CN108721132B - Suspended oil bead toning lotion containing sucrose acetate isobutyrate and preparation method thereof - Google Patents
Suspended oil bead toning lotion containing sucrose acetate isobutyrate and preparation method thereof Download PDFInfo
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- CN108721132B CN108721132B CN201810536535.9A CN201810536535A CN108721132B CN 108721132 B CN108721132 B CN 108721132B CN 201810536535 A CN201810536535 A CN 201810536535A CN 108721132 B CN108721132 B CN 108721132B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/044—Suspensions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/10—General cosmetic use
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
Abstract
The invention discloses a suspended oil bead toning lotion containing sucrose acetate isobutyrate and a preparation method thereof, the sucrose acetate isobutyrate is selected to be compounded with synthetic grease, vegetable grease and mineral oil, the selection range is wider, preservatives and oily color additives can be added, the oil phase selection space is large, the appearance color is diversified, the effect selection range is wide, the risk of microorganisms can be relatively more effectively controlled, meanwhile, the water phase thickening agent can be selected from different types such as inorganic high molecules, natural gums and the like, the selection of a thickening system can be expanded, and different skin feels can be given to products.
Description
Technical Field
The invention relates to the field of cosmetics, in particular to toning lotion with suspended oil droplets and a preparation method thereof.
Background
With the improvement of the life quality of people, cosmetics become skin care necessities in the life of women. The lotion is used as the first step in skin care, and the effect of the lotion cannot be ignored. For non-emulsified oil-water mixed water aqua products, the combined action of water replenishing and water locking achieves a better moisturizing effect than that of pure water aqua products, so that the skin is durably moisturized. The water aqua products of non-emulsified oil-water mixed type on the market at present have Europe clear moisturizing water, Korea ink chrysanthemum super-moist water, and the oil phases of the products are all silicon oil type grease, wherein the grease with the density rho more than 1 is trimethyl pentaphenyl trisiloxane. CN107595761A discloses a suspended oil bead toning lotion, which comprises a suspending agent, an oily component, a neutralizer and a toning lotion base material, wherein the oily component is one or more of phenyl polymethylsiloxane, phenyl polytrimethylsiloxane, diphenyl siloxy phenyl polytrimethylsiloxane, trimethyl pentaphenyl trisiloxane and diphenyl polydimethylsiloxane, and the components and the contents of the components are coordinated to prepare the suspended oil bead toning lotion which has high appearance transparency and good fluidity and can be uniformly and stably prepared. No matter the technology is Europe clear moisturizing day water, Korea Meju super-moist grunt water or CN107595761A technology, the oil phase of the products is silicon oil grease, wherein the grease with rho > 1 is trimethyl pentaphenyl trisiloxane, is colorless transparent viscous liquid, and has the density of 1.097 g/mL. When preparing a lotion for suspending oil beads, it is necessary that the oil phase have a density approximately equal to that of the aqueous phase. Therefore, when trimethyl pentaphenyl trisiloxane is selected as a part of oil phase, when the density of the oil phase is adjusted, the range of other liquid oil phases is relatively narrow, only silicon oil phase can be selected, other synthetic oil, vegetable oil and mineral oil with different efficacies and skin feelings cannot be adopted, oil-soluble preservatives cannot be added into the silicon oil phase, the preservative capability of a system cannot be further enhanced, and the toxicity or irritation is increased due to the excessive use of a single preservative.
Disclosure of Invention
In order to solve the above-mentioned technology, the invention aims to provide an application of sucrose acetate isobutyrate in a non-silicone oil-water mixing and non-emulsifying water agent system.
Another object of the present invention is to provide a suspended oil bead lotion containing sucrose acetate isobutyrate.
