CN107372550A - A kind of pesticide combination comprising folpet and benzo alkene fluorine bacterium azoles - Google Patents
A kind of pesticide combination comprising folpet and benzo alkene fluorine bacterium azoles Download PDFInfo
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- CN107372550A CN107372550A CN201710653098.4A CN201710653098A CN107372550A CN 107372550 A CN107372550 A CN 107372550A CN 201710653098 A CN201710653098 A CN 201710653098A CN 107372550 A CN107372550 A CN 107372550A
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- China
- Prior art keywords
- folpet
- fluorine bacterium
- sterilizing composition
- benzo alkene
- bacterium azoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
- A01N47/04—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing >N—S—C≡(Hal)3 groups
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to crop disease control field, it particularly relates to be it is a kind of be used to prevent and treat the composition pesticides of oomycetes diseases, the pesticide combination comprises at least component A and component B, and wherein component A is folpet, and component B is benzo alkene fluorine bacterium azoles；Wherein, the weight ratio of folpet and benzo the alkene fluorine bacterium azoles is 30:1‑1:10, more preferably 20:1‑1:1.Preventing and treating of the composition pesticide of the present invention within the above range to corps diseases has synergistic function, it is possible to reduce pesticide activity component usage amount, prevention effect is improved, and it is good to crop safety, Environmental compatibility.
Description
Technical field
The invention belongs to crop disease control field, it particularly relates to be a kind of to be used to prevent and treat oomycetes diseases
Composition pesticide, the pesticide combination includes component A and component B, and wherein component A is folpet, and component B is benzo alkene fluorine bacterium
Azoles.
Background technology
Oomycetes disease such as downy mildew, epidemic disease are diseases common in proportion of crop planting, yield and quality band to crops
Carry out very big damage.In the last few years, as the increase of China's cultivated area, causing harm for the vegetables production of oomycetes disease are also increasingly tight
Weight, the various diseases as caused by oomycetes are all the very strong species of harmfulness, although species is few, morbidity is rapid, propagates fast, danger
Evil weight.According to the literature, due to single drug and other irrational medications, already lead to some oomycetes disease such as downy mildew,
The diseases such as epidemic disease generate the resistance to the action of a drug to Multiple Pesticides, cause the prevention effect of these agricultural chemicals to decline, and for effectively preventing
Disease has in turn resulted in the pollution of environment, it is necessary to further increased to the usage amount of agricultural chemicals, is unfavorable for the sustainable development of agricultural
Exhibition.Therefore, find efficient, low toxicity, drug-fast novel agrochemical kind can be delayed to be one of important channel for solving the problem.
Folpet is organosulfureous fungicide, is mainly used in preventing and treating cereal crops, vegetables, the multiple diseases on fruit tree, and right
Plant growth has certain stimulation, and folpet can be widely used for preventing and treating rice blast, banded sclerotial blight, wheat rust, red mould
The multiple diseases such as disease, the late blight of potato, early blight of tomato, apple anthracnose.
The common name benzovindiflupyr of benzo alkene fluorine bacterium azoles, trade name Solatenol, CAS accession number are
1072957-71-1, benzo alkene fluorine bacterium azoles are first just up to the pyrazole amide series bactericidal agent of exploitation, are succinate dehydrogenase inhibitors.
The bactericide is mainly used in cereal crops, has outstanding preventive effect to the Major Diseases of the various crops such as wheat, corn and special crop,
Wheat leaf blight, the cercospora black spot of peanut, take-all and wheat basal stem rot can be prevented and treated well, especially to wheat powdery mildew, jade
Rice helminthosporium maydis and gray mold have special efficacy, excellent to Asian Soybean Rust preventive effect.It is killed with methoxy acrylic and triazole type
Microbial inoculum no interactions resistance, can be with various sterilization agent compounding use.Although benzo alkene fluorine bacterium azoles prevention effect is good, to use into
This higher and long-term use of generation for easily causing resistance, so as to reduce its service life.
How to delay the life-span of pesticide activity component is one of major issue to be solved, by different action of agricultural chemicals mechanism
It is a kind of relatively conventional mode that pesticide species, which carry out compounding,.Present inventor is exactly will not as point of penetration, research
Compounded, be found surprisingly that with pesticide species and benzo alkene fluorine bacterium azoles, after folpet and benzo alkene fluorine bacterium azoles are compounded,
Mutual effect is not simply to be superimposed, but can obtain unexpected cooperative synergism effect within the specific limits,
After further research, the present invention is completed, in addition, inventor by substantial amounts of retrieval, is also found no on by folpet
The relevant report compounded with benzo alkene fluorine bacterium azoles.
