CN108684676A - A kind of bactericidal composition containing volution bacterium amine and fludioxonil - Google Patents
A kind of bactericidal composition containing volution bacterium amine and fludioxonil Download PDFInfo
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- CN108684676A CN108684676A CN201810739958.0A CN201810739958A CN108684676A CN 108684676 A CN108684676 A CN 108684676A CN 201810739958 A CN201810739958 A CN 201810739958A CN 108684676 A CN108684676 A CN 108684676A
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- Prior art keywords
- fludioxonil
- bacterium amine
- volution bacterium
- bactericidal composition
- amine
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
- A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
- A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
- A01N43/30—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3 with two oxygen atoms in positions 1,3, condensed with a carbocyclic ring
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of bactericidal composition containing volution bacterium amine and fludioxonil comprising common disinfectant use in agriculture dosage form is made in the active ingredient be made of volution bacterium amine and fludioxonil and suitable disinfectant use in agriculture auxiliary combination.The present invention is good to the crops fungal disease control effect such as bakanae disease of rice and rice blast, and there are notable synergistic effects between two medicaments, can reduce dosage;Two kinds of active ingredients that the present invention contains have different chemical constitution and the mechanism of action, can delay drug resistance of the germ to single medicament;Volution bacterium amine and fludioxonil belong to low toxicity in the present invention, and to people and animals, beneficial organism, Environmental security.
Description
Technical field
The invention belongs to technical field of pesticide, are related to a kind of microbicide compositions.More specifically, being related to a kind of containing loop coil
The bactericidal composition of bacterium amine and fludioxonil.
Background technology
Volution bacterium amine (Spiroxamine) is substitutional amine-group fungicide, CAS 118134-30-8, chemical name N-
Ethyl-N- propyl -8- tertiary butyl -1,4- Er Yangzaluos [4.5]Decane -2- methylamines, molecular formula C18H35NO2, molecular weight
It is 297.48, boiling point 367.6 DEG C (760mmHg), 1.35 × 10-6Pa of vapour pressure (25 DEG C).The volution bacterium amine mechanism of action is suppression
Sterol biosynthesis processed, the main synthesis for inhibiting C-14 demethylation enzymes are a kind of novel, systemic fungicide, speed of action
The fast and lasting period is long, has both protection and therapeutic effect.
Fludioxonil (Fludioxonil) belongs to phenylpyrrole series bactericidal agent, and its chemical name is 4- (2,2- bis- fluoro- 1,3- benzene
And Dioxol-4 -yl) pyrroles's-3- nitriles.Active compound sterling is colorless and odorless crystalline solid, and fusing point is 199.8 DEG C, is steamed
3.9 × 10-7mPa of air pressure(20℃):Solubility(25 DEG C, g/L):Water 0.0018, acetone 190, ethyl alcohol 44, toluene 2.7.Low toxicity,
4000 mg/kg of rat acute LD50 >, percutaneous 5000 mg/kg of LD50 > of rat acute.Fludioxonil has antibacterial and kills
Bacterium acts on, and mainly by inhibiting transfer related with glucose phosphorylated, and then inhibits the growth of fungal mycelium, eventually leads to
Germ is dead, this mechanism of action unique and longer lasting period, does not have cross resistance with existing fungicide, is a kind of
Efficiently, the contact fungicide of wide spectrum, low toxicity, good to crop safety, the lasting period is 4 months or more.
Rice root rot, bakanae disease, seedling pest are the main sprout term diseases of rice, with the large area of machine rice transplantation in recent years
Promotion and application, industrial sprout cultivation are just gradually becoming the major measure of raising rice seedlings, and rice seedling disease is increasingly highlighted, given
Vast rice farmer brings serious loss.But there are still some problems for the control measure of current rice seedling disease, single medicament
Year after year using causing the pathogen of rice seedling disease to generate certain drug resistance and drug resistance, cause sprout term disease
It is very serious, affect Rice Production, how effectively to prevent rice seedling disease be numerous scientific and technical personnel and rice farmer very
The problem of concern.Therefore exploitation can both prevent rice seedling root rot, rice blast, and can prevent bakanae disease, cultivate disease-free
Strong seedling, to realizing that rice stable and high yields is of great significance.The present invention is tested by a large amount of indoor biometrics and field efficacy
Confirmatory test filters out volution bacterium amine and fludioxonil, and the two, which carries out compounding, has apparent synergistic effect, and there is no loop coil bacterium at present
Amine and the research of the development of fludioxonil complex composition and application report.
