CN109042701A - A kind of rosickyite azoles and the bactericidal composition of trifloxystrobin and application thereof for preventing and treating Cucumber Target Leaf Spot - Google Patents
A kind of rosickyite azoles and the bactericidal composition of trifloxystrobin and application thereof for preventing and treating Cucumber Target Leaf Spot Download PDFInfo
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- CN109042701A CN109042701A CN201811103670.0A CN201811103670A CN109042701A CN 109042701 A CN109042701 A CN 109042701A CN 201811103670 A CN201811103670 A CN 201811103670A CN 109042701 A CN109042701 A CN 109042701A
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- Prior art keywords
- trifloxystrobin
- rosickyite azoles
- leaf spot
- target leaf
- bactericidal composition
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/18—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
Abstract
The invention belongs to technical field of pesticide, more particularly to the bactericidal composition of a kind of the rosickyite azoles for preventing and treating Cucumber Target Leaf Spot and trifloxystrobin, it is prepared from the following raw materials: accounting for the water of the active constituent of composition weight 5% to 50%, the wetting dispersing agent for accounting for composition weight 2% to 6%, the thickener for accounting for composition weight 0.1% to 0.4%, the antifreezing agent for accounting for composition weight 3% to 5%, the defoaming agent for accounting for composition weight 0.4% to 0.6% and surplus, the active constituent is the mixture of rosickyite azoles and trifloxystrobin.Rosickyite azoles used in the present invention is absorbability rosickyite azoles fungicide, and trifloxystrobin is fungicides, and mutual mixture will not generate low touching, can be synergistic, i.e., the activity of mixture reduces dosage, slowing down resistance reduces cost greater than the activity of independent component.
Description
Technical field
The invention belongs to technical field of pesticide, it is related to a kind of for preventing and treating the pharmaceutical agent combinations of agricultural disease, relates more specifically to
Pharmaceutical agent combinations are configured to suspending agent, the prevention and treatment of Cucumber Target Leaf Spot in agricultural production.
Background technique
Cucumber Target Leaf Spot loses day mainly by a kind of microbial fungal disease of miliary damping-off caused by cucumber production
It is beneficial serious, the underproduction 20% is often resulted in, 70% is reached when serious.Often endanger melon and fruit class, greengrocery industrial crops and flowers lawn etc.
Vegetation is common one of the fungal disease of crop.Mostly fall ill since cucumber contains the melon phase, in, lower blade first fall ill, upwards
Development.Initial stage bears taupe fleck on blade face, is gradually extended to the circle to differ in size or subcircular edge is less neat
Filbert or brown scab.8 ~ 15 millimeters of scab majority diameter, small 3 ~ 5 millimeters, big 20 ~ 25 millimeters.In later period scab
Portion's lighter is in canescence, edge taupe sometimes.Sparse ficelle mustiness is given birth in scab front and back when humidity is big
Object.Sometimes scab blends, and blade is withered and yellow.Also it will appear the taupe scab of ellipse when severe disease, in vines and petiole.
2012, Guizhou road member biology plant pesticide research institute joint Beijing University of Chinese Medicine expert, Nanjing agriculture were big
It learns expert and beneficial one hundred pharmacy Miao Yao R&D team successfully develops the innovative green bactericide of rosickyite azoles.Rosickyite azoles (albendazole) is
A kind of people's insecticide sterilization component, mixed morbidities a variety of to plant are harmful and pathogenic infection has inhibiting effect.Belong to absorbability third
Sulphur azole a new generation disinfectant use in agriculture has prevention & protection, interior suction treatment, infiltration conduction.Wide sterilization spectrum has stronger
The complementarity of the mode of action and bioactivity.For efficient, less toxic, real wide spectrum systemic fungicide, it may have activity is high, holds
The feature that the effect phase is long, absorbability is strong, spraying time is flexible, it pair brown spot have favorable effect.
Trifloxystrobin class wide-spectrum bactericide be from natural products Strobilurins as fungicide lead compound successfully
A new class of fungicides of exploitation.With efficient, wide spectrum, protection, treats, roots out, permeates, the punching of systemic activity, resistance to rainwater
The characteristics such as brush, lasting period length.To Isosorbide-5-Nitrae-demethylation enzyme inhibitor, benzamides, dicarboxyl amine and benzimidazole are generated
The bacterial strain of resistance is effective, with current existing fungicide no interactions resistance.To nearly all Mycophytes (Ascomycetes, Basidiomycetes,
Oomycete and Fungi Imperfecti) disease such as powdery mildew, rust, Ying's blight, net blotch, downy mildew, rice blast etc. has good work
Property.In addition to having special efficacy to powdery mildew, leaf spot, have well to rust, downy mildew, damping-off, apple apple scab, sclerotinia sclerotiorum
Activity.To crop safety, because it is capable of being fast degraded in soil, water, thus it is environmentally safe.Due to trifloxystrobin have wide spectrum,
Infiltration, the quickly performances such as distribution, crop absorb that fast, it is with upward absorbability in addition, therefore resistance of rainwater washing against performance is good, holding effect
Phase is long, therefore is considered as second generation methoxy acrylic bactericide.
