set sublimation temperature as 10~12 DEG C, is parsed
Temperature is 33~35 DEG C, 15~30Pa of vacuum degree, dry 20~32h.
Preferably, the centrifugation in the step S1 and S2 be under conditions of 14000~20000 revs/min centrifugation 10~
20min。
Preferably, the mass ratio of ultra-high molecular weight polyethylene in the step S3, modified poly-dopamine particle, paraffin oil
For 1:(0.025~0.055): (0.04~0.08).
Preferably, the step S3 and S4 heating pressurization be temperature be 180~200 DEG C, pressure be 1.5~
5~30min of hot pressing under conditions of 3.2MPa.
Preferably, the fabric is the blended fabric of one of dacron, cotton synthetic fibre fabric or terylene and cotton synthetic fibre.
Optionally, the solvent is the mixing of one or more of dimethylbenzene, toluene, petroleum ether.
Preferred into one, the solvent is dimethylbenzene.
Preferably, the fabric finishing agent is mixed by following raw material: hydrophilic finishing agent, antistatic agent, softening agent,
UV resistance agent, water.
Preferred into one, the fabric finishing agent is mixed by the raw material of following mass percent: hydrophilic finishing agent 5
~15%, antistatic agent 5~15%, softening agent 5~20%, UV resistance agent 5~30%, surplus are water.
Optionally, the hydrophilic finishing agent is polyethylene glycol dimethyl ether, polypropylene glycol methyl ether, dimethyl terephthalate (DMT)
One or more of mixing.
Optionally, the antistatic agent be polyoxyethylene alkyl ether, polyoxyethylene alkyl amine, polyoxyethylene alkylamide,
One of alkyl polyols.
Optionally, the softening agent is polyvinylpyrrolidone.
Optionally, the UV resistance agent is Radix Arnebiae extract and/or quaternary ammonium alkali lignin.
It is further preferred that the UV resistance agent is Radix Arnebiae extract and/or quaternary ammonium alkali lignin-zinc oxide composite wood
Material.
As one of preferred embodiment, the UV resistance agent is that Radix Arnebiae extract and quaternary ammonium alkali lignin-zinc oxide are multiple
Condensation material is by quality (1~3): (1~3) mixes.
Preferably, Radix Arnebiae extract the preparation method comprises the following steps: by Asian puccoon pulverizing medicinal materials to 20~50 mesh, obtain Asian puccoon material powder
End, by mass volume ratio 1:(10~15) Asian puccoon material powder is added in 80~95wt% ethanol water 60 by g/mL~
1.5~3.0h of refluxing extraction at 75 DEG C, filtering, obtained filtrate are evaporated to no ethanol flavor through rotating pressure-decreasing, obtain Asian puccoon extraction
Object.
Preferably, the quaternary ammonium alkali lignin the preparation method comprises the following steps: 70~75g alkali lignin is added to 400~500mL
In the sodium hydrate aqueous solution that mass fraction is 20%, then with 0.05~0.15g/s under 100~300 revs/min of stirring
Speed be added dropwise 58~62mL mass fraction be 60% 3- chloro-2-hydroxypropyl-trimethyl ammonium chloride aqueous solution;It is added dropwise
Afterwards, in 80~90 DEG C of 3~5h of stirring, then solution is added in the bag filter that molecular cut off is 1000 in distilled water
For 24 hours, every 8h changes primary distilled water for dialysis, dialyzate through reduced pressure, vacuum freeze drying, pulverize, obtain quaternary ammonium base wood
Quality.
Preferably, the quaternary ammonium alkali lignin-zinc oxide composite the preparation method comprises the following steps:
1) 70~75g alkali lignin is added in the sodium hydrate aqueous solution that 400~500mL mass fraction is 20%, is connect
The 3- that 58~62mL mass fraction is 60% is added dropwise with the speed of 0.05~0.15g/s under 100~300 revs/min of stirring
Chloro-2-hydroxypropyl-trimethyl ammonium chloride aqueous solution;After being added dropwise, in 80~90 DEG C of 3~5h of stirring, then solution is added
It dialyses for 24 hours in distilled water in the bag filter for being 1000 to molecular cut off, every 8h changes primary distilled water, and dialyzate is through depressurizing
Concentration, is pulverized at vacuum freeze drying, and quaternary ammonium alkali lignin is obtained;
2) 0.4g quaternary ammonium alkali lignin, 2g sodium hydroxide are added in 50mL deionized water and are stirred to being completely dissolved, obtained
To quaternary ammonium alkali lignin solution;Under conditions of 100~300 revs/min, by quaternary ammonium alkali lignin solution with the speed of 0.05g/s
It is added dropwise in the zinc acetate aqueous solution that 50mL mass fraction is 2~5%, it is cold in 80~90 DEG C of stirring 3~5 h after being added dropwise
But to room temperature (25 DEG C), pH to 7.5 is adjusted with the aqueous sulfuric acid that mass fraction is 20% at 25 DEG C, it is old in 40 DEG C of standings
Change 1.5~3h, centrifugation takes precipitating, and deionized water is washed 3 times, and the dosage of each deionized water is 100mL, is in absolute pressure
0.08~0.09MPa, dry 12~20h at 60~70 DEG C, pulverize, obtain quaternary ammonium alkali lignin/zinc oxide composite wood
Material.