Invention content
The present invention provides a kind of bactericidal composition containing volution bacterium amine and fludioxonil, the bactericidal composition bactericidal activity
Height, wide sterilization spectrum can reduce prevention dosage total on unit area, and pathogen can be delayed anti-to volution bacterium amine and fludioxonil
The generation and development of pharmacological property, economic, efficient, environmental protection.
Two classes are had the fungicide of different types of structure and variant mechanism of action by the present invention, i.e. substitutional amine-group class is sterilized
Agent volution bacterium amine and phenylpyrrole series bactericidal agent fludioxonil are combined, and are developed into the upper easy-to-use biocide preparation of production, expand
Big fungicidal spectrum, bioactivity is high, reduces unit area prevention dosage, and pathogen drug resistance can be delayed to generate and hair
Exhibition, extends the service life of each component in bactericidal composition, to realize goal of the invention economic, efficiently, environmentally friendly.
To achieve the purpose of the present invention, the technical solution used is:
The bactericidal composition contains two kinds of active ingredients of volution bacterium amine and fludioxonil, the mass ratio of volution bacterium amine and fludioxonil
It is 50:1~1:10.
The mass ratio of the bactericidal composition containing volution bacterium amine and fludioxonil, preferred volution bacterium amine and fludioxonil is
2:1~1:1.
The bactericidal composition containing volution bacterium amine and fludioxonil is added with suitable agricultural bactericidal agent aid, is made
Common disinfectant use in agriculture dosage form.
The bactericidal composition containing volution bacterium amine and fludioxonil, it is seed treatment suspending agent, suspension emulsion that dosage form, which is made,
Or water-dispersible granules.
The active ingredient of the bactericidal composition containing volution bacterium amine and fludioxonil, volution bacterium amine and fludioxonil composition accounts for
The 10%~50% of bactericidal composition gross mass.
The bactericidal composition containing volution bacterium amine and fludioxonil, preferred volution bacterium amine and fludioxonil form effective
Ingredient accounts for the 30% of bactericidal composition gross mass.
The bactericidal composition containing volution bacterium amine and fludioxonil is in crops fungies such as prevention bakanae disease of rice, rice blast
It is applied in property disease control.
Beneficial effects of the present invention:(1)Compared with single dose, which has crop fungal disease higher
Control effect, there are notable synergistic effects between two components;(2)Dosage can be reduced, environmental pollution and pesticide are effectively reduced
Residual reduces use cost, and can improve crop yield and quality;(3)Volution bacterium amine and fludioxonil belong to low in the present invention
Toxicity, to people and animals, beneficial organism, Environmental security;(4)Volution bacterium amine and fludioxonil have different types of structure and have in the present invention
The fungicide of difference mechanism of action delays pathogen drug resistance to generate and development, extends making for each component in bactericidal composition
Use the service life.
Careful analysis is done to the sterilization idiocratic of volution bacterium amine and fludioxonil.
Volution bacterium amine and two single compound of fludioxonil are measured first(Hereinafter referred to as medicament)EC50(Drug safety refers to
Mark), according to the EC of two single medicaments50The portfolio ratio of two medicaments is set by Wadley methods, and synergy system is measured according to Wadley
Number SR values.
Test objective object is that fusarium moniliforme, rice blast fungus and corruption are mould, but not limited to this.It takes volution bacterium amine and coughs up
Bacterium nitrile is configured to various concentration liquid tablet, per ware about 15ml.It is straight with 5mm after pathogen is cultivated 3 days in PDA culture medium
Diameter card punch cuts mycelia block in colony edge, is transferred on the culture medium flat plate containing various concentration liquid and is trained respectively
It supports.Experiment uses mycelia growth measurement method, measures colony diameter using crossing method, measures colony diameter(mm), by following
Formula calculates growth inhibition ratio:
Mycelial growth inhibition rate %=(1- chemicals treatments colony diameter -5/ compares colony diameter -5)×100%
Mycelial growth inhibition rate is converted into inhibition probit value(Y), drug concentration is converted into log concentration(X), by log concentration
It is that ordinate makees toxicity regression straight line for abscissa, probit value, acquires volution bacterium amine and fludioxonil single dose and its mixture to germ
Virulence regression equation, and calculate EC50Value and correlation coefficient r value.
The interaction of mixture is evaluated according to Wadley methods, calculation formula is as follows:
EC50(theoretical value)=(a+b)/(a/EC50a+ b/EC50B),
SR = EC50(theoretical value)/EC50(actual value).
