CN108894034A - A kind of wool fabric method of modifying - Google Patents

A kind of wool fabric method of modifying Download PDF

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Publication number
CN108894034A
CN108894034A CN201810490198.4A CN201810490198A CN108894034A CN 108894034 A CN108894034 A CN 108894034A CN 201810490198 A CN201810490198 A CN 201810490198A CN 108894034 A CN108894034 A CN 108894034A
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China
Prior art keywords
wool fabric
wool
dyeing
excimer
modified
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Pending
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CN201810490198.4A
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Chinese (zh)
Inventor
王生
李朝晖
季莉
张威
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Nantong Textile Vocational Technology College
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Nantong Textile Vocational Technology College
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Priority to CN201810490198.4A priority Critical patent/CN108894034A/en
Publication of CN108894034A publication Critical patent/CN108894034A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/20Physical treatments affecting dyeing, e.g. ultrasonic or electric
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/39General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using acid dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653Nitrogen-free carboxylic acids or their salts
    • D06P1/6533Aliphatic, araliphatic or cycloaliphatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67333Salts or hydroxides
    • D06P1/6735Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341

Abstract

The invention discloses a kind of wool fabric method of modifying, include the following steps:The radiation irradiation that wool fabric is first passed through to Excimer UV lamp, is then handled through chitosan derivatives again, is finally tested using the detection that acid dyeing carries out dyeing effect.The present invention is by carrying out process modification to traditional wool fabric is modified, in such a way that Excimer UV lamp and chitosan derivatives processing technique combine, so that modified wool fabric enhances the absorption of dyestuff and binding ability, to improve the dyeing percentage and degree of fixation of dyestuff, and level-dyeing property and dyefastness are able to satisfy related request.

