CN109010083A - A kind of carbon dioxide composite facial mask composition of layered structure and preparation method thereof constituted with amphiphilic substance - Google Patents
A kind of carbon dioxide composite facial mask composition of layered structure and preparation method thereof constituted with amphiphilic substance Download PDFInfo
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- CN109010083A CN109010083A CN201811044360.6A CN201811044360A CN109010083A CN 109010083 A CN109010083 A CN 109010083A CN 201811044360 A CN201811044360 A CN 201811044360A CN 109010083 A CN109010083 A CN 109010083A
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0212—Face masks
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/602—Glycosides, e.g. rutin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/22—Gas releasing
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Abstract
The carbon dioxide composite facial mask composition of layered structure and preparation method thereof that the invention discloses a kind of to be constituted with amphiphilic substance.The mask composition by with layered structure adhesive matrix and carbon dioxide generation agent form.Adhesive matrix includes following components: 1~10% moisturizer, 0.1~5% thickener, 1%~30% grease, 0.1~5% amphiphilic substance, 0.1~10% emulsion adjuvant, 0~5% water soluble acid, 0~5% carbonate, 0~1% preservative, water are surplus.Carbon dioxide generation agent includes following components: 0~33% carbonate, 0~66% water soluble acid, 0.01~1% active constituent, 0~5% thickener, 0~10% water-soluble solid, excess water.The adhesive matrix preparation process of layered structure with amphiphilic substance composition is simple, skin sense does not stick greasy, composition generates carbon dioxide foaming abundant after being mixed, its layered structure can reduce the volatilization of carbon dioxide, improve carbon dioxide content in facial mask, and operating time extension is smeared, layered structure promotes active matter to absorb, can enhance cosmetic result simultaneously.
Description
Technical field
The present invention relates to cosmetic technical field, the dioxy of especially a kind of layered structure constituted with amphiphilic substance
Change carbon composite facial mask composition and preparation method thereof.
Background technique
With the development of the social economy, people increasingly pay attention to the maintenance of skin.Germany and Japan, there are many about
Beauty and medical effect case are obtained using carbonate spring.Currently, Japan develops the carbon dioxide mask composition product of series,
The advantages of mainly using carbon dioxide to skin, principle is according to Bohr effect, and carbonic acid molecular structure is small, can infiltrate into hair
Thin blood vessel, after carbon dioxide permeability to capillary, the gas concentration lwevel in blood can be significantly raised, and carbon dioxide is in blood
Middle formation carbonic acid, blood pH are reduced, and hemoglobin can be reduced with oxygen binding ability, and oxygen can be discharged into surrounding tissue, knot
Fruit telangiectasis, after promoting blood circulation, oxygen and nutritional ingredient will convey whole body, boost metabolism, to reach
To skin problems such as the improvement obscure, spots of skin.
It is used to prepare the composition of carbon dioxide preparation for external use, its manufacturing method disclosed in patent CN106535864A and comments
Valence method and carbon dioxide preparation for external use provide a kind of novel composition for being used to prepare carbon dioxide preparation for external use,
From after mixing two or more preparation until when being coated on skin, coating surface does not solidify and scalability is good, and for making
The composition of standby carbon dioxide preparation for external use do not remain on skin until using and terminating and gelation to peelable.Its composition
There is no addition grease type raw materials, and when peeling off the gel of film forming, skin can be relatively dry.Its surface can not observe titanium dioxide
The bubble that carbon is formed, has no pleasant feeling.
Patent CN101849894A discloses a kind of CO2Sustained release foam mask and preparation method thereof, oil components are selected from
One or more of olive oil, castor oil, saualane and jojoba oil；Surfactant is selected from Brij92, spits
One or more of temperature 20, Tween 80 and span 20.The grease of selection and surfactant skin sense are more thick and heavy, what is used
When have glutinous soapy feeling.Carbon dioxide release time can achieve 18 minutes in case study on implementation, but there is no hinder in its composition
The only related component that carbon dioxide is vaporized into air acts on the decline of skin carbon dioxide effective concentration.It is reported that titanium dioxide
Concentration of carbon is best in 1000ppm~4000ppm generation beautifying skin effect.
Carbon dioxide facial mask in the market is quickly generated carbon dioxide gas upon mixing, aqueous phase substrate formed foam, one
As in the case of foam be easy broken, be vaporized to air, especially after smearing on the face, substantially not it is observed that the presence of foam, explanation
Carbon dioxide effective concentration has declined, and cannot reach cosmetic result.
