CN112592774B - Washing gel bead for wool fabric washing and preparation method thereof - Google Patents
Washing gel bead for wool fabric washing and preparation method thereof Download PDFInfo
- Publication number
- CN112592774B CN112592774B CN202011516954.XA CN202011516954A CN112592774B CN 112592774 B CN112592774 B CN 112592774B CN 202011516954 A CN202011516954 A CN 202011516954A CN 112592774 B CN112592774 B CN 112592774B
- Authority
- CN
- China
- Prior art keywords
- washing
- bead
- polyoxyethylene ether
- wool
- isomeric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000005406 washing Methods 0.000 title claims abstract description 93
- 239000011324 bead Substances 0.000 title claims abstract description 81
- 210000002268 wool Anatomy 0.000 title claims abstract description 43
- 239000004744 fabric Substances 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title abstract description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 72
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 66
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 50
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 40
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 27
- 229920000570 polyether Polymers 0.000 claims abstract description 27
- 239000008139 complexing agent Substances 0.000 claims abstract description 25
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims abstract description 23
- 239000000049 pigment Substances 0.000 claims abstract description 23
- 125000005907 alkyl ester group Chemical group 0.000 claims abstract description 21
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims abstract description 21
- GNRKVLMFBDYHJW-UHFFFAOYSA-N 2-(methylamino)ethanol;methyl hydrogen sulfate Chemical compound C[NH2+]CCO.COS([O-])(=O)=O GNRKVLMFBDYHJW-UHFFFAOYSA-N 0.000 claims abstract description 20
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 20
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 20
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 20
- 239000003755 preservative agent Substances 0.000 claims abstract description 19
- 230000002335 preservative effect Effects 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 11
- 239000003899 bactericide agent Substances 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 66
- -1 silver ion compound Chemical class 0.000 claims description 27
- 239000008367 deionised water Substances 0.000 claims description 25
- 229910021641 deionized water Inorganic materials 0.000 claims description 25
- 238000002156 mixing Methods 0.000 claims description 24
- 238000003756 stirring Methods 0.000 claims description 24
- 229920001577 copolymer Polymers 0.000 claims description 23
- 239000007788 liquid Substances 0.000 claims description 17
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 230000002421 anti-septic effect Effects 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 238000007599 discharging Methods 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- 238000004806 packaging method and process Methods 0.000 claims description 8
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 6
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 4
- 229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 4
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 4
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 claims description 4
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 claims description 4
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 claims description 4
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 4
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 claims description 4
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 3
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims description 3
- 229940044120 2-n-octyl-4-isothiazolin-3-one Drugs 0.000 claims description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 3
- 239000000661 sodium alginate Substances 0.000 claims description 3
- 235000010413 sodium alginate Nutrition 0.000 claims description 3
- 229940005550 sodium alginate Drugs 0.000 claims description 3
- 239000000176 sodium gluconate Substances 0.000 claims description 3
- 235000012207 sodium gluconate Nutrition 0.000 claims description 3
- 229940005574 sodium gluconate Drugs 0.000 claims description 3
- ZAWGLAXBGYSUHN-UHFFFAOYSA-M sodium;2-[bis(carboxymethyl)amino]acetate Chemical compound [Na+].OC(=O)CN(CC(O)=O)CC([O-])=O ZAWGLAXBGYSUHN-UHFFFAOYSA-M 0.000 claims description 3
- 239000011975 tartaric acid Substances 0.000 claims description 3
- 235000002906 tartaric acid Nutrition 0.000 claims description 3
- 229960001367 tartaric acid Drugs 0.000 claims description 3
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 claims 2
- 229940087291 tridecyl alcohol Drugs 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 102000004190 Enzymes Human genes 0.000 abstract description 10
- 108090000790 Enzymes Proteins 0.000 abstract description 10
- 238000010006 anti-felting Methods 0.000 abstract description 7
- 239000000835 fiber Substances 0.000 abstract description 5
- 239000006260 foam Substances 0.000 abstract description 5
- 239000007844 bleaching agent Substances 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 11
- 238000009833 condensation Methods 0.000 description 9
- 230000005494 condensation Effects 0.000 description 9
- 239000000126 substance Substances 0.000 description 7
- 239000003599 detergent Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 238000005303 weighing Methods 0.000 description 5
- 239000004902 Softening Agent Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- 239000012752 auxiliary agent Substances 0.000 description 4
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 4
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 239000002216 antistatic agent Substances 0.000 description 3
- 230000001804 emulsifying effect Effects 0.000 description 3
- 238000005538 encapsulation Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000009950 felting Methods 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- KAKVFSYQVNHFBS-UHFFFAOYSA-N (5-hydroxycyclopenten-1-yl)-phenylmethanone Chemical compound OC1CCC=C1C(=O)C1=CC=CC=C1 KAKVFSYQVNHFBS-UHFFFAOYSA-N 0.000 description 1
