CN108468205A - 一种纺织品用无氟防水剂及其制备方法 - Google Patents

一种纺织品用无氟防水剂及其制备方法 Download PDF

Info

Publication number
CN108468205A
CN108468205A CN201810302285.2A CN201810302285A CN108468205A CN 108468205 A CN108468205 A CN 108468205A CN 201810302285 A CN201810302285 A CN 201810302285A CN 108468205 A CN108468205 A CN 108468205A
Authority
CN
China
Prior art keywords
parts
textiles
water
agent used
proofing agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810302285.2A
Other languages
English (en)
Inventor
胡玲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foshan Huichuang Zhengyuan New Mstar Technology Ltd
Original Assignee
Foshan Huichuang Zhengyuan New Mstar Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foshan Huichuang Zhengyuan New Mstar Technology Ltd filed Critical Foshan Huichuang Zhengyuan New Mstar Technology Ltd
Priority to CN201810302285.2A priority Critical patent/CN108468205A/zh
Publication of CN108468205A publication Critical patent/CN108468205A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
    • D06M11/65—Salts of oxyacids of nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/647—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/11—Oleophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本发明公开了一种纺织品用无氟防水剂，其由以下重量份数的原料组成：丙烯酸正丁酯20～30份、气相二氧化钛1～3份、高级脂肪醇丙烯酸酯10～15份、聚乙烯蜡1～3份、二丁基萘磺酸钠1～4份、烷基甘油醚磺酸盐2～5份、聚醚硅油2～4份、硬脂酸1.5～3份、六水合硝酸锌0.5～1份、催化剂0.2～0.5份、水100～140份。本发明提供的纺织品用防水剂创新性的将丙烯酸正丁酯、高级脂肪醇丙烯酸酯在催化剂的作用下产生反应，并于气相二氧化钛、聚乙烯蜡、二丁基萘磺酸钠、烷基甘油醚磺酸盐、聚醚硅油、硬脂酸、六水合硝酸锌共混反应，获得具有良好抗水防油效果，同时耐洗涤的纺织品用环保无氟防水整理剂。