But either rosickyite azoles or trifloxystrobin single dose be in use, the control efficiency for Cucumber Target Leaf Spot is significant,
Apparent preventive and therapeutic effect is not had.And the generation of Cucumber Target Leaf Spot and harm have chronicity, fulminant, popularity and variability
The features such as, germ can be with upper air current long-distance communications.Its effective prevention and control is long-term technical problem, causes the countries concerned of the world
And its extensive concern of international organization.Therefore, rosickyite azoles or trifloxystrobin answering in terms of preventing and treating Cucumber Target Leaf Spot are further studied
With being of great significance.
Summary of the invention
In view of this, the object of the present invention is to provide the sterilization groups of a kind of the rosickyite azoles for preventing and treating Cucumber Target Leaf Spot and trifloxystrobin
Object and application thereof is closed, to solve the technical problem that current Cucumber Target Leaf Spot is difficult to long control.
The present invention solves above-mentioned technical problem by the following technical programs:
A kind of bactericidal composition of rosickyite azoles that preventing and treating Cucumber Target Leaf Spot and trifloxystrobin, is prepared from the following raw materials: accounting for composition
The active constituent of weight 5% to 50%, accounts for composition weight 0.1% to 0.4% at the wetting dispersing agent for accounting for composition weight 2% to 6%
Thickener, the antifreezing agent for accounting for composition weight 3% to 5%, the defoaming agent for accounting for composition weight 0.4% to 0.6% and surplus water,
The active constituent is the mixture of rosickyite azoles and trifloxystrobin, and the weight ratio of rosickyite azoles and trifloxystrobin is (1 ~ 4): (1 ~ 4).
The weight ratio of the rosickyite azoles and trifloxystrobin is (1 ~ 2): (1 ~ 4).
The weight ratio of the rosickyite azoles and trifloxystrobin is 1:2.
The wetting dispersing agent is agriculture breast 600-1.
The thickener is xanthan gum.
The antifreezing agent is ethylene glycol.
The defoaming agent is methanol.
The rosickyite azoles of the prevention and treatment Cucumber Target Leaf Spot and the bactericidal composition of trifloxystrobin, are main with rosickyite azoles and trifloxystrobin
Effective component and insecticides adjuvant, excipients are configured to any one dosage form allowed on pesticide.
The dosage form of the bactericidal composition is suspending agent.
The rosickyite azoles of the prevention and treatment Cucumber Target Leaf Spot and the bactericidal composition of trifloxystrobin prevent and treat fungal diseases of plants in preparation
Application on germ killing drugs.
The rosickyite azoles of the prevention and treatment Cucumber Target Leaf Spot and the bactericidal composition of trifloxystrobin are preparing Cucumber Target Leaf Spot bactericide
Application on object.
The beneficial effects of the present invention are:
Firstly, rosickyite azoles used in the present invention is absorbability rosickyite azoles fungicide, trifloxystrobin is fungicides, mutually mixture
Low touching will not be generated, can be synergistic, i.e., the activity of mixture reduces dosage, slows down resistance greater than the activity of independent component
Reduce cost.
Secondly, composition of the invention has good control efficiency to Cucumber Target Leaf Spot；Since synergy causes to use
Amount reduces, and can inhibit fungi and develops drug resistance to single formulation (rosickyite azoles or trifloxystrobin).
Beneficial effects of the present invention are further verified below to test:
1, toxicity measures
1.1 Study on Fungicide Toxicity
Referring to farm-chemical indoor determination test rule, using mycelial growth rate method is used, measurement is brown to cucumber for examination single dose
The inhibiting rate of pinta.Using mycelial growth rate method, the PDA culture medium that 0.5ml medical fluid and 4.5ml melt is mixed, and is poured into sterile
Culture dish in be made band medicine culture medium flat plate.After culture medium solidification, 1 bacteria cake for trying bacterium is put into each culture base plane
(diameter 0.5cm) makes bacteria cake be attached to media surface on one side with mycelia, and 3 repetitions of every processing with alcohol solvent and contain
0.1% Tween 80 aqueous solution is control.After cultivating 72h at 25 DEG C, with crossing method measurement for trying bacterium colony growth diameter.