Summary of the invention
In order to overcome the above-mentioned deficiencies of the prior art, the present invention provides a kind of layer structures constituted with amphiphilic substance
Carbon dioxide composite facial mask composition of body and preparation method thereof.
The technical solution adopted by the present invention to solve the technical problems is as follows:
The mask composition by with layered structure adhesive matrix and carbon dioxide generation agent form.
Adhesive matrix with layered structure includes following component by mass percentage:
1~10% moisturizer, 0.1~5% thickener, 1%~30% grease, 0.1~5% amphiphilic substance, 0.1~10%
Emulsion adjuvant, 0~5% water soluble acid, 0~5% carbonate, 0~1% preservative, water are surplus.
Carbon dioxide generation agent includes mainly following component by mass percentage:
0~33% carbonate, 0~66% water soluble acid, 0.01~1% active constituent, 0~5% thickener, 0~10%
Water-soluble solid, excess water.
The layered structure is able to observe that Maltese cross structure under petrographic microscope.
The moisturizer be glycerol, propylene glycol, dipropylene glycol, 1,2- hexylene glycol, butanediol, polyethylene glycol, D-sorbite,
Sodium Hyaluronate, beta glucan, amino acid, pyrrolidone sodium carboxylate, sodium lactate, urea, ceramide, one in biological polyoses
Kind is a variety of.
The thickener electrolyte-resistant, thickener are one kind of natural polymer, synthesis macromolecule, inorganic tackifier, wax
Or more.Wherein, the thickener as natural polymer is xanthan gum, cellulose, modified cellulose, starch, modification
Starch, Arabic gum one kind or more.It is polyvinyl alcohol, polyvinylpyrrolidine that the conduct, which synthesizes high molecular thickener,
Ketone, polyacrylate one kind or more.The thickener as inorganic tackifier be kaolin, aluminum magnesium silicate, montmorillonite,
Seabed mud one kind or more.The thickener as wax is haze tallow, bayberry wax, candelila wax/bear wax in ground, Japan's essence
Wax, palm wax, rice bran wax, Jojoba Oil, castor wax animal wax, beeswax, insect wax/Chinese wax, lanocerin, lignite wax, ceresine/
Paraffin, polyethylene wax (PE wax), polypropylene wax (PP wax), ethane-acetic acid ethyenyl copolymerization wax (EVA wax) are one or more.
The grease be vegetable fat, animal fat, Synthetic Oil it is one or more.
The amphiphilic substance be cationic substance, anionic species, nonionic it is one or more.
The amphiphilic substance has hydrophilic group and lipophilic group, can be cationic surfactant, anion surface active
Agent, amphoteric surfactant, nonionic surfactant it is one or more.
The emulsion adjuvant is Long carbon chain alcohol, and mainly carbon number is in 12 or more higher alcohols.Wherein the Long carbon chain alcohol is
Laruyl alcohol, palmityl alcohol, cetanol, stearyl alcohol, cetostearyl alcohol, docosyl alcohol, arachidic alcohol it is one or more.
The water soluble acid be 'alpha '-hydroxy acids, glucolactone, ascorbic acid, 4- hydroxyethyl piperazineethanesulfonic acid it is a kind of or
It is a variety of.
The carbonate be sodium bicarbonate, saleratus, calcium bicarbonate, magnesium bicarbonate, sodium carbonate, potassium carbonate, calcium carbonate,
Barium carbonate, magnesium carbonate it is one or more.
The form of the mask composition can be following form:
1) titanium dioxide of the adhesive matrix for the layered structure that there is carbonate containing amphiphilic substance to constitute and containing water-soluble acid
The composition of carbon generating agent.
2) adhesive matrix for the layered structure that there is containing water-soluble acid amphiphilic substance to constitute and carbonato titanium dioxide
The composition of carbon generating agent.
3) the adherent base plastid with layer structure and the simultaneously carbon dioxide generation agent containing carbonate and water soluble acid
Composition.
Water-soluble solid ingredient is glucose, sucrose, xylitol, sodium chloride, grape in the carbon dioxide generation agent
Saccharic acid zinc, calcium gluconate, sodium gluconate, magnesium gluconate, copper gluconate, solid amino acid it is one or more.
Active constituent is ascorbic acid, ascorbic acid derivates, glutathione, view Huang in the carbon dioxide generation agent
Alcohol it is one or more.
After adhesive matrix and the solid powder mixing with layered structure, the aqueous solution pH of 10% mixture is
5.5~6.5.