Wherein a, b are each component content ratios in mixture, and the effect of mixture is analyzed with SR values.SR≤0.5, then two kinds of medicines
Agent mixture has antagonism;SR=0.5~1.5, then two kinds of medicament mixtures have addition;SR >=1.5, then two kinds of medicaments are mixed
Equipped with synergistic effect.
1 volution bacterium amine of table and fludioxonil single dose and its mixture are to fusarium moniliforme toxicity test result
As can be seen from the above table, the volution bacterium amine of different proportion and fludioxonil composition are each to the fungistatic effect of fusarium moniliforme
It differs, the experimental results showed that it is than being listed in 8:1 to 1:There is addition in 8, than being listed in 2:1,1:There is synergy work when 1
With.
2 volution bacterium amine of table and fludioxonil single dose and its mixture are to rice blast fungus toxicity test result
As can be seen from the above table, the volution bacterium amine of different proportion and fludioxonil composition are each to the fungistatic effect of rice blast fungus
It differs, the experimental results showed that it is than being listed in 8:1 to 1:There is addition in 8, than being listed in 2:1 and 1:1 has synergistic effect.
According to volution bacterium amine and fludioxonil compounding to the indoor biometrics of fusarium moniliforme and Pyricularia oryzae as a result, main choosing
With the proportioning with notable synergistic effect(Volution bacterium amine:Fludioxonil is 2:1,1:1)It carries out with volution bacterium amine and fludioxonil being to have
The bactericidal composition development for imitating ingredient, develops the preparation suitable for the crops fungal disease such as bakanae disease of rice, rice blast, shape
At product of the present invention.The present invention has a higher control effect to crop fungal disease, and there are notable synergistic works between two components
With effectively reducing dosage;Volution bacterium amine and fludioxonil belong to low toxicity in the present invention, and to people and animals, beneficial organism,
Environmental security;Two kinds of active ingredients have different chemical constitution and the mechanism of action, can delay anti-medicine of the germ to single medicament
Property.
Specific implementation mode
With reference to embodiment, the invention will be further described, but present disclosure is not limited to following embodiments.
Embodiment 1
The preparation method of 30% volution bacterium amine fludioxonil seed treatment suspending agent:By mass percentage.
Active component, volution bacterium amine 20%;
Active component, fludioxonil 10%;
Fulvic acid 1%;
Ricinate, castor oil-ethylene-oxide condensation product 2%;
Polyoxyethylene carboxylate 5%;
Paraffin oil 20%;
Sodium lignin sulfonate 3%;
Film forming agent, polyvinyl acetate 3%;
Pigment, acid scarlet 0.01%;
Thickener, xanthans 0.15%;
Preservative, Kathon CG 0.3%;
Ethylene glycol 3%;
Water surplus.
Preparation method:According to formula, by fludioxonil active compound, fulvic acid, sodium lignin sulfonate, film forming agent polyvinyl acetate
Ester, thickener xanthans, Preservative Kathon CG(Methylchloroisothiazolinone/Methylisothiazolinone combination) weigh in proportion, ball mill ball milling are added 60 minutes, and filtering is pumped into dispersion tank high speed
Shearing is fully ground after 3 minutes through sand mill, and control solid component particle diameter stirs equal within 2 microns, after grinding
It is even, obtain suspending liquid A;According to formula, weigh volution bacterium amine and paraffin oil in proportion, stirring makes volution bacterium amine fully dissolve, by than
Example, which weighs, is added castor oil-ethylene-oxide condensation product, polyoxyethylene carboxylate, stirs evenly, obtains oil-phase product B;It is stirring
A is introduced into B under state, antifreeze glycol and pigment acid scarlet, high speed shear 30 minutes, mistake are proportionally added into according to formula
Filter, obtains finished product.
Up to suspension seed-coating agent agent product.According to every 100kg seeds, with 60ml, the product carries out dressing seed, for preventing
Bakanae disease of rice and seedling pest, preventive effect respectively reach 89.4% and 86.7%.
Embodiment 2
The preparation method of 30% volution bacterium amine fludioxonil seed treatment suspending agent:By mass percentage.
Active component, volution bacterium amine 15%;
Active component, fludioxonil 15%;
Fulvic acid 1%;
Ricinate, castor oil-ethylene-oxide condensation product 2%;
Polyoxyethylene carboxylate 5%;
Paraffin oil 20%;
Sodium lignin sulfonate 3%;
Film forming agent, polyvinyl acetate 3%;
Pigment, acid scarlet 0.01%;
Thickener, xanthans 0.15%;
Preservative, Kathon CG 0.3%;
Ethylene glycol 3%;
Water surplus.