Inhibiting rate is calculated according to the following formula.And by probit analysis find out salicyloyl enamine, hymexazol single dose toxicity regression curve with
EC50Value, SD and 95% confidence limit.
Mycelial growth inhibition rate (%)=(control colony growth diameter-processing colony growth diameter)/control bacterium colony growth is straight
Diameter × 100
1.2 rosickyite azoles and the research of the complex role of trifloxystrobin
Rosickyite azoles and trifloxystrobin are compounded: two kinds of raw medicines are configured to 4:1,3:1,2:1,1:1,1:2,1 by effective component:
3,1:4 totally 7 proportions (mass ratio).Above-mentioned formula presses Study on Fungicide Toxicity method respectively and carries out toxicity test.
Mixture synergy is evaluated, with EC50Based on value, mixture joint is evaluated by calculating mixture co-toxicity coefficient
Type of action.
CTC120 be synergistic effect, and 80≤CTC < 120 are summation action, and CTC < 80 are antagonism.
2, test result
2.1 Study on Fungicide Toxicity results
The Toxicity Determination result of the 12 kinds of medicaments of table to Cucumber Target Leaf Spot
| Treatment agent | Virulence regression equation | EC50(mgL–1) | Related coefficient | SD | CL0.95 |
| Rosickyite azoles | y = 0.6857x + 3.8808 | 43.1675 | 0.9729 | 0.3317 | 9.6593~192.9161 |
| Trifloxystrobin | y = 1.5775x + 3.8471 | 5.3817 | 0.9990 | 0.1555 | 2.6675~10.8579 |
As it can be seen from table 1 EC of the rosickyite azoles to Cucumber Target Leaf Spot50For 43.1675 μ g/mL；Trifloxystrobin is to Cucumber Target Leaf Spot
EC50For 5.3817 μ g/mL.
2 rosickyite azoles of table compounds the The Toxicity Determination result to Cucumber Target Leaf Spot with trifloxystrobin
| Rosickyite azoles: trifloxystrobin | Virulence regression equation | Related coefficient | EC50(μ g/mL) | Co-toxicity coefficient |
| 1:4 | y = 1.1368x + 4.3468 | 0.9804 | 3.7371 | 174.5674 |
| 1:3 | y = 0.5125x + 4.7003 | 0.9926 | 3.8498 | 178.9544 |
| 1:2 | y = 0.9979x + 4.4659 | 0.9777 | 3.4158 | 222.4615 |
| 1:1 | y = 1.3381x + 4.0968 | 0.9863 | 4.6810 | 204.4499 |
| 2:1 | y = 1.1031x + 4.0671 | 0.9449 | 6.8318 | 189.1592 |
| 3:1 | y = 0.8163x + 4.2493 | 0.8857 | 8.0981 | 193.4671 |
| 4:1 | y = 1.1991x + 3.705 | 0.9803 | 11.9179 | 150.6534 |
As shown in Table 2, rosickyite azoles and all proportions of trifloxystrobin compounding show higher synergistic effect, but different compounding ratios
Example coefficient of synergism difference.Wherein, when rosickyite azoles and the compound proportion of trifloxystrobin are 1:2, co-toxicity coefficient highest is
222.4615.Show that the compounding of rosickyite azoles and trifloxystrobin has preferable effect to the prevention and treatment of Cucumber Target Leaf Spot.
Specific embodiment
In order to facilitate the understanding of those skilled in the art, below in conjunction with embodiment, the present invention will be further described.
Embodiment is only to the invention for example, not being limitation of the invention, the step of not illustrating in embodiment
It is prior art, is not described in detail herein.
Embodiment one
It weighs rosickyite azoles 4kg, trifloxystrobin 1kg, wetting dispersing agent (agriculture breast 600-1) 2kg, thickener (xanthan gum) 0.1kg, prevent
Freeze agent (ethylene glycol) 3kg, defoaming agent (methanol) 0.4kg, complements to 100kg with water, above-mentioned raw materials are cut at a high speed at normal temperature
It cuts uniformly mixed, uniformly mixed material is then put into abrading-ball 2h under room temperature in the ball mill, bactericidal composition of the present invention is made
Suspending agent.