Description

一种纺织品用无氟防水剂及其制备方法
技术领域
本发明涉及纺织品加工用料及制备领域，具体涉及一种纺织品用无氟防水剂及其制备方法。
背景技术
为了适应人们对纺织品的不断要求，越来越多的纺织品被赋予功能性，而防水功能就是其中一个重要的分支。拒水拒油织物是一种功能化、智能化的织物。经过拒水拒油整理的纺织品能抵御雨水、油迹，而且能让人体的汗液、汗气及时地排出，从而使人体保持干爽和温暖，并且在装饰、产业领域中应用的具有拒水拒油功能的餐桌布、汽车防护罩等也备受青睐。
目前最优秀的防水整理剂仍然是含氟的有机聚合物。当然，这些防水整理剂大都含有PFOS或其衍生物，但是随着人们对环保要求的不断提高，氟碳型拒水剂的应用被严格限制。欧盟最新禁令出台以后，这些防水整理剂及其整理工艺不能再使用。因此其替代品的开发十分迫切。随着人们对纺织品以及化学品安全的要求进一步的提高，环保无氟型防水剂将会越来越受欢迎，但现有的无氟环保型防水剂的缺点是防油性能及防水耐洗涤性不够，远远达不到氟系产品的效果，从而在一定程度上限制了其在纺织品领域的发展和应用。
发明内容
针对现有技术不足，本发明提供了一种抗水防油效果良好的耐洗涤的纺织品用无氟防水剂及其制备方法。
本发明解决上述技术问题采用的技术方案为：一种纺织品用无氟防水剂，其由以下重量份数的原料组成：丙烯酸正丁酯20～30份、气相二氧化钛1～3份、高级脂肪醇丙烯酸酯10～15份、聚乙烯蜡1～3份、二丁基萘磺酸钠1～4份、烷基甘油醚磺酸盐2～5份、聚醚硅油2～4份、硬脂酸1.5～3份、六水合硝酸锌0.5～1份、催化剂0.2～0.5份、水100～140份。
进一步地，所述的一种纺织品用无氟防水剂，其由以下重量份数的原料组成：丙烯酸正丁酯25份、气相二氧化钛2份、高级脂肪醇丙烯酸酯12份、聚乙烯蜡2份、二丁基萘磺酸钠3份、烷基甘油醚磺酸盐4份、聚醚硅油3份、硬脂酸2份、六水合硝酸锌0.7份、催化剂0.3份、水120份。
进一步地，所述的催化剂为正丁基锂。
所述的一种纺织品用无氟防水剂的制备方法，其包括以下步骤：
(1)按照所述重量份数备取原料；
(2)将气相二氧化钛、六水合硝酸锌和聚醚硅油置于容器中搅拌1～1.5h，得匀混物料；
(3)将丙烯酸正丁酯、高级脂肪醇丙烯酸酯、聚乙烯蜡、二丁基萘磺酸钠、烷基甘油醚磺酸盐、硬脂酸和占水总量三分之二的水与步骤(2)得到的匀混物料混合，并在75～85℃下保温搅拌40～50min，得匀混液；
(4)将步骤(3)得到的匀混液温度降至55～65℃，并保温滴加催化剂与剩余水的共混液，滴加时间控制在50～70min，滴加完毕后继续保温搅拌2～2.5h；
(5)将步骤(4)得到的混合液体冷却到室温，用剪切机进行剪切处理，剪切机转速为5000rpm，剪切时间为10～20min，剪切后过滤，即得到本发明的纺织品用无氟防水剂。
与现有技术相比，本发明具备的有益效果为：本发明提供的纺织品用防水剂创新性的将丙烯酸正丁酯、高级脂肪醇丙烯酸酯在催化剂的作用下产生反应，并与气相二氧化钛、聚乙烯蜡、二丁基萘磺酸钠、烷基甘油醚磺酸盐、聚醚硅油、硬脂酸、六水合硝酸锌共混反应，获得具有良好抗水防油效果，同时耐洗涤的纺织品用环保无氟防水整理剂。
具体实施方式
下面结合具体实施例对本发明做进一步详细的说明。
实施例1：一种纺织品用无氟防水剂，其由以下重量份数的原料组成：丙烯酸正丁酯25份、气相二氧化钛2份、高级脂肪醇丙烯酸酯12份、聚乙烯蜡2份、二丁基萘磺酸钠3份、烷基甘油醚磺酸盐4份、聚醚硅油3份、硬脂酸2份、六水合硝酸锌0.7份、催化剂0.3份、水120份；所述的催化剂为正丁基锂。
所述的一种纺织品用无氟防水剂的制备方法，其包括以下步骤：
(1)按照所述重量份数备取原料；
(2)将气相二氧化钛、六水合硝酸锌和聚醚硅油置于容器中搅拌75min，得匀混物料；
(3)将丙烯酸正丁酯、高级脂肪醇丙烯酸酯、聚乙烯蜡、二丁基萘磺酸钠、烷基甘油醚磺酸盐、硬脂酸和80份的水与步骤(2)得到的匀混物料混合，并在80℃下保温搅拌45min，得匀混液；
(4)将步骤(3)得到的匀混液温度降至60℃，并保温滴加催化剂与剩余水的共混液，滴加时间控制在60min，滴加完毕后继续保温搅拌135min；
(5)将步骤(4)得到的混合液体冷却到室温，用剪切机进行剪切处理，剪切机转速为5000rpm，剪切时间为15min，剪切后过滤，即得到本发明的纺织品用无氟防水剂。
实施例2：一种纺织品用无氟防水剂，其由以下重量份数的原料组成：丙烯酸正丁酯20份、气相二氧化钛1份、高级脂肪醇丙烯酸酯10份、聚乙烯蜡1份、二丁基萘磺酸钠1份、烷基甘油醚磺酸盐2份、聚醚硅油2份、硬脂酸1.5份、六水合硝酸锌0.5份、催化剂正丁基锂0.2份、水100份。
所述的一种纺织品用无氟防水剂的制备方法，其包括以下步骤：