Description

A kind of wool fabric method of modifying
Technical field
The invention belongs to textile dyeing and finishing manufacture fields, and in particular to a kind of wool fabric method of modifying.
Background technique
Wool has the characteristics that elasticity, soft touch, warmth retention property are good, while there are also good as a kind of high-grade textile fabric Moisture absorption well, crease-resistant and soil resistance performance.Although wool advantage is numerous, since the scale layer and scale of wool surfaces are outermost The hydrophobic layer of layer exists, so that dyestuff is difficult to dye, has played inhibition to dye in the absorption of dyestuff.
It generally requires before woolen dyed and is first pre-processed, the preprocess method of early stage wool is mainly oxidizing process, is passed through Oxidizer containing chlorine destroys the disulfide bond and protein peptide bond of the scale layer of wool fiber, increases the soluble groups of scale layer, Hygroscopicity enhancing generally uses high temperature boiling dye, dyeing time is longer, energy to achieve the effect that wool softens when woolen dyed The problems such as consumption is high, big to fibre damage, more easily leads to wool fiber strength and declines, and feel is coarse, color yellowing, and oxidizing process Generated AOX will cause serious environmental pollution, strictly be limited by the regulation of many developed countries.Therefore research is to environment Close friend, the wool pre-treatment method of modifying having no adverse effects to wool characteristic is one of current trends.
Excimer UV lamp is a kind of novel high-strength incoherence Monochromatic UV sources, it is using in specific wavelength The lower textile polymer host material of Excimer UV line irradiation has high absorbent properties, and reaction medium passes through thoroughly in irradiation Optical medium layer is irradiated strong absorption base, and matrix and reaction medium is caused to react, so that fabric surface obtains Modified effect.Therefore the technology is a kind of cleaning, low-loss and energy-saving, anhydrous free of contamination novel processing method.
Chitosan is as chitin by a kind of native biopolymer obtained from de- second phthaleinization reaction, is natural polysaccharide In unique alkaline polysaccharide.With complicated double-spiral structure, there are-OH ,-NH in molecular structure2Group all has stronger anti- Answer activity, and a small number of one of natural products with charge.After handling wool fabric with chitosan, wool is fine The negative charge amount of institute's band is reduced in dimension, the negative electrical charge in dyeing course on fiber to the Coulomb repulsion of anion in chromosin also with Reduction, to improve the dyeing rate and final dye-uptake of dyestuff.Chitosan guanidine salt hydrochlorate has dye ions stronger Suction-operated considerably increases the dye seat number contaminated on anionic dye, therefore be used for changing when it is adsorbed on wool surfaces The dyeability of kind wool has more advantage.
Summary of the invention
Goal of the invention:The present invention aiming at the shortcomings in the prior art, provides a kind of method modified for wool fabric, should Method green non-pollution, and can make wool fabric that there is high dyeability and obtain preferable dyefastness.
Technical solution:A kind of wool fabric method of modifying, includes the following steps:
(1) wool grease scouring pre-treatment:
Hair-wool Woven Fabric 500g, serves as a contrast or foil dacron 500g, and paregal O 20-30g, A613 Lei meter nation 10-20g is being marked After washed once under quasi- washing 7A program, naturally dry is stand-by in draught cupboard;
(2) wool fabric is first passed through into Excimer UV lamp modification:
Wool fabric is irradiated by the radiation of Excimer UV lamp and is modified processing, at the Excimer UV lamp Under vacuum conditions, Excimer UV line is high energy, high-strength, incoherent narrowband wave to reason, wavelength 222nm, and processing power is 10W-30W, pressure 50Pa, processing time are 1-5min, and the radiation length between the Excimer UV lamp and fabric is Wool fabric is placed in drying in drying box after being disposed, used to next step process by 0.1-10cm;
(3) chitosan derivatives modification:
Wool fabric Jing Guo the modification of Excimer UV lamp is modified using chitosan derivatives, and the program uses The proportion group of padding method, maceration extract is divided into:Chitosan derivatives that mass fraction is 1%-4%, mass fraction be 1% it is time sub- Wool fabric, is put into maceration extract at 60 DEG C and impregnates 10min, electronic by the citric acid that sodium phosphate and mass fraction are 1% Second dipping and rolling on padding machine, then preliminary drying 10min under the conditions of 80-100 DEG C, then under conditions of 120-130 DEG C, by wool fabric 3min is baked, for use;
(4) acid dyeing testing inspection is tested:
It is dyed using acid dyeing to Conventional wool fabric and by modified wool fabric, detection is by being modified Fastness after the dyeing percentage and dye of wool fabric afterwards determines whether modified technique is reasonable;
The technique of acid dyes dyeing wool is punished and process flow:
Prepare dye liquor:Dye strength is the acid red A2R of 2%-5% (omf), anhydrous sodium sulphate is 5%-8% (omf), defoaming Agent is 0.3-0.5g/L, bath raio 1:30, pH are adjusted to 5, and dye liquor temperature is risen to 60 DEG C, wool fabric is put into dye liquor, by Gradually be warming up to 100 DEG C, heating rate is 2 DEG C/min, dyeing time 60min, after take out sample, using soap, hot water Wash, cold water is washed, drying be placed in it is to be detected in drying box, wherein in soaping:Soap flakes 2-4g/L, temperature are 80 DEG C -90 DEG C, when Between be 10-15min, bath raio 1:20.
