CN109055036A - A kind of liquid detergent and preparation method thereof - Google Patents
A kind of liquid detergent and preparation method thereof Download PDFInfo
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- CN109055036A CN109055036A CN201811123217.6A CN201811123217A CN109055036A CN 109055036 A CN109055036 A CN 109055036A CN 201811123217 A CN201811123217 A CN 201811123217A CN 109055036 A CN109055036 A CN 109055036A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/1266—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2072—Aldehydes-ketones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3726—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to a kind of liquid detergents and preparation method thereof, belong to daily-use chemical industry technical field.According to parts by weight, the raw material of every 100 parts by weight includes the 2 of the modified alta-mud of 0.2-1 parts by weight, the lauric acid amide of ethanol of 15-18 parts by weight, the fatty acid methyl ester ethoxylate of 12-15 parts by weight, the sodium sulfate of polyethenoxy ether of fatty alcohol of 15-20 parts by weight, the nano-ZnO of 0.5-1 parts by weight, the silk gum of 0.8-1.2 parts by weight, the polyurethane of 0.5-0.8 parts by weight and 1-2 parts by weight, 4- dihydroxy benaophenonel, surplus are deionized water.Modified alta-mud is modified through dodecyl trimethyl ammonium bromide and obtains.The laundry liquid formulation is reasonable, and cost is relatively low, and dirt-removing power is strong, can not only effectively avoid clothing corrugation from shrinking, moreover it is possible to clothing yellowing phenomenon be effectively relieved.Preparation method can mix above-mentioned raw materials according to the ratio, simple and quick, be suitable for industrialized production.
Description
Technical field
The present invention relates to daily-use chemical industry technical fields, and in particular to a kind of liquid detergent and preparation method thereof.
Background technique
With society, science and technology, expanding economy, the raising of people's life consumption level, articles for washing has become people
The necessary article of daily life, detergent product type are increasing, and demand is also increasing, development speed it is very fast and by
Gradually develop towards environmentally protective, functionalization, specialization and the direction of seriation.Currently, alternative articles for washing in the market
Type and variety protection are extensive, and from soap, washing powder again to liquid detergent, the range of selection is bigger.Liquid detergent is in 20th century
The eighties entrance daily life just slowly, liquid detergent is soluble because its is easy to use, and dirt-removing power is strong, Neng Goushen
Enter and play cleaning function inside clothes fiber, the advantages that decontamination is more thorough, is slowly accepted by people.
But the case where shrinking after current liquid detergent use there are clothing corrugation, pure cotton class is particularly evident.
Summary of the invention
The purpose of the present invention is to provide a kind of liquid detergents, and the laundry liquid formulation is reasonable, and cost is relatively low, and dirt-removing power is strong,
It can not only effectively avoid clothing corrugation from shrinking, while clothing yellowing phenomenon can also be effectively relieved.
The second object of the present invention is to provide a kind of preparation method of above-mentioned liquid detergent, and this method is simple and quick, is suitable for
Industrialized production.
The present invention solves its technical problem and adopts the following technical solutions to realize:
The present invention proposes a kind of liquid detergent, and according to parts by weight, the raw material of every 100 parts by weight includes 0.2-1 parts by weight
Modified alta-mud, the lauric acid amide of ethanol of 15-18 parts by weight, 12-15 parts by weight fatty acid methyl ester ethoxylate,
The sodium sulfate of polyethenoxy ether of fatty alcohol of 15-20 parts by weight, the nano-ZnO of 0.5-1 parts by weight, 0.8-1.2 parts by weight silk gum,
The polyurethane of 0.5-0.8 parts by weight and the 2,4-DihydroxyBenzophenone of 1-2 parts by weight, surplus is deionized water.Modification is swollen
Profit soil is obtained through dodecyl trimethyl ammonium bromide is modified.
The present invention also proposes the preparation method of above-mentioned liquid detergent: mixed raw material according to the ratio.
The beneficial effect for the liquid detergent and preparation method thereof that present pre-ferred embodiments provide includes:
The laundry liquid formulation that present pre-ferred embodiments provide is reasonable, and cost is relatively low, and dirt-removing power is strong, can not only effectively keep away
Exempt from clothing corrugation to shrink, while clothing yellowing phenomenon can also be effectively relieved.Preparation method includes mixing above-mentioned raw materials according to the ratio,
It is simple and quick, it is suitable for industrialized production.