The adhesive matrix preparation method with layer structure the following steps are included:
1) 80~90 DEG C are heated water to, water phase is made in moisturizer, thickener stirring and dissolving in water.
2) liquid fat, amphiphilic substance, emulsion adjuvant are heated to 80~90 DEG C, dissolve and oily phase is made.
3) water phase is added in oily phase, 4~10min of homogeneous is kept the temperature with homogeneous speed 6000rpm~10000rpm.
4) after homogeneous, natural cooling cools down at 150~300rpm, is down to 45 DEG C to temperature and stirs hereinafter, preservative is added
It mixes uniformly.
5) part water is added and dissolves 0~5% water soluble acid or 0~5% carbonate in advance, stir evenly.
The carbon dioxide generation agent preparation method is the following steps are included: by carbonate, water soluble acid, active constituent, increasing
Thick dose, excess water mixing it is uniform.
The frontier district foam Plateau is accumulated in the layered structure tendency that amphiphilic substance is constituted, increases the face in the area
Product, makes radius of curvature become larger, reduces the Laplace pressure of liquid film drain, to improve the stability of foam.In addition, stratiform
Structural body significantly increases the mechanical strength of foam system.So composition generates carbon dioxide foaming abundant after being mixed,
The layered structure that can be constituted with amphiphilic substance is stablized, and reduces and is vaporized to air.
In terms of skin sense, the phosphatide of the cell membrane of the layered structure and human skin cell that are constituted due to amphiphilic substance is double
Molecular layer structure is similar, thus can provide a kind of skin sense of salubrious non-greasy, while promoting the absorption of active matter.
Compared with prior art, the beneficial effects of the invention are as follows mainly provide a kind of stratiform knot constituted with amphiphilic substance
Structure body and carbon dioxide composite facial mask composition and preparation method thereof, the adherent base with the layered structure that amphiphilic substance is constituted
Matter preparation process is simple, skin sense do not stick it is greasy, composition be mixed after generate carbon dioxide foaming abundant, layered structure
The volatilization of carbon dioxide can be reduced, carbon dioxide content in facial mask is improved, and smears operating time extension, layered structure is same
When promote active matter absorb, cosmetic result can be enhanced.
Detailed description of the invention
Fig. 1: being the adherent base that the layered structure constituted with amphiphilic substance is prepared in the present invention according to embodiment 1
Microscope photo of the matter in petrographic microscope amplification 630X.
Fig. 2: being to contain sodium bicarbonate (0.4g) according to 20g prepared by embodiment 1 in the present invention to constitute with amphiphilic substance
Layered structure adhesive matrix and 3g containing ascorbic acid (0.78g) carbon dioxide generation agent mixing after generate carbon dioxide
Composite facial mask petrographic microscope amplification 630X microscope photo.
Fig. 3: the adhesive matrix being prepared in the present invention according to comparative example 1 amplifies the microscope of 630X in petrographic microscope
Photo.
Fig. 4: sodium carbonate is contained according to 20g prepared by embodiment 1 in the present invention prepared in the present invention according to embodiment 1
The adhesive matrix and carbon dioxide generation agent for the layered structure that (0.4g) there is amphiphilic substance to constitute contain ascorbic acid containing 3g
15min foam state after (0.78g) mixing.
Fig. 5: comparison commercial samples, 15min foam after the mixing of Mei Diruoya carbon dioxide facial mask 26g, 1.6g particle powder
State.
Specific embodiment
Now in conjunction with drawings and examples, the present invention will be described in detail.
Embodiment 1: a kind of layered structure and carbon dioxide composite facial mask composition constituted with amphiphilic substance is prepared.
1. preparation has layer structure adhesive matrix, calculate in percentage by weight, raw material composition and content are as follows:
5% butanediol
1% xanthan gum
10% dimethyl silicone polymer
5% Jojoba (SIMMONDSIACHINENSIS) seed oil
The hard ester glucoside of 1% spermaceti
4% cetostearyl alcohol
2% sodium bicarbonate
0.5% Phenoxyethanol
71.5% water
The preparation method is as follows:
1) 80~90 DEG C are heated water to, water phase is made in butanediol, xanthan gum stirring and dissolving in the water of part.
2) by dimethyl silicone polymer, Jojoba (SIMMONDSIA CHINENSIS) seed oil, the hard ester glucoside of spermaceti,
Cetostearyl alcohol is heated to 80~90 DEG C, dissolves and oily phase is made.