- VHGFAEBHLBZCIX-UHFFFAOYSA-N 2-dodecylbenzenesulfonate;2-hydroxyethylazanium Chemical compound NCCO.CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O VHGFAEBHLBZCIX-UHFFFAOYSA-N 0.000 description 1
- JFAFIIAJXLHDQH-UHFFFAOYSA-N 2-hydroxyethyl methyl sulfate Chemical compound COS(=O)(=O)OCCO JFAFIIAJXLHDQH-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 208000004350 Strabismus Diseases 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000000022 bacteriostatic agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- BKRJTJJQPXVRRY-UHFFFAOYSA-M dodecyl-(2-hydroxyethyl)-dimethylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CCO BKRJTJJQPXVRRY-UHFFFAOYSA-M 0.000 description 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 1
- CMMAZUPDHKDVOI-UHFFFAOYSA-N ethyl(2-hydroxyethyl)azanium;methyl sulfate Chemical compound CC[NH2+]CCO.COS([O-])(=O)=O CMMAZUPDHKDVOI-UHFFFAOYSA-N 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- BOWVQLFMWHZBEF-KTKRTIGZSA-N oleoyl ethanolamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)NCCO BOWVQLFMWHZBEF-KTKRTIGZSA-N 0.000 description 1
- 150000003961 organosilicon compounds Chemical class 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/043—Liquid or thixotropic (gel) compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
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- Oil, Petroleum & Natural Gas (AREA)
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- Health & Medical Sciences (AREA)
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Abstract
The invention relates to a washing condensing bead for wool fabric washing, which comprises 15-25% of propylene glycol by weight percentage; 5-15% of glycerol; 15-25% of isomeric alcohol polyether; 15-30% of fatty alcohol-polyoxyethylene ether; 8-16% of fatty alcohol-polyoxyethylene ether sodium sulfate; 2-15% of di-fatty alkyl ester hydroxyethyl methyl ammonium methyl sulfate; 2-15% of cocamidopropyl betaine; 0.2-0.5% of diethanolamine; 0.05-0.1% of pH regulator; 0.1-0.5% of a bactericide; 0.005-0.015% of complexing agent; 1% -3% of anti-redeposition agent; 0.03-0.06% of preservative; 1-2.5% of essence; 0.001-0.003% of pigment; and, the balance water. The present invention also relates to a process for the preparation of laundry beads as described above. The laundry beads described herein are free of active enzymes, enzymes and bleach materials, and have suitable ph values, without the problem of poor hand feel caused by damage to the fiber structure of the wool fabric. Moreover, the washing bead has low foam, easy rinsing and good anti-felting performance.
Description
Technical Field
The invention relates to the technical field of detergents and daily chemicals, in particular to a washing gel bead for wool fabric washing and a preparation method thereof.
Background
Laundry beads are household laundry detergent products which have emerged in recent years, are innovative laundry products and are increasingly subjected to the action of squints by young consumers in China. The product is a laundry product which is formed by wrapping highly concentrated laundry detergent, softener and other auxiliary agents by a water-soluble polymer film bag, and is packaged into a bead shape or a bag shape, when the product is used, one laundry detergent, softener and other auxiliary agents are directly put into a washing machine, and the laundry detergent, softener and other auxiliary agents are dissolved in water within 0.5 minute and completely dissolved within 15 minutes, so that 6-14 pieces of laundry can be washed.
In recent years, many researchers in China have studied the formulation of laundry beads to explore its versatility, for example, the domestic invention patent CN108893212B provides a formulation: 46% of fatty alcohol-polyoxyethylene ether, 6% of glycerol, 10% of propylene glycol, 10% of potassium laurate, 10% of fatty acid methyl ester ethoxylate, 8.418% of deionized water, 2% of acrylic acid-acrylate copolymer, 3% of organic silicon compound, 3% of essence, 0.4% of complex enzyme, 0.4% of microcapsule essence, 0.3% of silver ion compound, 0.3% of glutamic acid N, N-acetyl acetic acid tetrasodium, 0.08% of preservative, 0.002% of pigment and 0.1% of citric acid, and the laundry gel bead is efficient, safe, lasting in fragrance, bactericidal and has a softening function; the domestic invention patent CN111234967 provides a formula: 25-35 parts of dodecyl benzene sulfonate, 25-35 parts of dodecyl benzene sulfonic acid monoethanolamine salt, 8-12 parts of oleic acid monoethanolamide polyoxyethylene ether, 3-7 parts of fatty acid methyl ester ethoxylate, 3-7 parts of amine oxide, 1-2 parts of organosilicon compound, 3-7 parts of deionized water, 3-7 parts of propylene glycol, 1-3 parts of anti-redeposition agent, 0.3-0.7 part of triisopropanolamine, 1-2 parts of anti-cross color agent, 1-1.5 parts of bacteriostatic agent, 0.5-1 part of complex enzyme, 0.1-0.5 part of water softener, 0.3-0.6 part of fluorescent whitening agent, 0.05-0.2 part of preservative, 0.05-0.1 part of citric acid and 0.5-1 part of essence and perfume, and the washing coagulant is safe and efficient, the active matter content is high, the stain can be effectively removed, the low foam is easy to rinse, the water resource is not wasted, and meanwhile, the whitening, color cross-linking prevention, sterilization and bacteriostasis effects are realized by adding other auxiliary agents; the domestic invention patent 111471543A provides a formula: 15-25% of propylene glycol, 5-8% of triethanolamine, 15-20% of fatty alcohol polyoxyethylene ether sodium sulfate, 8-10% of fatty acid potassium soap, 10-15% of fatty acid methyl ester ethoxylate, 8-10% of AEO-7, 1-3% of nonionic surfactant Emulgen LS-114, 2-6% of alpha-sulfo fatty acid methyl ester sodium salt, 1.5-3% of dipalmitate ethyl hydroxyethyl ammonium methyl sulfate, 1-1.5% of anti-redeposition agent, 0.5-1% of enzyme preparation and enzyme stabilizer, 1-1.5% of essence, 1-2.5% of removability bactericide, 0.5-1.25% of hydroxyethyl lauryl dimethyl ammonium chloride and the balance of deionized water.