A kind of absorbing sweat hydrofuge open air UV resistance fabric, using the preparation side of above-mentioned absorbing sweat hydrofuge open air UV resistance fabric
Method is prepared.
Bring technical effect of the present invention has:
(1) the present invention provides preparation poly-dopamine/ultra-high molecular weight polyethylene/parafilm is passed through, by wrapping up hot pressing
Poly-dopamine/ultra-high molecular weight polyethylene/parafilm is completely immersed in fabric, by solvent by the paraffin in fabric, is prepared
Obtain porous ultra-high molecular weight polyethylene/compound fabric;Porous ultra-high molecular weight polyethylene/the compound fabric has good
Water suction, hydrofuge, airing function, functional materials that can preferably in absorbing fabric finishing agent.
(2) the present invention provides absorbing sweat hydrofuge open air UV resistance fabric there is moisture absorbing and sweat releasing and the dual function of antiultraviolet
Can, while injury of the ultraviolet light being alleviated or avoided in sunlight to human body, moisture absorption ability of sweat absorption can increase human body dress
Comfort level.
Specific embodiment
Each raw material sources in embodiment:
It is analytically pure commercial goods if not refering in particular to, heretofore described chemical component.
Spun polyester thread, specification 150D, the chemical fibre factory Zhuji City Chen Rui.
Asian puccoon: scientific name: Lithospermum erythrorhizon Sieb.et Zucc. is Boraginaceae Lithospermum many years
Raw herbaceous plant.Asian puccoon medicinal material source area Yunnan in the present invention is purchased from Xichou County Xiang Guang medicinal material Co., Ltd.
Alkali lignin: 1000~2000,80 mesh of molecular weight, Jin get Lai Biotechnology Co., Ltd of Xinyi City.
3- chloro-2-hydroxypropyl-trimethyl ammonium chloride: CAS 3327-22-8, Wuhan La Nabai medication chemistry Co., Ltd.
Dopamine hydrochloride: CAS 62-31-7, the bright Jilong pharmaceutcal corporation, Ltd in Hunan.
Methoxy poly (ethylene glycol) amine: English abbreviation mPEG-NH2, CAS 80506-64-5, Tianjin red sun gold boda biology
Technology Co., Ltd..
Paraffin oil: 46# paraffin oil, Mo Jiezuo petrochemical industry (Shanghai).
Ultra-high molecular weight polyethylene: molecular weight 4,000,000, Dongguan City camphorwood Tou Huaxin plastic material business department.
Methoxypolyethylene glycol: CAS 9004-74-4, Shandong mole Chemical Co., Ltd..
Polyoxyethylene alkyl ether: also known as alkyl phenol polyoxyethylene ether, english abbreviation APEO, CAS 658-9-68, Guangdong
Fine Chemical Co., Ltd of middle federation.
Polyvinylpyrrolidone: CAS 9003-39-8, Henan Qi Nuo food ingredient Co., Ltd.
Embodiment 1
Radix Arnebiae extract the preparation method comprises the following steps: by Asian puccoon pulverizing medicinal materials to 20 mesh, Asian puccoon medicinal powder is obtained, by quality
Asian puccoon medicinal powder is added in 80wt% ethanol water the refluxing extraction 2.0h at 60 DEG C by volume ratio 1:12g/mL, and 200
The filtering of mesh grenadine, obtained filtrate rotate reduction vaporization to no ethanol flavor under absolute pressure 0.09MPa, temperature 60 C, obtain
To Radix Arnebiae extract.
The quaternary ammonium alkali lignin the preparation method comprises the following steps: 70.10g alkali lignin be added to 450 mL mass fractions be 20%
Sodium hydrate aqueous solution in, 61mL mass fraction then, which is added dropwise, with the speed of 0.1g/s under 1200 revs/min of stirring is
60% 3- chloro-2-hydroxypropyl-trimethyl ammonium chloride aqueous solution;After being added dropwise, in 85 DEG C of stirring 4h, then solution is added
It dialyses for 24 hours in distilled water in the bag filter for being 1000 to molecular cut off, every 8h changes primary distilled water, and dialyzate is absolute
The 1/4 of original volume is concentrated under reduced pressure under pressure 0.09MPa, temperature 60 C, then vacuum freeze drying, pulverize, obtain season
Ammonium alkali lignin;The condition of the vacuum freeze drying is control material thickness 8mm, sets pre-freezing temperature as -20 DEG C, works as sample
Product temperature degree keeps 1.5h after dropping to -20 DEG C, sets sublimation temperature as 12 DEG C, resolution temperature is 34 DEG C, absolute pressure 25Pa, is done
It is dry for 24 hours.