The content of the invention
It is an object of the invention to provide a kind of prevention effect is good, synergistic sterilizing composition to crop safety.
Another object of the present invention is to provide the synergistic sterilizing composition to be used to prevent and treat corps diseases, especially
It is the purposes of oomycetes diseases.
Another object of the present invention also resides in a kind of method for preventing and treating corps diseases that provides, including the collaboration by the present invention
The methods of Synergistic bactericidal composition is such as sprayed by conventional method, spread fertilizer over the fields, atomizing, drip irrigation and the environment of pathogen or its existence enter
OK.
To achieve these goals, technical scheme obtains in the following manner：
A kind of synergistic sterilizing composition, its active component comprise at least folpet and benzo alkene fluorine bacterium azoles.
In order to reach synergistic function, the weight ratio of folpet and benzo the alkene fluorine bacterium azoles is 30:1-1:10.
Further, the weight ratio of folpet and benzo the alkene fluorine bacterium azoles is preferably 20:1-1:1.
Further, active component accounts for the percentage by weight of composition in synergistic sterilizing composition of the present invention
For 15-80%, preferably 20-60%, remaining is the conventional auxiliary element in Pesticide formulation, such as dispersant, wetting agent, breast
The auxiliary agents such as agent, stabilizer, antifreezing agent, disintegrant, binding agent, solvent and other active ingredients that are beneficial to are stablized in the formulation
The known substance played with drug effect, is not particularly limited, the species and dosage of the auxiliary element can lead to according to pharmaceutical formulation
Simple experiment is crossed to determine to obtain.
Further, synergistic sterilizing composition of the invention can pass through the routine techniques hand of those skilled in the art
Section is prepared into any one formulation for being adapted to agriculturally use, including but not limited to missible oil, wettable powder, suspending agent, moisture
Shot agent, aqueous emulsion, microemulsion, granule etc..
Further, synergistic sterilizing composition of the invention can also include other active materials, such as insecticide,
One kind in attractant, herbicide, synergist, safener, fertilizer, biostimulant, plant growth regulator, semiochemical
Or it is several more than, or can with the present invention bactericidal composition be used in conjunction with.
Further, synergistic sterilizing composition of the invention can be provided in the form of finished product preparation, i.e., in composition
Each material has been adequately mixed and has been prepared into the dosage form for being adapted to use, and can also be used alone with unit dose preparation, uses
It is preceding voluntarily to be mixed in bucket or tank, and optionally mixed and be diluted with water according to the concentration of required active material.
Compared with prior art, synergistic sterilizing composition of the invention has the beneficial effect that：（1）The sterilization of the present invention
Interaction in composition between active component folpet and benzo alkene fluorine bacterium azoles is not simply to be superimposed, both compound after
Preventing and treating in certain scope to corps diseases shows obvious synergistic function, it is possible to reduce pesticide activity component makes
Dosage, improve prevention effect；（2）The active component mechanism of action differs in the bactericidal composition of the present invention, and both uses can be with
Increasing action site, overcome resistance, extend pesticide activity component service life；（3）The bactericidal composition of the present invention is pacified to crop
Entirely, to also being had no adverse effects beneficial to natural enemy.
Embodiment
In order that the purpose of the present invention, technical scheme are definitely, present disclosure is made with reference to embodiment into
One step is described in detail, and the content mentioned in embodiment is not construed as limitation of the invention, and the selection of material prescription can basis
Actual conditions are replaced by other equivalent or with similar purpose alternative features.That is, such as it is not particularly limited, each feature is only
It is a series of equivalent or similar characteristics a example, the protection domain of technical scheme is defined to claim
It is accurate.
First, indoor bioassay
1st, subjects：Cucumber downy mildew；
2nd, test method：Experiment uses pot-culture method, chooses and grows consistent two panels leaf period cucumber seedling, and 10 basins are selected in each processing
For trying melon seedling, numbering is standby.Sprayed with Potter spray towers under 50 PSI pressure, per basin 5mL.Each medicament setting 6 is dense
Gradient is spent, to spray the processing of equivalent clear water as blank control.The downy mildew leaf for picking up from field is taken, 10 DEG C or so are dipped with writing brush
Distillation washing lower back face sporangium, be made into concentration as 3 × 105Individual/mL sporangia suspension.After the h of chemicals treatment 24
Spray inoculation spore cyst fluid, cucumber seedling is placed in growth cabinet (relative humidity 100%, 15~20 DEG C of temperature) training after inoculation
Support, 15~24 DEG C of keeping temperature, the moisturizing of relative humidity 90% or so induction after 24 h, investigation record incidence after 10 d, meter
Calculate disease index and prevention effect.Concentration EC in suppressing is calculated with least square method50, then according to the abundant method calculating co-toxicity coefficients of Sun Yun
(CTC).As CTC ＜ 80, then composition shows as antagonism, and as 80 ＜ CTC ＜ 120, then composition shows as being added and made
With as CTC ＞ 120, then composition shows as synergistic effect.