The formulations all contain active enzyme substances, and for washing wool fabrics, the problem of poor hand feeling caused by the fact that the protein fiber structure is gradually damaged after long-time use cannot be met, so that the preparation of the washing gel bead for washing wool fabrics is particularly important.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide a washing gel bead for washing wool fabrics, which can be used for washing wool fabrics, cotton fibers, polyester fibers and the like. The laundry beads described herein have good solubility in water, low gel tendency, and good anti-felting effect. In addition, the laundry beads described herein are free of active enzymes, enzymes and bleach materials, and have suitable ph values, without the problem of poor hand feel caused by damage to the fiber structure of the wool fabric. Moreover, the washing bead has low foam and is easy to rinse.
In one embodiment, the laundry beads provided herein comprise, in mass percent: 15-25% of propylene glycol, 5-15% of glycerol, 5-10% of deionized water, 15-25% of heterogeneous alcohol polyether (XL-80), 15-30% of fatty alcohol-polyoxyethylene ether (AEO-7), 8-16% of fatty alcohol-polyoxyethylene ether sodium sulfate (AES), 2-15% of di-fatty alkyl ester group hydroxyethyl methyl ammonium methyl sulfate, 2-15% of cocamidopropyl betaine, 0.2-0.5% of diethanolamine, 0.05-0.1% of citric acid, 0.1-0.5% of silver ion compound, 0.005-0.015% of complexing agent, 1-3% of acrylic acid-acrylate copolymer, 0.03-0.06% of preservative, 1-2.5% of essence and 0.001-0.003% of pigment.
The application also aims to provide a preparation method of the washing condensation bead for washing the wool fabrics.
In order to achieve the object of the present invention, the present application provides the following technical solutions.
In a first aspect, the present application provides a wool fabric washing laundry bead, characterised in that it comprises, in weight percent:
15-25% of propylene glycol;
5-15% of glycerol;
15-25% of isomeric alcohol polyether;
15% -30% of fatty alcohol-polyoxyethylene ether;
8-16% of fatty alcohol-polyoxyethylene ether sodium sulfate;
2-15% of di-fatty alkyl ester hydroxyethyl methyl ammonium methyl sulfate;
2-15% of cocamidopropyl betaine;
0.2-0.5% of diethanolamine;
0.05-0.1% of pH regulator;
0.1-0.5% of a bactericide;
0.005-0.015% of complexing agent;
1% -3% of anti-redeposition agent;
0.03-0.06% of preservative;
1-2.5% of essence;
0.001-0.003% of pigment;
and, the balance water.
In one embodiment of the first aspect, the isomeric alcohol polyether is an isomeric dodecanol alkoxylate, preferably XL-80;
the fatty alcohol-polyoxyethylene ether is AEO-7;
the pH regulator is citric acid;
the bactericide is a silver ion compound;
the anti-redeposition agent is an acrylic acid-acrylate copolymer;
the water is deionized water.
In one embodiment of the first aspect, the complexing agent is one or more of an aminocarboxylate and a hydroxycarboxylic acid.
In one embodiment of the first aspect, the aminocarboxylate is one or more of sodium aminotriacetate, disodium ethylenediaminetetraacetate, and diethylenetriaminepentacarboxylate;
the hydroxy carboxylate is one or more of tartaric acid, sodium gluconate and sodium alginate.
In one embodiment of the first aspect, the preservative is one or more of 1, 2-benzisothiazolin-3-one, 2-n-octyl-4-isothiazolin-3-one, 2-methyl-4-isothiazolin-3-one, and 5-chloro-2-methyl-4-isothiazolin-3-one.
In one embodiment of the first aspect, the wool washing laundry bead comprises the following components in weight percent: 15% of propylene glycol, 7% of glycerol, 8.984% of deionized water, XL-8020% of heterogeneous alcohol polyether, AEO-716% of fatty alcohol-polyoxyethylene ether, 12% of sodium fatty alcohol-polyoxyethylene ether sulfate, 8% of ammonium bis (fatty alkyl ester) hydroxyethyl methyl sulfate, 8% of cocamidopropyl betaine, 0.2% of diethanolamine, 0.02% of citric acid, 0.25% of silver ion compound, 0.005% of complexing agent, 2.5% of acrylic acid-acrylate copolymer, 0.04% of preservative, 2% of essence and 0.001% of pigment, wherein the sum of the total amount of the components is 100%.
