CN107326676A - 一种服装面料用环保耐久防水剂及其制备方法 - Google Patents

一种服装面料用环保耐久防水剂及其制备方法 Download PDF

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CN107326676A
CN107326676A CN201710635759.0A CN201710635759A CN107326676A CN 107326676 A CN107326676 A CN 107326676A CN 201710635759 A CN201710635759 A CN 201710635759A CN 107326676 A CN107326676 A CN 107326676A
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龚利峰
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SUZHOU IMURA GARMENTS CO Ltd
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Abstract

本发明公开了一种服装面料用环保耐久防水剂及其制备方法，所述防水剂包括如下重量份的成分：聚乙烯醇，碳酸钠，月桂醇聚氧乙烯醚，松香；硬脂酸，氢氧化钠，苯甲酸钠，二乙醇酰胺，醋酸，甲基纤维素，乳化剂，偶联剂，交联剂，阻燃剂，去离子水。所述防水剂适用于天然纤维、涤棉混纺、锦棉混纺、合成纤维等织物面料的一般防水防油加工，对各种纤维面料均具有优良的防水防油性能，不损害纤维原有的手感，不降低面料原有的摩擦牢度，具有优异的剥离强度，与其它纺织助剂并用时，具有优良的稳定性，无着火点，属非危险品类，使用更安全。

