CN108611858A - 一种耐强洗涤的纺织品用防水涂层胶粘整理剂及其制备方法 - Google Patents

一种耐强洗涤的纺织品用防水涂层胶粘整理剂及其制备方法 Download PDF

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CN108611858A
CN108611858A CN201810427457.9A CN201810427457A CN108611858A CN 108611858 A CN108611858 A CN 108611858A CN 201810427457 A CN201810427457 A CN 201810427457A CN 108611858 A CN108611858 A CN 108611858A
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胡玲
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Foshan Huichuang Zhengyuan New Mstar Technology Ltd
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Abstract

本发明公开了一种耐强洗涤的纺织品用防水涂层胶粘整理剂，其由以下重量份数的原料组成：丙烯酸全氟辛基乙酯10～20份、丙烯酸正丁酯20～30份、气相二氧化钛1～3份、高级脂肪醇丙烯酸酯10～15份、二丁基萘磺酸钠1～4份、非离子疏水改性环氧乙烷聚氨酯共聚物3～6份、聚醚硅油2～4份、二羟甲基脲1.5～3份、六水合硝酸锌0.5～1份、催化剂0.2～0.5份、水100～140份。本发明将丙烯酸全氟辛基乙酯、丙烯酸正丁酯、高级脂肪醇丙烯酸酯在催化剂的作用下产生反应，并与气相二氧化钛、二丁基萘磺酸钠、聚醚硅油、二羟甲基脲、六水合硝酸锌、非离子疏水改性环氧乙烷聚氨酯共聚物共混反应，获得具有良好抗水防油效果，同时耐强洗涤的纺织品用防水胶粘剂。