Specific embodiment
It in order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below will be in the embodiment of the present invention
Technical solution be clearly and completely described.The person that is not specified actual conditions in embodiment, according to normal conditions or manufacturer builds
The condition of view carries out.Reagents or instruments used without specified manufacturer is the conventional production that can be obtained by commercially available purchase
Product.
Liquid detergent of the embodiment of the present invention and preparation method thereof is specifically described below.
The liquid detergent of the application, according to parts by weight, the raw material of every 100 parts by weight may include changing for 0.2-1 parts by weight
Property bentonite, the lauric acid amide of ethanol of 15-18 parts by weight, the fatty acid methyl ester ethoxylate of 12-15 parts by weight, 15-
The sodium sulfate of polyethenoxy ether of fatty alcohol of 20 parts by weight, the nano-ZnO of 0.5-1 parts by weight, 0.8-1.2 parts by weight silk gum,
The polyurethane of 0.5-0.8 parts by weight and the 2,4-DihydroxyBenzophenone of 1-2 parts by weight, surplus is deionized water.Modification is swollen
Profit soil is obtained through dodecyl trimethyl ammonium bromide is modified.
In some specific embodiments, the raw material of every 100 parts by weight may include that the modification of 0.4-0.8 parts by weight is swollen
Moisten soil, the lauric acid amide of ethanol of 16-17 parts by weight, the fatty acid methyl ester ethoxylate of 13-14 parts by weight, 16-18 weight
Measure the sodium sulfate of polyethenoxy ether of fatty alcohol of part, the nano-ZnO of 0.6-0.8 parts by weight, 0.8-1 parts by weight silk gum, 0.6-0.8
The polyurethane of parts by weight and the 2,4-DihydroxyBenzophenone of 1.5-2 parts by weight, surplus is deionized water.
In some specific preferred embodiments, the raw material of every 100 parts by weight may include that the modification of 0.6 parts by weight is swollen
Moisten the rouge of soil, the lauric acid amide of ethanol of 16.5 parts by weight, the fatty acid methyl ester ethoxylate of 14 parts by weight, 17 parts by weight
Fat alcohol polyethenoxy ether sodium sulfate, the nano-ZnO of 0.6 parts by weight, the silk gum of 1 parts by weight, 0.8 parts by weight polyurethane and 2
The 2,4-DihydroxyBenzophenone of parts by weight, surplus are deionized water.
Under above-mentioned optimum ratio, each raw material cooperation is more particularly suitable, can play to the clothing cleaned through above-mentioned liquid detergent
More preferably decontamination, crease-resistant and anti-shrink effect.
In the application, modified alta-mud is that bentonite is mixed with dodecyl trimethyl ammonium bromide in water, then in micro-
It is modified and obtains under wave atmosphere.There is stronger adsorption capacity, and its to spot, such as grease by modified bentonite
Body can be used as emulsifier, and liquid detergent can be made to form stable dispersion, be conducive to the dirt-removing power for improving liquid detergent.This
Outside, bentonite can also play certain dephosphorization function in liquid detergent.
With can refer to, in the application, the weight ratio of bentonite and dodecyl trimethyl ammonium bromide can be 1:1-1.2,
Such as 1:1,1:1.5 or 1:2.It is contained in cation contained by dodecyl trimethyl ammonium bromide and bentonite by said ratio
Cation ion-exchange reactions occurs, dodecyl trimethyl ammonium bromide ion enters between bentonite bed, increases bentonitic
Interlamellar spacing, the dirt-removing power after raising is bentonite modified.It is worth noting that the amount of dodecyl trimethyl ammonium bromide should not mistake
More, the amount of dodecyl trimethyl ammonium bromide can weaken bentonite suction after being more than bentonitic ion-exchange capacity instead
The effect of attached spot.