Quaternary ammonium alkali lignin-the zinc oxide composite the preparation method comprises the following steps:
0.4g quaternary ammonium alkali lignin, 2g sodium hydroxide are added in 50mL deionized water and are stirred to being completely dissolved, is obtained
Quaternary ammonium alkali lignin solution;Under conditions of 200 revs/min, quaternary ammonium alkali lignin solution is added dropwise to the speed of 0.05g/s
In the zinc acetate aqueous solution that 50mL mass fraction is 3%, in 85 DEG C of stirring 4h after being added dropwise, (25 DEG C) are cooled to room temperature,
PH to 7.5, in 40 DEG C of still aging 2h, 6000 revs/min are adjusted with the aqueous sulfuric acid that mass fraction is 20% at 25 DEG C
Under the conditions of be centrifuged 15min, take precipitating, deionized water is washed 3 times, and the dosage of each deionized water is 100mL, in absolute pressure
For 18h dry at 0.085MPa, 65 DEG C, pulverizes, obtain quaternary ammonium alkali lignin-zinc oxide composite.
Embodiment 2
A kind of preparation method of absorbing sweat hydrofuge open air UV resistance fabric, includes the following steps:
S1 by mass volume ratio 2:1000g/mL by dopamine hydrochloride be added alkaline ethanol aqueous solution in, 200 turns/
It being stirred for 24 hours under conditions of point, is centrifuged 15min under conditions of 15000 revs/min, take lower sediment, deionized water is washed 3 times,
The dosage of each deionized water is 100mL, obtains poly-dopamine particle after vacuum freeze drying;
The condition of the vacuum freeze drying is control material thickness 8mm, sets pre-freezing temperature as -20 DEG C, when sample temperature
Degree keeps 1.5h after dropping to -20 DEG C, sets sublimation temperature as 12 DEG C, resolution temperature is 24 DEG C, vacuum degree 25Pa, and drying is for 24 hours;
The alkaline ethanol aqueous solution is by dehydrated alcohol: water: 40:90:0.6 is mixed a hydration ammonia by volume;
Methoxy poly (ethylene glycol) amine is added to the poly-dopamine that concentration is 1.0g/L by mass volume ratio 5:1mg/mL by S2
It in aqueous dispersions, is stirred under conditions of 500 revs/min for 24 hours, is centrifuged 15min under conditions of 15000 revs/min, take lower layer heavy
It forms sediment, deionized water is washed 3 times, and the dosage of each deionized water is 100mL, and modified poly-dopamine is obtained after vacuum freeze drying
Particle;
The concentration is the poly-dopamine aqueous dispersions of 1.0g/L the preparation method comprises the following steps: 1g poly-dopamine particle is added
Into 1L water, ultrasonic power be 200W, supersonic frequency be 24kHz under conditions of ultrasonic treatment 15min to get;
The condition of the vacuum freeze drying is control material thickness 8mm, sets pre-freezing temperature as -20 DEG C, when sample temperature
Degree keeps 1.5h after dropping to -20 DEG C, sets sublimation temperature as 12 DEG C, resolution temperature is 24 DEG C, vacuum degree 25Pa, and drying is for 24 hours;
S3 is by ultra-high molecular weight polyethylene, modified poly-dopamine particle, paraffin oil under conditions of 60 revs/min, 200 DEG C
Stir 20min;Then hot pressing 20min under conditions of temperature is 190 DEG C, pressure is 2.0MPa;(25 DEG C) are cooled to room temperature,
It obtains with a thickness of 300 μm of modified poly-dopamine/ultra-high molecular weight polyethylene/parafilms;
The ultra-high molecular weight polyethylene, modified poly-dopamine particle, paraffin oil mass ratio be 1:0.03:0.05;
S4 will grow × width x thickness be 50cm × 50cm × 300 μm modification poly-dopamine/ultra-high molecular weight polyethylene/stone
Cere tiling, then stacking one layer of long × width x thickness is 50cm × 50 cm × 0.5mm fabric, is then stacked again one layer long
× width x thickness is modification poly-dopamine/ultra-high molecular weight polyethylene/parafilm of cm × 300 μm 50cm × 50, is stacked neatly,
Hot pressing 20min under conditions of temperature is 190 DEG C, pressure is 2.0MPa, it is ensured that modified poly-dopamine/superhigh molecular weight polyethylene
Alkene/parafilm fully penetrates into fabric, the fabric after obtaining hot-pressing processing;(25 DEG C) are cooled to room temperature, by mass volume ratio 1:
Fabric after hot-pressing processing is submerged 30min by 15g/mL in dimethylbenzene, is pulled out, naturally dry;It repeats immersion step 3 times;
Porous ultra-high molecular weight polyethylene/compound fabric is obtained after natural drying;
S5 UV resistance arranges: by porous ultra-high molecular weight polyethylene/compound fabric with bath raio 1:30g/mL in textile finishing
Impregnate 60min in agent, an immersing and rolling, pick-up 80wt%, by the fabric after padding at 175 DEG C forced air drying 30min, it is cold
But to room temperature (25 DEG C) to get absorbing sweat hydrofuge open air UV resistance fabric.