Description

一种耐强洗涤的纺织品用防水涂层胶粘整理剂及其制备方法
技术领域
本发明涉及纺织品加工用料及制备领域，具体涉及一种耐强洗涤的纺织品用防水涂层胶粘整理剂及其制备方法。
背景技术
为了适应人们对纺织品的不断要求，越来越多的纺织品被赋予功能性，而防水功能就是其中一个重要的分支。拒水拒油织物是一种功能化、智能化的织物。经过拒水拒油涂层胶整理的化纤、纯棉或化纤与纯棉混纺织物纺织品，面料达到仿真皮效果，手感柔软，能抵御雨水、油迹，并且在装饰、产业领域中应用的具有拒水拒油功能的餐桌布、汽车防护罩等也备受青睐。目前纺织品用防水涂层胶粘整理剂存在的缺点是防油性能不够，以及耐洗涤性、耐寒性较差，从而在一定程度上限制了其在纺织品领域的应用。
发明内容
针对现有技术不足，本发明提供了一种抗水防油效果良好的耐强洗涤的纺织品用防水剂及其制备方法。
本发明解决上述技术问题采用的技术方案为：一种耐强洗涤的纺织品用防水涂层胶粘整理剂，其由以下重量份数的原料组成：丙烯酸全氟辛基乙酯10～20份、丙烯酸正丁酯20～30份、气相二氧化钛1～3份、高级脂肪醇丙烯酸酯10～15份、二丁基萘磺酸钠1～4份、非离子疏水改性环氧乙烷聚氨酯共聚物3～6份、聚醚硅油2～4份、二羟甲基脲1.5～3份、六水合硝酸锌0.5～1份、催化剂0.2～0.5份、水100～140份。
进一步地，所述的一种耐强洗涤的纺织品用防水涂层胶粘整理剂，其由以下重量份数的原料组成：丙烯酸全氟辛基乙酯15份、丙烯酸正丁酯25份、气相二氧化钛2份、高级脂肪醇丙烯酸酯12份、二丁基萘磺酸钠3份、非离子疏水改性环氧乙烷聚氨酯共聚物4份、聚醚硅油3份、二羟甲基脲2份、六水合硝酸锌0.7份、催化剂0.3份、水120份。
进一步地，所述的催化剂为正丁基锂。
所述的一种耐强洗涤的纺织品用防水涂层胶粘整理剂的制备方法，其包括以下步骤：
(1)按照所述重量份数备取原料；
(2)将气相二氧化钛、六水合硝酸锌和聚醚硅油置于容器中搅拌1～1.5h，得匀混物料；
(3)将丙烯酸全氟辛基乙酯、丙烯酸正丁酯、高级脂肪醇丙烯酸酯、二丁基萘磺酸钠、二羟甲基脲和占水总量三分之一的水与步骤(2)得到的匀混物料混合，并在75～85℃下保温搅拌40～50min，得匀混液；
(4)将步骤(3)得到的匀混液温度降至55～65℃，并保温滴加催化剂与占水总量三分之一的水的共混液，滴加时间控制在50～70min，滴加完毕后继续保温搅拌2～2.5h；
(5)将非离子疏水改性环氧乙烷聚氨酯共聚物加入步骤(4)得到的溶液中保温搅拌1～2h，然后加入剩余的水保温搅拌0.5～1h；
(6)冷却、过滤后得到本发明的纺织品用防水涂层胶粘整理剂。
与现有技术相比，本发明具备的有益效果为：本发明提供的纺织品用防水涂层胶粘整理剂创新性的将丙烯酸全氟辛基乙酯、丙烯酸正丁酯、高级脂肪醇丙烯酸酯在催化剂的作用下产生反应，并与气相二氧化钛、二丁基萘磺酸钠、非离子疏水改性环氧乙烷聚氨酯共聚物、聚醚硅油、二羟甲基脲、六水合硝酸锌共混反应，最后与非离子疏水改性环氧乙烷聚氨酯共聚物增稠反应，获得具有良好抗水防油效果，同时耐强洗涤的纺织品用防水涂层胶粘整理剂。
具体实施方式
下面结合具体实施例对本发明做进一步详细的说明。
实施例1：一种耐强洗涤的纺织品用防水涂层胶粘整理剂，其由以下重量份数的原料组成：丙烯酸全氟辛基乙酯15份、丙烯酸正丁酯25份、气相二氧化钛2份、高级脂肪醇丙烯酸酯12份、二丁基萘磺酸钠3份、非离子疏水改性环氧乙烷聚氨酯共聚物4份、聚醚硅油3份、二羟甲基脲2份、六水合硝酸锌0.7份、催化剂0.3份、水120份；所述的催化剂为正丁基锂。
所述的一种耐强洗涤的纺织品用防水涂层胶粘整理剂的制备方法，其包括以下步骤：
(1)按照所述重量份数备取原料；
(2)将气相二氧化钛、六水合硝酸锌和聚醚硅油置于容器中搅拌75min，得匀混物料；
(3)将丙烯酸全氟辛基乙酯、丙烯酸正丁酯、高级脂肪醇丙烯酸酯、二丁基萘磺酸钠、二羟甲基脲和80份的水与步骤(2)得到的匀混物料混合，并在80℃下保温搅拌45min，得匀混液；
(4)将步骤(3)得到的匀混液温度降至60℃，并保温滴加催化剂与占水总量三分之一的水的共混液，滴加时间控制在60min，滴加完毕后继续保温搅拌135min；
(5)将非离子疏水改性环氧乙烷聚氨酯共聚物加入步骤(4)得到的溶液中保温搅拌1.5h，然后加入剩余的水保温搅拌45min；
(6)冷却、过滤后得到本发明的纺织品用防水涂层胶粘整理剂。
实施例2：一种耐强洗涤的纺织品用防水涂层胶粘整理剂，其由以下重量份数的原料组成：丙烯酸全氟辛基乙酯10份、丙烯酸正丁酯20份、气相二氧化钛1份、高级脂肪醇丙烯酸酯10份、二丁基萘磺酸钠1份、非离子疏水改性环氧乙烷聚氨酯共聚物3份、聚醚硅油2份、二羟甲基脲1.5份、六水合硝酸锌0.5份、催化剂正丁基锂0.2份、水100份。
所述的一种耐强洗涤的纺织品用防水涂层胶粘整理剂的制备方法，其包括以下步骤：
