CN107326676A - 一种服装面料用环保耐久防水剂及其制备方法 - Google Patents

一种服装面料用环保耐久防水剂及其制备方法 Download PDF

Info

Publication number
CN107326676A
CN107326676A CN201710635759.0A CN201710635759A CN107326676A CN 107326676 A CN107326676 A CN 107326676A CN 201710635759 A CN201710635759 A CN 201710635759A CN 107326676 A CN107326676 A CN 107326676A
Authority
CN
China
Prior art keywords
parts
agent
garment material
durable waterproof
environmental protection
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710635759.0A
Other languages
English (en)
Inventor
龚利峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SUZHOU IMURA GARMENTS CO Ltd
Original Assignee
SUZHOU IMURA GARMENTS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SUZHOU IMURA GARMENTS CO Ltd filed Critical SUZHOU IMURA GARMENTS CO Ltd
Priority to CN201710635759.0A priority Critical patent/CN107326676A/zh
Publication of CN107326676A publication Critical patent/CN107326676A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/2035—Aromatic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/05—Cellulose or derivatives thereof
    • D06M15/09—Cellulose ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/17—Natural resins, resinous alcohols, resinous acids, or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/11—Oleophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本发明公开了一种服装面料用环保耐久防水剂及其制备方法，所述防水剂包括如下重量份的成分：聚乙烯醇，碳酸钠，月桂醇聚氧乙烯醚，松香；硬脂酸，氢氧化钠，苯甲酸钠，二乙醇酰胺，醋酸，甲基纤维素，乳化剂，偶联剂，交联剂，阻燃剂，去离子水。所述防水剂适用于天然纤维、涤棉混纺、锦棉混纺、合成纤维等织物面料的一般防水防油加工，对各种纤维面料均具有优良的防水防油性能，不损害纤维原有的手感，不降低面料原有的摩擦牢度，具有优异的剥离强度，与其它纺织助剂并用时，具有优良的稳定性，无着火点，属非危险品类，使用更安全。