Embodiment two
Weigh rosickyite azoles 10kg, trifloxystrobin 40kg, wetting dispersing agent (agriculture breast 600-1) 6kg, thickener (xanthan gum) 0.4kg,
Antifreezing agent (ethylene glycol) 5kg, defoaming agent (methanol) 0.6kg, complement to 100kg with water, by above-mentioned raw materials at normal temperature through high speed
Shear-mixed is uniform, and uniformly mixed material is then put abrading-ball 3h under room temperature in the ball mill, and Bactericidal composite of the present invention is made
The suspending agent of object.
Embodiment three
Weigh rosickyite azoles 5kg, trifloxystrobin 15kg, wetting dispersing agent (agriculture breast 600-1) 3kg, thickener (xanthan gum) 0.2kg,
Antifreezing agent (ethylene glycol) 4kg, defoaming agent (methanol) 0.5kg, complement to 100kg with water, by above-mentioned raw materials at normal temperature through high speed
Shear-mixed is uniform, and uniformly mixed material is then put abrading-ball 2.2h under room temperature in the ball mill, and sterilization group of the present invention is made
Close the suspending agent of object.
Example IV
Weigh rosickyite azoles 10kg, trifloxystrobin 20kg, wetting dispersing agent (agriculture breast 600-1) 4kg, thickener (xanthan gum) 0.3kg,
Antifreezing agent (ethylene glycol) 3kg, defoaming agent (methanol) 0.4kg, complement to 100kg with water, by above-mentioned raw materials at normal temperature through high speed
Shear-mixed is uniform, and uniformly mixed material is then put abrading-ball 2.5h under room temperature in the ball mill, and sterilization group of the present invention is made
Close the suspending agent of object.
Embodiment five
Weigh rosickyite azoles 20kg, trifloxystrobin 20kg, wetting dispersing agent (agriculture breast 600-1) 4kg, thickener (xanthan gum) 0.3kg,
Antifreezing agent (ethylene glycol) 4kg, defoaming agent (methanol) 0.5kg, complement to 100kg with water, by above-mentioned raw materials at normal temperature through high speed
Shear-mixed is uniform, and uniformly mixed material is then put abrading-ball 2.5h under room temperature in the ball mill, and sterilization group of the present invention is made
Close the suspending agent of object.
Embodiment six
Weigh rosickyite azoles 24kg, trifloxystrobin 8kg, wetting dispersing agent (agriculture breast 600-1) 3kg, thickener (xanthan gum) 0.2kg,
Antifreezing agent (ethylene glycol) 5kg, defoaming agent (methanol) 0.6kg, complement to 100kg with water, by above-mentioned raw materials at normal temperature through high speed
Shear-mixed is uniform, and uniformly mixed material is then put abrading-ball 3h under room temperature in the ball mill, and Bactericidal composite of the present invention is made
The suspending agent of object.
Embodiment seven
Weigh rosickyite azoles 30kg, trifloxystrobin 15kg, wetting dispersing agent (agriculture breast 600-1) 5kg, thickener (xanthan gum) 0.3kg,
Antifreezing agent (ethylene glycol) 4kg, defoaming agent (methanol) 0.5kg, complement to 100kg with water, by above-mentioned raw materials at normal temperature through high speed
Shear-mixed is uniform, and uniformly mixed material is then put abrading-ball 2.5h under room temperature in the ball mill, and sterilization group of the present invention is made
Close the suspending agent of object.
Rosickyite azoles and the bactericidal composition of trifloxystrobin of prevention and treatment Cucumber Target Leaf Spot of the invention and application thereof have passed through specifically
Embodiment be described.Those skilled in the art can use for reference the appropriate feed change of the contents of the present invention, process conditions etc.
Link realizes corresponding other purposes, and correlation changes all without departing from the contents of the present invention, all similar replacements and changes
It moves it will become apparent to those skilled in the art that being considered as being included within the scope of the present invention.
Claims (10)
1. a kind of bactericidal composition of the rosickyite azoles for preventing and treating Cucumber Target Leaf Spot and trifloxystrobin, it is characterised in that: it is by following raw material
It is made: accounting for the active constituent of composition weight 5% to 50%, the wetting dispersing agent for accounting for composition weight 2% to 6%, accounts for composition weight
The thickener of amount 0.1% to 0.4% accounts for the antifreezing agent of composition weight 3% to 5%, accounts for the defoaming of composition weight 0.4% to 0.6%
The water of agent and surplus, the active constituent are the mixture of rosickyite azoles and trifloxystrobin, and the weight ratio of rosickyite azoles and trifloxystrobin is
(1 ~ 4): (1 ~ 4).