3) water phase is added in oily phase, homogeneous 4min is kept the temperature with homogeneous speed 6000rpm~10000rpm.
4) after homogeneous, natural cooling cools down at 150rpm, is down to 45 DEG C hereinafter, Phenoxyethanol stirring is added to temperature
It is even.
5) aqueous solution of dissolution sodium bicarbonate in advance is added, stirs evenly.
2, carbon dioxide generation agent is prepared, is calculated in percentage by weight, raw material composition and content are as follows:
26% ascorbic acid
1% glutathione
1% zinc gluconate
1% calcium gluconate
1% magnesium gluconate
1% copper gluconate
69% xylitol
Above-mentioned raw materials grind into powder is mixed, stored dry is protected from light.
Comparative example 1:
Compared with Example 1, adhesive matrix main component is identical, and cetostearyl alcohol dosage is 0.
Embodiment 2: a kind of layered structure and carbon dioxide composite facial mask composition constituted with amphiphilic substance is prepared.
1. preparation has layer structure adhesive matrix, calculate in percentage by weight, raw material composition and content are as follows:
1% butanediol
3% xanthan gum
20% dimethyl silicone polymer
5% Jojoba (SIMMONDSIACHINENSIS) seed oil
The hard ester glucoside of 3% spermaceti
4% cetostearyl alcohol
3% sodium bicarbonate
0.5% Phenoxyethanol
60.5% water
The preparation method is as follows:
1) 80~90 DEG C are heated water to, water phase is made in butanediol, xanthan gum stirring and dissolving in the water of part.
2) by dimethyl silicone polymer, Jojoba (SIMMONDSIA CHINENSIS) seed oil, the hard ester glucoside of spermaceti,
Cetostearyl alcohol is heated to 80~90 DEG C, dissolves and oily phase is made.
3) water phase is added in oily phase, homogeneous 4min is kept the temperature with homogeneous speed 6000rpm~10000rpm.
4) after homogeneous, natural cooling cools down at 150rpm, is down to 45 DEG C hereinafter, Phenoxyethanol stirring is added to temperature
It is even.
5) aqueous solution of dissolution sodium bicarbonate in advance is added, stirs evenly.
2, carbon dioxide generation agent is prepared, is calculated in percentage by weight, raw material composition and content are as follows:
20% citric acid
1% glutathione
1% zinc gluconate
1% calcium gluconate
1% magnesium gluconate
1% copper gluconate
75% xylitol
Above-mentioned raw materials grind into powder is mixed, stored dry is protected from light.
Embodiment 3: a kind of layered structure and carbon dioxide composite facial mask composition constituted with amphiphilic substance is prepared.
1. preparation has layer structure adhesive matrix, calculate in percentage by weight, raw material composition and content are as follows:
10% butanediol
3% xanthan gum
25% dimethyl silicone polymer
5% Jojoba (SIMMONDSIACHINENSIS) seed oil
The hard ester glucoside of 3% spermaceti
0.1% cetostearyl alcohol
3% sodium carbonate
0.5% Phenoxyethanol
50.4% water
The preparation method is as follows:
1) 80~90 DEG C are heated water to, water phase is made in butanediol, xanthan gum stirring and dissolving in the water of part.
2) by dimethyl silicone polymer, Jojoba (SIMMONDSIA CHINENSIS) seed oil, the hard ester glucoside of spermaceti,
Cetostearyl alcohol is heated to 80~90 DEG C, dissolves and oily phase is made.
3) water phase is added in oily phase, homogeneous 4min is kept the temperature with homogeneous speed 6000rpm~10000rpm.
4) after homogeneous, natural cooling cools down at 150rpm, is down to 45 DEG C hereinafter, Phenoxyethanol stirring is added to temperature
It is even.
5) aqueous solution of dissolution sodium carbonate in advance is added, stirs evenly.
2, carbon dioxide generation agent is prepared, is calculated in percentage by weight, raw material composition and content are as follows:
26% citric acid
1% glutathione
1% zinc gluconate
1% calcium gluconate
1% magnesium gluconate
1% copper gluconate
69% xylitol
Above-mentioned raw materials grind into powder is mixed, stored dry is protected from light.
Embodiment 4: a kind of layered structure and carbon dioxide composite facial mask composition constituted with amphiphilic substance is prepared.