In order to realize the purpose, the invention is realized by the following technical scheme:
the invention provides application of sucrose acetate isobutyrate in preparation of a non-silicone oil-water mixed non-emulsified water agent system. The sucrose acetate isobutyrate is light yellow transparent viscous liquid, the density is 1.15g/mL, and compared with trimethyl pentaphenyl trisiloxane, the sucrose acetate isobutyrate can be compounded by selecting synthetic grease, animal grease, vegetable grease and mineral oil under the condition of the same oil phase density, and the range is wider. The oily preservative and the oily color additive can be added, so that the oil phase selection space is large, the appearance color is diversified, the effect selection range is wide, and the risk of microorganisms can be relatively effectively controlled. Meanwhile, the water phase thickening agent can select different types such as inorganic high molecules, natural gums and the like, so that the selection of a thickening system can be expanded, and different skin feelings can be given to the product.
The non-emulsifying aqueous solution comprises an aqueous phase and an oil phase, wherein the density rho of the oil phaseOil phaseDensity of aqueous phase rhoAqueous phase±0.1。
The invention provides suspended oil bead toning lotion containing sucrose acetate isobutyrate, which comprises, by weight, 2-8% of grease, 0-1.2% of preservative, 0-2% of thickening agent, 2-10% of humectant, 1-5% of auxiliary components and the balance of water.
More preferably, the toning lotion containing suspended oil globules of sucrose acetate isobutyrate comprises, by weight, 3-6% of oil and fat, 0.3-1% of preservative, 0.2-1% of thickening agent, 5-9% of humectant, 1.5-5% of auxiliary components and the balance of water.
Further preferably, the toning lotion containing suspended oil globules of sucrose acetate isobutyrate comprises 3-4% of raw material oil and fat, 0.35-0.65% of preservative, 0.2-0.6% of thickening agent, 7-8% of humectant, 1.5-3% of auxiliary component and the balance of water by weight percentage.
The grease is non-silicone oil grease, which is obtained by compounding the substrate grease sucrose acetate isobutyrate with one or more of synthetic grease, vegetable grease, mineral oil and animal oil. The synthetic oil, the vegetable oil, the mineral oil and the animal oil are all liquid oil. The matrix oil sucrose acetate isobutyrate is light yellow transparent viscous liquid, and the density is 1.15 g/mL. The qualified and stable cosmetic water with suspended oil droplets requires that the density of the oil phase is approximately equal to that of the water phase, and the settlement-diffusion balance state of the oil droplets in the system can be achieved by adjusting the viscosity of the water phase, namely adjusting the compounding ratio of each liquid oil and the matrix oil and the particle size of the oil droplets in the oil phase. Preferably, sucrose acetate isobutyrate accounts for 40 to 70%, more preferably 42 to 55% by weight of the fat or oil. When the content of sucrose acetate isobutyrate in the grease is more than 70%, the oil drops sink, and when the content is less than 40%, the oil drops float. When the sucrose acetate isobutyrate accounts for 42-55% of the weight of the grease, the suspension oil drop toning lotion has better stability, oil drops do not float and sink, and the oil drops do not obviously aggregate after being placed.
The synthetic oils and fats according to the present invention include, but are not limited to, liquid paraffin, isopropyl myristate, isopropyl palmitate, 2-ethylhexyl palmitate, unsaturated fatty acids such as palmitic acid oleate, linoleic acid, isotridecanol isononanoate, isononyl isononanoate, isodecyl neopentanoate, neopentyl glycol diheptanoate, ethylhexyl methoxycinnamate, diisostearyl malate, tris (ethylhexanoate), isopropyl myristate, caprylic/capric triglyceride, ethylhexyl palmitate, caprylic/dicaprate, octyldodecanol, squalane, etc. More preferably, the synthetic fat or oil is a polar fat or oil such as caprylic/capric triglyceride, neopentyl glycol diheptanoate, octanediol dioctoic/dicaprate, etc., and sucrose acetate isobutyrate is more preferably compatible with most polar fats or oils.