As optimization:The chitosan derivatives are water-soluble chitosan guanidine salt hydrochlorate.
As optimization:The pick-up of the second dipping and rolling is 80%-90%.
Beneficial effect:Advantages of the present invention is as follows:
1. the present invention is improved by the method to processing wool fabric, using Excimer UV line and chitosan guanidine salt The mode that hydrochlorate combines, so that modified wool fiber enhances the absorption of acid dyes and binding ability, to improve The dyeing percentage of dyestuff, improves woolen dyed fastness.
2. the present invention is used as a kind of wool fabric method of modifying, processing wool is carried out using Excimer UV line, belongs to nothing Processing mode that water is pollution-free meets the environmentally protective theory of sustainability discovery.
3. chitosan guanidine salt acid used in the present invention has stronger suction-operated to dyestuff, it is further to be conducive to dyestuff It is combined into fibrous inside and fiber, improves the dyeing percentage of dyeing, the level-dyeing property and dyestuff fastness of dyeing are different Degree is improved.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, so that the technology of this field Personnel can better understand advantages and features of the invention, to make apparent boundary to protection scope of the present invention It is fixed.Embodiment described in the invention is only a part of the embodiment of the present invention, instead of all the embodiments, based on the present invention In embodiment, those of ordinary skill in the art's every other implementation obtained without making creative work Example, shall fall within the protection scope of the present invention.
Specific embodiment 1:
A kind of wool fabric method of modifying, includes the following steps:
(1) wool grease scouring pre-treatment:
Hair-wool Woven Fabric 500g serves as a contrast or foil dacron 500g, paregal O 20g, A613 Lei meter nation 10g, in standard wash After washed once under 7A program, naturally dry is stand-by in draught cupboard;
(2) wool fabric is first passed through into Excimer UV lamp modification:
Wool fabric is irradiated by the radiation of Excimer UV lamp and is modified processing, at the Excimer UV lamp Under vacuum conditions, Excimer UV line is high energy, high-strength, incoherent narrowband wave to reason, wavelength 222nm, and processing power is 10W, pressure 50Pa, processing time are 1min, and the radiation length between the Excimer UV lamp and fabric is 0.1cm, Wool fabric is placed in drying in drying box after being disposed, is used to next step process;
(3) chitosan derivatives modification:
Wool fabric Jing Guo the modification of Excimer UV lamp is modified using chitosan derivatives, the chitosan Derivative is water-soluble chitosan guanidine salt hydrochlorate, and the program uses padding method, and the proportion group of maceration extract is divided into:Mass fraction For 1% chitosan derivatives, mass fraction be 1% sodium hypophosphite and mass fraction be 1% citric acid, at 60 DEG C Wool fabric is put into maceration extract and impregnates 10min, the second dipping and rolling on electronic padding machine, pick-up 80%, then at 80 DEG C Under the conditions of preliminary drying 10min, then under conditions of 120 DEG C, wool fabric is baked into 3min, for use;
(4) acid dyeing testing inspection is tested:
It is dyed using acid dyeing to Conventional wool fabric and by modified wool fabric, detection is by being modified Fastness after the dyeing percentage and dye of wool fabric afterwards determines whether modified technique is reasonable;
The technique of acid dyes dyeing wool is punished and process flow:
Prepare dye liquor:Dye strength is the acid red A2R of 2% (omf), anhydrous sodium sulphate is 5% (omf), defoaming agent 0.3g/ L, bath raio 1:30, pH are adjusted to 5, and dye liquor temperature is risen to 60 DEG C, wool fabric is put into dye liquor, is gradually heated to 100 DEG C, Heating rate be 2 DEG C/min, dyeing time 60min, after take out sample, using soap, hot water wash, cold water are washed, drying It is placed in be detected in drying box, wherein in soaping:Soap flakes 2g/L, temperature are 80 DEG C, time 10min, bath raio 1:20.
It is tested by the dyeing percentage of dyestuff after dyeing, passes through the upper of modified technique treated wool fabric Dye percentage reaches 86.5%, and the dyeing percentage after non-modified wool fabric dyeing is 42.6%;Modified sheep Wool fabric homogenized diet Sr value by raw wool 0.438 decline 0.124, level-dyeing property significantly improves;Modified dyed fabric Pure color light, without dyeing defect phenomenon, perspiration resistance, washable color, fastness to rubbing can reach 4 grades or more, and anti-fluffing and anti-pilling reaches 3.5 Grade or more.
Specific embodiment 2:
A kind of wool fabric method of modifying, includes the following steps:
(1) wool grease scouring pre-treatment:
Hair-wool Woven Fabric 500g serves as a contrast or foil dacron 500g, paregal O 30g, A613 Lei meter nation 20g, in standard wash After washed once under 7A program, naturally dry is stand-by in draught cupboard;
(2) wool fabric is first passed through into Excimer UV lamp modification:
Wool fabric is irradiated by the radiation of Excimer UV lamp and is modified processing, at the Excimer UV lamp Under vacuum conditions, Excimer UV line is high energy, high-strength, incoherent narrowband wave to reason, wavelength 222nm, and processing power is 30W, pressure 50Pa, processing time are 5min, and the radiation length between the Excimer UV lamp and fabric is 10cm, place Wool fabric is placed in drying in drying box after reason, is used to next step process;
(3) chitosan derivatives modification:
Wool fabric Jing Guo the modification of Excimer UV lamp is modified using chitosan derivatives, the chitosan Derivative is water-soluble chitosan guanidine salt hydrochlorate, and the program uses padding method, and the proportion group of maceration extract is divided into:Mass fraction For 4% chitosan derivatives, mass fraction be 1% sodium hypophosphite and mass fraction be 1% citric acid, at 60 DEG C Wool fabric is put into maceration extract and impregnates 10min, the second dipping and rolling on electronic padding machine, pick-up 90%, then at 100 DEG C Under the conditions of preliminary drying 10min, then under conditions of 130 DEG C, wool fabric is baked into 3min, for use;
(4) acid dyeing testing inspection is tested:
It is dyed using acid dyeing to Conventional wool fabric and by modified wool fabric, detection is by being modified Fastness after the dyeing percentage and dye of wool fabric afterwards determines whether modified technique is reasonable;
The technique of acid dyes dyeing wool is punished and process flow:
Prepare dye liquor:Dye strength is the acid red A2R of 5% (omf), anhydrous sodium sulphate is 8% (omf), defoaming agent 0.5g/ L, bath raio 1:30, pH are adjusted to 5, and dye liquor temperature is risen to 60 DEG C, wool fabric is put into dye liquor, is gradually heated to 100 DEG C, Heating rate be 2 DEG C/min, dyeing time 60min, after take out sample, using soap, hot water wash, cold water are washed, drying It is placed in be detected in drying box, wherein in soaping:Soap flakes 4g/L, temperature are 90 DEG C, time 15min, bath raio 1:20.
It is tested by the dyeing percentage of dyestuff after dyeing, passes through the upper of modified technique treated wool fabric Dye percentage reaches 88.7%, and the dyeing percentage after non-modified wool fabric dyeing is 42.6%;Modified sheep Wool fabric homogenized diet Sr value by raw wool 0.438 decline 0.121, level-dyeing property significantly improves;Modified dyed fabric Pure color light, without dyeing defect phenomenon, perspiration resistance, washable color, fastness to rubbing can reach 4 grades or more, and anti-fluffing and anti-pilling reaches 3.5 Grade or more.
Specific embodiment 3:
A kind of wool fabric method of modifying, includes the following steps:
(1) wool grease scouring pre-treatment:
Hair-wool Woven Fabric 500g serves as a contrast or foil dacron 500g, paregal O 24g, A613 Lei meter nation 13g, in standard wash After washed once under 7A program, naturally dry is stand-by in draught cupboard;
(2) wool fabric is first passed through into Excimer UV lamp modification:
Wool fabric is irradiated by the radiation of Excimer UV lamp and is modified processing, at the Excimer UV lamp Under vacuum conditions, Excimer UV line is high energy, high-strength, incoherent narrowband wave to reason, wavelength 222nm, and processing power is 23W, pressure 50Pa, processing time are 3min, and the radiation length between the Excimer UV lamp and fabric is 6cm, place Wool fabric is placed in drying in drying box after reason, is used to next step process;
(3) chitosan derivatives modification:
Wool fabric Jing Guo the modification of Excimer UV lamp is modified using chitosan derivatives, the chitosan Derivative is water-soluble chitosan guanidine salt hydrochlorate, and the program uses padding method, and the proportion group of maceration extract is divided into:Mass fraction For 3% chitosan derivatives, mass fraction be 1% sodium hypophosphite and mass fraction be 1% citric acid, at 60 DEG C Wool fabric is put into maceration extract and impregnates 10min, the second dipping and rolling on electronic padding machine, pick-up 84%, then at 90 DEG C Under the conditions of preliminary drying 10min, then under conditions of 124 DEG C, wool fabric is baked into 3min, for use;
(4) acid dyeing testing inspection is tested:
It is dyed using acid dyeing to Conventional wool fabric and by modified wool fabric, detection is by being modified Fastness after the dyeing percentage and dye of wool fabric afterwards determines whether modified technique is reasonable;
The technique of acid dyes dyeing wool is punished and process flow:
Prepare dye liquor:Dye strength is the acid red A2R of 3% (omf), anhydrous sodium sulphate is 6% (omf), defoaming agent 0.4g/ L, bath raio 1:30, pH are adjusted to 5, and dye liquor temperature is risen to 60 DEG C, wool fabric is put into dye liquor, is gradually heated to 100 DEG C, Heating rate be 2 DEG C/min, dyeing time 60min, after take out sample, using soap, hot water wash, cold water are washed, drying It is placed in be detected in drying box, wherein in soaping:Soap flakes 3g/L, temperature are 87 DEG C, time 13min, bath raio 1:20.
It is tested by the dyeing percentage of dyestuff after dyeing, passes through the upper of modified technique treated wool fabric Dye percentage reaches 89.7%, and the dyeing percentage after non-modified wool fabric dyeing is 42.6%;Modified sheep Wool fabric homogenized diet Sr value by raw wool 0.438 decline 0.117, level-dyeing property significantly improves;Modified dyed fabric Pure color light, without dyeing defect phenomenon, perspiration resistance, washable color, fastness to rubbing can reach 4-5 grades, anti-fluffing and anti-pilling reach 4 grades with On.
The present invention is improved by the method to processing wool fabric, using Excimer UV line and chitosan guanidine salt acid The mode that salt combines, so that modified wool fiber enhances the absorption of acid dyes and binding ability, to improve The dyeing percentage of dyestuff improves woolen dyed fastness.
The present invention carries out processing wool as a kind of wool fabric method of modifying, using Excimer UV line, belongs to anhydrous Pollution-free processing mode meets the environmentally protective theory of sustainability discovery.
Chitosan guanidine salt acid used in the present invention has stronger suction-operated to dyestuff, be conducive to dyestuff further into Enter fibrous inside and fiber combines, improves the dyeing percentage of dyeing, the different journeys of the level-dyeing property and dyestuff fastness of dyeing Degree is improved.