With can refer to, in the application, microwave atmosphere refers to that the intensity of microwave irradiation can be 100-120W/g, such as 100-
120W/g, 105W/g, 110W/g, 115W/g or 120W/g.The time of microwave irradiation can be 30-40min, such as 30min,
32min, 34min, 36min, 38min or 40min.After microwave irradiation under above-mentioned microwave atmosphere, bentonite entirety can be improved
Mass transfer velocity, accelerate ion exchange.It is worth noting that the intensity of microwave irradiation and the time of microwave irradiation cannot mistakes
Height, it is excessively high or excessively dry otherwise to will lead to modified alta-mud temperature, destroys ion exchange chemical balance, is unfavorable for adsorbing instead
Spot.
Lauric acid amide of ethanol, fatty acid methyl ester ethoxylate and sodium sulfate of polyethenoxy ether of fatty alcohol are collectively formed
The surfactant component of liquid detergent in the application, three mix according to proportion provided herein, liquid detergent can be made to have
There are good dissolubility and detergency.
In this application, net mainly is formed by the way that chemical crosslink reaction occurs between polyurethane, silk gum and clothes fiber
Shape structure improves the crease-resistant and anti-shrink ability of clothing.Nano-ZnO mainly plays above-mentioned cross-linking reaction urge in this application
Change effect, improves polyurethane, the crosslinking degree of silk gum and clothes fiber at normal temperature.
Preferably, the average grain diameter of the nano-ZnO in the application is no more than 50nm.ZnO under the partial size has biggish
Surface area and catalytic action further increase crease-resistant and other effects.
But cotton class clothing, polyurethane and silk gum are easy that it is made yellowing phenomenon occur, mainly pass through in the application
Nano-ZnO and 2,4 dihydroxyl benzophenone from cleaning process and dry the process mitigation problem.
Itself whiteness with higher of nano-ZnO, can reduce in the process of cleaning polyurethane and silk gum generate it is general
Yellow phenomenon, and then reduce the possibility of clothing yellowing.2,4 dihydroxyl benzophenone can absorb in sunray to colored objects
Harmful ultraviolet light, and be transformed into harmless form and discharge, avoid cotton clothes interior molecules during sunning
Generation yellowing phenomenon is damaged to clothing color through ultraviolet irradiation.
Further, the raw material of liquid detergent may also include the stannous chloride of 0.06-0.08 parts by weight in the application.Dichloride
2,4-DihydroxyBenzophenone can be bonded on clothing by tin and clothes fiber after reacting, and then extend 2,4- dihydroxy two
The action time of Benzophenone is effectively relieved or avoids clothing to generate yellowing phenomenon.
It holds, above-mentioned laundry liquid formulation provided by the present application is reasonable, and cost is relatively low, and dirt-removing power is strong, can not only effectively keep away
Exempt from clothing corrugation to shrink, moreover it is possible to clothing yellowing phenomenon be effectively relieved.
In addition, present invention also provides a kind of preparation methods of above-mentioned liquid detergent, such as it may comprise steps of: by matching
Compare mixed raw material.
When being free of stannous chloride in raw material, i.e. mixed and modified bentonite, lauric acid amide of ethanol, fatty acid according to the ratio
Methyl ester ethoxylates, sodium sulfate of polyethenoxy ether of fatty alcohol, nano-ZnO, silk gum, polyurethane, 2,4 dihydroxyl benzophenone
And deionized water.
When containing stannous chloride in raw material, i.e. mixed and modified bentonite, lauric acid amide of ethanol, fatty acid according to the ratio
Methyl ester ethoxylates, sodium sulfate of polyethenoxy ether of fatty alcohol, nano-ZnO, silk gum, polyurethane, 2,4 dihydroxyl benzophenone,
Stannous chloride and deionized water.
Above-mentioned preparation method provided by the present application is simple and quick, is suitable for industrialized production.
Feature and performance of the invention are described in further detail with reference to embodiments.
Embodiment 1
Contain the coconut oil diethanol acyl of the modified alta-mud of 0.2 parts by weight, 15 parts by weight by the raw material of every 100 parts by weight
Amine, the fatty acid methyl ester ethoxylate of 12 parts by weight, the sodium sulfate of polyethenoxy ether of fatty alcohol of 15 parts by weight, 0.5 parts by weight
Average grain diameter is the nano-ZnO of 50nm, the silk gum of 0.8 parts by weight, the polyurethane of 0.5 parts by weight and the 2,4- bis- of 1 parts by weight
Dihydroxy benaophenonel, surplus are that the ratio of deionized water mixes above-mentioned raw materials, obtain liquid detergent.