(1)按照所述重量份数备取原料；
(2)将气相二氧化钛、六水合硝酸锌和聚醚硅油置于容器中搅拌1h，得匀混物料；
(3)将丙烯酸全氟辛基乙酯、丙烯酸正丁酯、高级脂肪醇丙烯酸酯、二丁基萘磺酸钠、二羟甲基脲和占水总量三分之一的水与步骤(2)得到的匀混物料混合，并在75℃下保温搅拌40min，得匀混液；
(4)将步骤(3)得到的匀混液温度降至55℃，并保温滴加催化剂与占水总量三分之一的水的共混液，滴加时间控制在50min，滴加完毕后继续保温搅拌2h；
(5)将非离子疏水改性环氧乙烷聚氨酯共聚物加入步骤(4)得到的溶液中保温搅拌1h，然后加入剩余的水保温搅拌0.5h；
(6)冷却、过滤后得到本发明的纺织品用防水涂层胶粘整理剂。
实施例3：一种耐强洗涤的纺织品用防水涂层胶粘整理剂，其由以下重量份数的原料组成：丙烯酸全氟辛基乙酯20份、丙烯酸正丁酯30份、气相二氧化钛3份、高级脂肪醇丙烯酸酯15份、二丁基萘磺酸钠4份、非离子疏水改性环氧乙烷聚氨酯共聚物6份、聚醚硅油4份、二羟甲基脲3份、六水合硝酸锌1份、催化剂正丁基锂0.5份、水140份。
所述的一种耐强洗涤的纺织品用防水涂层胶粘整理剂的制备方法，其包括以下步骤：
(1)按照所述重量份数备取原料；
(2)将气相二氧化钛、六水合硝酸锌和聚醚硅油置于容器中搅拌1.5h，得匀混物料；
(3)将丙烯酸全氟辛基乙酯、丙烯酸正丁酯、高级脂肪醇丙烯酸酯、二丁基萘磺酸钠、二羟甲基脲和占水总量三分之一的水与步骤(2)得到的匀混物料混合，并在85℃下保温搅拌50min，得匀混液；
(4)将步骤(3)得到的匀混液温度降至65℃，并保温滴加催化剂与占水总量三分之一的水的共混液，滴加时间控制在70min，滴加完毕后继续保温搅拌2.5h；
(5)将非离子疏水改性环氧乙烷聚氨酯共聚物加入步骤(4)得到的溶液中保温搅拌2h，然后加入剩余的水保温搅拌1h；
(6)冷却、过滤后得到本发明的纺织品用防水涂层胶粘整理剂。
实施例4：一种耐强洗涤的纺织品用防水涂层胶粘整理剂，其由以下重量份数的原料组成：丙烯酸全氟辛基乙酯10份、丙烯酸正丁酯30份、气相二氧化钛1份、高级脂肪醇丙烯酸酯15份、二丁基萘磺酸钠1份、非离子疏水改性环氧乙烷聚氨酯共聚物6份、聚醚硅油2份、二羟甲基脲3份、六水合硝酸锌0.5份、催化剂正丁基锂0.5份、水100份。
所述的一种耐强洗涤的纺织品用防水涂层胶粘整理剂的制备方法，其包括以下步骤：
(1)按照所述重量份数备取原料；
(2)将气相二氧化钛、六水合硝酸锌和聚醚硅油置于容器中搅拌70min，得匀混物料；
(3)将丙烯酸全氟辛基乙酯、丙烯酸正丁酯、高级脂肪醇丙烯酸酯、二丁基萘磺酸钠、二羟甲基脲和占水总量三分之一的水与步骤(2)得到的匀混物料混合，并在75℃下保温搅拌50min，得匀混液；
(4)将步骤(3)得到的匀混液温度降至55℃，并保温滴加催化剂与占水总量三分之一的水的共混液，滴加时间控制在70min，滴加完毕后继续保温搅拌2.2h；
(5)将非离子疏水改性环氧乙烷聚氨酯共聚物加入步骤(4)得到的溶液中保温搅拌1h，然后加入剩余的水保温搅拌1h；
(6)冷却、过滤后得到本发明的纺织品用防水涂层胶粘整理剂。
实施例5：一种耐强洗涤的纺织品用防水涂层胶粘整理剂，其由以下重量份数的原料组成：丙烯酸全氟辛基乙酯12份、丙烯酸正丁酯28份、气相二氧化钛1.5份、高级脂肪醇丙烯酸酯13份、二丁基萘磺酸钠3份、非离子疏水改性环氧乙烷聚氨酯共聚物5份、聚醚硅油2份、二羟甲基脲2.5份、六水合硝酸锌0.7份、催化剂正丁基锂0.3份、水130份。
所述的一种耐强洗涤的纺织品用防水涂层胶粘整理剂的制备方法，其包括以下步骤：
(1)按照所述重量份数备取原料；
(2)将气相二氧化钛、六水合硝酸锌和聚醚硅油置于容器中搅拌70min，得匀混物料；
(3)将丙烯酸全氟辛基乙酯、丙烯酸正丁酯、高级脂肪醇丙烯酸酯、二丁基萘磺酸钠、二羟甲基脲和占水总量三分之一的水与步骤(2)得到的匀混物料混合，并在78℃下保温搅拌46min，得匀混液；
(4)将步骤(3)得到的匀混液温度降至62℃，并保温滴加催化剂与占水总量三分之一的水的共混液，滴加时间控制在55min，滴加完毕后继续保温搅拌2.5h；
(5)将非离子疏水改性环氧乙烷聚氨酯共聚物加入步骤(4)得到的溶液中保温搅拌70min，然后加入剩余的水保温搅拌50min；
(6)冷却、过滤后得到本发明的纺织品用防水涂层胶粘整理剂。
对上述实施例1-5所得的防水涂层胶粘整理剂进行性能测试，具体采用40*40/133*100的棉织物，涂覆底胶烘干后涂覆实施例1-5得到的整理剂2遍，烘干后测试性能，其中涂覆底胶干增重2～4g/m2，涂覆整理剂干增重15～18g/m2。结果如下表所示：
经本发明的防水涂层胶粘整理剂整理后的面料表面光滑柔软，防水涂层胶粘整理剂可以均匀的覆盖在面料表面，具有较好的防水抗油效果，并且多次洗涤后仍可保持良好的防水抗油性能。