Survey toxicity index (ATI)=(standard agent EC50/ reagent agent EC50)×100
In theoretical toxicity index (TTI)=A medicament toxicity index × mixture in A percentage composition+B medicament toxicity index × mixture
B percentage composition
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theoretical toxicity index (TTI)] × 100
Toxicity test the results are shown in Table 1.
As can be seen from Table 1, folpet and benzo alkene fluorine bacterium azoles are 30:1-1：To cucumber downy mildew in 10 proportion
Preventing and treating show synergistic function.Wherein, when both compound proportions are 20:When 7, synergistic function is most obvious.
2nd, example of formulations
1st, embodiment 1：44% folpet benzo alkene triflumizole wettable powder（1:1）
Folpet 22%
Benzo alkene fluorine bacterium azoles 22%
Naphthalene sulfonic acid-formaldehyde condensation product sodium salt 4%
Sodium lignin sulfonate 5%
Talcum powder 20%
Attapulgite surplus
The preparation method of the wettable powder is：Customary preparation methods by above-mentioned formula by wettable powder, Ji Jiangyuan
After expecting blended, air-flow crushing, you can 44% folpet benzo alkene triflumizole wettable powder of the present invention is made.
2nd, embodiment 2:54% folpet benzo alkene triflumizole water dispersant（20:7）
Folpet 40%
Benzo alkene fluorine bacterium azoles 14%
Polycarboxylate 4%
Alkyl phenol polyethenoxy ether sodium sulfate 4%
Hydroxymethyl cellulose 3%
Arabic gum 2%
Kaolin surplus
The preparation method of the water dispersible granules is：It is i.e. mixed by the conventional method for producing water dispersible granules according to above-mentioned formula
Conjunction, ultra micro air-flow crushing, mixing, granulation step can be prepared by 54% folpet benzo alkene fluorine bacterium azoles moisture of the present invention
Shot agent.
3rd, embodiment 3:42% folpet benzo alkene fluorine bacterium azoles suspending agent（5:1）
Folpet 35%
Benzo alkene fluorine bacterium azoles 7%
Polycarboxylate 3%
Polyoxyethylene carboxylate 2%
NPE 3%
Organic silicone oil 0.9%
Aluminium-magnesium silicate 2.1%
Ethylene glycol 4%
OIT 0.8%
Deionized water surplus
The preparation method of the suspending agent is：Customary preparation methods by above-mentioned formula by suspending agent, are passed through after raw material is mixed
High speed shear mixes more than 30 minutes, 2-3 hours is sanded with sand mill, you can folpet benzo alkene of the present invention is made
Fluorine bacterium azoles suspending agent.
3rd, field control effectiveness test
1st, controlling object：Cucumber downy mildew；
2nd, test method：Test site is arranged in Shouguang City of Shandong Province somewhere green house of vegetables, is screened full cucumber seeds, is urged
Bud is cultivated into transplanting rice greenhouse during 2 needles, normal cultivation management to being seeded in when showing money or valuables one carries unintentionally in a diameter of 10 cm dixie cup,
When cucumber is grown to 10 needles by embodiment 1-3 and contrast single dose（Comparative example 1:50% folpet wettable powder；Comparative example
2:15% benzo alkene triflumizole water dispersant）Preparation be watered and be uniformly sprayed at afterwards on the positive and negative of cucumber leaves；Chemical drugs
Agent and blank control clear water processing method are identical with the former.20 cucumber are often handled, are repeated 4 times, random alignment.After sprinkling 1 day,
Spray inoculation bacterium of downy mildew of cucumber, greenhouse temperature is controlled after inoculation between 20-24 DEG C, humidity 80-90%；Treat clear water blank pair
Incidence is investigated during according to abundant morbidity and after falling ill 7 days, and calculates disease index and preventive effect.Result of the test is as shown in table 2.