Wherein, it is that 1:1 is mixed with dodecyl trimethyl ammonium bromide that modified alta-mud is bentonite by weight in water,
Then it is modified and obtains after irradiating 40min under conditions of microwave irradiation intensity is 100W/g.
Embodiment 2
Contain the coconut oil diethanol acyl of the modified alta-mud of 1 parts by weight, 18 parts by weight by the raw material of every 100 parts by weight
Amine, the fatty acid methyl ester ethoxylate of 15 parts by weight, the sodium sulfate of polyethenoxy ether of fatty alcohol of 20 parts by weight, 1 parts by weight
Nano-ZnO, the silk gum of 1.2 parts by weight, the polyurethane of 0.7 parts by weight and 1.8 parts by weight 2,4-DihydroxyBenzophenone, it is remaining
Amount is that the ratio of deionized water mixes above-mentioned raw materials, obtains liquid detergent.
Wherein, it is that 1:1 is mixed with dodecyl trimethyl ammonium bromide that modified alta-mud is bentonite by weight in water,
Then it is modified and obtains after irradiating 40min under conditions of microwave irradiation intensity is 100W/g.
Embodiment 3
Contain the coconut oil diethanol acyl of the modified alta-mud of 0.4 parts by weight, 16 parts by weight by the raw material of every 100 parts by weight
Amine, the fatty acid methyl ester ethoxylate of 13 parts by weight, the sodium sulfate of polyethenoxy ether of fatty alcohol of 16 parts by weight, 0.6 parts by weight
Nano-ZnO, the silk gum of 0.8 parts by weight, the polyurethane of 0.6 parts by weight and 1.5 parts by weight 2,4-DihydroxyBenzophenone,
Surplus is that the ratio of deionized water mixes above-mentioned raw materials, obtains liquid detergent.
Wherein, it is that 1:1 is mixed with dodecyl trimethyl ammonium bromide that modified alta-mud is bentonite by weight in water,
Then it is modified and obtains after irradiating 40min under conditions of microwave irradiation intensity is 100W/g.
Embodiment 4
Contain the coconut oil diethanol acyl of the modified alta-mud of 0.8 parts by weight, 17 parts by weight by the raw material of every 100 parts by weight
Amine, the fatty acid methyl ester ethoxylate of 13.5 parts by weight, the sodium sulfate of polyethenoxy ether of fatty alcohol of 18 parts by weight, 0.7 weight
Part nano-ZnO, the silk gum of 0.9 parts by weight, the polyurethane of 0.7 parts by weight and 1.8 parts by weight 2,4- dihydroxy hexichol first
Ketone, surplus are that the ratio of deionized water mixes above-mentioned raw materials, obtain liquid detergent.
Wherein, it is that 1:1 is mixed with dodecyl trimethyl ammonium bromide that modified alta-mud is bentonite by weight in water,
Then it is modified and obtains after irradiating 40min under conditions of microwave irradiation intensity is 100W/g.
Embodiment 5
Contain the coconut oil diethanol of the modified alta-mud of 0.6 parts by weight, 16.5 parts by weight by the raw material of every 100 parts by weight
Amide, the fatty acid methyl ester ethoxylate of 14 parts by weight, the sodium sulfate of polyethenoxy ether of fatty alcohol of 17 parts by weight, 0.6 weight
Part nano-ZnO, the silk gum of 1 parts by weight, the polyurethane of 0.8 parts by weight and 2 parts by weight 2,4-DihydroxyBenzophenone, it is remaining
Amount is that the ratio of deionized water mixes above-mentioned raw materials, obtains liquid detergent.
Wherein, it is that 1:1 is mixed with dodecyl trimethyl ammonium bromide that modified alta-mud is bentonite by weight in water,
Then it is modified and obtains after irradiating 40min under conditions of microwave irradiation intensity is 100W/g.