Claims (3)

1. a kind of wool fabric method of modifying, it is characterised in that:Include the following steps:
(1) wool grease scouring pre-treatment:
Hair-wool Woven Fabric 500g, serves as a contrast or foil dacron 500g, and paregal O 20-30g, A613 Lei meter nation 10-20g is washed in standard It washs after washed once under 7A program, naturally dry is stand-by in draught cupboard;
(2) wool fabric is first passed through into Excimer UV lamp modification:
Wool fabric is modified processing by the radiation irradiation of Excimer UV lamp, the Excimer UV lamp processing exists Under vacuum state, Excimer UV line is high energy, high-strength, incoherent narrowband wave, wavelength 222nm, processing power 10W- 30W, pressure 50Pa, processing time are 1-5min, and the radiation length between the Excimer UV lamp and fabric is 0.1- Wool fabric is placed in drying in drying box after being disposed, used to next step process by 10cm;
(3) chitosan derivatives modification:
Wool fabric Jing Guo the modification of Excimer UV lamp is modified using chitosan derivatives, and the program, which uses, pads The proportion group of method, maceration extract is divided into:The ortho phosphorous acid that chitosan derivatives that mass fraction is 1%-4%, mass fraction are 1% Wool fabric, is put into maceration extract at 60 DEG C and impregnates 10min, in electronic padding machine by the citric acid that sodium and mass fraction are 1% Upper second dipping and rolling, then preliminary drying 10min under the conditions of 80-100 DEG C, then under conditions of 120-130 DEG C, wool fabric is baked 3min, for use;
(4) acid dyeing testing inspection is tested:
It is dyed using acid dyeing to Conventional wool fabric and by modified wool fabric, detection is by modified Fastness after the dyeing percentage and dye of wool fabric determines whether modified technique is reasonable;
The technique of acid dyes dyeing wool is punished and process flow:
Prepare dye liquor:Dye strength is the acid red A2R of 2%-5% (omf), anhydrous sodium sulphate is 5%-8% (omf), defoaming agent is 0.3-0.5g/L, bath raio 1:30, pH are adjusted to 5, and dye liquor temperature is risen to 60 DEG C, and wool fabric is put into dye liquor, is gradually risen For temperature to 100 DEG C, heating rate is 2 DEG C/min, dyeing time 60min, after take out sample, using soap, it is hot water wash, cold Washing, drying are placed in be detected in drying box, wherein in soaping:Soap flakes 2-4g/L, temperature are 80 DEG C -90 DEG C, and the time is 10-15min, bath raio 1:20.
2. wool fabric method of modifying according to claim 1, it is characterised in that:The chitosan derivatives are to dissolve in The chitosan guanidine salt hydrochlorate of water.
3. wool fabric method of modifying according to claim 1, it is characterised in that:The pick-up of the second dipping and rolling is 80%-90%.
CN201810490198.4A 2018-05-21 2018-05-21 A kind of wool fabric method of modifying Pending CN108894034A (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111411508A (en) * 2020-05-21 2020-07-14 中国农业科学院兰州畜牧与兽药研究所 Clean wool with strong anti-felting property and manufacturing method thereof
CN111793994A (en) * 2020-08-20 2020-10-20 江苏阳光股份有限公司 Mordant dyeing process of wool fabric
CN112442907A (en) * 2019-08-29 2021-03-05 江苏阳光股份有限公司 Chitosan oligosaccharide pretreatment worsted fabric dyeing process