Claims (4)

1.一种耐强洗涤的纺织品用防水涂层胶粘整理剂，其特征在于：由以下重量份数的原料组成：丙烯酸全氟辛基乙酯10～20份、丙烯酸正丁酯20～30份、气相二氧化钛1～3份、高级脂肪醇丙烯酸酯10～15份、二丁基萘磺酸钠1～4份、非离子疏水改性环氧乙烷聚氨酯共聚物3～6份、聚醚硅油2～4份、二羟甲基脲1.5～3份、六水合硝酸锌0.5～1份、催化剂0.2～0.5份、水100～140份。
2.根据权利要求1所述的一种耐强洗涤的纺织品用防水涂层胶粘整理剂，其特征在于：由以下重量份数的原料组成：丙烯酸全氟辛基乙酯15份、丙烯酸正丁酯25份、气相二氧化钛2份、高级脂肪醇丙烯酸酯12份、二丁基萘磺酸钠3份、非离子疏水改性环氧乙烷聚氨酯共聚物4份、聚醚硅油3份、二羟甲基脲2份、六水合硝酸锌0.7份、催化剂0.3份、水120份。
3.根据权利要求1或2所述的一种耐强洗涤的纺织品用防水涂层胶粘整理剂，其特征在于：所述的催化剂为正丁基锂。
4.权利要求1或2所述的一种耐强洗涤的纺织品用防水涂层胶粘整理剂的制备方法，其特征在于，包括以下步骤：
(1)按照所述重量份数备取原料；
(2)将气相二氧化钛、六水合硝酸锌和聚醚硅油置于容器中搅拌1～1.5h，得匀混物料；
(3)将丙烯酸全氟辛基乙酯、丙烯酸正丁酯、高级脂肪醇丙烯酸酯、二丁基萘磺酸钠、二羟甲基脲和占水总量三分之一的水与步骤(2)得到的匀混物料混合，并在75～85℃下保温搅拌40～50min，得匀混液；
(4)将步骤(3)得到的匀混液温度降至55～65℃，并保温滴加催化剂与占水总量三分之一的水的共混液，滴加时间控制在50～70min，滴加完毕后继续保温搅拌2～2.5h；
(5)将非离子疏水改性环氧乙烷聚氨酯共聚物加入步骤(4)得到的溶液中保温搅拌1～2h，然后加入剩余的水保温搅拌0.5～1h；
(6)冷却、过滤后得到本发明的纺织品用防水涂层胶粘整理剂。
CN201810427457.9A 2018-05-07 2018-05-07 一种耐强洗涤的纺织品用防水涂层胶粘整理剂及其制备方法 Withdrawn CN108611858A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115726219A (zh) * 2021-08-31 2023-03-03 温岭市丝美达草艺厂 一种防水性能好的纳米纸纱制备方法

