CN113930977A - Antistatic fabric care spray and preparation method thereof - Google Patents

Antistatic fabric care spray and preparation method thereof Download PDF

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Publication number
CN113930977A
CN113930977A CN202111289350.0A CN202111289350A CN113930977A CN 113930977 A CN113930977 A CN 113930977A CN 202111289350 A CN202111289350 A CN 202111289350A CN 113930977 A CN113930977 A CN 113930977A
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percent
antistatic
fabric
spray
care spray
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CN202111289350.0A
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谢辉
高林君
张丽丽
何流
唐涛
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Hefei Junchen Biotechnology Co ltd
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Hefei Junchen Biotechnology Co ltd
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Priority to CN202111289350.0A priority Critical patent/CN113930977A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0059Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • D06N3/009Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin by spraying components on the web
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/04Properties of the materials having electrical or magnetic properties
    • D06N2209/046Anti-static

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses an antistatic fabric care spray and a preparation method thereof, wherein the antistatic fabric care spray comprises the following components in percentage by mass: 0.5-3.0 percent of cationic surfactant, 0.5-5.0 percent of fabric softener, 1.0-5.0 percent of antistatic agent, 0.1-2.0 percent of nonionic surfactant, 0.1-2.0 percent of deodorant, 1.0-10.0 percent of polyol, 0.05-1.0 percent of color fixative, 0.01-1.0 percent of essence and the balance of water; the antistatic care spray for the fabric avoids complicated procedures of cleaning and rinsing by directly spraying the antistatic care spray on the clothes, and simultaneously obtains good antistatic capability and excellent softening performance by compounding the cationic surfactant and the fabric softener, namely compounding the cationic alkyl glycoside with the quaternary ammonium salt cation, and finally obtains colorless transparent liquid which can be directly sprayed and is convenient to use.