The fabric is dacron.Dacron the preparation method is as follows: spun polyester thread is knitted into using needle 12G
Horizontal close 37 stringers/10cm, close 58.5 rows/10cm single side plain fabric, i.e. dacron are indulged.
The fabric finishing agent is mixed by the raw material of following mass percent: hydrophilic finishing agent 10%, antistatic agent
10%, softening agent 12%, UV resistance agent 25%, surplus are water.
The hydrophilic finishing agent is methoxypolyethylene glycol.
The antistatic agent is polyoxyethylene alkyl ether.
The softening agent is polyvinylpyrrolidone.
The UV resistance agent is Radix Arnebiae extract.
The preparation method is the same as that of Example 1 for the Radix Arnebiae extract unanimously, and details are not described herein again.
Comparative example 1
A kind of preparation method of absorbing sweat hydrofuge open air UV resistance fabric, includes the following steps:
S1 by mass volume ratio 2:1000g/mL by dopamine hydrochloride be added alkaline ethanol aqueous solution in, 200 turns/
It being stirred for 24 hours under conditions of point, is centrifuged 15min under conditions of 15000 revs/min, take lower sediment, deionized water is washed 3 times,
The dosage of each deionized water is 100mL, obtains poly-dopamine particle after vacuum freeze drying;
The condition of the vacuum freeze drying is control material thickness 8mm, sets pre-freezing temperature as -20 DEG C, when sample temperature
Degree keeps 1.5h after dropping to -20 DEG C, sets sublimation temperature as 12 DEG C, resolution temperature is 24 DEG C, vacuum degree 25Pa, and drying is for 24 hours;
The alkaline ethanol aqueous solution is by dehydrated alcohol: water: 40:90:0.6 is mixed a hydration ammonia by volume;
S2 stirs ultra-high molecular weight polyethylene, poly-dopamine particle, paraffin oil under conditions of 60 revs/min, 200 DEG C
20min;Then hot pressing 20min under conditions of temperature is 190 DEG C, pressure is 2.0MPa;(25 DEG C) are cooled to room temperature, are obtained
With a thickness of 300 μm of poly-dopamine/ultra-high molecular weight polyethylene/parafilms;
The ultra-high molecular weight polyethylene, poly-dopamine particle, paraffin oil mass ratio be 1:0.03:0.05;
S3 will grow × width x thickness be 50cm × 50cm × 300 μm poly-dopamine/ultra-high molecular weight polyethylene/parafilm
Tiling then stacks the fabric that one layer of long × width x thickness is the mm of 50cm × 50cm × 0.5, then stacks again one layer long × wide
× thickness is 50cm × 50cm × 300 μm poly-dopamine/ultra-high molecular weight polyethylene/parafilm, stacks neatly, is 190 in temperature
DEG C, pressure be 2.0MPa under conditions of hot pressing 20min, it is ensured that poly-dopamine/ultra-high molecular weight polyethylene/parafilm seeps completely
Enter in fabric, the fabric after obtaining hot-pressing processing;(25 DEG C) are cooled to room temperature, it will be at hot pressing by mass volume ratio 1:15g/mL
Fabric after reason submerges 30min in dimethylbenzene, pulls out, naturally dry;It repeats immersion step 3 times;It obtains after natural drying
Porous ultra-high molecular weight polyethylene/compound fabric;
S4 UV resistance arranges: by porous ultra-high molecular weight polyethylene/compound fabric with bath raio 1:30g/mL in textile finishing
Impregnate 60min in agent, an immersing and rolling, pick-up 80wt%, by the fabric after padding at 175 DEG C forced air drying 30min, it is cold
But to room temperature (25 DEG C) to get absorbing sweat hydrofuge open air UV resistance fabric.
The fabric is dacron.Dacron the preparation method is as follows: spun polyester thread is knitted into using needle 12G
Horizontal close 37 stringers/10cm, close 58.5 rows/10cm single side plain fabric, i.e. dacron are indulged.
The fabric finishing agent is mixed by the raw material of following mass percent: hydrophilic finishing agent 10%, antistatic agent
10%, softening agent 12%, UV resistance agent 25%, surplus are water.
The hydrophilic finishing agent is methoxypolyethylene glycol.
The antistatic agent is polyoxyethylene alkyl ether.
The softening agent is polyvinylpyrrolidone.
The UV resistance agent is Radix Arnebiae extract.
The preparation method is the same as that of Example 1 for the Radix Arnebiae extract unanimously, and details are not described herein again.