In one embodiment of the first aspect, the wool washing laundry bead comprises the following components in weight percent: 17% of propylene glycol, 5% of glycerol, 8.019% of deionized water, XL-8018% of heterogeneous alcohol polyether, AEO-720% of fatty alcohol-polyoxyethylene ether, 10% of sodium fatty alcohol-polyoxyethylene ether sulfate, 10% of ammonium bis (fatty alkyl ester-hydroxyethyl methyl sulfate), 8% of cocamidopropyl betaine, 0.2% of diethanolamine, 0.02% of citric acid, 0.2% of silver-ion compound, 0.01% of complexing agent, 1.5% of acrylic acid-acrylate copolymer, 0.05% of preservative, 2% of essence and 0.001% of pigment, wherein the sum of the total amount of the components is 100%.
In one embodiment of the first aspect, the wool washing laundry bead comprises the following components in weight percent: 15% of propylene glycol, 7% of glycerol, 8.439% of deionized water, XL-8015% of heterogeneous alcohol polyether, AEO-715% of fatty alcohol-polyoxyethylene ether, 10% of sodium fatty alcohol-polyoxyethylene ether sulfate, 15% of ammonium bis (fatty alkyl ester-hydroxyethyl methyl sulfate), 10% of cocamidopropyl betaine, 0.2% of diethanolamine, 0.02% of citric acid, 0.3% of silver-ion compound, 0.01% of complexing agent, 2% of acrylic acid-acrylate copolymer, 0.03% of preservative, 2% of essence and 0.001% of pigment, wherein the sum of the total amount of the components is 100%.
In a second aspect, the present application provides a method of preparing a wool washing bead according to the first aspect, characterised in that the method comprises the steps of:
(1) at room temperature, adding propylene glycol, glycerol, deionized water, diethanolamine and a complexing agent into a reaction kettle, and mixing and stirring uniformly;
(2) adding isomeric alcohol polyether, fatty alcohol-polyoxyethylene ether sodium sulfate, a softening agent, cocamidopropyl betaine and an anti-redeposition agent, heating to 40-50 ℃, and mixing and stirring uniformly;
(3) cooling to room temperature, adding bactericide, antiseptic, essence and pigment, mixing and stirring;
(4) adjusting the pH value of the reaction system to 7-8 by using a pH regulator, filtering and discharging after physicochemical indexes are qualified to obtain a washing coagulated bead feed liquid;
(5) and adding the obtained washing gel bead material liquid into an automatic washing gel bead packaging machine, and encapsulating by adopting a water-soluble film to obtain the washing gel beads for wool fabric washing.
In one embodiment of the second aspect, the isomeric alcohol polyether is an isomeric dodecanol alkoxylate, preferably XL-80;
the fatty alcohol-polyoxyethylene ether is AEO-7;
the softening agent is di-fatty alkyl ester hydroxyethyl methyl ammonium methyl sulfate;
the pH regulator is citric acid;
the bactericide is a silver ion compound;
the anti-redeposition agent is an acrylic acid-acrylate copolymer;
the water is deionized water.
Compared with the prior art, the invention has the beneficial effects that:
(1) in the formula, the isomeric alcohol polyether (XL-80) with narrow gel zone and good dispersion solubility is compounded with the fatty alcohol-polyoxyethylene ether (AEO-7) and the fatty alcohol-polyoxyethylene ether sodium sulfate (AES), so that the dissolving capacity of the washing gel bead in water is effectively improved, the gel tendency of the washing gel bead is inhibited, and the requirement that the washing gel bead is dissolved when meeting water is met;
(2) the addition of the di-fatty alkyl ester hydroxyethyl methyl ammonium methyl sulfate and the cocamidopropyl betaine in the formula effectively improves the anti-felting performance of the wool fabric;
(3) the laundry bead provided by the invention does not contain active enzyme and bleaching agent substances, has proper pH value, and does not cause the problem of hand feeling deterioration caused by damaging the fiber structure of wool fabric. Moreover, the washing gel bead is low in foam, easy to rinse, strong in detergency and degerming performance, and very suitable for cleaning wool fabrics. However, for some expensive woollen fabrics, it is recommended not to wash with water if particular attention is paid to the prohibition of washing with water.
Detailed Description
In a specific embodiment, the application provides a laundry bead for washing wool fabrics and a preparation method thereof, wherein the laundry bead comprises the following components in percentage by mass: 15-25% of propylene glycol, 5-15% of glycerol, 5-10% of deionized water, 15-25% of heterogeneous alcohol polyether (XL-80), 15-30% of fatty alcohol-polyoxyethylene ether (AEO-7), 8-16% of fatty alcohol-polyoxyethylene ether sodium sulfate (AES), 2-15% of di-fatty alkyl ester group hydroxyethyl methyl ammonium methyl sulfate, 2-15% of cocamidopropyl betaine, 0.2-0.5% of diethanolamine, 0.05-0.1% of citric acid, 0.1-0.5% of silver ion compound, 0.005-0.015% of complexing agent, 1-3% of acrylic acid-acrylate copolymer, 0.03-0.06% of preservative, 1-2.5% of essence and 0.001-0.003% of pigment.
