CN108977098A - 压敏pvc覆盖条带 - Google Patents

压敏pvc覆盖条带 Download PDF

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CN108977098A
CN108977098A CN201810550706.3A CN201810550706A CN108977098A CN 108977098 A CN108977098 A CN 108977098A CN 201810550706 A CN201810550706 A CN 201810550706A CN 108977098 A CN108977098 A CN 108977098A
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CN108977098B (zh
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M·J·斯卡尼斯
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Carlisle Intangible LLC
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/245—Vinyl resins, e.g. polyvinyl chloride [PVC]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/22—Layered products comprising a layer of synthetic resin characterised by the use of special additives using plasticisers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/29—Laminated material
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/383—Natural or synthetic rubber
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/40—Adhesives in the form of films or foils characterised by release liners
    • C09J7/401—Adhesives in the form of films or foils characterised by release liners characterised by the release coating composition
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/50—Adhesives in the form of films or foils characterised by a primer layer between the carrier and the adhesive
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D13/00—Special arrangements or devices in connection with roof coverings; Protection against birds; Roof drainage ; Sky-lights
    • E04D13/15—Trimming strips; Edge strips; Fascias; Expansion joints for roofs
    • E04D13/155—Trimming strips; Edge strips; Fascias; Expansion joints for roofs retaining the roof sheathing
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D5/00—Roof covering by making use of flexible material, e.g. supplied in roll form
    • E04D5/10—Roof covering by making use of flexible material, e.g. supplied in roll form by making use of compounded or laminated materials, e.g. metal foils or plastic films coated with bitumen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C09J123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C09J123/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefines
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2409/00—Presence of diene rubber
    • C09J2409/001—Presence of diene rubber in the barrier layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2413/00—Presence of rubbers containing carboxyl groups
    • C09J2413/001—Presence of rubbers containing carboxyl groups in the barrier layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2423/00—Presence of polyolefin
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2427/00—Presence of halogenated polymer
    • C09J2427/006—Presence of halogenated polymer in the substrate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2433/00—Presence of (meth)acrylic polymer
    • C09J2433/003—Presence of (meth)acrylic polymer in the primer coating
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D13/00—Special arrangements or devices in connection with roof coverings; Protection against birds; Roof drainage ; Sky-lights
    • E04D13/04—Roof drainage; Drainage fittings in flat roofs, balconies or the like
    • E04D13/0404—Drainage on the roof surface
    • E04D13/0459—Drainage borders, e.g. dripping edges, gravel stops or dispersers
    • E04D2013/0468—Drip edges
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D5/00—Roof covering by making use of flexible material, e.g. supplied in roll form
    • E04D5/12—Roof covering by making use of flexible material, e.g. supplied in roll form specially modified, e.g. perforated, with granulated surface, with attached pads

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Laminated Bodies (AREA)
  • Adhesive Tapes (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

一种设计用于结合至非PVC材料以及PVC材料的PVC基覆盖条带包括涂覆有有效防止增塑剂从PVC层迁移的隔离的PVC层。隔离层依次涂覆有底涂料并且随后涂覆有压敏粘合剂。隔离层通常是极性聚合物，例如耐邻苯二甲酸酯增塑剂迁移的丙烯腈橡胶。压敏粘合剂层是适用于屋顶应用的压敏粘合剂。