(1)按照所述重量份数备取原料；
(2)将气相二氧化钛、六水合硝酸锌和聚醚硅油置于容器中搅拌1h，得匀混物料；
(3)将丙烯酸正丁酯、高级脂肪醇丙烯酸酯、聚乙烯蜡、二丁基萘磺酸钠、烷基甘油醚磺酸盐、硬脂酸和占水总量三分之二的水与步骤(2)得到的匀混物料混合，并在75℃下保温搅拌40min，得匀混液；
(4)将步骤(3)得到的匀混液温度降至55℃，并保温滴加催化剂与剩余水的共混液，滴加时间控制在50min，滴加完毕后继续保温搅拌2h；
(5)将步骤(4)得到的混合液体冷却到室温，用剪切机进行剪切处理，剪切机转速为5000rpm，剪切时间为10min，剪切后过滤，即得到本发明的纺织品用无氟防水剂。
实施例3：一种纺织品用无氟防水剂，其由以下重量份数的原料组成：丙烯酸正丁酯30份、气相二氧化钛3份、高级脂肪醇丙烯酸酯15份、聚乙烯蜡3份、二丁基萘磺酸钠4份、烷基甘油醚磺酸盐5份、聚醚硅油4份、硬脂酸3份、六水合硝酸锌1份、催化剂正丁基锂0.5份、水140份。
所述的一种纺织品用无氟防水剂的制备方法，其包括以下步骤：
(1)按照所述重量份数备取原料；
(2)将气相二氧化钛、六水合硝酸锌和聚醚硅油置于容器中搅拌1.5h，得匀混物料；
(3)将丙烯酸正丁酯、高级脂肪醇丙烯酸酯、聚乙烯蜡、二丁基萘磺酸钠、烷基甘油醚磺酸盐、硬脂酸和占水总量三分之二的水与步骤(2)得到的匀混物料混合，并在85℃下保温搅拌50min，得匀混液；
(4)将步骤(3)得到的匀混液温度降至65℃，并保温滴加催化剂与剩余水的共混液，滴加时间控制在70min，滴加完毕后继续保温搅拌2.5h；
(5)将步骤(4)得到的混合液体冷却到室温，用剪切机进行剪切处理，剪切机转速为5000rpm，剪切时间为20min，剪切后过滤，即得到本发明的纺织品用无氟防水剂。
实施例4：一种纺织品用无氟防水剂，其由以下重量份数的原料组成：丙烯酸正丁酯30份、气相二氧化钛1份、高级脂肪醇丙烯酸酯15份、聚乙烯蜡1份、二丁基萘磺酸钠1份、烷基甘油醚磺酸盐5份、聚醚硅油2份、硬脂酸3份、六水合硝酸锌0.5份、催化剂正丁基锂0.5份、水100份。
所述的一种纺织品用无氟防水剂的制备方法，其包括以下步骤：
(1)按照所述重量份数备取原料；
(2)将气相二氧化钛、六水合硝酸锌和聚醚硅油置于容器中搅拌70min，得匀混物料；
(3)将丙烯酸正丁酯、高级脂肪醇丙烯酸酯、聚乙烯蜡、二丁基萘磺酸钠、烷基甘油醚磺酸盐、硬脂酸和占水总量三分之二的水与步骤(2)得到的匀混物料混合，并在75℃下保温搅拌50min，得匀混液；
(4)将步骤(3)得到的匀混液温度降至55℃，并保温滴加催化剂与剩余水的共混液，滴加时间控制在70min，滴加完毕后继续保温搅拌2.2h；
(5)将步骤(4)得到的混合液体冷却到室温，用剪切机进行剪切处理，剪切机转速为5000rpm，剪切时间为12min，剪切后过滤，即得到本发明的纺织品用无氟防水剂。
实施例5：一种纺织品用无氟防水剂，其由以下重量份数的原料组成：丙烯酸正丁酯28份、气相二氧化钛1.5份、高级脂肪醇丙烯酸酯13份、聚乙烯蜡1.5份、二丁基萘磺酸钠3份、烷基甘油醚磺酸盐3份、聚醚硅油2份、硬脂酸2.5份、六水合硝酸锌0.7份、催化剂正丁基锂0.3份、水130份。
所述的一种纺织品用无氟防水剂的制备方法，其包括以下步骤：
(1)按照所述重量份数备取原料；
(2)将气相二氧化钛、六水合硝酸锌和聚醚硅油置于容器中搅拌70min，得匀混物料；
(3)将丙烯酸正丁酯、高级脂肪醇丙烯酸酯、聚乙烯蜡、二丁基萘磺酸钠、烷基甘油醚磺酸盐、硬脂酸和占水总量三分之二的水与步骤(2)得到的匀混物料混合，并在78℃下保温搅拌46min，得匀混液；
(4)将步骤(3)得到的匀混液温度降至62℃，并保温滴加催化剂与剩余水的共混液，滴加时间控制在55min，滴加完毕后继续保温搅拌2.5h；
(5)将步骤(4)得到的混合液体冷却到室温，用剪切机进行剪切处理，剪切机转速为5000rpm，剪切时间为18min，剪切后过滤，即得到本发明的纺织品用无氟防水剂。
对上述实施例1-5所得的防水剂加水配置成12g/L的整理液，将涤纶织物进行一浸一轧，浸轧液位70％，160℃烘焙90S，然后对其进行防水(标准AATCC-227，两次平均值)、防油(标准FZ/T
01067-1999，两次平均值)测试并进行多次洗涤(试样在SW-12型水洗牢度仪上进行洗涤，洗涤条件为：无水碳酸钠2.5g/L，净洗剂209，2.5g/L，浴比1:20，温度70℃，时间30min)测试其洗涤后的防水、防油性能，采用市售常见的防水剂为对比例做相同的测试，结果如下表所示：
经本发明的防水剂整理后的织物表面光滑柔软，防水剂成膜效果较好，可以均匀的覆盖在织物表面，具有较好的防水抗油效果，并且多次洗涤后仍可保持良好的防水抗油性能。