The vegetable oil and fat include but are not limited to olive oil, rice bran oil, palm oil, soybean oil, sesame oil, peach kernel oil, jojoba seed oil, cottonseed oil, coconut oil, babassu oil, almond oil, avocado oil, wheat germ oil, macadamia nut oil and the like, and the preferred vegetable oil and fat is jojoba seed oil, macadamia nut seed oil and the like.
Including but not limited to whale oil, fish oil, and the like.
In order to ensure that the oil drops of the suspended oil bead toning lotion are stably and uniformly distributed in the water, the particle size of the oil drops needs to be controlled within 0.6mm +/-0.2, and the oil phase density rho needs to be metOil phaseDensity of aqueous phase rhoAqueous phase0.1. Preferably, the weight ratio of the sucrose acetate isobutyrate to the synthetic grease and the vegetable grease (or animal oil or mineral oil) is (1.96-2.35) to (1.05-1.44): (0.3-0.9). More preferably, the weight ratio of the sucrose acetate isobutyrate to the synthetic grease and vegetable grease (or animal oil or mineral oil) is (1.96-2.35) to (1.05-1.44): 0.6. or sucrose acetate isobutyrate and synthetic oil according to the weight ratio (2.23-2.75): (1.25-1.75).
The preservative comprises a water-soluble preservative and an oily preservative. In the suspension toning lotion containing silicon oil, an oily preservative cannot be added, and in order to achieve a better preservative and sterilization effect, the use of one preservative often seriously exceeds the safe use dosage, so that potential safety hazards are brought. In the non-silicone oil suspension cosmetic prepared by sucrose acetate isobutyrate, the invention preferably uses the combination of aqueous preservative and oily preservative. Preferably, at least one of propyl hydroxybenzoate, methyl hydroxybenzoate, phenoxyethanol and bis (hydroxymethyl) imidazolidinyl urea.
The thickening agent is selected from inorganic high molecules and natural gums, so that the thickening system is diversified in selection, and different skin feels are given to the product. Further comprises one or more of sodium/lithium magnesium silicate, transparent xanthan gum, gellan gum, dehydroxanthan gum, acacia, tragacanth gum, and guar gum.
More preferably any two of sodium/lithium magnesium silicate, dehydroxanthan gum, gellan gum and transparent xanthan gum according to (1-10): 1, compounding. Most preferably, any two of dehydroxanthan gum, gellan gum and sodium/lithium magnesium silicate are selected according to a ratio of 1: 1, compounding. By controlling the selection and the compounding proportion of the thickening agent, the suspended oil bead toning lotion which has high appearance transparency and good fluidity and can be uniform and stable can be obtained. When the amount of the thickener is more than 0.6%, the mobile phase becomes poor and is in the form of gel, and when the amount is less than 0.2%, the suspension ability becomes weak and a uniform and stable suspension state cannot be formed.
The humectant includes but is not limited to at least one of 1, 3-propylene glycol, 1, 3-butylene glycol, PEG-400, glyceryl polyether-26, dipropylene glycol, glycerin, ethylhexyl glycerin, sodium hyaluronate, and caprylyl glycol.
The auxiliary components include but are not limited to one or more of skin conditioning agents, antioxidants, electrolytes, perfumes, chelating agents, color additives and the like.
Such skin conditioning agents include, but are not limited to, dipotassium glycyrrhizinate, ethanol, and the like.
The antioxidants include, but are not limited to, butylated hydroxytoluene, pentaerythritol tetrakis (di-t-butyl hydroxyhydrocinnamate), tocopherol acetate, tocopherol (vitamin E), and the like.
The electrolyte includes, but is not limited to, calcium chloride and the like.
Such chelating agents include, but are not limited to, disodium EDTA and the like.
