CN102206558A - Environmental-friendly cleaning agent containing cationic alkyl polyglucoside - Google Patents
Environmental-friendly cleaning agent containing cationic alkyl polyglucoside Download PDFInfo
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- CN102206558A CN102206558A CN2011100947953A CN201110094795A CN102206558A CN 102206558 A CN102206558 A CN 102206558A CN 2011100947953 A CN2011100947953 A CN 2011100947953A CN 201110094795 A CN201110094795 A CN 201110094795A CN 102206558 A CN102206558 A CN 102206558A
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Abstract
The invention relates to an environmental-friendly cleaning agent containing cationic alkyl polyglucoside. The environmental-friendly cleaning agent containing the cationic alkyl polyglucoside is characterized by being prepared by taking the CAPG (Cationic Alkyl Polyglucoside) as a main surface active agent and blending with green surface active agents, i.e. nonionic APG (Alkyl Polyglucoside), fatty acid MES (Methyl Ester Sulfonate), a succinic acid ester nonionic Gemini surface active agent (AEO9-SA-AEO9), and green auxiliary agents, i.e. sodium citrate, sodium gluconate, bentonite, and the like. According to the invention, the cleaning property is enhanced through the cooperative and synergistic action of the various surface active agents by adopting an anionic-cationic-nonionic surface active agent blending system supplemented by an efficient Gemini surface active agent, the using amount of the cleaning agent can be reduced under the condition of achieving same cleaning effect and the environmental friendliness is obtained; and in addition, the environmental-friendly cleaning agent disclosed by the invention can be used for cleaning tableware and fruits, also be used for cleaning doors, windows, glasses, clothes, mechanical equipment and precise instruments and also be used for cleaning heavy oil stains and the like.
Description
Technical field
The present invention relates to a kind of clean-out system, be specially a kind of environment-friendly cleaning agent of cation alkyl glycoside.
Background technology
Clean decontamination process and be actually a complex physicochemical process, under the effect of mechanical force, clean-out system is washed the lip-deep water-soluble dirt (sugar of matrix (hard surface or all kinds of fabric) with being adsorbed on, starch, fruit juice, organic acids and base, blood, protein and inorganic salt etc.) and water-insoluble dirt (animal-plant oil, Fatty Alcohol(C12-C14 and C12-C18), mineral oil and oxide compound thereof, cigarette ash, dust, metal oxide etc.) physicochemical change of a series of complexity of generation on the interface, thereby finish cleaning, clean-out system to dirt by sticking, wetting, emulsification, disperse, effects such as solubilising, dirt is hightailed washed matrix surface, be suspended in the scavenging solution, remove by rinsing, finish cleaning process.Clean-out system commonly used has individual common characteristic to be processed by tensio-active agent and additive compound exactly, wherein tensio-active agent has hydrophilic, lipophilic amphiphilic nature, can dirt is wetting, infiltration, and the external force effect such as scrub by means of kneading and make dirt emulsification, be dispersed in the detergent solution, and then reach soil-removing action.Therefore we can say that the performance of tensio-active agent has directly reflected the quality of clean-out system, the security of its biological degradability and degraded product and to the pungency of skin is directly connected to the ecotope and the use properties of washing composition.
At present, the tensio-active agent that clean-out system adopted is mainly linear alkylbenzene sulphonic acid (LAS), poly alkyl alcohol ether sulfate (AES), fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene etc., auxiliary agent adopts tripoly phosphate sodium STPP (STPP), sodium ethylene diamine tetracetate (EDTA) etc., has also added some solvents in the formula for a product that has.At first, these materials may cause human body generation anaphylaxis, and improper use has the possibility that causes allergic dermatitis and eczema, and the short-term health problem that can cause is as stimulating eyes, cough, vomiting, diarrhoea etc.; Clean-out system residual accumulated over a long period, and can see through skin and inhale, and invading behind the human body can the infringement lymphsystem, causes that resistance of human body descends the long-term health problem that can cause such as the damage of liver or kidney, pulmonary emphysema, brain injury, cancer etc.Secondly, because clean-out system just directly has been discharged in the environment after using, this will cause wherein phosphorous assistant can cause the eutrophication of water body, and the tensio-active agent in the clean-out system mostly biological degradability be not fine, be discharged in the environment and will cause biological hazard, cause the environment negative impact.In addition, it is not very good that also there is cleaning performance in present rinse product, the shortcoming that the clean-out system usage quantity is bigger.