The isomeric alcohol ether (XL-80) is isomeric decyl alcohol alkoxylate, a nonionic surfactant, low foam, easy rinsing, and excellent surface activity, wetting permeability and emulsifying power.
The fatty alcohol-polyoxyethylene ether (AEO-7) has an HLB value of about 12, is a nonionic surfactant, and has good wettability and excellent emulsifying power.
The sodium fatty alcohol polyoxyethylene ether sulfate (AES) is an anionic surfactant, has excellent decontamination, wetting, emulsifying, dispersing and foaming performances, has good biodegradation performance (the degradation degree is 99 percent), and has low irritation to skin and eyes.
The di-fatty alkyl ester hydroxyethyl methyl ammonium methyl sulfate is a novel cationic surfactant, is easy to biodegrade as a softening agent, and is green and environment-friendly.
The cocamidopropyl betaine is an amphoteric surfactant with small irritation and mild performance, can be used as a softening agent and an antistatic agent, can be used together with an anionic surfactant, a cationic surfactant and a nonionic surfactant, and has good compatibility.
The silver ion compound is a green sterilization product which is nontoxic, tasteless, non-irritant and pollution-free, and is harmless to human bodies.
The complexing agent is one or more of amino carboxylate and hydroxy carboxylate; the amino carboxylate is one or more of sodium aminotriacetate, disodium ethylene diamine tetraacetate and diethylenetriamine pentacarboxylate; the hydroxy carboxylate is one or more of tartaric acid, sodium gluconate and sodium alginate.
The acrylic acid-propionate copolymer is an anti-redeposition agent and has excellent scale inhibition and dispersion effects.
The preservative is one or more of 1, 2-benzisothiazolin-3-one (BIT), 2-n-octyl-4-isothiazolin-3-One (OIT), 2-methyl-4-isothiazolin-3-one (MIT) and 5-chloro-2-methyl-4-isothiazolin-3-one (CMIT).
The invention relates to a washing condensation bead for wool fabric washing and a preparation method thereof, which are prepared by the following steps:
(1) at room temperature, adding propylene glycol, glycerol, deionized water, diethanolamine and a complexing agent into a reaction kettle, and mixing and stirring uniformly;
(2) adding isomeric alcohol polyether (XL-80), fatty alcohol-polyoxyethylene ether (AEO-7), fatty alcohol-polyoxyethylene ether sodium sulfate (AES), di-fatty alkyl ester hydroxyethyl methyl ammonium methyl sulfate, cocamidopropyl betaine and acrylic acid-acrylate copolymer, heating to 40-50 ℃, and mixing and stirring uniformly;
(3) cooling to room temperature, adding silver ion compound, antiseptic, essence and pigment, mixing and stirring;
(4) adjusting the pH value to 7-8 by using citric acid, filtering and discharging after the physicochemical indexes are qualified to obtain a washing gel bead material liquid;
(5) adding the obtained washing gel material liquid into an automatic washing gel bead packaging machine, and encapsulating by using a water-soluble film to obtain the washing gel bead.
Examples
The following will describe in detail the embodiments of the present invention, which are implemented on the premise of the technical solution of the present invention, and the detailed embodiments and the specific operation procedures are given, but the scope of the present invention is not limited to the following embodiments.
In the following examples and comparative examples, XL-80 manufacturer was Shanghai Dongda chemical Co., Ltd; the AEO-7 manufacturer is Shanghai Dongda chemical Co., Ltd; SILVER ion compound manufacturer and SILVER-T450, Guangzhou Shengxin chemical technology Limited; complexing agent manufacturers and EDTA-2Na with the brand name of Jinan Zhupu chemical technology Co., Ltd; acrylic acid-acrylate copolymer manufacturers and T-225 of Jinan san and chemical Co., Ltd; the preservative manufacturer and the brand are Kathon of Shandong Xin chemical industry Co., Ltd; the essence manufacturer is Guangdong Fenghao essence Co., Ltd; the pigment manufacturer is Shenzhen chemical technology Limited.
Example 1
The washing condensation bead for washing wool fabrics comprises the following components in percentage by mass:
15% of propylene glycol, 7% of glycerol, 8.984% of deionized water, 20% of isomeric alcohol polyether (XL-80), 16% of fatty alcohol-polyoxyethylene ether (AEO-7), 12% of fatty alcohol-polyoxyethylene ether sodium sulfate (AES), 8% of di-fatty alkyl ester group hydroxyethyl methyl ammonium methyl sulfate, 8% of cocamidopropyl betaine, 0.2% of diethanolamine, 0.02% of citric acid, 0.25% of silver ion compound, 0.005% of complexing agent, 2.5% of acrylic acid-acrylate copolymer, 0.04% of preservative, 2% of essence and 0.001% of pigment. The sum of the total amount of all the components is 100 percent.
