CN1087189C - 铬基氟化催化剂及其制备方法和用途 - Google Patents

铬基氟化催化剂及其制备方法和用途 Download PDF

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Publication number
CN1087189C
CN1087189C CN94115127A CN94115127A CN1087189C CN 1087189 C CN1087189 C CN 1087189C CN 94115127 A CN94115127 A CN 94115127A CN 94115127 A CN94115127 A CN 94115127A CN 1087189 C CN1087189 C CN 1087189C
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CN
China
Prior art keywords
catalyst
chromium
fluorination
reaction
precursor
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Expired - Lifetime
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CN94115127A
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English (en)
Chinese (zh)
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CN1105951A (zh
Inventor
辻胜行
中条哲夫
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Resonac Holdings Corp
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Showa Denko KK
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Publication of CN1105951A publication Critical patent/CN1105951A/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/132—Halogens; Compounds thereof with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
    • C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B01J37/26—Fluorinating
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C07C17/21—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms with simultaneous increase of the number of halogen atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN94115127A 1993-09-07 1994-09-07 铬基氟化催化剂及其制备方法和用途 Expired - Lifetime CN1087189C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP22263393 1993-09-07
JP222633/93 1993-09-07

Publications (2)

Publication Number Publication Date
CN1105951A CN1105951A (zh) 1995-08-02
CN1087189C true CN1087189C (zh) 2002-07-10

Family

ID=16785516

Family Applications (1)

Application Number Title Priority Date Filing Date
CN94115127A Expired - Lifetime CN1087189C (zh) 1993-09-07 1994-09-07 铬基氟化催化剂及其制备方法和用途

Country Status (7)

Country Link
US (1) US5494873A (fr)
EP (1) EP0641598B1 (fr)
KR (1) KR100351211B1 (fr)
CN (1) CN1087189C (fr)
CA (1) CA2131361C (fr)
DE (1) DE69415748T2 (fr)
GR (1) GR3029365T3 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1310860C (zh) * 2002-08-22 2007-04-18 纳幕尔杜邦公司 制备1,1,1,2,2－五氟乙烷的方法

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* Cited by examiner, † Cited by third party
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US5494877A (en) * 1994-06-20 1996-02-27 Showa Denko K. K. Chromium-based fluorination catalyst containing gallium and production method thereof
KR0152580B1 (ko) * 1995-08-23 1998-10-15 김은영 1,1,1,2-테트라플루오로에탄, 펜타플루오로에탄 및 1,1,1-트리플루오로에탄의 병산 방법
FR2740994B1 (fr) * 1995-11-10 1997-12-05 Atochem Elf Sa Catalyseurs massiques a base d'oxyde de chrome, leur procede de preparation et leur application a la fluoration d'hydrocarbures halogenes
FR2740995B1 (fr) * 1996-04-09 1998-02-06 Atochem Elf Sa Catalyseurs massiques a base d'oxyde de chrome, leur procede de preparation et leur application a la fluoration d'hydrocarbures halogenes
WO1998010862A1 (fr) * 1996-09-10 1998-03-19 Imperial Chemical Industries Plc Catalyseur et procede de fluoration
US6074985A (en) * 1999-08-03 2000-06-13 Elf Atochem North America, Inc. Fluorination catalysts
FR2807751B1 (fr) * 2000-04-12 2005-05-20 Solvay Procede pour la preparation d'un hydro (chloro) fluoroalcane et catalyseur
FR2807752A1 (fr) * 2000-04-12 2001-10-19 Solvay Procede pour la preparation d'un hydrochlorofluoroalcane et catalyseur
US7485598B2 (en) * 2006-06-21 2009-02-03 Arkema Inc. High pressure catalyst activation method and catalyst produced thereby
JP4397687B2 (ja) * 2001-06-28 2010-01-13 ハネウェル・インターナショナル・インコーポレーテッド 弗素化触媒を調製する方法
RU2318595C2 (ru) 2002-08-22 2008-03-10 Е.И.Дюпон Де Немур Энд Компани Никельзамещенные и смешанные никель- и кобальтзамещенные хромоксидные композиции, их получение и применение в качестве катализаторов и предшественников катализаторов
AU2003265591A1 (en) * 2002-08-22 2004-03-11 E.I. Du Pont De Nemours And Company Cobalt-substituted chromium oxide compositions, their preparation, and their use as catalysts and catalyst precursors
AU2004281816B2 (en) * 2003-10-14 2010-05-27 E.I. Dupont De Nemours And Company Chromium oxide compositions containing zinc, their preparation, and their use as catalysts and catalyst precursors
JP2008531261A (ja) * 2005-02-25 2008-08-14 グレート・レイクス・ケミカル・コーポレイション 製造プロセス、製造システム、および触媒組成物
GB0507139D0 (en) 2005-04-08 2005-05-18 Ineos Fluor Holdings Ltd Catalyst
CN1911512B (zh) * 2005-07-07 2011-12-07 独立行政法人产业技术综合研究所 氟化催化剂及其制备方法、以及使用了该催化剂的氟化合物的制备方法
TW200800387A (en) * 2006-06-01 2008-01-01 Ritek Corp Catalyst for catalyzing carbon nanotubes growth
CN100444958C (zh) * 2006-11-08 2008-12-24 浙江衢化氟化学有限公司 一种氟化催化剂及其制备方法和用途
US20080207964A1 (en) * 2007-02-23 2008-08-28 Velliyur Nott Mallikarjuna Rao Compositions containing chromium, oxygen and gold, their preparation, and their use as catalysts and catalyst precursors
US20080207963A1 (en) * 2007-02-23 2008-08-28 Velliyur Nott Mallikarjuna Rao Preparation of composition containing chromium, oxygen, and either silver or palladium, and their use as catalysts and catalyst precursors
US9035111B2 (en) 2007-08-22 2015-05-19 Honeywell International Inc. Method for producing fluorinated organic compounds
JP6213480B2 (ja) * 2012-07-10 2017-10-18 ダイキン工業株式会社 含フッ素オレフィンの製造方法
RU2594485C1 (ru) * 2015-06-25 2016-08-20 Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук Способ активации катализатора для получения фторсодержащих углеводородов
CN108014817B (zh) * 2016-11-01 2019-12-10 中国石油化工股份有限公司 丁二烯合成1,4-二乙酰氧基丁烷过程的催化剂
CN107803195B (zh) * 2017-09-22 2020-12-22 乳源东阳光氟有限公司 一种氟化催化剂的活化方法
CN111036225B (zh) * 2019-12-17 2023-03-07 山东东岳化工有限公司 一种分段焙烧、分段氟化制备高活性五氟乙烷铬基催化剂的方法
CN111013612B (zh) * 2019-12-20 2022-12-06 山东东岳化工有限公司 一种固体氟化催化剂的制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3992325A (en) * 1975-09-25 1976-11-16 E. I. Du Pont De Nemours And Company γ-CrOOH fluorination catalysts
US5177273A (en) * 1991-02-01 1993-01-05 E. I. Du Pont De Nemours And Company Process for the manufacture of halogen-substituted propanes containing hydrogen and at least five fluorine substituents
CN1068521A (zh) * 1991-05-24 1993-02-03 大金工业株式会社 氟化卤代烃的氟化催化剂和方法