Embodiment 6
Contain the coconut oil diethanol of the modified alta-mud of 0.6 parts by weight, 16.5 parts by weight by the raw material of every 100 parts by weight
Amide, the fatty acid methyl ester ethoxylate of 14 parts by weight, the sodium sulfate of polyethenoxy ether of fatty alcohol of 17 parts by weight, 0.6 weight
Part nano-ZnO, the silk gum of 1 parts by weight, the polyurethane of 0.8 parts by weight, 2 parts by weight 2,4 dihydroxyl benzophenone and
The stannous chloride of 0.06 parts by weight, surplus are that the ratio of deionized water mixes above-mentioned raw materials, obtain liquid detergent.
Wherein, it is that 1:1 is mixed with dodecyl trimethyl ammonium bromide that modified alta-mud is bentonite by weight in water,
Then it is modified and obtains after irradiating 40min under conditions of microwave irradiation intensity is 100W/g.
Embodiment 7
Contain the coconut oil diethanol of the modified alta-mud of 0.6 parts by weight, 16.5 parts by weight by the raw material of every 100 parts by weight
Amide, the fatty acid methyl ester ethoxylate of 14 parts by weight, the sodium sulfate of polyethenoxy ether of fatty alcohol of 17 parts by weight, 0.6 weight
Part nano-ZnO, the silk gum of 1 parts by weight, the polyurethane of 0.8 parts by weight, 2 parts by weight 2,4 dihydroxyl benzophenone and
The stannous chloride of 0.07 parts by weight, surplus are that the ratio of deionized water mixes above-mentioned raw materials, obtain liquid detergent.
Wherein, it is that 1:1 is mixed with dodecyl trimethyl ammonium bromide that modified alta-mud is bentonite by weight in water,
Then it is modified and obtains after irradiating 40min under conditions of microwave irradiation intensity is 100W/g.
Embodiment 8
Contain the coconut oil diethanol of the modified alta-mud of 0.6 parts by weight, 16.5 parts by weight by the raw material of every 100 parts by weight
Amide, the fatty acid methyl ester ethoxylate of 14 parts by weight, the sodium sulfate of polyethenoxy ether of fatty alcohol of 17 parts by weight, 0.6 weight
Part nano-ZnO, the silk gum of 1 parts by weight, the polyurethane of 0.8 parts by weight, 2 parts by weight 2,4 dihydroxyl benzophenone and
The stannous chloride of 0.08 parts by weight, surplus are that the ratio of deionized water mixes above-mentioned raw materials, obtain liquid detergent.
Wherein, it is that 1:1 is mixed with dodecyl trimethyl ammonium bromide that modified alta-mud is bentonite by weight in water,
Then it is modified and obtains after irradiating 40min under conditions of microwave irradiation intensity is 100W/g.
Embodiment 9
The present embodiment and the difference of embodiment 5 are: modified alta-mud be bentonite in water with trimethyl
Ammonium bromide is 1:1.5 mixing by weight, then irradiated under conditions of microwave irradiation intensity is 120W/g it is modified after 35min and
?.
Embodiment 10
The present embodiment and the difference of embodiment 5 are: modified alta-mud be bentonite in water with trimethyl
Ammonium bromide is 1:2 mixing by weight, then irradiated under conditions of microwave irradiation intensity is 110W/g it is modified after 30min and
?.
Embodiment 11
The present embodiment and the difference of embodiment 5 are: the average grain diameter of nano-ZnO is 20nm.
Test example 1
It repeats to implement above-described embodiment 1-11, obtains enough liquid detergents.Control group 1 is set, and control group 1 is washed for standard
Clothing liquid.According to " measurement that GB/T 13174-2008 dress material washes agent detergency and anti-stain redeposition ability by liquid " to reality
It applies a 1-11 and control group carries out detergency detection, the results are shown in Table 1.
1 testing result of table
Comparative example 1-11 and control group 1 can be seen that embodiment 1-11 to JIB-01, JB-02 and JB-03
Clean effect is more excellent compared with the standard liquid detergent of control group 1.
Comparative example 1-5, which can be seen that liquid detergent of the embodiment 5 compared with embodiment 1-4, has more preferably clean effect, says
In bright embodiment 5 in liquid detergent each raw material with comparing embodiment 1-4 more preferably.