Description

一种服装面料用环保耐久防水剂及其制备方法
技术领域
本发明属于服装面料助剂技术领域，具体涉及一种服装面料用环保耐久防水剂及其制备方法。
背景技术
面料就是用来制作服装的材料。作为服装三要素之一，面料不仅可以诠释服装的风格和特性，而且直接左右着服装的色彩、造型的表现效果。
服装以面料制作而成，面料就是用来制作服装的材料。作为服装三要素之一，面料不仅可以诠释服装的风格和特性，而且直接左右着服装的色彩、造型的表现效果。呈现出自身的高贵完美，手感柔软。
现代制作在正式的社交场合所穿著的服装，多选用优质的混纺面料。而纯棉、纯毛、纯丝、纯麻等天然面料因为有着易皱、易变形等天然面料的缺点，已经沦为一般布料，较少作为高档服装用料。混纺面料有着天然面料吸汗透气、柔软舒服的特点，又吸收了化纤面料结实耐穿、垂悬挺括、光泽好颜色鲜亮等优点，每年有大量的高档优质混纺面料被开发出来。有时，穿著纯皮革制作的服装，也是允许的。
对于服装面料的防水，目前国内主要存在如下专利文献：
授权公告号为104562686B的中国专利公开了一种持久性良好的纺织品用防水剂，包括以下质量份的组分：聚乙烯醇15～20，环氧氯丙烷15～18，皂粉10～14，脂肪酸纳8～12，醋酸5～10，乙醇25～30，松香5～10，甲基纤维素2～3。本发明的制备方法为，称取所需原料，将松香置于乙醇中，加热至40～50℃，搅拌均匀；于上述溶液中保温依次加入醋酸、皂粉、脂肪酸纳、环氧氯乙烷、甲基纤维素和聚乙烯醇，搅拌混合均匀，冷却至室温既得成品。本发明的织物防水剂制备工艺简单，原料易得，生产成本低，抗渗防渗效果好；处理后的织物耐水洗和干洗，持久性良好；本发明的织物防水剂还具有安全无害的特点。然而，该专利所提供的防水剂，成分原料设计简单，防水效果有待商榷。
发明内容
为解决上述存在的问题，本发明的目的在于提供一种服装面料用环保耐久防水剂及其制备方法，所述防水剂适用于天然纤维、涤棉混纺、锦棉混纺、合成纤维等织物面料的一般防水防油加工，对各种纤维面料均具有优良的防水防油性能，不损害纤维原有的手感，不降低面料原有的摩擦牢度，具有优异的剥离强度，与其它纺织助剂并用时，具有优良的稳定性，无着火点，属非危险品类，使用更安全。
为达到上述目的，本发明的技术方案是：
一种服装面料用环保耐久防水剂，所述防水剂包括如下重量份的成分：聚乙烯醇：20~30份，碳酸钠：10~15份，月桂醇聚氧乙烯醚：15~25份，松香：5~10份；硬脂酸：10~15份，氢氧化钠：10~15份，苯甲酸钠：1~5份，二乙醇酰胺：10~15份，醋酸：5~10份，甲基纤维素：5~10份，乳化剂：5~10份，偶联剂：1~5份，交联剂：1~5份，阻燃剂：1~5份，去离子水：40~50份。
进一步，所述防水剂包括如下重量份的成分：聚乙烯醇：25~30份，碳酸钠：13~15份，月桂醇聚氧乙烯醚：15~20份，松香：5~8份；硬脂酸：12~15份，氢氧化钠：10~14份，苯甲酸钠：3~5份，二乙醇酰胺：13~15份，醋酸：5~7份，甲基纤维素：6~10份，乳化剂：8~10份，偶联剂：1~4份，交联剂：3~5份，阻燃剂：2~5份，去离子水：40~45份。
优选地，所述防水剂包括如下重量份的成分：聚乙烯醇：25份，碳酸钠：13份，月桂醇聚氧乙烯醚：20份，松香：8份；硬脂酸：13份，氢氧化钠：12份，苯甲酸钠：4份，二乙醇酰胺：14份，醋酸：6份，甲基纤维素：7份，乳化剂：9份，偶联剂：3份，交联剂：4份，阻燃剂：2份，去离子水：45份。
优选地，所述偶联剂为N-(β-氨乙基)-γ-氨丙基甲基二甲氧基硅烷或N-2-(氨乙基)-3-氨丙基三甲氧基硅烷。
优选地，所述交联剂为二羟甲基脲、二羟甲基乙烯脲或二羟甲基二羟基乙烯脲。
优选地，所述乳化剂为脂肪酸多元醇酯或脂肪酸聚氧乙烯多元醇酯。
优选地，所述阻燃剂为阻燃剂CP。
以上几种助剂的优选搭配，使得所述防水剂适用于天然纤维、涤棉混纺、锦棉混纺、合成纤维等织物面料的一般防水防油加工，对各种纤维面料均具有优良的防水防油性能。