Preparation method, with embodiment 1.With 60ml, the product carries out dressing seed to 100kg seeds, for preventing prevention rice
Bakanae disease and seedling pest, preventive effect respectively reach 87.6% and 89.4%.
Embodiment 3
The preparation method of 36% volution bacterium amine fludioxonil seed treatment suspending agent:By mass percentage.
Active component, volution bacterium amine 32%;
Active component, fludioxonil 4%;
Fulvic acid 1%;
Ricinate, castor oil-ethylene-oxide condensation product 2%;
Polyoxyethylene carboxylate 5%;
Paraffin oil 20%;
Sodium lignin sulfonate 3%;
Film forming agent, polyvinyl acetate 3%;
Pigment, acid scarlet 0.01%;
Thickener, xanthans 0.15%;
Preservative, Kathon CG 0.3%;
Ethylene glycol 3%;
Water surplus.
Preparation method, with embodiment 1.With 55ml, the product carries out dressing seed to 100kg wheats, for preventing prevention rice
Bakanae disease and seedling pest, preventive effect respectively reach 63.8% and 71.4%.
Embodiment 4
The preparation method of 30% volution bacterium amine fludioxonil seed treatment suspending agent:By mass percentage.
Active component, volution bacterium amine 24%;
Active component, fludioxonil 6%;
Fulvic acid 1%;
Ricinate, castor oil-ethylene-oxide condensation product 2%;
Polyoxyethylene carboxylate 5%;
Paraffin oil 20%;
Sodium lignin sulfonate 3%;
Film forming agent, polyvinyl acetate 3%;
Pigment, acid scarlet 0.01%;
Thickener, xanthans 0.15%;
Preservative, Kathon CG 0.3%;
Ethylene glycol 3%;
Water surplus.
Preparation method, with embodiment 1.With 60ml, the product carries out dressing seed to 100kg wheats, for preventing prevention rice
Bakanae disease and seedling pest, preventive effect respectively reach 67.1% and 75.4%.
Embodiment 5
The preparation method of 30% volution bacterium amine fludioxonil seed treatment suspending agent:By mass percentage.
Active component volution bacterium amine 10%;
Active component fludioxonil 20%;
Fulvic acid 1%;
Ricinate, castor oil-ethylene-oxide condensation product 2%;
Polyoxyethylene carboxylate 5%;
Paraffin oil 20%;
Sodium lignin sulfonate 3%;
Film forming agent, polyvinyl acetate 3%;
Pigment, acid scarlet 0.01%;
Thickener, xanthans 0.15%;
Preservative, Kathon CG 0.3%;
Ethylene glycol 3%;
Water surplus.
Preparation method, with embodiment 1.With 60ml, the product carries out dressing seed to 100kg wheats, for preventing prevention rice
Bakanae disease and seedling pest, preventive effect respectively reach 87.7% and 84.2%.
Embodiment 6
The preparation method of 30% volution bacterium amine fludioxonil suspension emulsion:By mass percentage.
Active component volution bacterium amine 15%;
Active component fludioxonil 15%;
Ricinate, castor oil-ethylene-oxide condensation product 2%;
Polyoxyethylene carboxylate 5%;
Paraffin oil 20%;
Sodium lignin sulfonate 3%;
Thickener, xanthans 0.15%;
Preservative, Kathon CG 0.3%;
Ethylene glycol 3%;
Water surplus.
Preparation method:According to formula, fludioxonil active compound, sodium lignin sulfonate, thickener xanthans, Preservative Kathon CG(Methylchloroisothiazolinone/Methylisothiazolinone combination) are pressed
Ratio weighs, and ball mill ball milling is added 60 minutes, and filtering is pumped into dispersion tank high speed shear and is fully ground through sand mill after 3 minutes,
Solid component particle diameter is controlled within 2 microns, is stirred evenly after grinding, obtains suspending liquid A;According to formula, in proportion
Volution bacterium amine and paraffin oil are weighed, stirring makes volution bacterium amine fully dissolve, and weighs castor oil-ethylene-oxide condensation is added in proportion
Object, polyoxyethylene carboxylate, stir evenly, and obtain oil-phase product B;A is introduced into B under stirring, in proportion according to formula
Ethylene glycol, high speed shear 30 minutes is added, filtering obtains finished product.Dosage 60g prevents bakanae disease of rice and seedling pest, preventive effect point per acre
87.3% and 88.9% are not reached.
Embodiment 7
The preparation method of 30% volution bacterium amine fludioxonil suspension emulsion:By mass percentage.