Description

压敏PVC覆盖条带
背景技术
在屋顶产业中，覆盖条带通常用于将两种材料结合在一起，例如边缘条带和屋顶膜。通常，这些是涂覆有压敏粘合剂层的6至9英寸宽的膜条带。传统的PVC屋顶膜含有液体邻苯二甲酸酯增塑剂，该液体邻苯二甲酸酯增塑剂将会侵蚀屋顶市场中的许多传统压敏(PS)粘合剂。目前，没有制造商为PVC屋顶提供PS覆盖条带产品。这对于处理边缘金属是有问题的。目前，与PVC膜屋顶一起使用的所有边缘金属都必须进行PVC涂覆，以允许非PS PVC防水板焊接到金属以及PVC屋顶膜。这限制了金属可用的颜色。最后，目前还没有简单的方法将PVC屋顶膜搭接至EPDM或TPO膜而在两个膜间没有缘饰。
发明内容
本发明提供了一种底涂料和PS粘合剂的系统，其允许生产待粘附到包括PVC和KEEPVC膜、金属饰边、EPDM和TPO屋顶膜的各种基材的PS PVC覆盖条带。所提出的PS PVC覆盖条带的构造使用了一系列底涂料，这些底涂料允许普通屋顶PS粘合剂与PVC膜一起使用。第一底涂料提供了高增塑剂抗性层。这防止来自PVC膜的增塑剂侵蚀PS粘合剂。第二底涂料为PS粘合剂的粘合准备PVC表面。PS粘合剂必须充分构建为允许适应突降、长期性能、耐积水以及与其他常见的单层屋顶材料兼容。
附图说明
图1是根据本发明的覆盖条带的横截面图；
图2是用于与边缘终端一起使用的本发明的覆盖条带的横截面图；以及
图3是示出了覆盖条带在PVC膜和非PVC膜上的应用的部分分解横截面图。
具体实施方式
如图1所示，本发明是一种覆盖条带10，其包含通常用于屋顶应用类型的通常约60密耳厚的上PVC层12。PVC层12的底表面涂覆有隔离层14，该隔离层14防止增塑剂从PVC层12迁移。隔离层14又涂覆有底涂料层16，该底涂料层16又涂覆有压敏(PS)粘合剂层18。最后，PS层覆盖有硅橡胶涂覆分离片22。覆盖条带将是6-12英寸宽，通常为6-9英寸宽。
隔离层14是防止通常用于PVC膜中的邻苯二甲酸酯型增塑剂迁移的层。通常，隔离层将是极性聚合物。一种适用于本发明的极性聚合物是丙烯腈橡胶或NBR，其直接应用到表面和PVC并被允许凝固。通常这将是0.167密耳至2.5密耳厚。
底涂料的组成将由压敏粘合剂的组成决定。通常，底涂料将为0.2密耳至0.6密耳厚。压敏粘合剂可以是通常用于屋顶应用中的任何压敏粘合剂，例如溴化丁基橡胶、压敏粘合剂等。其他合适的压敏粘合剂可以是基于丁基、聚异丁烯、卤丁基或其他合适的聚合物。底涂料通常具有类似的组成，但固体含量低。底涂料被简单地应用到隔离层14并允许凝固。然后，将压敏粘合剂层18和分离片22层压至底涂料层18。
图2示出了本发明的将刚性边缘构件30应用至覆盖有PVC膜34的屋顶表面32的使用。在该应用中，将PVC膜34如通常在屋顶应用期间所做的那样应用至屋顶32。连接条带33钉固至屋顶32的角落。边缘终端条带30在一个边缘处接合至连接条带33并钉固至屋顶32，从而将PVC膜挤陷于屋顶表面和边缘处理部30之间。本应用中的边缘处理部30没有涂覆PVC涂层，反而可以是涂绘金属表面等。基本上，在此应用中，可以使用任何非PVC涂覆边缘处理部。
将覆盖条带10应用在边缘处理部30上和PVC膜34上。通常与隔离涂层14相同的条带隔离涂层36和底涂料涂层38(也与图1中的底涂料涂层16相同)应用至PVC膜34。将分离片22从覆盖条带10移除并且将覆盖条带10应用至PVC 34的隔离和底涂料涂覆部分上并直接应用到边缘处理部30的上表面40上。密封剂42可以应用在覆盖条带10的任一边缘处以提供另外的防水隔离，但不是必需的。压敏粘合剂层18将使用底涂料层38直接结合到边缘处理部的表面40并且进一步结合到涂覆有单独的隔离层36和单独的底涂料层38的PVC 34。
图3示出了本发明的另一种使用，其中覆盖条带10用于将PVC膜50结合至非PVC膜52，例如TPO，EPDM等。PVC膜50的边缘54首先涂覆有隔离层56的条带并且随后涂覆有底涂料层58。由于非PVC膜52不包含增塑剂，所以非PVC膜52不需要隔离层。但是将底涂料58的条带应用至膜52的边缘62以改善对PSA的粘合。将覆盖条带10简单地直接应用至两个膜的边缘部分。压敏粘合剂18将结附至PVC层上的底涂料层58并直接结合至非PVC膜52的表面。此外，保护覆盖条带上的压敏粘合剂免受PVC中存在的增塑剂。此外，不需要焊接来形成任何结合。
已经连同实施本发明的优选方法对本发明进行了描述。然而，本发明本身应该仅由所附权利要求限定。

Claims (8)

1.一种具有压敏层的PVC覆盖条带，所述覆盖条带包括：
PVC膜层，其具有第一表面和第二表面；
所述第二表面涂覆有隔离层；
所述隔离层有效防止来自所述PVC膜的邻苯二甲酸酯迁移；
所述隔离层又涂覆有底涂料层，所述底涂料层然后涂覆有压敏粘合剂层。
2.根据权利要求1所述的覆盖条带，其中，所述隔离层是丙烯腈橡胶。
3.如权利要求1或2所述的覆盖条带，其中，所述压敏粘合剂是溴化丁基橡胶。
4.一种包括PVC膜条带的覆盖条带，所述PVC膜条带具有涂覆有丙烯腈隔离层并又涂覆有压敏粘合剂层的底表面。
5.一种用于包括根据权利要求1,2,3或4中任一项所述的覆盖条带的屋顶的边缘处理部。
6.一种具有根据权利要求1,2,3或4中任一项所述的覆盖条带的屋顶表面。
7.一种用于屋顶的边缘处理部，其中所述屋顶涂覆有PVC膜，所述边缘处理部包括：
金属面板条带，其固定至所述屋顶，所述PVC膜挤陷于所述面板构件和所述屋顶之间；
覆盖条带，其将所述面板条带结合至所述PVC膜；
其中，所述覆盖条带包括外PVC层，其中所述PVC层具有覆盖有有效防止增塑剂迁移的隔离层的底表面；
其中，所述隔离层又涂覆有压敏粘合剂层。
8.一种具有与非PVC层相邻的PVC层的屋顶表面，其中，所述PVC层通过覆盖条带结合至所述非PVC层；
所述覆盖条带包括PVC层，所述PVC层又涂覆有隔离层和压敏粘合剂层；
其中，所述PVC层的边缘部分覆盖有所述隔离层并且所述PVC层和所述非PVC层均覆盖有底涂料层。
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