A washing condensation bead for wool fabric washing is prepared by the following steps:
(1) weighing the raw materials according to the proportion, adding propylene glycol, glycerol, deionized water, diethanolamine and a complexing agent into a reaction kettle at room temperature, and mixing and stirring uniformly;
(2) adding isomeric alcohol polyether (XL-80), fatty alcohol-polyoxyethylene ether (AEO-7), fatty alcohol-polyoxyethylene ether sodium sulfate (AES), di-fatty alkyl ester hydroxyethyl methyl ammonium methyl sulfate, cocamidopropyl betaine and acrylic acid-acrylate copolymer, heating to 40-50 ℃, and mixing and stirring uniformly;
(3) cooling to room temperature, adding silver ion compound, antiseptic, essence and pigment, mixing and stirring;
(4) adjusting the pH value to 7-8 by using citric acid, filtering and discharging after the physicochemical indexes are qualified to obtain a washing gel bead material liquid;
(5) the obtained washing gel material liquid is added into an automatic washing gel bead packaging machine and is encapsulated by a water-soluble film, so that the washing gel beads according to the embodiment 1 are obtained.
Example 2
The washing condensation bead for wool fabric washing comprises the following components in percentage by mass:
17% of propylene glycol, 5% of glycerol, 8.019% of deionized water, 18% of isomeric alcohol polyether (XL-80), 20% of fatty alcohol-polyoxyethylene ether (AEO-7), 10% of fatty alcohol-polyoxyethylene ether sodium sulfate (AES), 10% of di-fatty alkyl ester group hydroxyethyl methyl ammonium methyl sulfate, 8% of cocamidopropyl betaine, 0.2% of diethanolamine, 0.02% of citric acid, 0.2% of silver ion compound, 0.01% of complexing agent, 1.5% of acrylic acid-acrylate copolymer, 0.05% of preservative, 2% of essence and 0.001% of pigment. The sum of the total amount of all the components is 100 percent.
A wool fabric washing laundry gel bead is prepared by the following steps:
(1) weighing the raw materials of the formula according to the proportion, adding propylene glycol, glycerol, deionized water, diethanolamine and a complexing agent into a reaction kettle at room temperature, and mixing and stirring uniformly;
(2) adding isomeric alcohol polyether (XL-80), fatty alcohol-polyoxyethylene ether (AEO-7), fatty alcohol-polyoxyethylene ether sodium sulfate (AES), di-fatty alkyl ester hydroxyethyl methyl ammonium methyl sulfate, cocamidopropyl betaine and acrylic acid-acrylate copolymer, heating to 40-50 ℃, and mixing and stirring uniformly;
(3) cooling to room temperature, adding silver ion compound, antiseptic, essence and pigment, mixing and stirring;
(4) adjusting the pH value to 7-8 by using citric acid, filtering and discharging after the physicochemical indexes are qualified to obtain a washing gel bead material liquid;
(5) the obtained washing gel material liquid is added into an automatic washing gel bead packaging machine, and a water-soluble film is adopted for encapsulation, so that the washing gel beads according to the embodiment 2 are obtained.
Example 3
The washing condensation bead for wool fabric washing comprises the following components in percentage by mass:
15% of propylene glycol, 7% of glycerol, 8.439% of deionized water, 15% of isomeric alcohol polyether (XL-80), 15% of fatty alcohol-polyoxyethylene ether (AEO-7), 10% of fatty alcohol-polyoxyethylene ether sodium sulfate (AES), 15% of di-fatty alkyl ester group hydroxyethyl methyl ammonium methyl sulfate, 10% of cocamidopropyl betaine, 0.2% of diethanolamine, 0.02% of citric acid, 0.3% of silver ion compound, 0.01% of complexing agent, 2% of acrylic acid-acrylate copolymer, 0.03% of preservative, 2% of essence and 0.001% of pigment. The sum of the total amount of all the components is 100 percent.
A wool fabric washing laundry gel bead is prepared by the following steps:
(1) weighing the raw materials according to the proportion, adding propylene glycol, glycerol, deionized water, diethanolamine and a complexing agent into a reaction kettle at room temperature, and mixing and stirring uniformly;
(2) adding isomeric alcohol polyether (XL-80), fatty alcohol-polyoxyethylene ether (AEO-7), fatty alcohol-polyoxyethylene ether sodium sulfate (AES), di-fatty alkyl ester hydroxyethyl methyl ammonium methyl sulfate, cocamidopropyl betaine and acrylic acid-acrylate copolymer, heating to 40-50 ℃, and mixing and stirring uniformly;
(3) cooling to room temperature, adding silver ion compound, antiseptic, essence and pigment, mixing and stirring;
(4) adjusting the pH value to 7-8 by using citric acid, filtering and discharging after the physicochemical indexes are qualified to obtain a washing gel bead material liquid;
(5) the obtained washing gel material liquid is added into an automatic washing gel bead packaging machine and is encapsulated by a water-soluble film, so that the washing gel beads according to the embodiment 3 are obtained.