Comparative example 2
A kind of preparation method of absorbing sweat hydrofuge open air UV resistance fabric, includes the following steps:
Ultra-high molecular weight polyethylene, paraffin oil are stirred 20min under conditions of 60 revs/min, 200 DEG C by S1;Then in temperature
Hot pressing 20min under conditions of degree is 190 DEG C, pressure is 2.0MPa;(25 DEG C) are cooled to room temperature, are obtained with a thickness of 300 μm of superelevation
Molecular weight polyethylene/parafilm;
The ultra-high molecular weight polyethylene, paraffin oil mass ratio be 1:0.05;
S2 will grow × width x thickness be 50cm × 50cm × 300 μm ultra-high molecular weight polyethylene/parafilm tiling, then
Stacking one layer of long × width x thickness is 50cm × 50cm × 0.5mm fabric, and then stacking one layer of long × width x thickness again is 50cm
Ultra-high molecular weight polyethylene/parafilm of × 50cm × 300 μm, stack it is neat, temperature be 190 DEG C, pressure 2.0MPa
Under conditions of hot pressing 20min, it is ensured that ultra-high molecular weight polyethylene/parafilm fully penetrates into fabric, after obtaining hot-pressing processing
Fabric;(25 DEG C) are cooled to room temperature, submerge the fabric after hot-pressing processing in dimethylbenzene by mass volume ratio 1:15g/mL
30min is pulled out, naturally dry;It repeats immersion step 3 times;Porous ultra-high molecular weight polyethylene/compound is obtained after natural drying
Fabric;
S3 UV resistance arranges: by porous ultra-high molecular weight polyethylene/compound fabric with bath raio 1:30g/mL in textile finishing
Impregnate 60min in agent, an immersing and rolling, pick-up 80wt%, by the fabric after padding at 175 DEG C forced air drying 30min, it is cold
But to room temperature (25 DEG C) to get absorbing sweat hydrofuge open air UV resistance fabric.
The fabric is dacron.Dacron the preparation method is as follows: spun polyester thread is knitted into using needle 12G
Horizontal close 37 stringers/10cm, close 58.5 rows/10cm single side plain fabric, i.e. dacron are indulged.
The fabric finishing agent is mixed by the raw material of following mass percent: hydrophilic finishing agent 10%, antistatic agent
10%, softening agent 12%, UV resistance agent 25%, surplus are water.
The hydrophilic finishing agent is methoxypolyethylene glycol.
The antistatic agent is polyoxyethylene alkyl ether.
The softening agent is polyvinylpyrrolidone.
The UV resistance agent is Radix Arnebiae extract.
The preparation method is the same as that of Example 1 for the Radix Arnebiae extract unanimously, and details are not described herein again.
Embodiment 3
A kind of preparation method of absorbing sweat hydrofuge open air UV resistance fabric, includes the following steps:
S1 by mass volume ratio 2:1000g/mL by dopamine hydrochloride be added alkaline ethanol aqueous solution in, 200 turns/
It being stirred for 24 hours under conditions of point, is centrifuged 15min under conditions of 15000 revs/min, take lower sediment, deionized water is washed 3 times,
The dosage of each deionized water is 100mL, obtains poly-dopamine particle after vacuum freeze drying;
The condition of the vacuum freeze drying is control material thickness 8mm, sets pre-freezing temperature as -20 DEG C, when sample temperature
Degree keeps 1.5h after dropping to -20 DEG C, sets sublimation temperature as 12 DEG C, resolution temperature is 24 DEG C, vacuum degree 25Pa, and drying is for 24 hours;
The alkaline ethanol aqueous solution is by dehydrated alcohol: water: 40:90:0.6 is mixed a hydration ammonia by volume;
Methoxy poly (ethylene glycol) amine is added to the poly-dopamine that concentration is 1.0g/L by mass volume ratio 5:1mg/mL by S2
It in aqueous dispersions, is stirred under conditions of 500 revs/min for 24 hours, is centrifuged 15min under conditions of 15000 revs/min, take lower layer heavy
It forms sediment, deionized water is washed 3 times, and the dosage of each deionized water is 100mL, and modified poly-dopamine is obtained after vacuum freeze drying
Particle;
The concentration is the poly-dopamine aqueous dispersions of 1.0g/L the preparation method comprises the following steps: 1g poly-dopamine particle is added
Into 1L water, ultrasonic power be 200W, supersonic frequency be 24kHz under conditions of ultrasonic treatment 15min to get;
The condition of the vacuum freeze drying is control material thickness 8mm, sets pre-freezing temperature as -20 DEG C, when sample temperature
Degree keeps 1.5h after dropping to -20 DEG C, sets sublimation temperature as 12 DEG C, resolution temperature is 24 DEG C, vacuum degree 25Pa, and drying is for 24 hours;
S3 is by ultra-high molecular weight polyethylene, modified poly-dopamine particle, paraffin oil under conditions of 60 revs/min, 200 DEG C
Stir 20min;Then hot pressing 20min under conditions of temperature is 190 DEG C, pressure is 2.0MPa;(25 DEG C) are cooled to room temperature,