Comparative example 5 and embodiment 9-10 can be seen that embodiment 9-10 compared with embodiment 5 clean effect more preferably, say
It is bright to assist liquid detergent that there is stronger clean effect through the modified resulting modified alta-mud of embodiment 9-10.
Test example 2
Control group 2-7 is set, and the content of nano-ZnO, silk gum and polyurethane contained in raw material is respectively such as 2 institute of table
Show.By taking identical cloth as an example, the method on pincher elasticity instrument by " GB/T3819-83 " is to respectively through embodiment 1-5, implementation
The cloth that the liquid detergent of example 11 and control group 2-7 cleaned carries out elastic creasy recovery angle test, and the results are shown in Table 3.
2 component content of table
| Nano-ZnO | Silk gum | Polyurethane | |
| Embodiment 5 | 0.6 | 1 | 0.8 |
| Control group 2 | 0 | 1 | 1.4 |
| Control group 3 | 0 | 1.6 | 0.8 |
| Control group 4 | 1.6 | 0 | 0.8 |
| Control group 5 | 0.6 | 0 | 1.8 |
| Control group 6 | 1.4 | 1 | 0 |
| Control group 7 | 0.6 | 1.8 | 0 |
3 test result of table
| Creasy recovery angle (°) | |
| Embodiment 1 | 270.5 |
| Embodiment 2 | 274.8 |
| Embodiment 3 | 282.4 |
| Embodiment 4 | 286.5 |
| Embodiment 5 | 291.7 |
| Embodiment 11 | 293.3 |
| Control group 2 | 261.1 |
| Control group 3 | 254.0 |
| Control group 4 | 222.5 |
| Control group 5 | 240.8 |
| Control group 6 | 206.7 |
| Control group 7 | 232.5 |
Comparative example 1-5, which can be seen that liquid detergent of the embodiment 5 compared with embodiment 1-4, has the more preferably crease-resistant energy of clothing
Power illustrates the proportion with comparing embodiment 1-4 of each raw material in liquid detergent in embodiment 5 more preferably.Comparative example 5 and embodiment
11, which can be seen that embodiment 11, has more preferably clothing anti-wrinkle effect compared with the liquid detergent of embodiment 5, illustrates being averaged for nano-ZnO
Partial size has a direct impact the clothing anti-wrinkle effect of liquid detergent, and partial size is smaller, and effect is better.
Comparative example 5 and control group 2-7 can be seen that nano-ZnO, silk gum and polyurethane in this application for
The clothing anti-wrinkle effect of liquid detergent has synergistic function.
Test example 3
Control group 8-10 is set, nano-ZnO, 2,4-DihydroxyBenzophenone contained in raw material and stannous chloride
Content difference is as shown in table 4.By taking identical cloth as an example, on WS-SDd/o shape whiteness instrument to respectively through embodiment 1-8 and
The cloth that the liquid detergent of control group 8-10 cleaned measures longitude and latitude whiteness each 3 times, is averaged, the results are shown in Table 5.
4 component content of table
| Nano-ZnO | 2,4 dihydroxyl benzophenone | Stannous chloride | |
| Embodiment 8 | 0.6 | 2 | 0.08 |
| Control group 8 | 0 | 2.6 | 0.08 |
| Control group 9 | 0 | 2 | 0.68 |
| Control group 10 | 2.6 | 0 | 0.08 |
5 measurement result of table
| Whiteness | |
| Embodiment 1 | 76.4 |
| Embodiment 2 | 76.3 |
| Embodiment 3 | 76.6 |
| Embodiment 4 | 76.7 |
| Embodiment 5 | 77.2 |
| Embodiment 6 | 78.2 |
| Embodiment 7 | 78.5 |
| Embodiment 8 | 79.1 |
| Control group 8 | 78.0 |
| Control group 9 | 79.1 |
| Control group 10 | 44.9 |
The liquid detergent that comparative example 1-8 can be seen that embodiment 5 in embodiment 1-5 has the more preferably anti-yellowing of clothing
Ability, embodiment 6-8 have more preferably clothing wrinkling resistance compared with the liquid detergent of embodiment 5, illustrate to contain in liquid detergent raw material
Stannous chloride is not compared with containing the anti-yellowing ability of clothing that can be improved liquid detergent.In embodiment 5 in liquid detergent each raw material proportion
Proportion compared with embodiment 1-4 is more preferably.