Description

Antistatic fabric care spray and preparation method thereof
Technical Field
The invention belongs to the field of fabric care agents, and particularly relates to an antistatic care spray for fabrics and a preparation method thereof.
Background
Static electricity is a charge in a static state. Any two different objects are separated by contact with each other, or contact and rub against each other, and charge transfer and redistribution between the objects occurs, and static electricity is formed when the charges accumulate on or on the objects. In daily life, static electricity is possibly generated at any time and place, and particularly in dry seasons of autumn and winter, the static electricity generated on human bodies and clothes can bring great inconvenience and discomfort to our life. Static electricity generated when fabrics rub with each other can adsorb dust powder and the like in the surrounding environment, so that the attractiveness of clothes is influenced; meanwhile, the long-term static environment can also cause symptoms such as dry skin, pruritus and the like, and seriously harm the human health.
With the continuous development of technology, various new materials appear. The use of synthetic fibers and artificial fibers is more and more frequent, and the popularization of high-grade fabrics such as wool and silk, which are the improvement of living conditions of people, makes the electrostatic phenomenon more and more prominent. Meanwhile, the wearing comfort of clothes is gradually increased, so that the clothes are treated by using a clothes care agent (such as a softener) or a detergent with an antistatic effect to reduce the generation of static electricity on the fabric.
The traditional clothes care agent in the market is added in the post-rinsing process of the clothes washing procedure, so as to achieve the effect of softening the fabric. This operation has certain drawbacks and drawbacks. The washing is more complicated for consumers who are used to hand washing or washing machines which are not provided with a softener box; secondly, a softener is added in the post-rinsing process, and part of consumers can feel that the rinsing is not clean; and thirdly, in the washing process, if the detergent and the softener are added simultaneously, the washing effect is reduced, and the use experience of the product is influenced.
The raw materials of the existing fabric softener are mainly quaternary ammonium salt cations, wherein the fabric softener is widely applied to dioctadecyl dimethyl ammonium chloride, amide ester quaternary ammonium salts, imidazoline quaternary ammonium salts, ester quaternary ammonium salts and the like. Among them, dioctadecyl dimethyl ammonium chloride has excellent softening property, but has the disadvantages of yellowing, low biodegradability and the like; other softening components such as amide ester quaternary ammonium salt, imidazoline quaternary ammonium salt, ester quaternary ammonium salt and the like have the defects of insufficient stability of a product system, poor rewetting performance and the like.
Therefore, a new fabric care agent with environmental friendliness, excellent biodegradability, simple production formula and easy operation, and good antistatic property and softness is needed in the market.
Disclosure of Invention
The invention aims to provide an antistatic fabric care spray which is directly sprayed on clothes through spraying, avoids complex procedures of cleaning and rinsing, and simultaneously obtains good antistatic capability and excellent softening performance through compounding a cationic surfactant and a fabric softener, namely compounding a cationic alkyl glycoside with a quaternary ammonium salt cation, and finally obtains colorless transparent liquid which can be directly sprayed and is convenient to use.
The invention relates to an antistatic fabric care spray, which mainly comprises the following components in percentage by mass: 0.5 to 3.0 percent of cationic surfactant, 0.5 to 5.0 percent of fabric softener, 1.0 to 5.0 percent of antistatic agent, 0.1 to 2.0 percent of nonionic surfactant, 0.1 to 2.0 percent of deodorant, 1.0 to 10.0 percent of polyol, 0.05 to 1.0 percent of color fixative and 65 to 98 percent of deionized water;
the cationic surfactant is cationic alkyl glycoside;
the fabric softener is one or a mixture of more of quaternary ammonium compounds, siloxane derivatives, triethanolamine ester quaternary ammonium salts, imidazoline quaternary ammonium salts, polyquaternium-10, polyquaternium-18 and polyquaternium-22;
the antistatic agent is one or a mixture of more of octadecyl dimethyl hydroxyethyl quaternary ammonium nitrate, nonionic Gemini surfactant, fatty alcohol polyoxyethylene ether phosphate and polyethyleneimine ethoxy compound;
the nonionic surfactant is one or a mixture of more of fatty alcohol-polyoxyethylene ether (7), fatty alcohol-polyoxyethylene ether (9), secondary alcohol-polyoxyethylene ether and alkyl glycoside;
the deodorant is one or a mixture of tea polyphenol and zinc ricinoleate;
the polyalcohol is one or a mixture of more of absolute ethyl alcohol, polyethylene glycol and sorbitol;
the color fixative is one or a mixture of two of vinyl pyrrolidone/vinyl imidazole copolymer and polyvinylpyrrolidone.