同时，本发明还提供一种服装面料用环保耐久防水剂的制备方法，所述制备方法包括如下步骤：1)取搅拌釜，加入所述聚乙烯醇、碳酸钠、月桂醇聚氧乙烯醚、松香、硬脂酸、氢氧化钠、苯甲酸钠及40~50%的去离子水，在800~1000转/分的转速下搅拌15~25分钟，搅拌温度30~40℃；2)升温至50~60℃，加入二乙醇酰胺、醋酸、甲基纤维素、乳化剂、偶联剂、交联剂、阻燃剂及剩余去离子水，在1000~1200转/分的转速下搅拌15~20分钟，搅拌完毕后冷却至室温，即得所述服装面料用环保耐久防水剂。
本发明具有如下优点：
所述防水剂适用于天然纤维、涤棉混纺、锦棉混纺、合成纤维等织物面料的一般防水防油加工，对各种纤维面料均具有优良的防水防油性能，不损害纤维原有的手感，不降低面料原有的摩擦牢度，具有优异的剥离强度，与其它纺织助剂并用时，具有优良的稳定性，无着火点，属非危险品类，使用更安全。
具体实施方式
下面通过具体实施例对本发明做进一步的说明，但实施例并不限制本发明的保护范围。
本发明所提供的一种服装面料用环保耐久防水剂，所述防水剂包括如下重量份的成分：聚乙烯醇：20~30份，碳酸钠：10~15份，月桂醇聚氧乙烯醚：15~25份，松香：5~10份；硬脂酸：10~15份，氢氧化钠：10~15份，苯甲酸钠：1~5份，二乙醇酰胺：10~15份，醋酸：5~10份，甲基纤维素：5~10份，乳化剂：5~10份，偶联剂：1~5份，交联剂：1~5份，阻燃剂：1~5份，去离子水：40~50份。
进一步，所述防水剂包括如下重量份的成分：聚乙烯醇：25~30份，碳酸钠：13~15份，月桂醇聚氧乙烯醚：15~20份，松香：5~8份；硬脂酸：12~15份，氢氧化钠：10~14份，苯甲酸钠：3~5份，二乙醇酰胺：13~15份，醋酸：5~7份，甲基纤维素：6~10份，乳化剂：8~10份，偶联剂：1~4份，交联剂：3~5份，阻燃剂：2~5份，去离子水：40~45份。
优选地，所述防水剂包括如下重量份的成分：聚乙烯醇：25份，碳酸钠：13份，月桂醇聚氧乙烯醚：20份，松香：8份；硬脂酸：13份，氢氧化钠：12份，苯甲酸钠：4份，二乙醇酰胺：14份，醋酸：6份，甲基纤维素：7份，乳化剂：9份，偶联剂：3份，交联剂：4份，阻燃剂：2份，去离子水：45份。
优选地，所述偶联剂为N-(β-氨乙基)-γ-氨丙基甲基二甲氧基硅烷或N-2-(氨乙基)-3-氨丙基三甲氧基硅烷。
优选地，所述交联剂为二羟甲基脲、二羟甲基乙烯脲或二羟甲基二羟基乙烯脲。
优选地，所述乳化剂为脂肪酸多元醇酯或脂肪酸聚氧乙烯多元醇酯。
优选地，所述阻燃剂为阻燃剂CP。
以上几种助剂的优选搭配，使得所述防水剂适用于天然纤维、涤棉混纺、锦棉混纺、合成纤维等织物面料的一般防水防油加工，对各种纤维面料均具有优良的防水防油性能。
同时，本发明还提供一种服装面料用环保耐久防水剂的制备方法，所述制备方法包括如下步骤：1)取搅拌釜，加入所述聚乙烯醇、碳酸钠、月桂醇聚氧乙烯醚、松香、硬脂酸、氢氧化钠、苯甲酸钠及40~50%的去离子水，在800~1000转/分的转速下搅拌15~25分钟，搅拌温度30~40℃；2)升温至50~60℃，加入二乙醇酰胺、醋酸、甲基纤维素、乳化剂、偶联剂、交联剂、阻燃剂及剩余去离子水，在1000~1200转/分的转速下搅拌15~20分钟，搅拌完毕后冷却至室温，即得所述服装面料用环保耐久防水剂。
本发明所提供的一种服装面料用环保耐久防水剂，适用于天然纤维、涤棉混纺、锦棉混纺、合成纤维等织物面料的一般防水防油加工，对各种纤维面料均具有优良的防水防油性能，不损害纤维原有的手感，不降低面料原有的摩擦牢度，具有优异的剥离强度，与其它纺织助剂并用时，具有优良的稳定性，无着火点，属非危险品类，使用更安全。
需要说明的是，以上实施例仅用以说明本发明的技术方案而非限制。尽管参照较佳实施例对本发明进行了详细说明，本领域的普通技术人员应当理解，可以对发明的技术方案进行修改或者等同替换，而不脱离本发明技术方案的范围，其均应涵盖在本发明的权利要求范围中。