1. preparing the adhesive matrix for the layered structure that there is amphiphilic substance to constitute, calculate in percentage by weight, it is former
Material composition and content are as follows:
5% dipropylene glycol
3% aluminum magnesium silicate
8% saualane
7% Jojoba (SIMMONDSIACHINENSIS) seed oil
3% behenyl base trimethyl ammonium chloride
10% docosyl alcohol
2% citric acid
0.5% Phenoxyethanol
64.5% water
The preparation method is as follows:
1) 80~90 DEG C are heated water to, water phase is made in dipropylene glycol, aluminum magnesium silicate stirring and dissolving in the water of part.
2) by saualane, Jojoba (SIMMONDSIACHINENSIS) seed oil, behenyl base trimethyl ammonium chloride, docosyl alcohol
80~90 DEG C are heated to, dissolves and oily phase is made.
3) water phase is added in oily phase, homogeneous 4min is kept the temperature with homogeneous speed 6000rpm~10000rpm.
4) after homogeneous, natural cooling cools down at 200 rpm, is down to 45 DEG C hereinafter, Phenoxyethanol stirring is added to temperature
It is even.
5) aqueous solution of dissolution citric acid in advance is added, stirs evenly.
2, carbon dioxide generation agent is prepared, is calculated in percentage by weight, raw material composition and content are as follows:
2% sodium bicarbonate
2% xanthan gum
1% zinc gluconate
1% calcium gluconate
1% magnesium gluconate
1% copper gluconate
5% glycine
87% water
Above-mentioned raw materials are mixed uniform.
Embodiment 5: a kind of layered structure and carbon dioxide composite facial mask composition constituted with amphiphilic substance is prepared.
1. preparing the adhesive matrix for the layered structure that there is amphiphilic substance to constitute, calculate in percentage by weight, it is former
Material composition and content are as follows:
10% glycerol
1% aluminum magnesium silicate
8% saualane
7% Jojoba (SIMMONDSIACHINENSIS) seed oil
5% behenyl base trimethyl ammonium chloride
0.1% docosyl alcohol
1.5% malic acid
0.5% Phenoxyethanol
66.9% water
The preparation method is as follows:
1) 80~90 DEG C are heated water to, water phase is made in glycerol, aluminum magnesium silicate stirring and dissolving in the water of part.
2) by saualane, Jojoba (SIMMONDSIACHINENSIS) seed oil, behenyl base trimethyl ammonium chloride, docosyl alcohol
80~90 DEG C are heated to, dissolves and oily phase is made.
3) water phase is added in oily phase, homogeneous 4min is kept the temperature with homogeneous speed 6000rpm~10000rpm.
4) after homogeneous, natural cooling cools down at 200 rpm, is down to 45 DEG C hereinafter, Phenoxyethanol stirring is added to temperature
It is even.
5) aqueous solution of dissolution malic acid in advance is added, stirs evenly.
2, carbon dioxide generation agent is prepared, is calculated in percentage by weight, raw material composition and content are as follows:
2% sodium bicarbonate
2% xanthan gum
1% zinc gluconate
1% calcium gluconate
1% magnesium gluconate
1% copper gluconate
92% water
Above-mentioned raw materials are mixed uniform.
Embodiment 6: a kind of layered structure and carbon dioxide composite facial mask composition constituted with amphiphilic substance is prepared.
1. preparing the adhesive matrix for the layered structure that there is amphiphilic substance to constitute, calculate in percentage by weight, it is former
Material composition and content are as follows:
10% glycerol
5% aluminum magnesium silicate
8% saualane
7% Jojoba (SIMMONDSIACHINENSIS) seed oil
3% behenyl base trimethyl ammonium chloride
10% docosyl alcohol
2% tartaric acid
0.5% Phenoxyethanol
54.5% water
The preparation method is as follows:
1) 80~90 DEG C are heated water to, water phase is made in glycerol, aluminum magnesium silicate stirring and dissolving in the water of part.
2) by saualane, Jojoba (SIMMONDSIACHINENSIS) seed oil, behenyl base trimethyl ammonium chloride, docosyl alcohol
80~90 DEG C are heated to, dissolves and oily phase is made.
3) water phase is added in oily phase, homogeneous 4min is kept the temperature with homogeneous speed 6000rpm~10000rpm.
4) after homogeneous, natural cooling cools down at 200 rpm, is down to 45 DEG C hereinafter, Phenoxyethanol stirring is added to temperature
It is even.
5) aqueous solution of dissolution tartaric acid in advance is added, stirs evenly.
