CN1088050C - 使用β－沸石的烷基化方法 - Google Patents

使用β－沸石的烷基化方法 Download PDF

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Publication number
CN1088050C
CN1088050C CN97198573A CN97198573A CN1088050C CN 1088050 C CN1088050 C CN 1088050C CN 97198573 A CN97198573 A CN 97198573A CN 97198573 A CN97198573 A CN 97198573A CN 1088050 C CN1088050 C CN 1088050C
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CN
China
Prior art keywords
benzene
ethylene
catalyst
stream
ethylbenzene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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CN97198573A
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English (en)
Chinese (zh)
Other versions
CN1239471A (zh
Inventor
D·E·亨德里克森
J·R·莱特纳
M·J·G·詹森
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
ExxonMobil Chemical Patents Inc
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Filing date
Publication date
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Publication of CN1239471A publication Critical patent/CN1239471A/zh
Application granted granted Critical
Publication of CN1088050C publication Critical patent/CN1088050C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C07C15/073—Ethylbenzene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S203/00—Distillation: processes, separatory
    • Y10S203/06—Reactor-distillation

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
CN97198573A 1996-09-06 1997-09-05 使用β－沸石的烷基化方法 Expired - Lifetime CN1088050C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US2557796P 1996-09-06 1996-09-06
US60/025,577 1996-09-06

Publications (2)

Publication Number Publication Date
CN1239471A CN1239471A (zh) 1999-12-22
CN1088050C true CN1088050C (zh) 2002-07-24

Family

ID=21826869

Family Applications (1)

Application Number Title Priority Date Filing Date
CN97198573A Expired - Lifetime CN1088050C (zh) 1996-09-06 1997-09-05 使用β－沸石的烷基化方法

Country Status (9)

Country Link
US (1) US6002057A (enExample)
EP (1) EP0929502B1 (enExample)
JP (1) JP4275739B2 (enExample)
CN (1) CN1088050C (enExample)
AU (1) AU743095B2 (enExample)
CA (1) CA2264700C (enExample)
DE (1) DE69705958T2 (enExample)
ES (1) ES2162327T3 (enExample)
WO (1) WO1998009928A2 (enExample)

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US5894076A (en) * 1997-05-12 1999-04-13 Catalytic Distillation Technologies Process for alkylation of benzene
US5880320A (en) 1997-08-05 1999-03-09 Netzer; David Combination process for manufacturing ethylene ethylbenzene and styrene
IT1299035B1 (it) * 1998-04-07 2000-02-07 Enichem Spa Processo per la preparazione di composti aromatici monoalchilati
US5977423A (en) * 1998-06-19 1999-11-02 Netzer; David Mixed phase ethylation process for producing ethylbenzene
US6252126B1 (en) 1998-06-19 2001-06-26 David Netzer Method for producing ethylbenzene
US6783659B2 (en) 2001-11-16 2004-08-31 Chevron Phillips Chemical Company, L.P. Process to produce a dilute ethylene stream and a dilute propylene stream
BR0214206B1 (pt) * 2001-11-16 2013-02-19 processo para a produÇço de um fluxo de etileno diluÍdo e um fluxo de propileno diluÍdo.
US6878327B2 (en) * 2002-04-19 2005-04-12 Fina Technology, Inc. Process of making polypropylene fibers
WO2004000974A1 (en) 2002-06-19 2003-12-31 Exxonmobil Chemical Patents Inc. Manufacture of xylenes from reformate
WO2004000768A1 (en) * 2002-06-19 2003-12-31 Exxonmobil Chemical Patents Inc. Manufacture of xylenes by reactive distillation of reformate
US7119239B2 (en) 2002-06-19 2006-10-10 Exxonmobil Chemical Patents Inc. Manufacture of xylenes using reformate
EP1479663A1 (en) * 2003-05-17 2004-11-24 Haldor Topsoe A/S Process for catalytic alkylation of monocyclic aromatic compounds and composition of use therein
US7071369B2 (en) 2003-06-10 2006-07-04 Abb Lummus Global Inc. Process for the production of alkylbenzene with ethane stripping
US20040254414A1 (en) 2003-06-11 2004-12-16 Hildreth James M. Process for production of propylene and ethylbenzene from dilute ethylene streams
US7259282B2 (en) * 2003-09-08 2007-08-21 Abb Lummus Global Inc. Process for production of ethylbenzene from dilute ethylene streams
EP1780786A4 (en) * 2004-06-07 2009-11-25 Nikon Corp STAGE DEVICE, EXPOSURE DEVICE AND EXPOSURE METHOD
TWI376361B (en) * 2004-08-13 2012-11-11 Exxonmobil Chem Patents Inc Process for producing phenol and methyl ethyl ketone
US7348465B2 (en) 2005-02-08 2008-03-25 Shell Oil Company Selective alkylation of aromatic hydrocarbons
US7488861B2 (en) * 2005-03-17 2009-02-10 Catalytic Distillation Technologies Process for the co-production of cumene and secondary butyl benzene
US20060247479A1 (en) * 2005-04-29 2006-11-02 Nova Chemicals Inc. Ethyl benzene from refinery grade feedstocks
US7326815B2 (en) * 2005-12-27 2008-02-05 Exxonmobil Chemical Patents Inc. Selective oxidation of alkylbenzenes
BRPI0706421A2 (pt) * 2006-01-07 2011-03-29 Fina Technology alquilação em fase lìquida diluìda
US20080058566A1 (en) * 2006-09-05 2008-03-06 Fina Technology, Inc. Processes for reduction of alkylation catalyst deactivation utilizing low silica to alumina ratio catalyst
US9375706B2 (en) 2006-09-05 2016-06-28 Fina Technology, Inc. Use of swing preliminary alkylation reactors
CN101784507A (zh) 2007-08-22 2010-07-21 埃克森美孚化学专利公司 仲丁基苯的制备方法
EP2098498A1 (en) 2008-03-04 2009-09-09 ExxonMobil Chemical Patents Inc. Selective oligomerization of isobutene
EP2110368A1 (en) 2008-04-18 2009-10-21 Total Petrochemicals France Alkylation of aromatic substrates and transalkylation process
US20110092742A1 (en) * 2008-08-26 2011-04-21 Dakka Jihad M Process for Producing Alkylbenzene Hydroperoxides
US8865958B2 (en) * 2008-09-30 2014-10-21 Fina Technology, Inc. Process for ethylbenzene production
WO2010042269A1 (en) 2008-10-10 2010-04-15 Exxonmobil Chemical Patents Inc. Process for producing phenol and methyl ethyl ketone
US8440864B2 (en) * 2008-10-10 2013-05-14 Exxonmobil Chemical Patents Inc. Process for producing sec-butylbenzene
KR20110086162A (ko) 2008-12-15 2011-07-27 엑손모빌 케미칼 패턴츠 인코포레이티드 알킬방향족 화합물의 산화
US8455383B2 (en) * 2009-09-28 2013-06-04 Fina Technology, Inc. Process for catalyst regeneration and extended use
RU2505515C1 (ru) * 2010-06-11 2014-01-27 Юоп Ллк Способ и устройство для снижения содержания бензола в бензине при алкилировании разбавленным этиленом
EP3313962A1 (en) 2015-06-29 2018-05-02 SABIC Global Technologies B.V. Process for producing cumene and/or ethylbenzene from a mixed hydrocarbon feedstream
CN107922289B (zh) * 2015-09-07 2021-01-26 沙特基础工业全球技术有限公司 使用混合烯烃流股作为烷基化剂生产枯烯和/或仲丁苯的方法
CN111450662B (zh) * 2020-05-29 2022-08-02 山东京博石油化工有限公司 一种用于制乙苯的原料干气的净化方法及装置