Claims (8)

1.一种服装面料用环保耐久防水剂，其特征在于，所述防水剂包括如下重量份的成分：聚乙烯醇：20~30份，碳酸钠：10~15份，月桂醇聚氧乙烯醚：15~25份，松香：5~10份；硬脂酸：10~15份，氢氧化钠：10~15份，苯甲酸钠：1~5份，二乙醇酰胺：10~15份，醋酸：5~10份，甲基纤维素：5~10份，乳化剂：5~10份，偶联剂：1~5份，交联剂：1~5份，阻燃剂：1~5份，去离子水：40~50份。
2.根据权利要求1所述的服装面料用环保耐久防水剂，其特征在于，所述防水剂包括如下重量份的成分：聚乙烯醇：25~30份，碳酸钠：13~15份，月桂醇聚氧乙烯醚：15~20份，松香：5~8份；硬脂酸：12~15份，氢氧化钠：10~14份，苯甲酸钠：3~5份，二乙醇酰胺：13~15份，醋酸：5~7份，甲基纤维素：6~10份，乳化剂：8~10份，偶联剂：1~4份，交联剂：3~5份，阻燃剂：2~5份，去离子水：40~45份。
3.根据权利要求1所述的服装面料用环保耐久防水剂，其特征在于，所述防水剂包括如下重量份的成分：聚乙烯醇：25份，碳酸钠：13份，月桂醇聚氧乙烯醚：20份，松香：8份；硬脂酸：13份，氢氧化钠：12份，苯甲酸钠：4份，二乙醇酰胺：14份，醋酸：6份，甲基纤维素：7份，乳化剂：9份，偶联剂：3份，交联剂：4份，阻燃剂：2份，去离子水：45份。
4.根据权利要求1所述的服装面料用环保耐久防水剂，其特征在于，所述偶联剂为N-(β-氨乙基)-γ-氨丙基甲基二甲氧基硅烷或N-2-(氨乙基)-3-氨丙基三甲氧基硅烷。
5.根据权利要求1所述的服装面料用环保耐久防水剂，其特征在于，所述交联剂为二羟甲基脲、二羟甲基乙烯脲或二羟甲基二羟基乙烯脲。
6.根据权利要求1所述的服装面料用环保耐久防水剂，其特征在于，所述乳化剂为脂肪酸多元醇酯或脂肪酸聚氧乙烯多元醇酯。
7.根据权利要求1所述的服装面料用环保耐久防水剂，其特征在于，所述阻燃剂为阻燃剂CP。
8.一种如权利要求1~7中任一项所述的服装面料用环保耐久防水剂的制备方法，其特征在于，所述制备方法包括如下步骤：1)取搅拌釜，加入所述聚乙烯醇、碳酸钠、月桂醇聚氧乙烯醚、松香、硬脂酸、氢氧化钠、苯甲酸钠及40~50%的去离子水，在800~1000转/分的转速下搅拌15~25分钟，搅拌温度30~40℃；2)升温至50~60℃，加入二乙醇酰胺、醋酸、甲基纤维素、乳化剂、偶联剂、交联剂、阻燃剂及剩余去离子水，在1000~1200转/分的转速下搅拌15~20分钟，搅拌完毕后冷却至室温，即得所述服装面料用环保耐久防水剂。
CN201710635759.0A 2017-07-31 2017-07-31 一种服装面料用环保耐久防水剂及其制备方法 Pending CN107326676A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710635759.0A CN107326676A (zh) 2017-07-31 2017-07-31 一种服装面料用环保耐久防水剂及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710635759.0A CN107326676A (zh) 2017-07-31 2017-07-31 一种服装面料用环保耐久防水剂及其制备方法

Publications (1)

Publication Number Publication Date
CN107326676A true CN107326676A (zh) 2017-11-07

Family

ID=60199515

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710635759.0A Pending CN107326676A (zh) 2017-07-31 2017-07-31 一种服装面料用环保耐久防水剂及其制备方法

Country Status (1)

Country Link
CN (1) CN107326676A (zh)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108570854A (zh) * 2018-05-07 2018-09-25 佛山慧创正元新材料科技有限公司 一种耐强洗涤的纺织品用防水剂及其制备方法
CN108611858A (zh) * 2018-05-07 2018-10-02 佛山慧创正元新材料科技有限公司 一种耐强洗涤的纺织品用防水涂层胶粘整理剂及其制备方法
CN110172822A (zh) * 2019-06-11 2019-08-27 淄博大洋阻燃制品有限公司 一种腈纶/聚酯混纺面料阻燃防水织物的制备方法
CN111139650A (zh) * 2020-03-03 2020-05-12 南通天梭纺织有限公司 一种防水纺织面料的制备工艺