2. the bactericidal composition of the rosickyite azoles of prevention and treatment Cucumber Target Leaf Spot and trifloxystrobin as described in claim 1, it is characterised in that:
The weight ratio of the rosickyite azoles and trifloxystrobin is (1 ~ 2): (1 ~ 4).
3. the bactericidal composition of the rosickyite azoles of prevention and treatment Cucumber Target Leaf Spot and trifloxystrobin, feature exist as claimed in claim 1 or 2
In: the weight ratio of the rosickyite azoles and trifloxystrobin is 1:2.
4. the bactericidal composition of the rosickyite azoles of prevention and treatment Cucumber Target Leaf Spot and trifloxystrobin as described in claim 1, it is characterised in that:
The wetting dispersing agent is agriculture breast 600-1.
5. the bactericidal composition of the rosickyite azoles of prevention and treatment Cucumber Target Leaf Spot and trifloxystrobin as described in claim 1, it is characterised in that:
The thickener is xanthan gum.
6. the bactericidal composition of the rosickyite azoles of prevention and treatment Cucumber Target Leaf Spot and trifloxystrobin as described in claim 1, it is characterised in that:
The antifreezing agent is ethylene glycol.
7. the bactericidal composition of the rosickyite azoles of prevention and treatment Cucumber Target Leaf Spot and trifloxystrobin as described in claim 1, it is characterised in that:
The defoaming agent is methanol.
8. the bactericidal composition of the rosickyite azoles of prevention and treatment Cucumber Target Leaf Spot and trifloxystrobin as described in claim 1, it is characterised in that:
The bactericidal composition is configured to allow on pesticide using rosickyite azoles and trifloxystrobin as principle active component and insecticides adjuvant, excipients
Any one dosage form.
9. the rosickyite azoles of prevention and treatment Cucumber Target Leaf Spot as claimed in claim 1 or 8 and the bactericidal composition of trifloxystrobin, feature exist
In: the dosage form of the bactericidal composition is suspending agent.
10. preventing and treating the rosickyite azoles of Cucumber Target Leaf Spot described in claim 1 ~ 9 any one and the bactericidal composition of trifloxystrobin being made
Application on standby Cucumber Target Leaf Spot germ killing drugs.
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| CN201811103670.0A CN109042701A (en) | 2018-09-21 | 2018-09-21 | A kind of rosickyite azoles and the bactericidal composition of trifloxystrobin and application thereof for preventing and treating Cucumber Target Leaf Spot |
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| CN201811103670.0A CN109042701A (en) | 2018-09-21 | 2018-09-21 | A kind of rosickyite azoles and the bactericidal composition of trifloxystrobin and application thereof for preventing and treating Cucumber Target Leaf Spot |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109006849A (en) * | 2018-10-16 | 2018-12-18 | 深圳诺普信农化股份有限公司 | A kind of bactericidal composition containing rosickyite azoles and its application |
| CN116508779A (en) * | 2023-04-17 | 2023-08-01 | 浙江大学 | Bactericide for preventing and treating bacterial fruit blotch of melons and application of bactericide |
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| CN1608464A (en) * | 2003-10-24 | 2005-04-27 | 沈阳化工研究院 | Bactericide composition containing enostroburin |
| US20060004070A1 (en) * | 2002-06-24 | 2006-01-05 | Ulrike Wachendorff-Neumann | Fungicidal active substance combinations |
| CN105407721A (en) * | 2013-07-31 | 2016-03-16 | 龙灯农业化工国际有限公司 | Fungicidal compositions and their use |
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2018
- 2018-09-21 CN CN201811103670.0A patent/CN109042701A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060004070A1 (en) * | 2002-06-24 | 2006-01-05 | Ulrike Wachendorff-Neumann | Fungicidal active substance combinations |
| CN1608464A (en) * | 2003-10-24 | 2005-04-27 | 沈阳化工研究院 | Bactericide composition containing enostroburin |
| CN105407721A (en) * | 2013-07-31 | 2016-03-16 | 龙灯农业化工国际有限公司 | Fungicidal compositions and their use |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109006849A (en) * | 2018-10-16 | 2018-12-18 | 深圳诺普信农化股份有限公司 | A kind of bactericidal composition containing rosickyite azoles and its application |
| CN116508779A (en) * | 2023-04-17 | 2023-08-01 | 浙江大学 | Bactericide for preventing and treating bacterial fruit blotch of melons and application of bactericide |
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Application publication date: 20181221 |
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| WW01 | Invention patent application withdrawn after publication |