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Publication number Priority date Publication date Assignee Title
US4891458A (en) * 1987-12-17 1990-01-02 Innes Robert A Liquid phase alkylation or transalkylation process using zeolite beta
FR2689501A1 (fr) * 1992-04-01 1993-10-08 Atochem Elf Sa Procédé de fabrication d'éthylbenzène.

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US4215011A (en) * 1979-02-21 1980-07-29 Chemical Research And Licensing Company Catalyst system for separating isobutene from C4 streams
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DE3267236D1 (en) * 1981-04-02 1985-12-12 Mobil Oil Corp Zeolite, method of preparing same, and catalytic conversion therewith
US4443559A (en) * 1981-09-30 1984-04-17 Chemical Research & Licensing Company Catalytic distillation structure
NZ204091A (en) * 1982-05-18 1986-03-14 Mobil Oil Corp Manufacture of synthetic crystalling zeolite beta with a low aluminium content
US4440871A (en) * 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
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US4554145A (en) * 1984-04-16 1985-11-19 Mobil Oil Corporation Preparation of crystalline silicate zeolite Beta
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NZ212014A (en) * 1984-06-11 1988-05-30 Mobil Oil Corp Preparation of a zeolite and composition thereof
US5081323A (en) * 1987-12-17 1992-01-14 Chevron Research And Technology Company Liquid phase alkylation or transalkylation process using zeolite beta
US5082990A (en) * 1988-10-28 1992-01-21 Chevron Research And Technology Company Alkylation of aromatics-containing refinery streams
IT1237198B (it) * 1989-11-16 1993-05-26 Eniricerche Spa Processo per l'alchilazione di composti aromatici.
US5454913A (en) * 1990-02-06 1995-10-03 Koch Engineering Company, Inc. Internals for distillation columns including those for use in catalytic reactions
ATE122908T1 (de) * 1990-03-30 1995-06-15 Koch Eng Co Inc Struktur und verfahren zum katalytischen reagieren von fluidströmen in einem stoffaustauschapparat.
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Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
US4891458A (en) * 1987-12-17 1990-01-02 Innes Robert A Liquid phase alkylation or transalkylation process using zeolite beta
FR2689501A1 (fr) * 1992-04-01 1993-10-08 Atochem Elf Sa Procédé de fabrication d'éthylbenzène.

Also Published As

Publication number Publication date
EP0929502A2 (en) 1999-07-21
US6002057A (en) 1999-12-14
DE69705958D1 (de) 2001-09-06
CA2264700C (en) 2006-11-21
ES2162327T3 (es) 2001-12-16
DE69705958T2 (de) 2002-04-04
JP4275739B2 (ja) 2009-06-10
AU743095B2 (en) 2002-01-17
WO1998009928A2 (en) 1998-03-12
JP2001503025A (ja) 2001-03-06
AU4254797A (en) 1998-03-26
CN1239471A (zh) 1999-12-22
CA2264700A1 (en) 1998-03-12
EP0929502B1 (en) 2001-08-01
WO1998009928A3 (en) 1999-04-15

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SE01 Entry into force of request for substantive examination
C53 Correction of patent of invention or patent application
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Applicant after: Exxon Chemical Patents Inc.

Applicant before: Exxon Chemical Patents Inc.

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Free format text: CORRECT: APPLICANT; FROM: EXXON CHEMICAL PATENTS INC. TO: EXXON.MOBIL CHEMICAL PATENTS CORP.

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