The color additives include, but are not limited to, oil-soluble pigments (CI 77492, CI 77491, etc.), colored oil-soluble materials (marigold flower (TAGETES ERECTA) flower extract/safflower (Carthamus TINCTORIUS) seed oil), sunflower (Helianthus ANNUUS) seed oil), etc. By compounding the oily color additive, the appearance color diversity is prepared and is pleasant.
The invention also comprises a preparation method of the suspended oil bead toning lotion, which comprises the following steps:
step (1) water phase: adding the thickening agent into the room-temperature humectant, and uniformly premixing to obtain a premixed phase; adding water into the main kettle, adding the premixed phase and the aqueous preservative into water at room temperature, stirring and heating to 80-85 ℃, fully swelling, cooling to 60-65 ℃, adding electrolyte, cooling to 40-45 ℃, adding a skin regulator, and detecting the density of the water phase;
step (2) oil phase: according to the density of the water phase, the usage amount of sucrose acetate isobutyrate and other liquid oil in the oil phase is calculated, and rho is adjustedOil phase=ρAqueous phase+/-0.01, adding an oil phase preservative and an antioxidant, heating to more than 75 ℃ until the mixture is dissolved and transparent, cooling to 40 +/-5 ℃, adding a color additive, and uniformly stirring;
and (3) finishing: adding the oil phase into the water phase of the main kettle under the stirring condition until the oil drops are suspended in the water phase, stirring or homogenizing, confirming the particle size of the oil drops once every 15-60s, if the particle size of the oil drops does not reach the standard, increasing the stirring or homogenizing speed until the particle size of the oil drops is within the range of 0.6mm +/-0.2, and discharging after the detection is qualified.
And (3) preferably, adding the oil phase into the water phase in the main kettle under the condition of stirring until the oil drops are suspended in the water phase, homogenizing at the stirring speed of over 600rpm or the lowest speed of homogenizing equipment, confirming the particle size of the oil drops once every 30 seconds, if the particle size of the oil drops does not reach the standard, properly increasing the stirring or homogenizing speed until the particle size of the oil drops is within the range of 0.6mm +/-0.2, and discharging after the detection is qualified.
Compared with the prior art, the invention has the following beneficial effects:
1. compared with trimethyl pentaphenyl trisiloxane, the sucrose acetate isobutyrate has wider range of selecting synthetic grease, vegetable grease and mineral oil under the condition of the same oil phase density, and can be added with preservative and oily color additive, thereby achieving large oil phase selection space, diversified appearance colors, wide effect selection range and relatively more effective control of microbial risk. Meanwhile, the water phase thickening agent can select different types such as inorganic high molecules, natural gums and the like, so that the selection of a thickening system can be expanded, and different skin feelings can be given to the product.
2. The suspended oil drop toning lotion prepared by the specific compounding proportion of the specific matrix oil sucrose acetate isobutyrate and other oils has better stability, oil drops do not float up or sink, the oil drops are not obviously gathered, and the particle size of the oil drops is within the range of 0.6mm +/-0.2. The cosmetic water containing the suspended oil beads has high appearance transparency, good fluidity, uniformity and stability, can realize coexistence of oil and water without adding an additional emulsifier, reduces stimulation of the emulsifier to skin, and endows the product with fresh, cool, easy absorption and non-greasy skin feeling.
3. Compared with the suspended oil toning lotion prepared from trimethyl pentaphenyl trisiloxane, the toning lotion has stronger stability, particularly has no precipitation in low-temperature environment, and is suitable for storage and transportation in cold regions.
4. Compared with the silicone oil-water mixed non-emulsified aqueous solution products on the market, the non-silicone oil-water mixed non-emulsified aqueous solution has better moisturizing effect.
Drawings
FIG. 1 is a comparative graph of the oil phase stability experiment of the cosmetic water containing suspended oil beads of the present invention.
FIG. 2 is a characteristic diagram of the cosmetic water containing suspended oil droplets according to the present invention.
Detailed Description
The following detailed description of the present invention is provided in conjunction with the accompanying drawings, but it should be understood that the scope of the present invention is not limited to the specific embodiments.