Preferably, the antistatic fabric care spray also comprises 0.01-1.0% of essence.
Preferably, the antistatic fabric care spray consists of the following components in percentage by mass: 0.5 to 3.0 percent of cationic surfactant, 0.5 to 5.0 percent of fabric softener, 1.0 to 5.0 percent of antistatic agent, 0.1 to 2.0 percent of nonionic surfactant, 0.1 to 2.0 percent of deodorant, 1.0 to 10.0 percent of polyol, 0.05 to 1.0 percent of color fixative, 0.01 to 1.0 percent of essence and 65 to 98 percent of deionized water.
Preferably, the antistatic fabric care spray consists of the following components in percentage by mass: 0.7 to 2.0 percent of cationic surfactant, 1.0 to 3.0 percent of fabric softener, 1.5 to 4.0 percent of antistatic agent, 0.5 to 1.5 percent of nonionic surfactant, 0.5 to 1.5 percent of deodorant, 3.0 to 6.0 percent of polyol, 0.1 to 0.5 percent of color fixative, 0.01 to 0.5 percent of essence and 75 to 95 percent of deionized water.
The preparation method of the antistatic fabric care spray comprises the following steps of: firstly, fully stirring a cationic surfactant, a fabric softener, an antistatic agent, a nonionic surfactant and polyhydric alcohol to obtain a first mixed solution; then sequentially adding the smell removing agent, the color fixative and the essence in the formula proportion into the first mixed solution, and fully dispersing and stirring to obtain a second mixed solution; then, adding deionized water according to the formula proportion into the second mixed solution, and fully stirring; finally, sieving and filling into a spray bottle.
The antistatic fabric care spray has the beneficial effects that:
1. by adopting the novel cationic alkyl glycoside, the raw material has the advantages of green, low toxicity, small irritation to skin, rapid biodegradation, environmental friendliness and the like of the alkyl glycoside, and has various characteristics of quaternary ammonium salt. Meanwhile, the composition can be compounded and mixed with quaternary ammonium salt cations, and has excellent synergistic performance; and the other components adopted in the invention are all raw materials with excellent performance, low toxicity, low irritation and easy biodegradation.
2. The present invention is very different from conventional laundry care products in practical use. The operation is simple and convenient, the pre-dilution is not needed, and the water can be directly and uniformly sprayed on clothes in a spraying mode.
3. The water-soluble formula has low viscosity and stability, can be used in different seasons, has small foam amount and simple preparation process, and does not need an emulsifier.
4. The formula raw materials are mild, safe, non-irritant and harmless to human bodies and the environment.
5. The method can quickly eliminate the electric charges accumulated on the surface of the clothes, so that the fabric keeps good antistatic performance, has no water mark residue and color change phenomena, and does not affect the fibers and the color of the clothes.
6. Meanwhile, the fabric contains components such as a softener, a deodorant, a color fixative and the like, so that the clothes feel soft after being used, the wrinkles of the fabric are reduced, the peculiar smell is removed, and the long-acting fragrance retention, the clothes protection and the color protection can be realized.
Detailed Description
In order to facilitate the understanding of the technical solutions of the present invention by those skilled in the art, the technical solutions of the present invention will now be further described.
In view of the fact that the softener is mainly used for achieving static electricity removal or static electricity prevention on clothes in a mode of soaking and washing clothes like a laundry detergent in the prior art, the fabric electrostatic nursing spray with good stability and excellent performance is obtained by compounding the conventional common raw materials in the application of the invention.
Based on the technical scheme, two formulas of the antistatic care spray for the fabric are provided below, wherein the mass fraction ranges of the components in each formula are as follows:
an antistatic fabric nursing spray comprises 0.5-3.0% of cationic surfactant, 0.5-5.0% of fabric softener, 1.0-5.0% of antistatic agent, 0.1-2.0% of nonionic surfactant, 0.1-2.0% of deodorant, 1.0-10.0% of polyol, 0.05-1.0% of color fixative, 0.01-1.0% of essence and 65-98% of deionized water.
An antistatic fabric nursing spray comprises 0.7-2.0% of cationic surfactant, 1.0-3.0% of fabric softener, 1.5-4.0% of antistatic agent, 0.5-1.5% of nonionic surfactant, 0.5-1.5% of deodorant, 3.0-6.0% of polyol, 0.1-0.5% of color fixative, 0.01-0.5% of essence and 75-95% of deionized water.
The cationic surfactant is cationic alkyl glycoside.
The fabric softener is one or a mixture of more of quaternary ammonium compounds, siloxane derivatives, triethanolamine ester quaternary ammonium salts, imidazoline quaternary ammonium salts, polyquaternium-10, polyquaternium-18 and polyquaternium-22.
The antistatic agent is one or a mixture of more of octadecyl dimethyl hydroxyethyl quaternary ammonium nitrate, nonionic Gemini surfactant, fatty alcohol polyoxyethylene ether phosphate and polyethyleneimine ethoxy compound.