2, carbon dioxide generation agent is prepared, is calculated in percentage by weight, raw material composition and content are as follows:
2% sodium bicarbonate
2% xanthan gum
1% zinc gluconate
1% calcium gluconate
1% magnesium gluconate
1% copper gluconate
92% water
Above-mentioned raw materials are mixed uniform.
A kind of embodiment 7: layered structure and carbon dioxide composite facial mask composition constituted with amphiphilic substance.
1. preparing the adhesive matrix for the layered structure that there is amphiphilic substance to constitute, calculate in percentage by weight, it is former
Material composition and content are as follows:
5% propylene glycol
2% 1,2- hexylene glycol
3% polyvinylpyrrolidone
8% saualane
7% isononyl isononanoate
3% stearoyl dilactic acid sodium
2% stearyl alcohol
0.5% parahydroxyacet-ophenone
69.5% water
The preparation method is as follows:
1) 85 DEG C are heated water to, water phase is made in propylene glycol, xanthan gum stirring and dissolving in the water of part.
2) saualane, beeswax, isononyl isononanoate, stearoyl dilactic acid sodium, stearyl alcohol are heated to 85 DEG C, dissolution system
Obtain oily phase.
3) water phase is added in oily phase, homogeneous 5min is kept the temperature with homogeneous speed 8000rpm.
4) after homogeneous, natural cooling cools down at 300 rpm, is down to 45 DEG C hereinafter, addition 1,2- hexylene glycol is preparatory to temperature
The parahydroxyacet-ophenone of dissolution, stirs evenly.
2, carbon dioxide generation agent powder is prepared, is calculated in percentage by weight, raw material composition and content are as follows:
33% sodium bicarbonate
66% ascorbic acid
1% glycine
Above-mentioned raw materials grind into powder is mixed, stored dry is protected from light.
A kind of embodiment 8: layered structure and carbon dioxide composite facial mask composition constituted with amphiphilic substance.
1. preparing the adhesive matrix for the layered structure that there is amphiphilic substance to constitute, calculate in percentage by weight, it is former
Material composition and content are as follows:
5% butanediol
2% 1,2- hexylene glycol
2% beeswax
4% hydroxypropyl starch phosphate
8% saualane
7% isononyl isononanoate
3% stearoyl dilactic acid sodium
2% cetostearyl alcohol
0.5% parahydroxyacet-ophenone
66.5% water
The preparation method is as follows:
1) 90 DEG C are heated water to, water phase is made in butanediol, xanthan gum stirring and dissolving in the water of part.
2) saualane, beeswax, isononyl isononanoate, stearoyl dilactic acid sodium, cetostearyl alcohol are heated to 90 DEG C, it is molten
Oily phase is made in solution.
3) water phase is added in oily phase, homogeneous 5min is kept the temperature with homogeneous speed 10000rpm.
4) after homogeneous, natural cooling cools down at 300 rpm, is down to 45 DEG C hereinafter, addition 1,2- hexylene glycol is preparatory to temperature
The parahydroxyacet-ophenone of dissolution, stirs evenly.
2, carbon dioxide generation agent powder is prepared, is calculated in percentage by weight, raw material composition and content are as follows:
33% sodium bicarbonate
66% ascorbic acid
1% trehalose
Above-mentioned raw materials grind into powder is mixed, stored dry is protected from light.
A kind of embodiment 9: layered structure and carbon dioxide composite facial mask composition constituted with amphiphilic substance.
1. preparing the adhesive matrix for the layered structure that there is amphiphilic substance to constitute, calculate in percentage by weight, it is former
Material composition and content are as follows:
5% butanediol
2% 1,2- hexylene glycol
1% beeswax
1% hydroxypropyl starch phosphate
8% saualane
7% isononyl isononanoate
3% stearoyl dilactic acid sodium
2% cetostearyl alcohol
0.5% parahydroxyacet-ophenone
70.5% water
The preparation method is as follows:
1) 80 DEG C are heated water to, water phase is made in butanediol, hydroxypropyl starch phosphate stirring and dissolving in the water of part.
2) saualane, beeswax, isononyl isononanoate, stearoyl dilactic acid sodium, cetostearyl alcohol are heated to 80 DEG C, it is molten
Oily phase is made in solution.
3) water phase is added in oily phase, homogeneous 5min is kept the temperature with homogeneous speed 6000rpm.
4) after homogeneous, natural cooling cools down at 300 rpm, is down to 45 DEG C hereinafter, addition 1,2- hexylene glycol is preparatory to temperature
The parahydroxyacet-ophenone of dissolution, stirs evenly.