Throughout the specification and claims, unless explicitly stated otherwise, the word "comprise", or variations such as "comprises" or "comprising", will be understood to imply the inclusion of a stated element or component but not the exclusion of any other element or component.
Table 1 examples 1 and 2 the respective component ratios (in weight percent)
The preparation method comprises the following steps:
(1) water phase: adding transparent xanthan gum, gellan gum and sodium hyaluronate into glycerol, premixing uniformly to obtain a premixed phase, adding water into a main kettle, adding the premixed phase and methyl hydroxybenzoate into room-temperature water, stirring and heating to 80-85 ℃, fully swelling, cooling to 60-65 ℃, adding calcium chloride, cooling to 40-45 ℃, adding bis (hydroxymethyl) imidazolidinyl urea, caprylyl glycol and ethanol, and detecting the density of an aqueous phase;
(2) oil phase: according to the density of the water phase, calculating the dosage of each liquid grease in the oil phase, and controlling rhoOil phase=ρAqueous phase+/-0.01, then adding propyl hydroxybenzoate and butylated hydroxytoluene, heating to over 75 ℃ until the mixture is dissolved and transparent, and cooling to about 40 ℃;
(3) and (3) finished product: and adding the oil phase into the water phase of the main kettle under the stirring condition until oil drops are suspended in the water phase, wherein the particle size of the oil drops is within the range of 0.6mm +/-0.2, and discharging after the detection is qualified.
TABLE 2 examples 3-5 the proportions of the ingredients (in weight percent)
The preparation method comprises the following steps:
(1) adding water into a main kettle, adding dehydro xanthan gum and gellan gum into glycerol, premixing uniformly to obtain a premixed phase, adding water into the main kettle, then adding the premixed phase, methyl hydroxybenzoate and electrolyte into the water at room temperature, stirring and heating to 80-85 ℃, fully swelling, cooling to 60-65 ℃, adding the electrolyte, cooling to 40-45 ℃, adding bis (hydroxymethyl) imidazolidinyl urea, ethanol, caprylyl glycol and sodium hyaluronate, and detecting the density of the water phase;
(2) according to the density of the water phase, calculating the dosage of each liquid grease in the oil phase, and controlling rhoOil phase=ρAqueous phase+/-0.01, then adding propyl hydroxybenzoate and butylated hydroxytoluene, heating to over 75 ℃ until the mixture is dissolved and transparent, cooling to 40-45 ℃, adding a color additive, and uniformly stirring;
(3) and adding the oil phase into the water phase of the main kettle under the stirring condition until oil drops are suspended in the water phase, wherein the particle size of the oil drops is within the range of 0.6mm +/-0.2, and discharging after the detection is qualified.
Table 3 examples 6-7:
the preparation method comprises the following steps:
(1) water phase: adding dehydroxanthan gum and gellan gum into glycerol, and premixing to obtain a premixed phase; adding water into the main kettle, adding the premixed phase, methyl hydroxybenzoate and calcium chloride into room-temperature water, stirring and heating to 80-85 ℃, fully swelling, cooling to 60-65 ℃, adding electrolyte, cooling to 40-45 ℃, adding bis (hydroxymethyl) imidazolidinyl urea and ethanol, and detecting the density of the water phase;
(2) oil phase: according to the density of the water phase, calculating the dosage of each liquid grease in the oil phase, and controlling rhoOil phase=ρAqueous phasePlus or minus 0.01, then adding propyl hydroxybenzoate and butylated hydroxytolueneHeating to above 75 deg.C for dissolving and transparency, cooling to 40-45 deg.C, adding color additive, and stirring;
(3) and (3) finished product: and adding the oil phase into the water phase of the main kettle under the stirring condition until oil drops are suspended in the water phase, wherein the particle size of the oil drops is within the range of 0.6mm +/-0.2, and discharging after the detection is qualified.