Comparative example 8 and control group 8-10 can be seen that nano-ZnO, 2,4-DihydroxyBenzophenone and dichloride
Tin has synergistic function for the clothing anti-wrinkle effect of liquid detergent in this application.
In conclusion the laundry liquid formulation that present pre-ferred embodiments provide is reasonable, cost is relatively low, and dirt-removing power is strong, no
It is only capable of that clothing corrugation is effectively avoided to shrink, moreover it is possible to clothing yellowing phenomenon be effectively relieved.Preparation method can mix above-mentioned according to the ratio
Raw material, it is simple and quick, it is suitable for industrialized production.
Embodiments described above is a part of the embodiment of the present invention, instead of all the embodiments.Reality of the invention
The detailed description for applying example is not intended to limit the range of claimed invention, but is merely representative of selected implementation of the invention
Example.Based on the embodiments of the present invention, obtained by those of ordinary skill in the art without making creative efforts
Every other embodiment, shall fall within the protection scope of the present invention.
Claims (10)
1. a kind of liquid detergent, which is characterized in that according to parts by weight, the raw material of every 100 parts by weight includes changing for 0.2-1 parts by weight
Property bentonite, the lauric acid amide of ethanol of 15-18 parts by weight, the fatty acid methyl ester ethoxylate of 12-15 parts by weight, 15-
The sodium sulfate of polyethenoxy ether of fatty alcohol of 20 parts by weight, the nano-ZnO of 0.5-1 parts by weight, 0.8-1.2 parts by weight silk gum,
The polyurethane of 0.5-0.8 parts by weight and the 2,4-DihydroxyBenzophenone of 1-2 parts by weight, surplus is deionized water；
The modified alta-mud is obtained through dodecyl trimethyl ammonium bromide is modified.
2. liquid detergent according to claim 1, which is characterized in that the raw material of every 100 parts by weight includes 0.4-0.8 weight
Measure the modified alta-mud of part, the lauric acid amide of ethanol of 16-17 parts by weight, 13-14 parts by weight the fat
Sour methyl ester ethoxylates, the sodium sulfate of polyethenoxy ether of fatty alcohol of 16-18 parts by weight, 0.6-0.8 parts by weight it is described
Nano-ZnO, the silk gum of 0.8-1 parts by weight, the polyurethane of 0.6-0.8 parts by weight and 1.5-2 parts by weight it is described
2,4-DihydroxyBenzophenone, surplus are the deionized water.
3. liquid detergent according to claim 2, which is characterized in that the raw material of every 100 parts by weight includes 0.6 parts by weight
The modified alta-mud, the lauric acid amide of ethanol of 16.5 parts by weight, 14 parts by weight the fatty acid methyl ester second
Oxygroup compound, the sodium sulfate of polyethenoxy ether of fatty alcohol of 17 parts by weight, the nano-ZnO of 0.6 parts by weight, 1 parts by weight
The silk gum, the polyurethane of 0.8 parts by weight and the 2,4-DihydroxyBenzophenone of 2 parts by weight, surplus is institute
State deionized water.
4. liquid detergent according to claim 1-3, which is characterized in that the modified alta-mud is existed by bentonite
It is mixed in water with the dodecyl trimethyl ammonium bromide, is then modified and obtains under microwave atmosphere.
5. liquid detergent according to claim 4, which is characterized in that the bentonite and the trimethyl bromination
The weight ratio of ammonium is 1:1-1.2.
6. liquid detergent according to claim 4, which is characterized in that the intensity of microwave irradiation is 100-120W/g.
7. liquid detergent according to claim 4, which is characterized in that the time of microwave irradiation is 30-40min.
8. liquid detergent according to claim 1-3, which is characterized in that the average grain diameter of the nano-ZnO does not surpass
Cross 50nm.
9. liquid detergent according to claim 1-3, which is characterized in that the raw material further includes 0.06-0.08 weight
Measure the stannous chloride of part.
10. such as the preparation method of the described in any item liquid detergents of claim 1-9, which comprises the following steps: by matching
Than mixing the raw material.
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Application publication date: 20181221 |