Summary of the invention
The purpose of this invention is to provide a kind of without phosphorus, organic solvent-free, to human temperature and, non-stimulated, have fewer environmental impacts, and have the environment-friendly cleaning agent of the cation alkyl glycoside of better use properties.It is characterized in that with CAPG (CAPG) be the major surfaces promoting agent, composite with green surfactant nonionic alkyl glycoside (APG), fatty acid methyl ester sulfonate (MES), succinate nonionic Gemini tensio-active agent (AEO
9-SA-AEO
9) and green auxiliary agent Trisodium Citrate, Sunmorl N 60S, wilkinite etc. and make, this clean-out system can be used as the cleaning of tableware, fruit, can also be used for the cleaning of door and window, glass, clothing, mechanical means, precision instrument, also can be used for the dirty cleaning of heavy oil.
The technical scheme of this invention is specific as follows:
With a certain amount of wilkinite of crossing through acidification (about 200 orders), join in the reactor that fills a certain amount of deionized water, high-speed stirring after waiting to become gel, adds CAPG (CAPG), succinate nonionic Gemini tensio-active agent (AEO respectively successively
9-SA-AEO
9), nonionic alkyl glycoside (APG), fatty acid methyl ester sulfonate (MES), Trisodium Citrate and Sunmorl N 60S, the control stir speed (S.S.) prevents that a large amount of foams from producing, temperature is controlled at 55 ℃, continues to stir 60～120min, is cooled to the environment-friendly cleaning agent that room temperature gets the cation alkyl glycoside.
The following component that has of described this clean-out system makes, and each component is mass percent:
The CAPG (CAPG) that described this clean-out system uses has following structure:
The succinate nonionic Gemini tensio-active agent (AEO that described this clean-out system uses
9-SA-AEO
9) have a following structure:
The present invention has following outstanding advantage and positively effect:
1, this clean-out system raw material is made by the natural reproducible plant, biodegradability is good, to human temperature and, pungency is low, and not phosphorous and organic solvent had overcome when clean-out system used in the past the bad ecological pollution problem that causes of injury, body eutrophication and the biological degradability of human body.
2, this cleaning agent formula employing CAPG is the major surfaces promoting agent, makes it to have concurrently sterilization, antibacterial antiseptic property, need not additionally add sterilization bacteriostat and sanitas etc. again in the clean-out system.
3, added nonionic Gemini tensio-active agent in this cleaning agent formula, improved its surfactivity, reduced the solution surface tension ability and significantly improve.And dissolution in low temperature that nonionic Gemini tensio-active agent is good and moisture dispersibility energy improve the low temperature use properties of product.
4, male-female-nonionogenic tenside compound system has been adopted in the design of this cleaning agent formula, and be aided with Gemini tensio-active agent efficiently, by each tensio-active agent synergistic function, improved cleaning performance, reaching under the situation of identical cleaning performance, can reduce the usage quantity of clean-out system.And cats product and Gemini tensio-active agent have been realized newly the putting into practice of cleaning agent formula, new breakthrough as the principal constituent of clean-out system in this prescription, have represented a kind of new direction of clean-out system.
Embodiment
Provide embodiments of the invention and preparation method below.