Table 4 examples 8-12:
the preparation method comprises the following steps:
step (1) water phase: adding a thickening agent into a humectant, premixing uniformly to obtain a premixed phase, adding water into a main kettle, adding the premixed phase and an aqueous preservative into water at room temperature, stirring and heating to 80-85 ℃, fully swelling, cooling to 60-65 ℃, adding an electrolyte, cooling to 40-45 ℃, adding a skin conditioning agent, and detecting the density of an aqueous phase;
step (2) oil phase: according to the density of the water phase, the usage amount of sucrose acetate isobutyrate and other liquid oil in the oil phase is calculated, and rho is adjustedOil phase=ρAqueous phase+/-0.01, adding an oil phase preservative and an antioxidant, heating to more than 75 ℃ until the mixture is dissolved and transparent, cooling to 40 +/-5 ℃, adding a color additive, and uniformly stirring;
and (3) finishing: and adding the oil phase into the water phase of the main kettle under the stirring condition until oil drops are suspended in the water phase, wherein the particle size of the oil drops is within the range of 0.6mm +/-0.2, and discharging after the detection is qualified.
Table 5 examples 13-14:
preparation process
Step (1) water phase: adding a thickening agent into a humectant, premixing uniformly to obtain a premixed phase, adding water into a main kettle, adding the premixed phase and an aqueous preservative into water at room temperature, stirring and heating to 80-85 ℃, fully swelling, cooling to 60-65 ℃, adding an electrolyte, cooling to 40-45 ℃, adding a skin conditioning agent, and detecting the density of an aqueous phase;
step (2) oil phase: according to the density of the water phase, the usage amount of sucrose acetate isobutyrate and other liquid oil in the oil phase is calculated, and rho is adjustedOil phase=ρAqueous phase+/-0.01, adding the oil phase preservative and the antioxidant, then adding the oil phase preservative and the antioxidant, heating to the temperature of over 75 ℃ until the mixture is dissolved and transparent, cooling to the temperature of 40 +/-5 ℃, adding the color additive, and uniformly stirring;
and (3) finishing: and adding the oil phase into the water phase of the main kettle under the stirring condition until oil drops are suspended in the water phase, wherein the particle size of the oil drops is within the range of 0.6mm +/-0.2, and discharging after the detection is qualified.
Table 6 examples 15-16:
the preparation method comprises the following steps:
step (1) water phase: adding a thickening agent into a humectant, premixing uniformly to obtain a premixed phase, adding water into a main kettle, adding the premixed phase and an aqueous preservative into water at room temperature, stirring and heating to 80-85 ℃, fully swelling, cooling to 60-65 ℃, adding an electrolyte, cooling to 40-45 ℃, adding a skin conditioning agent, and detecting the density of an aqueous phase;
step (2) oil phase: according to the density of the water phase, the usage amount of sucrose acetate isobutyrate and other liquid oil in the oil phase is calculated, and rho is adjustedOil phase=ρAqueous phase+/-0.01, adding the oil phase preservative and the antioxidant, then adding the oil phase preservative and the antioxidant, heating to the temperature of over 75 ℃ until the mixture is dissolved and transparent, cooling to the temperature of 40 +/-5 ℃, adding the color additive, and uniformly stirring;
and (3) finishing: and adding the oil phase into the water phase of the main kettle under the stirring condition until oil drops are suspended in the water phase, wherein the particle size of the oil drops is within the range of 0.6mm +/-0.2, and discharging after the detection is qualified.
Test example-stability and comparative test
The method comprises the following steps: the oil phase formulation of example 3 and the oil phase formulation of the comparative example are shown in Table 7, and the stability of the oil phase of the cosmetic water for suspended oil globules prepared is compared at low temperature of-18 ℃.