It obtains with a thickness of 300 μm of modified poly-dopamine/ultra-high molecular weight polyethylene/parafilms;
The ultra-high molecular weight polyethylene, modified poly-dopamine particle, paraffin oil mass ratio be 1:0.03:0.05;
S4 will grow × width x thickness be 50cm × 50cm × 300 μm modification poly-dopamine/ultra-high molecular weight polyethylene/stone
Cere tiling, then stacking one layer of long × width x thickness is 50cm × 50 cm × 0.5mm fabric, is then stacked again one layer long
× width x thickness is modification poly-dopamine/ultra-high molecular weight polyethylene/parafilm of cm × 300 μm 50cm × 50, is stacked neatly,
Hot pressing 20min under conditions of temperature is 190 DEG C, pressure is 2.0MPa, it is ensured that modified poly-dopamine/superhigh molecular weight polyethylene
Alkene/parafilm fully penetrates into fabric, the fabric after obtaining hot-pressing processing;(25 DEG C) are cooled to room temperature, by mass volume ratio 1:
Fabric after hot-pressing processing is submerged 30min by 15g/mL in dimethylbenzene, is pulled out, naturally dry;It repeats immersion step 3 times;
Porous ultra-high molecular weight polyethylene/compound fabric is obtained after natural drying;
S5 UV resistance arranges: by porous ultra-high molecular weight polyethylene/compound fabric with bath raio 1:30g/mL in textile finishing
Impregnate 60min in agent, an immersing and rolling, pick-up 80wt%, by the fabric after padding at 175 DEG C forced air drying 30min, it is cold
But to room temperature (25 DEG C) to get absorbing sweat hydrofuge open air UV resistance fabric.
The fabric is dacron.Dacron the preparation method is as follows: spun polyester thread is knitted into using needle 12G
Horizontal close 37 stringers/10cm, close 58.5 rows/10cm single side plain fabric, i.e. dacron are indulged.
The fabric finishing agent is mixed by the raw material of following mass percent: hydrophilic finishing agent 10%, antistatic agent
10%, softening agent 12%, UV resistance agent 25%, surplus are water.
The hydrophilic finishing agent is methoxypolyethylene glycol.
The antistatic agent is polyoxyethylene alkyl ether.
The softening agent is polyvinylpyrrolidone.
The UV resistance agent is quaternary ammonium alkali lignin.
The preparation method is the same as that of Example 1 for the quaternary ammonium alkali lignin unanimously, and details are not described herein again.
Embodiment 4
A kind of preparation method of absorbing sweat hydrofuge open air UV resistance fabric, includes the following steps:
S1 by mass volume ratio 2:1000g/mL by dopamine hydrochloride be added alkaline ethanol aqueous solution in, 200 turns/
It being stirred for 24 hours under conditions of point, is centrifuged 15min under conditions of 15000 revs/min, take lower sediment, deionized water is washed 3 times,
The dosage of each deionized water is 100mL, obtains poly-dopamine particle after vacuum freeze drying;
The condition of the vacuum freeze drying is control material thickness 8mm, sets pre-freezing temperature as -20 DEG C, when sample temperature
Degree keeps 1.5h after dropping to -20 DEG C, sets sublimation temperature as 12 DEG C, resolution temperature is 24 DEG C, vacuum degree 25Pa, and drying is for 24 hours;
The alkaline ethanol aqueous solution is by dehydrated alcohol: water: 40:90:0.6 is mixed a hydration ammonia by volume;
Methoxy poly (ethylene glycol) amine is added to the poly-dopamine that concentration is 1.0g/L by mass volume ratio 5:1mg/mL by S2
It in aqueous dispersions, is stirred under conditions of 500 revs/min for 24 hours, is centrifuged 15min under conditions of 15000 revs/min, take lower layer heavy
It forms sediment, deionized water is washed 3 times, and the dosage of each deionized water is 100mL, and modified poly-dopamine is obtained after vacuum freeze drying
Particle;
The concentration is the poly-dopamine aqueous dispersions of 1.0g/L the preparation method comprises the following steps: 1g poly-dopamine particle is added
Into 1L water, ultrasonic power be 200W, supersonic frequency be 24kHz under conditions of ultrasonic treatment 15min to get;
The condition of the vacuum freeze drying is control material thickness 8mm, sets pre-freezing temperature as -20 DEG C, when sample temperature
Degree keeps 1.5h after dropping to -20 DEG C, sets sublimation temperature as 12 DEG C, resolution temperature is 24 DEG C, vacuum degree 25Pa, and drying is for 24 hours;
S3 is by ultra-high molecular weight polyethylene, modified poly-dopamine particle, paraffin oil under conditions of 60 revs/min, 200 DEG C
Stir 20min;Then hot pressing 20min under conditions of temperature is 190 DEG C, pressure is 2.0MPa;(25 DEG C) are cooled to room temperature,
It obtains with a thickness of 300 μm of modified poly-dopamine/ultra-high molecular weight polyethylene/parafilms;
The ultra-high molecular weight polyethylene, modified poly-dopamine particle, paraffin oil mass ratio be 1:0.03:0.05;
S4 will grow × width x thickness be 50cm × 50cm × 300 μm modification poly-dopamine/ultra-high molecular weight polyethylene/stone