Field control effectiveness test result shows, the composition pesticide of folpet and benzo alkene fluorine bacterium azoles described in embodiment 1-3
Preferable lasting effect and quick-acting are shown to the prevention effect of cucumber downy mildew, in control fully morbidity, embodiment 1-3's
Pesticidal preparations are in 200-400g/ hectares, to the prevention effect of cucumber downy mildew between 73.2-83.2%, hence it is evident that be better than control
Single dose.The especially composition pesticide preparation of embodiment 2, each investigation phase prevention effect is more than 80%, hence it is evident that is better than it
It is handled.In addition, do not observe that the composition pesticide of the present invention and the test medicine of control group are made to cucumber in scope of medication
Thing has poisoning generation, to also being had no adverse effects beneficial to natural enemy.
Embodiment above describes some exemplary embodiments of the present invention, but it will be apparent to those skilled in the art that
Without departing from the principles and spirit of the present invention, some modifications, this hair can also be made to these exemplary embodiments
Bright scope is defined by the protection domain that claim is limited.
Claims (9)
1. a kind of synergistic sterilizing composition, it is characterised in that its active component comprises at least folpet and benzo alkene fluorine
Bacterium azoles.
2. synergistic sterilizing composition according to claim 1, it is characterised in that folpet and benzo alkene the fluorine bacterium
The weight ratio of azoles is 30:1-1:10.
3. synergistic sterilizing composition according to claim 1, it is characterised in that folpet and benzo alkene the fluorine bacterium
The weight ratio preferably 20 of azoles:1-1:1.
4. synergistic sterilizing composition according to claim 1, it is characterised in that the active component accounts for composition
Percentage by weight is 15-80%, preferably 20-60%, and remaining is the conventional auxiliary element in Pesticide formulation.
5. synergistic sterilizing composition according to claim 4, it is characterised in that the formulation of the bactericidal composition is
It is any in missible oil, wettable powder, suspending agent, water dispersible granules, aqueous emulsion, microemulsion, granule.
6. the synergistic sterilizing composition according to any one of claim 1-5 claim, it is characterised in that described
Synergistic sterilizing composition can also include other active materials, such as insecticide, attractant, herbicide, synergist, safety
It is more than the one or more in agent, fertilizer, biostimulant, plant growth regulator, semiochemical.
7. the synergistic sterilizing composition according to any one of claim 1-6 claim is used to prevent and treat crop disease
Harmful purposes.
8. purposes according to claim 7, it is characterised in that the corps diseases are preferably oomycetes diseases.
9. purposes according to claim 8, it is characterised in that the corps diseases are preferably downy mildew.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710653098.4A CN107372550A (en) | 2017-08-02 | 2017-08-02 | A kind of pesticide combination comprising folpet and benzo alkene fluorine bacterium azoles |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710653098.4A CN107372550A (en) | 2017-08-02 | 2017-08-02 | A kind of pesticide combination comprising folpet and benzo alkene fluorine bacterium azoles |
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| CN107372550A true CN107372550A (en) | 2017-11-24 |
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| CN201710653098.4A Pending CN107372550A (en) | 2017-08-02 | 2017-08-02 | A kind of pesticide combination comprising folpet and benzo alkene fluorine bacterium azoles |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108739837A (en) * | 2018-07-19 | 2018-11-06 | 广东广康生化科技股份有限公司 | A kind of bactericidal composition containing folpet and Metalaxyl-M |
| WO2020141512A1 (en) * | 2018-12-31 | 2020-07-09 | Adama Makhteshim Ltd. | Fungicidal mixture |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105409981A (en) * | 2014-09-19 | 2016-03-23 | 陕西美邦农药有限公司 | Sterilizing composition containing benzovindiflupyr |
-
2017
- 2017-08-02 CN CN201710653098.4A patent/CN107372550A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105409981A (en) * | 2014-09-19 | 2016-03-23 | 陕西美邦农药有限公司 | Sterilizing composition containing benzovindiflupyr |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108739837A (en) * | 2018-07-19 | 2018-11-06 | 广东广康生化科技股份有限公司 | A kind of bactericidal composition containing folpet and Metalaxyl-M |
| WO2020141512A1 (en) * | 2018-12-31 | 2020-07-09 | Adama Makhteshim Ltd. | Fungicidal mixture |
| EP4356735A3 (en) * | 2018-12-31 | 2024-07-03 | Adama Makhteshim Ltd. | Fungicidal mixture |
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Application publication date: 20171124 |