As a result: as shown in FIG. 1, the oil phase of the oil emulsion type make-up water emulsion prepared by adding an oily preservative and sucrose acetate isobutyrate to the oil phase formulation of example 3 was yellow and no precipitation was observed at-18 ℃ and the oil phase of the oil emulsion type make-up water emulsion prepared by adding an oily preservative to the system containing trimethylpentaphenyltrisiloxane oil and fat in the comparative example was transparent and no precipitation was observed at-18 ℃. The solubility of the mixed grease (containing synthetic grease, vegetable grease and the like) adopted by the invention on the propylparaben (oil-soluble solid) is proved to be greatly superior to that of a mixed silicone oil system. Therefore, the suspension toning lotion formula system of the invention has stronger practicability.
TABLE 7 oil phase composition
Test example two moisture retention test
Subject: see the formulation in Table 8
TABLE 8 moisture retention experiment ingredient table
The experimental method comprises the following steps: about 0.25g of each sample was applied to a 7.5cm × 7.5cm glass plate to which a 3M adhesive tape was attached, placed in a desiccator containing a saturated solution of sodium chloride (relative humidity: 78.5 ± 1%), allowed to stand for a certain period of time, weighed, and the moisture retention rates at different times were calculated.
Moisture retention rate%t/M0×100
Mt- -mass of water remaining after standing th;
M0- -mass of water before standing;
as a result: table 9 the non-silicone oil type oil-water mixed non-emulsified aqueous solution of the present invention has a slightly superior moisturizing effect compared to commercially available silicone oil type oil-water mixed non-emulsified aqueous solution products, and achieves rapid and lasting moisturizing.
Table 9 results of the moisture retention test
The foregoing descriptions of specific exemplary embodiments of the present invention have been presented for purposes of illustration and description. It is not intended to limit the invention to the precise form disclosed, and obviously many modifications and variations are possible in light of the above teaching. The exemplary embodiments were chosen and described in order to explain certain principles of the invention and its practical application to enable one skilled in the art to make and use various exemplary embodiments of the invention and various alternatives and modifications as are suited to the particular use contemplated. It is intended that the scope of the invention be defined by the claims and their equivalents.
Claims (15)
1. A suspended oil bead toning lotion containing sucrose acetate isobutyrate is characterized by comprising 2-8% of grease, 0-1.2% of preservative, 0-2% of thickening agent, 2-10% of humectant, 1-5% of auxiliary component and the balance of water by weight percentage; the grease is prepared from sucrose acetate isobutyrate and synthetic grease, vegetable grease or animal oil or mineral oil according to the weight ratio of (1.96-2.35) to (1.05-1.44): (0.3-0.9) or the grease is prepared by mixing sucrose acetate isobutyrate and synthetic oil according to the weight ratio of (2.23-2.75): (1.25-1.75).
2. The water according to claim 1, which comprises 3 to 6% by weight of the oil, 0.3 to 1% by weight of a preservative, 0.2 to 1% by weight of a thickener, 5 to 9% by weight of a humectant, 1.5 to 5% by weight of an auxiliary component, and the balance water.
3. The water according to claim 2, which comprises 3 to 4% by weight of the raw material oil, 0.35 to 0.65% by weight of a preservative, 0.2 to 0.6% by weight of a thickener, 7 to 8% by weight of a humectant, 1.5 to 3% by weight of an auxiliary component, and the balance of water.
4. The cosmetic water of suspended oil globules as claimed in any of claims 1 to 3, wherein the ratio by weight of sucrose acetate isobutyrate to synthetic, vegetable or animal or mineral oils (1.96-2.35) is (1.05-1.44): 0.6.
5. the water according to any one of claims 1 to 3, wherein the thickener is one or more selected from the group consisting of sodium/lithium magnesium silicate, xanthan gum, gellan gum, dehydroxanthan gum, gum arabic, tragacanth gum, guar gum.
6. The water according to claim 5, wherein the thickener is any two of sodium/lithium magnesium silicate, dehydroxanthan gum, gellan gum, and xanthan gum according to (1-10): 1, compounding.