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1460701A (zh) * 2003-05-06 2003-12-10 汕头市龙湖昌丰化工有限公司 一种水性受热分离复合胶
CN1493601A (zh) * 2003-07-23 2004-05-05 华东理工大学 一种水乳型含氟拒水拒油剂及其制备方法
CN1837456A (zh) * 2006-04-25 2006-09-27 辽宁氟材料研究院有限公司 一种乳液型含氟织物整理剂及其制法
CN1861680A (zh) * 2006-04-29 2006-11-15 广州市白云化工实业有限公司 一种低含氟量材料及其合成方法
CN1958937A (zh) * 2005-11-02 2007-05-09 巨化集团公司 一种含氟织物整理剂水乳液
CN101805990A (zh) * 2010-02-02 2010-08-18 广东鸿昌服饰创意股份有限公司 拒水整理剂及用拒水整理剂制作吸湿排汗牛仔面料的制造方法
CN102786629A (zh) * 2012-08-15 2012-11-21 佛山市顺德区鸿昌嘉特威服装有限公司 一种核壳结构含氟丙烯酸酯共聚物织物整理剂的制备及其在牛仔服装上的应用
CN105088788A (zh) * 2014-05-20 2015-11-25 东莞市长安东阳光铝业研发有限公司 一种含氟织物整理剂组合物及其制备方法
CN106957387A (zh) * 2017-03-09 2017-07-18 山东鲁普科技有限公司 一种户外运动绳索防水涂层剂的制备及使用方法
CN107326676A (zh) * 2017-07-31 2017-11-07 苏州井村服饰有限公司 一种服装面料用环保耐久防水剂及其制备方法
CN107815875A (zh) * 2017-11-14 2018-03-20 湖州泰鑫无纺布有限公司 一种无纺布用的防水剂

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1460701A (zh) * 2003-05-06 2003-12-10 汕头市龙湖昌丰化工有限公司 一种水性受热分离复合胶
CN1493601A (zh) * 2003-07-23 2004-05-05 华东理工大学 一种水乳型含氟拒水拒油剂及其制备方法
CN1958937A (zh) * 2005-11-02 2007-05-09 巨化集团公司 一种含氟织物整理剂水乳液
CN1837456A (zh) * 2006-04-25 2006-09-27 辽宁氟材料研究院有限公司 一种乳液型含氟织物整理剂及其制法
CN1861680A (zh) * 2006-04-29 2006-11-15 广州市白云化工实业有限公司 一种低含氟量材料及其合成方法
CN101805990A (zh) * 2010-02-02 2010-08-18 广东鸿昌服饰创意股份有限公司 拒水整理剂及用拒水整理剂制作吸湿排汗牛仔面料的制造方法
CN102786629A (zh) * 2012-08-15 2012-11-21 佛山市顺德区鸿昌嘉特威服装有限公司 一种核壳结构含氟丙烯酸酯共聚物织物整理剂的制备及其在牛仔服装上的应用
CN105088788A (zh) * 2014-05-20 2015-11-25 东莞市长安东阳光铝业研发有限公司 一种含氟织物整理剂组合物及其制备方法
CN106957387A (zh) * 2017-03-09 2017-07-18 山东鲁普科技有限公司 一种户外运动绳索防水涂层剂的制备及使用方法
CN107326676A (zh) * 2017-07-31 2017-11-07 苏州井村服饰有限公司 一种服装面料用环保耐久防水剂及其制备方法
CN107815875A (zh) * 2017-11-14 2018-03-20 湖州泰鑫无纺布有限公司 一种无纺布用的防水剂

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
纪惠军: "《印染技术》", 31 July 2012, 东华大学出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115726219A (zh) * 2021-08-31 2023-03-03 温岭市丝美达草艺厂 一种防水性能好的纳米纸纱制备方法

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