Description

一种服装面料用环保耐久防水剂及其制备方法
技术领域
本发明属于服装面料助剂技术领域，具体涉及一种服装面料用环保耐久防水剂及其制备方法。
背景技术
面料就是用来制作服装的材料。作为服装三要素之一，面料不仅可以诠释服装的风格和特性，而且直接左右着服装的色彩、造型的表现效果。
服装以面料制作而成，面料就是用来制作服装的材料。作为服装三要素之一，面料不仅可以诠释服装的风格和特性，而且直接左右着服装的色彩、造型的表现效果。呈现出自身的高贵完美，手感柔软。
现代制作在正式的社交场合所穿著的服装，多选用优质的混纺面料。而纯棉、纯毛、纯丝、纯麻等天然面料因为有着易皱、易变形等天然面料的缺点，已经沦为一般布料，较少作为高档服装用料。混纺面料有着天然面料吸汗透气、柔软舒服的特点，又吸收了化纤面料结实耐穿、垂悬挺括、光泽好颜色鲜亮等优点，每年有大量的高档优质混纺面料被开发出来。有时，穿著纯皮革制作的服装，也是允许的。
对于服装面料的防水，目前国内主要存在如下专利文献：
授权公告号为104562686B的中国专利公开了一种持久性良好的纺织品用防水剂，包括以下质量份的组分：聚乙烯醇15～20，环氧氯丙烷15～18，皂粉10～14，脂肪酸纳8～12，醋酸5～10，乙醇25～30，松香5～10，甲基纤维素2～3。本发明的制备方法为，称取所需原料，将松香置于乙醇中，加热至40～50℃，搅拌均匀；于上述溶液中保温依次加入醋酸、皂粉、脂肪酸纳、环氧氯乙烷、甲基纤维素和聚乙烯醇，搅拌混合均匀，冷却至室温既得成品。本发明的织物防水剂制备工艺简单，原料易得，生产成本低，抗渗防渗效果好；处理后的织物耐水洗和干洗，持久性良好；本发明的织物防水剂还具有安全无害的特点。然而，该专利所提供的防水剂，成分原料设计简单，防水效果有待商榷。
发明内容
为解决上述存在的问题，本发明的目的在于提供一种服装面料用环保耐久防水剂及其制备方法，所述防水剂适用于天然纤维、涤棉混纺、锦棉混纺、合成纤维等织物面料的一般防水防油加工，对各种纤维面料均具有优良的防水防油性能，不损害纤维原有的手感，不降低面料原有的摩擦牢度，具有优异的剥离强度，与其它纺织助剂并用时，具有优良的稳定性，无着火点，属非危险品类，使用更安全。
为达到上述目的，本发明的技术方案是：
一种服装面料用环保耐久防水剂，所述防水剂包括如下重量份的成分：聚乙烯醇：20~30份，碳酸钠：10~15份，月桂醇聚氧乙烯醚：15~25份，松香：5~10份；硬脂酸：10~15份，氢氧化钠：10~15份，苯甲酸钠：1~5份，二乙醇酰胺：10~15份，醋酸：5~10份，甲基纤维素：5~10份，乳化剂：5~10份，偶联剂：1~5份，交联剂：1~5份，阻燃剂：1~5份，去离子水：40~50份。
进一步，所述防水剂包括如下重量份的成分：聚乙烯醇：25~30份，碳酸钠：13~15份，月桂醇聚氧乙烯醚：15~20份，松香：5~8份；硬脂酸：12~15份，氢氧化钠：10~14份，苯甲酸钠：3~5份，二乙醇酰胺：13~15份，醋酸：5~7份，甲基纤维素：6~10份，乳化剂：8~10份，偶联剂：1~4份，交联剂：3~5份，阻燃剂：2~5份，去离子水：40~45份。
优选地，所述防水剂包括如下重量份的成分：聚乙烯醇：25份，碳酸钠：13份，月桂醇聚氧乙烯醚：20份，松香：8份；硬脂酸：13份，氢氧化钠：12份，苯甲酸钠：4份，二乙醇酰胺：14份，醋酸：6份，甲基纤维素：7份，乳化剂：9份，偶联剂：3份，交联剂：4份，阻燃剂：2份，去离子水：45份。
优选地，所述偶联剂为N-(β-氨乙基)-γ-氨丙基甲基二甲氧基硅烷或N-2-(氨乙基)-3-氨丙基三甲氧基硅烷。
优选地，所述交联剂为二羟甲基脲、二羟甲基乙烯脲或二羟甲基二羟基乙烯脲。
优选地，所述乳化剂为脂肪酸多元醇酯或脂肪酸聚氧乙烯多元醇酯。
优选地，所述阻燃剂为阻燃剂CP。
以上几种助剂的优选搭配，使得所述防水剂适用于天然纤维、涤棉混纺、锦棉混纺、合成纤维等织物面料的一般防水防油加工，对各种纤维面料均具有优良的防水防油性能。
同时，本发明还提供一种服装面料用环保耐久防水剂的制备方法，所述制备方法包括如下步骤：1)取搅拌釜，加入所述聚乙烯醇、碳酸钠、月桂醇聚氧乙烯醚、松香、硬脂酸、氢氧化钠、苯甲酸钠及40~50%的去离子水，在800~1000转/分的转速下搅拌15~25分钟，搅拌温度30~40℃；2)升温至50~60℃，加入二乙醇酰胺、醋酸、甲基纤维素、乳化剂、偶联剂、交联剂、阻燃剂及剩余去离子水，在1000~1200转/分的转速下搅拌15~20分钟，搅拌完毕后冷却至室温，即得所述服装面料用环保耐久防水剂。
本发明具有如下优点：
所述防水剂适用于天然纤维、涤棉混纺、锦棉混纺、合成纤维等织物面料的一般防水防油加工，对各种纤维面料均具有优良的防水防油性能，不损害纤维原有的手感，不降低面料原有的摩擦牢度，具有优异的剥离强度，与其它纺织助剂并用时，具有优良的稳定性，无着火点，属非危险品类，使用更安全。
具体实施方式
下面通过具体实施例对本发明做进一步的说明，但实施例并不限制本发明的保护范围。
本发明所提供的一种服装面料用环保耐久防水剂，所述防水剂包括如下重量份的成分：聚乙烯醇：20~30份，碳酸钠：10~15份，月桂醇聚氧乙烯醚：15~25份，松香：5~10份；硬脂酸：10~15份，氢氧化钠：10~15份，苯甲酸钠：1~5份，二乙醇酰胺：10~15份，醋酸：5~10份，甲基纤维素：5~10份，乳化剂：5~10份，偶联剂：1~5份，交联剂：1~5份，阻燃剂：1~5份，去离子水：40~50份。
进一步，所述防水剂包括如下重量份的成分：聚乙烯醇：25~30份，碳酸钠：13~15份，月桂醇聚氧乙烯醚：15~20份，松香：5~8份；硬脂酸：12~15份，氢氧化钠：10~14份，苯甲酸钠：3~5份，二乙醇酰胺：13~15份，醋酸：5~7份，甲基纤维素：6~10份，乳化剂：8~10份，偶联剂：1~4份，交联剂：3~5份，阻燃剂：2~5份，去离子水：40~45份。
优选地，所述防水剂包括如下重量份的成分：聚乙烯醇：25份，碳酸钠：13份，月桂醇聚氧乙烯醚：20份，松香：8份；硬脂酸：13份，氢氧化钠：12份，苯甲酸钠：4份，二乙醇酰胺：14份，醋酸：6份，甲基纤维素：7份，乳化剂：9份，偶联剂：3份，交联剂：4份，阻燃剂：2份，去离子水：45份。
优选地，所述偶联剂为N-(β-氨乙基)-γ-氨丙基甲基二甲氧基硅烷或N-2-(氨乙基)-3-氨丙基三甲氧基硅烷。
优选地，所述交联剂为二羟甲基脲、二羟甲基乙烯脲或二羟甲基二羟基乙烯脲。
优选地，所述乳化剂为脂肪酸多元醇酯或脂肪酸聚氧乙烯多元醇酯。
优选地，所述阻燃剂为阻燃剂CP。
以上几种助剂的优选搭配，使得所述防水剂适用于天然纤维、涤棉混纺、锦棉混纺、合成纤维等织物面料的一般防水防油加工，对各种纤维面料均具有优良的防水防油性能。
同时，本发明还提供一种服装面料用环保耐久防水剂的制备方法，所述制备方法包括如下步骤：1)取搅拌釜，加入所述聚乙烯醇、碳酸钠、月桂醇聚氧乙烯醚、松香、硬脂酸、氢氧化钠、苯甲酸钠及40~50%的去离子水，在800~1000转/分的转速下搅拌15~25分钟，搅拌温度30~40℃；2)升温至50~60℃，加入二乙醇酰胺、醋酸、甲基纤维素、乳化剂、偶联剂、交联剂、阻燃剂及剩余去离子水，在1000~1200转/分的转速下搅拌15~20分钟，搅拌完毕后冷却至室温，即得所述服装面料用环保耐久防水剂。
本发明所提供的一种服装面料用环保耐久防水剂，适用于天然纤维、涤棉混纺、锦棉混纺、合成纤维等织物面料的一般防水防油加工，对各种纤维面料均具有优良的防水防油性能，不损害纤维原有的手感，不降低面料原有的摩擦牢度，具有优异的剥离强度，与其它纺织助剂并用时，具有优良的稳定性，无着火点，属非危险品类，使用更安全。
需要说明的是，以上实施例仅用以说明本发明的技术方案而非限制。尽管参照较佳实施例对本发明进行了详细说明，本领域的普通技术人员应当理解，可以对发明的技术方案进行修改或者等同替换，而不脱离本发明技术方案的范围，其均应涵盖在本发明的权利要求范围中。