Cere tiling, then stacking one layer of long × width x thickness is 50cm × 50 cm × 0.5mm fabric, is then stacked again one layer long
× width x thickness is modification poly-dopamine/ultra-high molecular weight polyethylene/parafilm of cm × 300 μm 50cm × 50, is stacked neatly,
Hot pressing 20min under conditions of temperature is 190 DEG C, pressure is 2.0MPa, it is ensured that modified poly-dopamine/superhigh molecular weight polyethylene
Alkene/parafilm fully penetrates into fabric, the fabric after obtaining hot-pressing processing;(25 DEG C) are cooled to room temperature, by mass volume ratio 1:
Fabric after hot-pressing processing is submerged 30min by 15g/mL in dimethylbenzene, is pulled out, naturally dry;It repeats immersion step 3 times;
Porous ultra-high molecular weight polyethylene/compound fabric is obtained after natural drying;
S5 UV resistance arranges: by porous ultra-high molecular weight polyethylene/compound fabric with bath raio 1:30g/mL in textile finishing
Impregnate 60min in agent, an immersing and rolling, pick-up 80wt%, by the fabric after padding at 175 DEG C forced air drying 30min, it is cold
But to room temperature (25 DEG C) to get absorbing sweat hydrofuge open air UV resistance fabric.
The fabric is dacron.Dacron the preparation method is as follows: spun polyester thread is knitted into using needle 12G
Horizontal close 37 stringers/10cm, close 58.5 rows/10cm single side plain fabric, i.e. dacron are indulged.
The fabric finishing agent is mixed by the raw material of following mass percent: hydrophilic finishing agent 10%, antistatic agent
10%, softening agent 12%, UV resistance agent 25%, surplus are water.
The hydrophilic finishing agent is methoxypolyethylene glycol.
The antistatic agent is polyoxyethylene alkyl ether.
The softening agent is polyvinylpyrrolidone.
The UV resistance agent is Radix Arnebiae extract and quaternary ammonium alkali lignin.
The preparation method is the same as that of Example 1 for the Radix Arnebiae extract unanimously, and details are not described herein again.
The preparation method is the same as that of Example 1 for the quaternary ammonium alkali lignin unanimously, and details are not described herein again.
Embodiment 5
A kind of preparation method of absorbing sweat hydrofuge open air UV resistance fabric, includes the following steps:
S1 by mass volume ratio 2:1000g/mL by dopamine hydrochloride be added alkaline ethanol aqueous solution in, 200 turns/
It being stirred for 24 hours under conditions of point, is centrifuged 15min under conditions of 15000 revs/min, take lower sediment, deionized water is washed 3 times,
The dosage of each deionized water is 100mL, obtains poly-dopamine particle after vacuum freeze drying;
The condition of the vacuum freeze drying is control material thickness 8mm, sets pre-freezing temperature as -20 DEG C, when sample temperature
Degree keeps 1.5h after dropping to -20 DEG C, sets sublimation temperature as 12 DEG C, resolution temperature is 24 DEG C, vacuum degree 25Pa, and drying is for 24 hours;
The alkaline ethanol aqueous solution is by dehydrated alcohol: water: 40:90:0.6 is mixed a hydration ammonia by volume;
Methoxy poly (ethylene glycol) amine is added to the poly-dopamine that concentration is 1.0g/L by mass volume ratio 5:1mg/mL by S2
It in aqueous dispersions, is stirred under conditions of 500 revs/min for 24 hours, is centrifuged 15min under conditions of 15000 revs/min, take lower layer heavy
It forms sediment, deionized water is washed 3 times, and the dosage of each deionized water is 100mL, and modified poly-dopamine is obtained after vacuum freeze drying
Particle;
The concentration is the poly-dopamine aqueous dispersions of 1.0g/L the preparation method comprises the following steps: 1g poly-dopamine particle is added
Into 1L water, ultrasonic power be 200W, supersonic frequency be 24kHz under conditions of ultrasonic treatment 15min to get;
The condition of the vacuum freeze drying is control material thickness 8mm, sets pre-freezing temperature as -20 DEG C, when sample temperature
Degree keeps 1.5h after dropping to -20 DEG C, sets sublimation temperature as 12 DEG C, resolution temperature is 24 DEG C, vacuum degree 25Pa, and drying is for 24 hours;
S3 is by ultra-high molecular weight polyethylene, modified poly-dopamine particle, paraffin oil under conditions of 60 revs/min, 200 DEG C
Stir 20min;Then hot pressing 20min under conditions of temperature is 190 DEG C, pressure is 2.0MPa;(25 DEG C) are cooled to room temperature,
It obtains with a thickness of 300 μm of modified poly-dopamine/ultra-high molecular weight polyethylene/parafilms;
The ultra-high molecular weight polyethylene, modified poly-dopamine particle, paraffin oil mass ratio be 1:0.03:0.05;
S4 will grow × width x thickness be 50cm × 50cm × 300 μm modification poly-dopamine/ultra-high molecular weight polyethylene/stone