The environment-friendly cleaning agent of a kind of cation alkyl glycoside of the present invention comprises following component by massfraction:
Embodiment 1:
The environment-friendly cleaning agent of 100kg cation alkyl glycoside comprises following component:
Embodiment 2:
The environment-friendly cleaning agent of 100kg cation alkyl glycoside comprises following component:
Embodiment 3:
The environment-friendly cleaning agent of 100kg cation alkyl glycoside comprises following component:
Its preparation method is: with a certain amount of wilkinite of crossing through acidification (about 200 orders), join in the reactor that fills a certain amount of deionized water, high-speed stirring, after waiting to become gel, add CAPG (CAPG), succinate nonionic Gemini tensio-active agent (AEO successively respectively
9-SA-AEO
9), nonionic alkyl glycoside (APG), fatty acid methyl ester sulfonate (MES), Trisodium Citrate and Sunmorl N 60S, the control stir speed (S.S.) prevents that a large amount of foams from producing, temperature is controlled at 55 ℃, continues to stir 60～120min, is cooled to room temperature and gets product.This clean-out system can be used as the cleaning of tableware, fruit, can also be used for the cleaning of door and window, glass, clothing, mechanical means, precision instrument, also can be used for the dirty cleaning of heavy oil.
Claims (4)
1. the environment-friendly cleaning agent of a cation alkyl glycoside, it is characterized in that with CAPG (CAPG) be the major surfaces promoting agent, composite with green surfactant nonionic alkyl glycoside (APG), fatty acid methyl ester sulfonate (MES), succinate nonionic Gemini tensio-active agent (AEO
9-SA-AEO
9) and green auxiliary agent Trisodium Citrate, Sunmorl N 60S, wilkinite etc. and make.
2. according to the environment-friendly cleaning agent of the described a kind of cation alkyl glycoside of claim 1, it is characterized in that the following component of having of this clean-out system makes, each component is mass percent:
3. according to the environment-friendly cleaning agent of the described a kind of cation alkyl glycoside of claim 1, it is characterized in that the CAPG (CAPG) that uses has following structure:
4. according to the environment-friendly cleaning agent of the described a kind of cation alkyl glycoside of claim 1, it is characterized in that the succinate nonionic Gemini tensio-active agent (AEO that uses
9-SA-AEO
9) have a following structure:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110094795A CN102206558B (en) | 2011-04-15 | 2011-04-15 | Environmental-friendly cleaning agent containing cationic alkyl polyglucoside |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110094795A CN102206558B (en) | 2011-04-15 | 2011-04-15 | Environmental-friendly cleaning agent containing cationic alkyl polyglucoside |
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| Publication Number | Publication Date |
|---|---|
| CN102206558A true CN102206558A (en) | 2011-10-05 |
| CN102206558B CN102206558B (en) | 2012-09-19 |
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|---|---|---|---|
| CN201110094795A Expired - Fee Related CN102206558B (en) | 2011-04-15 | 2011-04-15 | Environmental-friendly cleaning agent containing cationic alkyl polyglucoside |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103820805A (en) * | 2012-11-16 | 2014-05-28 | 季爱英 | Rust removal cleaning agent |
| CN104031781A (en) * | 2014-06-17 | 2014-09-10 | 顾兴 | Detergent for precise instrument |
| CN104825093A (en) * | 2015-04-30 | 2015-08-12 | 威莱(广州)日用品有限公司 | Non-marking glass cleaning wet tissue and preparation method for same |
| CN105368587A (en) * | 2015-11-19 | 2016-03-02 | 深圳市天得一环境科技有限公司 | Touch screen water-based cleaning agent composition and use method thereof |