2, carbon dioxide generation agent powder is prepared, is calculated in percentage by weight, raw material composition and content are as follows:
33% sodium bicarbonate
66% ascorbic acid
1% sucrose
Above-mentioned raw materials grind into powder is mixed, stored dry is protected from light.
The carbon dioxide stable state comparative experiments of carbon dioxide facial mask:
Sodium bicarbonate (0.4g) and 3g are contained according to 20g adhesive matrix prepared by embodiment 1 in the present invention prepared by embodiment 1
Observation bubble regime is seen containing 15min after mixing after ascorbic acid (0.8g) solid powder.Compare commercial samples, Mei Diruoya dioxy
15min observes bubble regime after changing the mixing of carbon facial mask 26g, 1.6g particle powder.Found by Fig. 4 and Fig. 5, embodiment 1 due to
Stablize with its foam of layer structure, this operates for consumers and smear time extension, and effective carbon dioxide in facial mask
Content improves, and has stronger cosmetic result.
Comparative example 1, assistant for emulsifying agent cetostearyl alcohol dosage are that complete Malta's knot is not substantially observed in 0, Fig. 3
Structure is formed without layer structure.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair
The equivalent structure or equivalent flow shift that bright description is done is applied directly or indirectly in other relevant technology necks
Domain is included within the scope of the present invention.
Claims (16)
1. a kind of carbon dioxide composite facial mask composition of the layered structure constituted with amphiphilic substance, it is characterised in that: should
Mask composition by with layered structure adhesive matrix and carbon dioxide generation agent form；
Adhesive matrix with layered structure includes following component by mass percentage:
1~10% moisturizer, 0.1~5% thickener, 1%~30% grease, 0.1~5% amphiphilic substance, 0.1~10% emulsification
Auxiliary agent, 0~5% water soluble acid, 0~5% carbonate, 0~1% preservative, water are surplus；
Carbon dioxide generation agent includes mainly following component by mass percentage:
It is 0~33% carbonate, 0~66% water soluble acid, 0.01~1% active constituent, 0~5% thickener, 0~10% water-soluble
Property solid, excess water.
2. a kind of carbon dioxide composite facial mask group of layered structure constituted with amphiphilic substance according to claim 1
Close object, it is characterised in that: the layered structure constituted with amphiphilic substance is able to observe that horse under petrographic microscope
His cross structure of ear.
3. a kind of carbon dioxide composite facial mask group of layered structure constituted with amphiphilic substance according to claim 1
Close object, it is characterised in that: the moisturizer be glycerol, propylene glycol, dipropylene glycol, butanediol, 1,2- hexylene glycol, polyethylene glycol,
D-sorbite, Sodium Hyaluronate, beta glucan, amino acid, pyrrolidone sodium carboxylate, sodium lactate, urea, ceramide, biology
One of polysaccharide is a variety of.
4. a kind of carbon dioxide composite facial mask group of layered structure constituted with amphiphilic substance according to claim 3
Close object, it is characterised in that: the thickener electrolyte-resistant, thickener be natural polymer, synthesis macromolecule, inorganic tackifier,
Wax it is one or more；
Wherein, the thickener as natural polymer is xanthan gum, cellulose, modified cellulose, starch, modified shallow lake
Powder, Arabic gum one kind or more；The conduct synthesize high molecular thickener be polyvinyl alcohol, polyvinylpyrrolidone,
On polyacrylate is one or more；The thickener as inorganic tackifier be kaolin, aluminum magnesium silicate, montmorillonite,
On seabed mud is one or more；The thickener as wax is haze tallow, bayberry wax, candelila wax/bear wax in ground, Japan's essence
Wax, palm wax, rice bran wax, Jojoba Oil, castor wax animal wax, beeswax, insect wax/Chinese wax, lanocerin, lignite wax, ceresine/
Paraffin, polyethylene wax (PE wax), polypropylene wax (PP wax),
It is one or more that ethane-acetic acid ethyenyl is copolymerized wax (EVA wax).
5. a kind of carbon dioxide of the layered structure constituted with amphiphilic substance described according to claim 1 or 3 or 4 is compound
Mask composition, it is characterised in that: the grease be vegetable fat, animal fat, Synthetic Oil it is one or more.
6. a kind of carbon dioxide composite facial mask group of layered structure constituted with amphiphilic substance according to claim 5
Close object, it is characterised in that: the amphiphilic substance be cationic substance, anionic species, nonionic it is one or more.