Active component volution bacterium amine 20%;
Active component fludioxonil 10%;
Ricinate, castor oil-ethylene-oxide condensation product 2%;
Polyoxyethylene carboxylate 5%;
Paraffin oil 20%;
Sodium lignin sulfonate 3%;
Thickener, xanthans 0.15%;
Preservative, Kathon CG 0.3%;
Ethylene glycol 3%;
Water surplus.
Preparation method, with embodiment 6.Dosage 60g products per acre, prevent bakanae disease of rice and seedling pest, preventive effect reach respectively
To 89.5% and 87.6%.
Embodiment 8
The preparation method of 30% volution bacterium amine fludioxonil water dispersible granules:By mass percentage.
Active component volution bacterium amine 15%;
Active component fludioxonil 15%;
Calcium lignosulfonate 6%;
Polyvinyl alcohol 3%;
Ammonium sulfate 6%;
White carbon 10%;
Kaolin surplus.
Preparation method:Volution bacterium amine kaolin and white carbon are fully adsorbed by formula rate, it then will be above remaining
Component is added mixing machine by formula rate and carries out air-flow crushing after mixing, and a small amount of purified water, which is added, after the completion of crushing fully stirs
It mixes uniformly, extruder grain can obtain water dispersible granules product after drying.Dosage 60g prevents bakanae disease of rice and seedling pest per acre, prevents
Effect respectively reaches 85.6% and 87.1%.
Listed above is only several specific embodiments of the present invention.It is clear that the invention is not restricted to above example, also
There can be many variations.Those skilled in the art can be from disclosed by the invention interior all with what is directly exported or associate
Deformation, is considered protection scope of the present invention.
Claims (7)
1. a kind of bactericidal composition containing volution bacterium amine and fludioxonil, it is characterised in that:The composition contain volution bacterium amine and
The mass ratio of two kinds of active ingredients of fludioxonil, the volution bacterium amine and fludioxonil is 50:1~1:10.
2. the bactericidal composition according to claim 1 containing volution bacterium amine and fludioxonil, it is characterised in that:The loop coil bacterium
The mass ratio of amine and fludioxonil is 2:1~1:1.
3. the bactericidal composition according to claim 1 containing volution bacterium amine and fludioxonil, it is characterised in that:Added with appropriate
Agricultural bactericidal agent aid, common disinfectant use in agriculture dosage form is made.
4. the bactericidal composition according to claim 3 containing volution bacterium amine and fludioxonil, it is characterised in that:Dosage form, which is made, is
Seed treatment suspending agent, suspension emulsion or water-dispersible granules.
5. the bactericidal composition containing volution bacterium amine and fludioxonil according to claim 1-4, it is characterised in that:The loop coil
The active ingredient of bacterium amine and fludioxonil composition accounts for the 10%~50% of bactericidal composition gross mass.
6. the bactericidal composition according to claim 5 containing volution bacterium amine and fludioxonil, it is characterised in that:The loop coil bacterium
The active ingredient of amine and fludioxonil composition accounts for the 30% of bactericidal composition gross mass.
7. bactericidal composition of the claim 1-6 any one of them containing volution bacterium amine and fludioxonil prevention bakanae disease of rice,
It is applied in the prevention of the crops fungal disease such as rice blast.
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CN102388888A (en) * | 2011-10-11 | 2012-03-28 | 陕西上格之路生物科学有限公司 | Sterilization composite containing coumoxystrobin and fludioxonil |
CN105941419A (en) * | 2016-06-03 | 2016-09-21 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Fungicide composition containing spiroxamine and epoxiconazole |
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2018
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US4851405A (en) * | 1987-03-07 | 1989-07-25 | Bayer Aktiengesellschaft | Aminomethyl heterocyclic compounds |
CN1099552A (en) * | 1993-06-02 | 1995-03-08 | 拜尔公司 | Fungicidal compositions |
EP1925204A1 (en) * | 2006-11-23 | 2008-05-28 | Syngeta Participations AG | Plant propagation material treatment nematicides |
CN102388888A (en) * | 2011-10-11 | 2012-03-28 | 陕西上格之路生物科学有限公司 | Sterilization composite containing coumoxystrobin and fludioxonil |
CN105941419A (en) * | 2016-06-03 | 2016-09-21 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Fungicide composition containing spiroxamine and epoxiconazole |
CN107751192A (en) * | 2017-09-07 | 2018-03-06 | 京博农化科技股份有限公司 | Application of the trimethylglycine in pesticide suspension concentrate preparation |
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Title |
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陈培红 等: "新型水稻浸种剂对恶苗病及干尖线虫病的防治效果", 《江西农业学报》 * |
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Application publication date: 20181023 |