The nonionic surfactant is one or a mixture of a plurality of fatty alcohol-polyoxyethylene ether (7), fatty alcohol-polyoxyethylene ether (9), secondary alcohol-polyoxyethylene ether and alkyl glycoside.
The smell removing agent is one or the mixture of tea polyphenol and zinc ricinoleate.
The polyalcohol is one or more of anhydrous alcohol, polyethylene glycol and sorbitol.
The color fixative is one or two of vinyl pyrrolidone/vinyl imidazole copolymer and polyvinylpyrrolidone.
A preparation method of antistatic care spray for fabrics comprises the following steps: firstly, fully stirring a cationic surfactant, a fabric softener, an antistatic agent, a nonionic surfactant and polyhydric alcohol to obtain a first mixed solution. Then sequentially adding the smell removing agent, the color fixative and the essence in the formula ratio into the first mixed solution, and fully dispersing and stirring to obtain a second mixed solution; and then, adding deionized water according to the formula proportion into the second mixed solution, and fully stirring. Finally, sieving and filling into a spray bottle.
Based on the above technical solution, several examples of fabric antistatic care spray formulations are provided below:
Figure BDA0003334065480000051
(I) antistatic Property test
According to the determination method in national standard GB/T16801-1997 determination of antistatic performance of fabric conditioner, the antistatic care spray for fabric in the technical scheme of the invention greatly reduces the surface specific resistance (delta rho s) of the fabric after the fabric is treated by the fabric care agent, so the antistatic care spray has good antistatic performance.
(II) rewet Performance test
According to a determination method in national light industry standard QB/T4309-:
Figure BDA0003334065480000052
compared with the similar market competition products, the fabric care agent has the advantages of shorter capillary effect time, good rewetting performance and no influence on the actual wearing experience of consumers.
According to the fabric antistatic care spray disclosed by the technical scheme of the invention, the cationic surfactant alkyl glycoside (CAPG) is compounded with quaternary ammonium salt cations to obtain the fabric antistatic care agent with a water-soluble formula, the fabric antistatic care agent is low in viscosity and stable, can be directly sprayed on clothes without dilution, can effectively improve the generation of fabric surface static electricity, and has the functions of reducing fabric wrinkles, removing peculiar smell, protecting clothes and color, keeping fragrance for a long time and the like.
The antistatic fabric care spray adopts cationic alkyl glycoside, which is a quaternary ammonium salt cationic surfactant prepared by taking nonionic alkyl glycoside as a basic raw material and carrying out quaternization on active groups of the cationic alkyl glycoside or taking glucose as a raw material for direct quaternization. The raw material has the advantages of green and low toxicity of alkyl glycoside, small irritation to skin, quick biodegradation, environmental friendliness and the like, and has various characteristics of quaternary ammonium salt. Meanwhile, the composition can be compounded and mixed with quaternary ammonium salt cations, and has excellent synergistic performance.
Compared with the traditional fabric care product for clothes, the antistatic care spray for the fabric has the advantages that the antistatic care spray for the fabric is greatly different from the traditional fabric care product for the clothes in actual use, the operation is simple and convenient, the pre-dilution is not needed, the antistatic care spray can be directly and uniformly sprayed on the clothes in a spray mode, the care agent is a water-soluble formula, the viscosity is low and stable, the antistatic care spray can be used in different seasons, the foam amount is small, the preparation process is simple, and an emulsifier is not needed. The method can quickly eliminate the electric charges accumulated on the surface of the clothes, so that the fabric keeps good antistatic performance, has no water mark residue and color change phenomena, and does not affect the fibers and the color of the clothes.
The antistatic care spray for the fabric, provided by the technical scheme of the invention, is mild in formula raw materials, safe, free of stimulation and harmless to human bodies and the environment. Meanwhile, the fabric contains components such as a softener, a deodorant, a color fixative and the like, so that the clothes feel soft after being used, the wrinkles of the fabric are reduced, the peculiar smell is removed, and the long-acting fragrance retention, the clothes protection and the color protection can be realized.
Technical solution of the present invention has been described above for exemplary purposes, and it is obvious that the specific implementation of the present invention is not limited by the above-described manner, and it is within the scope of the present invention to employ various insubstantial modifications of the inventive concept and technical solution, or to apply the inventive concept and technical solution to other fields without any modification.