Claims (8)

1.一种服装面料用环保耐久防水剂，其特征在于，所述防水剂包括如下重量份的成分：聚乙烯醇：20~30份，碳酸钠：10~15份，月桂醇聚氧乙烯醚：15~25份，松香：5~10份；硬脂酸：10~15份，氢氧化钠：10~15份，苯甲酸钠：1~5份，二乙醇酰胺：10~15份，醋酸：5~10份，甲基纤维素：5~10份，乳化剂：5~10份，偶联剂：1~5份，交联剂：1~5份，阻燃剂：1~5份，去离子水：40~50份。
2.根据权利要求1所述的服装面料用环保耐久防水剂，其特征在于，所述防水剂包括如下重量份的成分：聚乙烯醇：25~30份，碳酸钠：13~15份，月桂醇聚氧乙烯醚：15~20份，松香：5~8份；硬脂酸：12~15份，氢氧化钠：10~14份，苯甲酸钠：3~5份，二乙醇酰胺：13~15份，醋酸：5~7份，甲基纤维素：6~10份，乳化剂：8~10份，偶联剂：1~4份，交联剂：3~5份，阻燃剂：2~5份，去离子水：40~45份。
3.根据权利要求1所述的服装面料用环保耐久防水剂，其特征在于，所述防水剂包括如下重量份的成分：聚乙烯醇：25份，碳酸钠：13份，月桂醇聚氧乙烯醚：20份，松香：8份；硬脂酸：13份，氢氧化钠：12份，苯甲酸钠：4份，二乙醇酰胺：14份，醋酸：6份，甲基纤维素：7份，乳化剂：9份，偶联剂：3份，交联剂：4份，阻燃剂：2份，去离子水：45份。
4.根据权利要求1所述的服装面料用环保耐久防水剂，其特征在于，所述偶联剂为N-(β-氨乙基)-γ-氨丙基甲基二甲氧基硅烷或N-2-(氨乙基)-3-氨丙基三甲氧基硅烷。
5.根据权利要求1所述的服装面料用环保耐久防水剂，其特征在于，所述交联剂为二羟甲基脲、二羟甲基乙烯脲或二羟甲基二羟基乙烯脲。
6.根据权利要求1所述的服装面料用环保耐久防水剂，其特征在于，所述乳化剂为脂肪酸多元醇酯或脂肪酸聚氧乙烯多元醇酯。
7.根据权利要求1所述的服装面料用环保耐久防水剂，其特征在于，所述阻燃剂为阻燃剂CP。
8.一种如权利要求1~7中任一项所述的服装面料用环保耐久防水剂的制备方法，其特征在于，所述制备方法包括如下步骤：1)取搅拌釜，加入所述聚乙烯醇、碳酸钠、月桂醇聚氧乙烯醚、松香、硬脂酸、氢氧化钠、苯甲酸钠及40~50%的去离子水，在800~1000转/分的转速下搅拌15~25分钟，搅拌温度30~40℃；2)升温至50~60℃，加入二乙醇酰胺、醋酸、甲基纤维素、乳化剂、偶联剂、交联剂、阻燃剂及剩余去离子水，在1000~1200转/分的转速下搅拌15~20分钟，搅拌完毕后冷却至室温，即得所述服装面料用环保耐久防水剂。
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