7. a kind of carbon dioxide composite facial mask group of layered structure constituted with amphiphilic substance according to claim 6
Close object, it is characterised in that: the amphiphilic substance has hydrophilic group and lipophilic group, can be cationic surfactant, anion
Surfactant, amphoteric surfactant, one kind of nonionic surfactant and or a variety of.
8. a kind of carbon dioxide composite surface of layered structure constituted with amphiphilic substance according to claim 1 or claim 7
Film composition, it is characterised in that: the emulsion adjuvant is Long carbon chain alcohol, and mainly carbon number is in 12 or more higher alcohols；It is wherein described
Long carbon chain alcohol be laruyl alcohol, palmityl alcohol, cetanol, stearyl alcohol, cetostearyl alcohol, docosyl alcohol, arachidic alcohol it is one or more.
9. a kind of carbon dioxide composite facial mask group of layered structure constituted with amphiphilic substance according to claim 8
Close object, it is characterised in that: the water soluble acid is 'alpha '-hydroxy acids, glucolactone, ascorbic acid, 4- hydroxyethyl piperazine second sulphur
Acid is one or more.
10. a kind of carbon dioxide composite surface of the layered structure constituted with amphiphilic substance according to claim 1 or described in 9
Film composition, it is characterised in that: the carbonate is sodium bicarbonate, saleratus, calcium bicarbonate, magnesium bicarbonate, sodium carbonate, carbon
Sour potassium, calcium carbonate, barium carbonate, one kind of magnesium carbonate or more.
11. a kind of carbon dioxide composite surface of layered structure constituted with amphiphilic substance according to claim 1 or claim 7
Film composition, it is characterised in that: the form of the mask composition can be following form:
1) carbon dioxide of the adhesive matrix for the layered structure that there is carbonate containing amphiphilic substance to constitute and containing water-soluble acid hair
The composition of raw agent；
2) adhesive matrix for the layered structure that there is containing water-soluble acid amphiphilic substance to constitute and carbonato carbon dioxide hair
The composition of raw agent；
3) group of the adherent base plastid with layer structure and the carbon dioxide generation agent simultaneously containing carbonate and water soluble acid
Close object.
12. a kind of carbon dioxide composite facial mask of layered structure constituted with amphiphilic substance according to claim 1
Composition, it is characterised in that: water-soluble solid ingredient is glucose, sucrose, xylitol, chlorine in the carbon dioxide generation agent
Change one kind of sodium, zinc gluconate, calcium gluconate, sodium gluconate, magnesium gluconate, copper gluconate, solid amino acid
Or more.
13. a kind of carbon dioxide composite facial mask of layered structure constituted with amphiphilic substance according to claim 1
Composition, it is characterised in that: active constituent is ascorbic acid, ascorbic acid derivates, paddy in the carbon dioxide generation agent
The sweet peptide of Guang, one kind of retinol or more.
14. a kind of carbon dioxide composite facial mask of layered structure constituted with amphiphilic substance according to claim 1
Composition, it is characterised in that: after adhesive matrix and the solid powder mixing with layered structure, the water of 10% mixture
PH value of solution is 5.5~6.5.
15. a kind of carbon dioxide composite facial mask of layered structure constituted with amphiphilic substance according to claim 1
Composition, it is characterised in that: the adhesive matrix preparation method with layer structure the following steps are included:
1) 80~90 DEG C are heated water to, water phase is made in moisturizer, thickener stirring and dissolving in water；
2) liquid fat, amphiphilic substance, emulsion adjuvant are heated to 80~90 DEG C, dissolve and oily phase is made；
3) water phase is added in oily phase, 4~10min of homogeneous is kept the temperature with homogeneous speed 6000rpm~10000rpm；
4) after homogeneous, natural cooling cools down at 150~300rpm, is down to 45 DEG C hereinafter, preservative stirring is added to temperature
It is even；
5) part water is added and dissolves 0~5% water soluble acid or 0~5% carbonate in advance, stir evenly.
16. according to claim 1 or a kind of carbon dioxide of the layered structure constituted with amphiphilic substance described in 15 is compound
Mask composition, it is characterised in that: the carbon dioxide generation agent preparation method is the following steps are included: by carbonate, water solubility
Acid, active constituent, thickener, excess water mixing are uniform.
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| CN201811044360.6A CN109010083B (en) | 2018-09-07 | 2018-09-07 | Carbon dioxide composite facial mask composition with layered structure composed of amphiphilic substances and preparation method thereof |
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|---|---|---|---|---|
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