Comparative example 1
The washing condensation bead for wool fabric washing comprises the following components in percentage by mass:
20% of propylene glycol, 10% of glycerol, 9.984% of deionized water, 20% of isomeric alcohol polyether (XL-80), 16% of fatty alcohol-polyoxyethylene ether (AEO-7), 12% of fatty alcohol-polyoxyethylene ether sodium sulfate (AES), 4% of di-fatty alkyl ester group hydroxyethyl methyl ammonium methyl sulfate, 3% of cocamidopropyl betaine, 0.2% of diethanolamine, 0.02% of citric acid, 0.25% of silver ion compound, 0.005% of complexing agent, 2.5% of acrylic acid-acrylate copolymer, 0.04% of preservative, 2% of essence and 0.001% of pigment. The sum of the total amount of all the components is 100 percent.
A washing condensation bead for wool fabric washing is prepared by the following steps:
(1) weighing the raw materials according to the proportion, adding propylene glycol, glycerol, deionized water, diethanolamine and a complexing agent into a reaction kettle at room temperature, and mixing and stirring uniformly;
(2) adding isomeric alcohol polyether (XL-80), fatty alcohol-polyoxyethylene ether (AEO-7), fatty alcohol-polyoxyethylene ether sodium sulfate (AES), di-fatty alkyl ester hydroxyethyl methyl ammonium methyl sulfate, cocamidopropyl betaine and acrylic acid-acrylate copolymer, heating to 40-50 ℃, and mixing and stirring uniformly;
(3) cooling to room temperature, adding silver ion compound, antiseptic, essence and pigment, mixing and stirring;
(4) adjusting the pH value to 7-8 by using citric acid, filtering and discharging after the physicochemical indexes are qualified to obtain a washing gel bead material liquid;
(5) the obtained washing gel bead material liquid is added into an automatic washing gel bead packaging machine, and a water-soluble film is adopted for encapsulation, so that the washing gel bead according to the comparative example 1 is obtained.
Comparative example 2
The washing condensation bead for wool fabric washing comprises the following components in percentage by mass:
24% of propylene glycol, 14% of glycerol, 8.439% of deionized water, 15% of isomeric alcohol polyether (XL-80), 15% of fatty alcohol polyoxyethylene ether (AEO-7), 10% of fatty alcohol polyoxyethylene ether sodium sulfate (AES), 5% of di-fatty alkyl ester group hydroxyethyl methyl ammonium methyl sulfate, 4% of cocamidopropyl betaine, 0.2% of diethanolamine, 0.02% of citric acid, 0.3% of silver ion compound, 0.01% of complexing agent, 2% of acrylic acid-acrylate copolymer, 0.03% of preservative, 2% of essence and 0.001% of pigment. The sum of the total amount of all the components is 100 percent.
A wool fabric washing laundry gel bead is prepared by the following steps:
(1) weighing the raw materials according to the proportion, adding propylene glycol, glycerol, deionized water, diethanolamine and a complexing agent into a reaction kettle at room temperature, and mixing and stirring uniformly;
(2) adding isomeric alcohol polyether (XL-80), fatty alcohol-polyoxyethylene ether (AEO-7), fatty alcohol-polyoxyethylene ether sodium sulfate (AES), di-fatty alkyl ester hydroxyethyl methyl ammonium methyl sulfate, cocamidopropyl betaine and acrylic acid-acrylate copolymer, heating to 40-50 ℃, and mixing and stirring uniformly;
(3) cooling to room temperature, adding silver ion compound, antiseptic, essence and pigment, mixing and stirring;
(4) adjusting the pH value to 7-8 by using citric acid, filtering and discharging after the physicochemical indexes are qualified to obtain a washing gel bead material liquid;
(5) the obtained washing gel bead material liquid is added into an automatic washing gel bead packaging machine, and a water-soluble film is adopted for encapsulation, so that the washing gel bead according to the comparative example 2 is obtained.
Performance testing
Detergency tests for laundry beads are described below.
1. Experimental samples: example 1, example 2, example 3 laundry beads prepared in comparative example 1 and comparative example 2.
2. The test method comprises the following steps:
the detergency test was carried out in accordance with the national standard GB/T13174-2008 "determination of detergency and circulating detergency for detergents for clothing".
3. The results of the experiment are shown in Table 1
Table 1: detergency results
As can be seen from the table, the laundry beads of the present invention have good detergency.
The laundry beading wool anti-felting test is described below.
1. Experimental samples: example 1, example 2 and example 3 prepared laundry beads.
2. The experimental method comprises the following steps:
the anti-felting test was carried out according to the national standard FZ/T20024-2012 "wool top felting test Wash method".
3. The results of the experiment are shown in Table 2
| Item | Example 1 | Example 2 | Example 3 | Comparative example 1 | Comparative example 2 |
| Felt reduction/degree | 2.67 | 1.85 | 1.23 | 5.41 | 4.98 |
As can be seen from the table, the softener and the antistatic agent in the laundry bead formulation of the present invention have a significant effect on the wool anti-felting property, and it can be seen from the two comparison results of example 1 and comparative example 1, and example 3 and comparative example 3 that the felting rate is reduced and the anti-felting property becomes better as the amounts of the softener and the antistatic agent are increased.