Claims (5)

1. An antistatic fabric care spray is characterized by mainly comprising the following components in percentage by mass: 0.5 to 3.0 percent of cationic surfactant, 0.5 to 5.0 percent of fabric softener, 1.0 to 5.0 percent of antistatic agent, 0.1 to 2.0 percent of nonionic surfactant, 0.1 to 2.0 percent of deodorant, 1.0 to 10.0 percent of polyol, 0.05 to 1.0 percent of color fixative and 65 to 98 percent of deionized water;
the cationic surfactant is cationic alkyl glycoside;
the fabric softener is one or a mixture of more of quaternary ammonium compounds, siloxane derivatives, triethanolamine ester quaternary ammonium salts, imidazoline quaternary ammonium salts, polyquaternium-10, polyquaternium-18 and polyquaternium-22;
the antistatic agent is one or a mixture of more of octadecyl dimethyl hydroxyethyl quaternary ammonium nitrate, nonionic Gemini surfactant, fatty alcohol polyoxyethylene ether phosphate and polyethyleneimine ethoxy compound;
the nonionic surfactant is one or a mixture of more of fatty alcohol-polyoxyethylene ether (7), fatty alcohol-polyoxyethylene ether (9), secondary alcohol-polyoxyethylene ether and alkyl glycoside;
the deodorant is one or a mixture of tea polyphenol and zinc ricinoleate;
the polyalcohol is one or a mixture of more of absolute ethyl alcohol, polyethylene glycol and sorbitol;
the color fixative is one or a mixture of two of vinyl pyrrolidone/vinyl imidazole copolymer and polyvinylpyrrolidone.
2. The fabric antistatic spray of claim 1, further comprising 0.01% -1.0% of a perfume.
3. The antistatic fabric care spray as claimed in claim 2, is characterized by comprising the following components in percentage by mass: 0.5 to 3.0 percent of cationic surfactant, 0.5 to 5.0 percent of fabric softener, 1.0 to 5.0 percent of antistatic agent, 0.1 to 2.0 percent of nonionic surfactant, 0.1 to 2.0 percent of deodorant, 1.0 to 10.0 percent of polyol, 0.05 to 1.0 percent of color fixative, 0.01 to 1.0 percent of essence and 65 to 98 percent of deionized water.
4. The antistatic fabric care spray as claimed in claim 3, is characterized by comprising the following components in percentage by mass: 0.7 to 2.0 percent of cationic surfactant, 1.0 to 3.0 percent of fabric softener, 1.5 to 4.0 percent of antistatic agent, 0.5 to 1.5 percent of nonionic surfactant, 0.5 to 1.5 percent of deodorant, 3.0 to 6.0 percent of polyol, 0.1 to 0.5 percent of color fixative, 0.01 to 0.5 percent of essence and 75 to 95 percent of deionized water.
5. A method for preparing an antistatic care spray for fabrics, which is characterized in that the antistatic care spray for fabrics as claimed in any one of claims 1 to 4 is prepared according to the following steps: firstly, fully stirring a cationic surfactant, a fabric softener, an antistatic agent, a nonionic surfactant and polyhydric alcohol to obtain a first mixed solution; then sequentially adding the smell removing agent, the color fixative and the essence in the formula proportion into the first mixed solution, and fully dispersing and stirring to obtain a second mixed solution; then, adding deionized water according to the formula proportion into the second mixed solution, and fully stirring; finally, sieving and filling into a spray bottle.
CN202111289350.0A 2021-11-02 2021-11-02 Antistatic fabric care spray and preparation method thereof Pending CN113930977A (en)

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CN114411420B (en) * 2022-01-24 2023-12-15 威莱(广州)日用品有限公司 Transparent antibacterial softener and preparation method thereof

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