Cere tiling, then stacking one layer of long × width x thickness is 50cm × 50 cm × 0.5mm fabric, is then stacked again one layer long
× width x thickness is that modification poly-dopamine/ultra-high molecular weight polyethylene/parafilm of cm × 300 μm 50cm × 50 stacks neatly,
Hot pressing 20min under conditions of temperature is 190 DEG C, pressure is 2.0MPa, it is ensured that modified poly-dopamine/superhigh molecular weight polyethylene
Alkene/parafilm fully penetrates into fabric, the fabric after obtaining hot-pressing processing;(25 DEG C) are cooled to room temperature, by mass volume ratio 1:
Fabric after hot-pressing processing is submerged 30min by 15g/mL in dimethylbenzene, is pulled out, naturally dry;It repeats immersion step 3 times;
Porous ultra-high molecular weight polyethylene/compound fabric is obtained after natural drying;
S5 UV resistance arranges: by porous ultra-high molecular weight polyethylene/compound fabric with bath raio 1:30g/mL in textile finishing
Impregnate 60min in agent, an immersing and rolling, pick-up 80wt%, by the fabric after padding at 175 DEG C forced air drying 30min, it is cold
But to room temperature (25 DEG C) to get absorbing sweat hydrofuge open air UV resistance fabric.
The fabric is dacron.Dacron the preparation method is as follows: spun polyester thread is knitted into using needle 12G
Horizontal close 37 stringers/10cm, close 58.5 rows/10cm single side plain fabric, i.e. dacron are indulged.
The fabric finishing agent is mixed by the raw material of following mass percent: hydrophilic finishing agent 10%, antistatic agent
10%, softening agent 12%, UV resistance agent 25%, surplus are water.
The hydrophilic finishing agent is methoxypolyethylene glycol.
The antistatic agent is polyoxyethylene alkyl ether.
The softening agent is polyvinylpyrrolidone.
The UV resistance agent is Radix Arnebiae extract and quaternary ammonium alkali lignin-zinc oxide composite mix by quality 3:1 and
At.
The preparation method is the same as that of Example 1 for the Radix Arnebiae extract unanimously, and details are not described herein again.
The preparation method is the same as that of Example 1 for the quaternary ammonium alkali lignin-zinc oxide composite unanimously, and details are not described herein again.
Test case 1
Water imbibition and penetrability are according to GB/T 21655.1-2008 " the evaluation part 1 of textile absorbing fast-drying: single
Item composite test method " it is tested.
Table 1: water imbibition and penetrability test result
As can be seen from Table 1, the water absorption rate of absorbing sweat hydrofuge prepared by the present invention open air UV resistance fabric reaches as high as
275% much higher than 100% specified in standard, and permeability amount reaches as high as 13072.58000g/d*m2Much larger than being provided in standard
8000g/d*m2。
Test case 2
The ultraviolet wire testing method of fabric presses national standard GB/T 18830-2009 " evaluation of ultraviolet resistance of fabric ".
One important parameter of evaluation fabric W protection is Ultraviolet Protection Factor UPF, which is used to measure ultraviolet spoke
Penetrate the extent of injury to human body.After UPF value refers to that certain shielding is used, it is (such as red that ultraviolet radioactive makes skin reach a certain damage
It is spot, eye injury, even carcinogenic etc.) threshold dose the time required to value and without reach when shielding same extent of injury when
Between be worth the ratio between.By the standard test, as the UPF ﹥ 40 of sample, and when UPA ﹤ 5%, " antiultraviolet product " can be described as.Fabric
UV resistance performance test results are shown in Table 2.
2 anti-UV performance test result of table
|
UPF |
Embodiment 2 |
67.7 |
Comparative example 1 |
60.2 |
Comparative example 2 |
56.7 |
Embodiment 3 |
69.2 |
Embodiment 4 |
77.5 |
Embodiment 5 |
83.7 |
As can be known from the above table, porous ultra-high molecular weight polyethylene/compound fabric of the invention passes through (purple containing UV resistance agent
Careless extract or quaternary ammonium alkali lignin or quaternary ammonium alkali lignin-zinc oxide composite) the padding of fabric finishing agent after obtain
Fabric not only have a good absorbing sweat ventilating capability, increase the comfort level of human body dress, moreover it is possible to significant to mitigate in sunlight
Injury of the ultraviolet light to human body.
The present invention is described in detail above, specific case used herein is to the principle of the present invention and implementation
Mode is expounded, and the above description of the embodiment is only used to help understand the method for the present invention and its core ideas;Together
When, for those of ordinary skill in the art, according to the thought of the present invention, can in specific embodiments and applications
There is change place, in conclusion the contents of this specification are not to be construed as limiting the invention.