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101235589A (en) * 2008-03-05 2008-08-06 东华大学 Quasi-molecule ultraviolet source treatment method and device for textile surface modifying
CN101649549A (en) * 2009-09-07 2010-02-17 东华大学 Multifunctional modification processing method for wool
CN102154830A (en) * 2010-11-28 2011-08-17 江南大学 Method for dyeing wool fabric at low temperature

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101235589A (en) * 2008-03-05 2008-08-06 东华大学 Quasi-molecule ultraviolet source treatment method and device for textile surface modifying
CN101649549A (en) * 2009-09-07 2010-02-17 东华大学 Multifunctional modification processing method for wool
CN102154830A (en) * 2010-11-28 2011-08-17 江南大学 Method for dyeing wool fabric at low temperature

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112442907A (en) * 2019-08-29 2021-03-05 江苏阳光股份有限公司 Chitosan oligosaccharide pretreatment worsted fabric dyeing process
CN111411508A (en) * 2020-05-21 2020-07-14 中国农业科学院兰州畜牧与兽药研究所 Clean wool with strong anti-felting property and manufacturing method thereof
CN111793994A (en) * 2020-08-20 2020-10-20 江苏阳光股份有限公司 Mordant dyeing process of wool fabric
CN111793994B (en) * 2020-08-20 2022-08-02 江苏阳光股份有限公司 Mordant dyeing process of wool fabric

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Application publication date: 20181127