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101805990A (zh) * 2010-02-02 2010-08-18 广东鸿昌服饰创意股份有限公司 拒水整理剂及用拒水整理剂制作吸湿排汗牛仔面料的制造方法
CN102011304A (zh) * 2009-09-08 2011-04-13 张启辉 棉织物抗水整理剂
CN102978925A (zh) * 2012-12-03 2013-03-20 吴江市鼎佳纺织有限公司 一种拒水整理剂
CN104179013A (zh) * 2014-08-28 2014-12-03 东莞市长安东阳光铝业研发有限公司 防水防油剂组合物及防水防油剂添加剂组合物
CN106087425A (zh) * 2016-07-18 2016-11-09 南通富之岛寝具发展有限公司 一种纺织品用防水剂及其制备方法
CN106220856A (zh) * 2016-08-01 2016-12-14 太仓中化环保化工有限公司 一种松香改性硅蜡及其制备方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102011304A (zh) * 2009-09-08 2011-04-13 张启辉 棉织物抗水整理剂
CN101805990A (zh) * 2010-02-02 2010-08-18 广东鸿昌服饰创意股份有限公司 拒水整理剂及用拒水整理剂制作吸湿排汗牛仔面料的制造方法
CN102978925A (zh) * 2012-12-03 2013-03-20 吴江市鼎佳纺织有限公司 一种拒水整理剂
CN104179013A (zh) * 2014-08-28 2014-12-03 东莞市长安东阳光铝业研发有限公司 防水防油剂组合物及防水防油剂添加剂组合物
CN106087425A (zh) * 2016-07-18 2016-11-09 南通富之岛寝具发展有限公司 一种纺织品用防水剂及其制备方法
CN106220856A (zh) * 2016-08-01 2016-12-14 太仓中化环保化工有限公司 一种松香改性硅蜡及其制备方法

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
化学工业出版社组织编写: "《中国化工和石油产品目录》", 31 May 1999, 化学工业出版社 *
宋小平: "《纺织染整添加剂生产与应用技术》", 30 April 2007, 中国石化出版社 *
闫克路: "《染整工艺学教程》", 30 September 2005, 中国纺织出版社 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108570854A (zh) * 2018-05-07 2018-09-25 佛山慧创正元新材料科技有限公司 一种耐强洗涤的纺织品用防水剂及其制备方法
CN108611858A (zh) * 2018-05-07 2018-10-02 佛山慧创正元新材料科技有限公司 一种耐强洗涤的纺织品用防水涂层胶粘整理剂及其制备方法
CN110172822A (zh) * 2019-06-11 2019-08-27 淄博大洋阻燃制品有限公司 一种腈纶/聚酯混纺面料阻燃防水织物的制备方法
CN111139650A (zh) * 2020-03-03 2020-05-12 南通天梭纺织有限公司 一种防水纺织面料的制备工艺

Similar Documents

Publication Publication Date Title
CN107326676A (zh) 一种服装面料用环保耐久防水剂及其制备方法
CN103031637B (zh) sorona/羊毛的半精纺纱线及其生产工艺和应用
CN106833940B (zh) 防沾色洗衣剂、防沾色洗衣液和防沾色洗衣布
CN108004771A (zh) 一种环保浆料助剂及其制备方法与应用
CN109554911A (zh) 一种基于生物基材料的记忆t400织物的染整加工工艺
CN106939515B (zh) 一种牛仔面料生产中球经丝光工艺及高效丝光渗透剂的制备
CN106758202A (zh) 一种衬衫的防缩吸湿快干型免烫整理液及其整理方法
CN104005238A (zh) 一种贴身功能性混纺面料
CN103147327B (zh) 一种染料固色剂及其制备方法
CN110079918A (zh) 环保保健型纺织品的生产工艺
CN101457488A (zh) 聚乳酸纤维梭织布的染色加工工艺
CN105239253B (zh) 一种耐久阻燃布及其制备方法
CN116461160A (zh) 一种耐磨透气的校服面料制备方法
CN113026396B (zh) 一种固色剂及应用该固色剂的棉布轧染染色工艺
CN101768874B (zh) 聚乳酸纤维织物分散染料低温染色方法
CN105040489A (zh) 一种新型固色剂的制备方法及其产品
KR20090132810A (ko) 양모와 폴리유산섬유의 합연사의 염색방법
CN103790315B (zh) 聚乳酸生物可降解墙面装饰材料及其制备方法
CN111452447A (zh) 一种多功能三层复合阻燃面料
CN106758200A (zh) 一种衬衫的抗紫外线防护型免烫整理液及其整理方法
CN103556508A (zh) 芳纶粘胶混纺迷彩印花织物的印花方法
CN102321980A (zh) 涤纶织物低温染色方法
CN111155223A (zh) 一种高强阻燃面料的制备方法
CN104032602B (zh) 防活性染料沾色剂
CN107326673A (zh) 一种服装面料用环保抗皱整理剂及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20171107

RJ01 Rejection of invention patent application after publication