7. The water according to any one of claims 1 to 3, wherein the humectant is at least one of 1, 3-propanediol, 1, 3-butanediol, PEG-400, glyceryl polyether-26, dipropylene glycol, glycerin, ethylhexyl glycerin, sodium hyaluronate, and caprylyl glycol.
8. The water according to any one of claims 1 to 3, wherein the auxiliary component is one or more of a skin conditioner, an antioxidant, an electrolyte, a perfume, a chelating agent, a color additive, and the like.
9. The cosmetic water as claimed in any one of claims 1 to 3, wherein the synthetic oil or fat is liquid paraffin, isopropyl myristate, isopropyl palmitate, 2-ethylhexyl palmitate, unsaturated fatty acids, palmitic acid oleate, linoleic acid, isotridecanol isononanoate, isononyl isononanoate, isodecyl neopentanoate, neopentyl glycol diheptanoate, ethylhexyl methoxycinnamate, diisostearyl malate, tris (ethylhexanoate) myristate, isopropyl myristate, caprylic/capric triglyceride, ethylhexyl palmitate, caprylic/dicaprate octanediol dioctanoate, octyldodecanol or squalane.
10. The suspended oil bead lotion according to claim 9, wherein the synthetic oil is caprylic/capric triglyceride, neopentyl glycol diheptanoate or octanediol dioctanoate/dicaprate.
11. The cosmetic water of any one of claims 1 to 3, wherein the vegetable oil is olive oil, rice bran oil, palm oil, soybean oil, sesame oil, persic oil, jojoba oil, cottonseed oil, coconut oil, babassu oil, almond oil, avocado oil, wheat germ oil, or macadamia nut oil.
12. The water according to claim 11, wherein the vegetable oil is jojoba oil or macadamia nut oil.
13. The water according to any one of claims 1 to 3, wherein the animal oil is whale oil or fish oil.
14. The cosmetic water according to any one of claims 1 to 3, wherein the preservative is a water-soluble preservative or an oily aqueous preservative, and the oily preservative is used in combination, and the preservative is one or more of propylparaben, methylparaben, phenoxyethanol, and bis-hydroxymethyl imidazolidinyl urea.
15. The method for preparing the suspended oil bead lotion containing sucrose acetate isobutyrate as set forth in claim 1, comprising the steps of:
step (1) water phase: adding the thickening agent into the room temperature humectant, and uniformly premixing to obtain a premixed phase; adding water into the main kettle, adding the premixed phase and the aqueous preservative into water at room temperature, stirring and heating to 80-85 ℃, fully swelling, cooling to 60-65 ℃, adding electrolyte, cooling to 40-45 ℃, adding a skin regulator, and detecting the density of the water phase;
step (2) oil phase: according to the density of the water phase, the usage amount of sucrose acetate isobutyrate and other liquid oil in the oil phase is calculated, and rho is adjustedOil phase=ρAqueous phase+/-0.01, adding an oil phase preservative and an antioxidant, heating to more than 75 ℃ until the mixture is dissolved and transparent, cooling to 40 +/-5 ℃, adding a color additive, and uniformly stirring;
and (3) finishing: adding the oil phase into the water phase of the main kettle under the stirring condition until the oil drops are suspended in the water phase, stirring or homogenizing, confirming the particle size of the oil drops once every 15-60s, if the particle size of the oil drops does not reach the standard, increasing the stirring or homogenizing speed until the particle size of the oil drops is within the range of 0.6mm +/-0.2, and discharging after the detection is qualified.
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EP3902512A4 (en) * | 2018-12-27 | 2022-12-21 | L'oreal | Anhydrous composition for caring for and/or making up keratin materials |
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JP7460123B2 (en) | 2020-03-12 | 2024-04-02 | 株式会社シーエスラボ | lotion |
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