| CN105385509A (en) * | 2015-11-30 | 2016-03-09 | 成都九十度工业产品设计有限公司 | Concentrated type laundry detergent |
| CN105505613A (en) * | 2015-11-30 | 2016-04-20 | 成都九十度工业产品设计有限公司 | Laundry detergent |
| CN105505641A (en) * | 2015-11-30 | 2016-04-20 | 成都九十度工业产品设计有限公司 | Efficient liquid detergent |
| CN105543001A (en) * | 2015-12-16 | 2016-05-04 | 安徽强英鸭业集团有限公司 | Duck hatching egg cleaning agent and its preparation method and use |
| CN106957746A (en) * | 2017-03-07 | 2017-07-18 | 广州小蜜蜂生物科技有限公司 | Baby's pro-skin plant liquid detergent |
| CN109022168A (en) * | 2018-10-10 | 2018-12-18 | 成都创巨油气工程技术有限公司 | A kind of cleaning agent and preparation method thereof for the pit shaft containing greasy dirt |
| CN111529425A (en) * | 2020-07-01 | 2020-08-14 | 广东润和新材料科技有限公司 | Disinfectant hand sanitizer for engine room and preparation method thereof |
| CN113930977A (en) * | 2021-11-02 | 2022-01-14 | 合肥钧辰生物科技有限公司 | Antistatic fabric care spray and preparation method thereof |
| CN114752942A (en) * | 2022-04-29 | 2022-07-15 | 泰伦特生物工程股份有限公司 | Industrial cleaning agent containing gemini surfactant and preparation method thereof |
| CN115975736A (en) * | 2023-01-06 | 2023-04-18 | 上海拓纳化学新材料有限公司 | Non-solvent water-based clay cylinder cleaning assistant, preparation method and application thereof |
-
2011
- 2011-04-15 CN CN201110094795A patent/CN102206558B/en not_active Expired - Fee Related
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103820805A (en) * | 2012-11-16 | 2014-05-28 | 季爱英 | Rust removal cleaning agent |
| CN104031781A (en) * | 2014-06-17 | 2014-09-10 | 顾兴 | Detergent for precise instrument |
| CN104825093A (en) * | 2015-04-30 | 2015-08-12 | 威莱(广州)日用品有限公司 | Non-marking glass cleaning wet tissue and preparation method for same |
| CN105368587A (en) * | 2015-11-19 | 2016-03-02 | 深圳市天得一环境科技有限公司 | Touch screen water-based cleaning agent composition and use method thereof |
| CN105368587B (en) * | 2015-11-19 | 2018-02-06 | 深圳市天得一环境科技有限公司 | Touch-screen water-base cleaning agent composition and its application method |
| CN105385509A (en) * | 2015-11-30 | 2016-03-09 | 成都九十度工业产品设计有限公司 | Concentrated type laundry detergent |
| CN105505613A (en) * | 2015-11-30 | 2016-04-20 | 成都九十度工业产品设计有限公司 | Laundry detergent |
| CN105505641A (en) * | 2015-11-30 | 2016-04-20 | 成都九十度工业产品设计有限公司 | Efficient liquid detergent |
| CN105543001B (en) * | 2015-12-16 | 2018-05-25 | 安徽强英鸭业集团有限公司 | A kind of duck hatching egg cleaning agent and its preparation method and application |
| CN105543001A (en) * | 2015-12-16 | 2016-05-04 | 安徽强英鸭业集团有限公司 | Duck hatching egg cleaning agent and its preparation method and use |
| CN106957746A (en) * | 2017-03-07 | 2017-07-18 | 广州小蜜蜂生物科技有限公司 | Baby's pro-skin plant liquid detergent |
| CN109022168A (en) * | 2018-10-10 | 2018-12-18 | 成都创巨油气工程技术有限公司 | A kind of cleaning agent and preparation method thereof for the pit shaft containing greasy dirt |
| CN111529425A (en) * | 2020-07-01 | 2020-08-14 | 广东润和新材料科技有限公司 | Disinfectant hand sanitizer for engine room and preparation method thereof |
| CN113930977A (en) * | 2021-11-02 | 2022-01-14 | 合肥钧辰生物科技有限公司 | Antistatic fabric care spray and preparation method thereof |
| CN114752942A (en) * | 2022-04-29 | 2022-07-15 | 泰伦特生物工程股份有限公司 | Industrial cleaning agent containing gemini surfactant and preparation method thereof |
| CN114752942B (en) * | 2022-04-29 | 2023-09-22 | 泰伦特生物工程股份有限公司 | Industrial cleaning agent containing gemini structure surfactant and preparation method thereof |
| CN115975736A (en) * | 2023-01-06 | 2023-04-18 | 上海拓纳化学新材料有限公司 | Non-solvent water-based clay cylinder cleaning assistant, preparation method and application thereof |
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|---|---|
| CN102206558B (en) | 2012-09-19 |
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