Family Cites Families (14)

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US2005707A (en) * 1932-08-31 1935-06-18 Kinetic Chemicals Inc Production of organic fluorine compounds
BE463409A (fr) * 1944-11-01
NL127399C (fr) * 1959-05-29
GB901297A (en) * 1960-04-12 1962-07-18 Union Carbide Corp Process for the production of pentafluoroethane
GB943627A (en) * 1960-07-06 1963-12-04 Union Carbide Corp Improvements in and relating to the use of chromia/alumina in fluorination catalysts
GB1025759A (fr) * 1962-01-13
NL148035B (nl) * 1965-09-14 1975-12-15 Montedison Spa Werkwijze voor de bereiding van gefluoreerde en/of gechlorofluoreerde organische verbindingen.
GB1307224A (en) * 1969-06-27 1973-02-14 Ici Ltd Chromium oxide catalyst
JPH0685878B2 (ja) * 1988-04-13 1994-11-02 ダイキン工業株式会社 クロム系フッ素化触媒の賦活方法
GB9104775D0 (en) * 1991-03-07 1991-04-17 Ici Plc Fluorination catalyst and process
US5155082A (en) * 1991-04-12 1992-10-13 Allied-Signal Inc. Catalyst for the manufacture of chlorofluorocarbons, hydrochlorofluorocarbons and hydrofluorocarbons
JP3412165B2 (ja) * 1991-05-24 2003-06-03 ダイキン工業株式会社 フッ素化触媒およびハロゲン化炭化水素のフッ素化方法
JP3248923B2 (ja) * 1991-05-29 2002-01-21 昭和電工株式会社 クロム系フッ素化触媒の賦活再生方法およびハロゲン化炭化水素の製造方法
FR2684567B1 (fr) * 1991-12-09 1994-11-04 Atochem Catalyseurs massiques a base d'oxydes de chrome et de nickel, et leur application a la fluoration d'hydrocarbures halogenes.

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3992325A (en) * 1975-09-25 1976-11-16 E. I. Du Pont De Nemours And Company γ-CrOOH fluorination catalysts
US5177273A (en) * 1991-02-01 1993-01-05 E. I. Du Pont De Nemours And Company Process for the manufacture of halogen-substituted propanes containing hydrogen and at least five fluorine substituents
CN1068521A (zh) * 1991-05-24 1993-02-03 大金工业株式会社 氟化卤代烃的氟化催化剂和方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1310860C (zh) * 2002-08-22 2007-04-18 纳幕尔杜邦公司 制备1,1,1,2,2－五氟乙烷的方法

Also Published As

Publication number Publication date
DE69415748T2 (de) 1999-08-19
DE69415748D1 (de) 1999-02-18
EP0641598A2 (fr) 1995-03-08
CA2131361C (fr) 2005-02-08
EP0641598A3 (fr) 1995-05-31
CA2131361A1 (fr) 1995-03-08
KR950007941A (ko) 1995-04-15
KR100351211B1 (ko) 2003-01-24
CN1105951A (zh) 1995-08-02
US5494873A (en) 1996-02-27
GR3029365T3 (en) 1999-05-28
EP0641598B1 (fr) 1999-01-07

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Expiration termination date: 20140907

Granted publication date: 20020710