The embodiments described above are intended to facilitate the understanding and appreciation of the application by those skilled in the art. It will be readily apparent to those skilled in the art that various modifications to these embodiments may be made, and the generic principles defined herein may be applied to other embodiments without the use of inventive faculty. Therefore, the present application is not limited to the embodiments herein, and those skilled in the art who have the benefit of this disclosure will appreciate that many modifications and variations are possible within the scope of the present application without departing from the scope and spirit of the present application.
Claims (7)
1. The washing gel bead for washing wool fabrics is characterized in that the feed liquid of the washing gel bead for washing wool fabrics consists of the following components in percentage by weight:
15-25% of propylene glycol;
5-15% of glycerol;
15-25% of isomeric alcohol polyether;
15-30% of fatty alcohol-polyoxyethylene ether;
8-16% of fatty alcohol-polyoxyethylene ether sodium sulfate;
2-15% of di-fatty alkyl ester hydroxyethyl methyl ammonium methyl sulfate;
2-15% of cocamidopropyl betaine;
0.2-0.5% of diethanolamine;
0.05-0.1% of pH regulator;
0.1-0.5% of a bactericide;
0.005-0.015% of complexing agent;
1% -3% of anti-redeposition agent;
0.03-0.06% of preservative;
1-2.5% of essence;
0.001-0.003% of pigment;
and, the balance water;
the isomeric alcohol polyether is isomeric decyl alcohol alkoxylate;
the fatty alcohol-polyoxyethylene ether is AEO-7.
2. A wool washing laundry bead as claimed in claim 1 wherein said isomeric alcohol polyether is an isomeric tridecyl alcohol alkoxylate of type XL-80;
the pH regulator is citric acid;
the bactericide is a silver ion compound;
the anti-redeposition agent is an acrylic acid-acrylate copolymer;
the water is deionized water.
3. A wool washing bead as claimed in claim 1 or claim 2 wherein the complexing agent is one or more of an aminocarboxylate and a hydroxycarboxylic acid.
4. A wool fabric washing laundry bead as claimed in claim 3 wherein the aminocarboxylate is one or more of sodium aminotriacetate, disodium ethylenediaminetetraacetate and diethylenetriaminepentacarboxylate;
the hydroxy carboxylate is one or more of tartaric acid, sodium gluconate and sodium alginate.
5. A wool washing bead according to claim 1 or claim 2 wherein the preservative is one or more of 1, 2-benzisothiazolin-3-one, 2-n-octyl-4-isothiazolin-3-one, 2-methyl-4-isothiazolin-3-one and 5-chloro-2-methyl-4-isothiazolin-3-one.
6. A process for preparing a wool washing bead according to claim 1, comprising the steps of:
(1) at room temperature, adding propylene glycol, glycerol, deionized water, diethanolamine and a complexing agent into a reaction kettle, and mixing and stirring uniformly;
(2) adding isomeric alcohol polyether, fatty alcohol-polyoxyethylene ether sodium sulfate, di-fatty alkyl ester group hydroxyethyl methyl ammonium methyl sulfate, cocamidopropyl betaine and an anti-redeposition agent, heating to 40-50 ℃, and mixing and stirring uniformly;
(3) cooling to room temperature, adding bactericide, antiseptic, essence and pigment, mixing and stirring;
(4) adjusting the pH value of the reaction system to 7-8 by using a pH regulator, filtering and discharging after the physicochemical indexes are qualified to obtain a washing gel bead material liquid;
(5) and adding the obtained washing gel bead material liquid into a washing gel bead automatic packaging machine, and encapsulating by adopting a water-soluble film to obtain the washing gel bead for washing wool fabrics.
7. The method of claim 6, wherein said isomeric alcohol polyether is isomeric tridecyl alcohol alkoxylate having the formula XL-80;
the pH regulator is citric acid;
the bactericide is a silver ion compound;
the anti-redeposition agent is an acrylic acid-acrylate copolymer;
the water is deionized water.
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| CN113373006A (en) * | 2021-06-08 | 2021-09-10 | 四川海辰日用化工有限公司 | Super-concentrated laundry detergent and preparation method thereof |
| CN114836270B (en) * | 2022-02-24 | 2024-02-23 | 青岛小鹿先生智能科技有限公司 | Machine-washing shoe-washing liquid and preparation method thereof |
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| CN108219993A (en) * | 2018-01-09 | 2018-06-29 | 广州市加茜亚化妆品有限公司 | A kind of micro-perfume capsule liquid detergent and preparation method thereof |
| CN108893212A (en) * | 2018-07-13 | 2018-11-27 | 威莱(广州)日用品有限公司 | A kind of solidifying pearl and preparation method thereof of doing washing |
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| CN106350284A (en) * | 2016-08-23 | 2017-01-25 | 余姚市德派日用品有限公司 | Laundry gel beads for washing real silk fabrics and preparation method of laundry gel beads |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108219993A (en) * | 2018-01-09 | 2018-06-29 | 广州市加茜亚化妆品有限公司 | A kind of micro-perfume capsule liquid detergent and preparation method thereof |
| CN108893212A (en) * | 2018-07-13 | 2018-11-27 | 威莱(广州)日用品有限公司 | A kind of solidifying pearl and preparation method thereof of doing washing |
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