Claims (5)

1.一种纺织品用无氟防水剂，其特征在于：由以下重量份数的原料组成：丙烯酸正丁酯20～30份、气相二氧化钛1～3份、高级脂肪醇丙烯酸酯10～15份、聚乙烯蜡1～3份、二丁基萘磺酸钠1～4份、烷基甘油醚磺酸盐2～5份、聚醚硅油2～4份、硬脂酸1.5～3份、六水合硝酸锌0.5～1份、催化剂0.2～0.5份、水100～140份。
2.根据权利要求1所述的一种纺织品用无氟防水剂，其特征在于：由以下重量份数的原料组成：丙烯酸正丁酯25份、气相二氧化钛2份、高级脂肪醇丙烯酸酯12份、聚乙烯蜡1～3份、二丁基萘磺酸钠3份、烷基甘油醚磺酸盐4份、聚醚硅油3份、硬脂酸2份、六水合硝酸锌0.7份、催化剂0.3份、水120份。
3.根据权利要求1所述的一种纺织品用无氟防水剂，其特征在于：由以下重量份数的原料组成：丙烯酸正丁酯28份、气相二氧化钛1.5份、高级脂肪醇丙烯酸酯13份、聚乙烯蜡1.5份、二丁基萘磺酸钠3份、烷基甘油醚磺酸盐3份、聚醚硅油2份、硬脂酸2.5份、六水合硝酸锌0.7份、催化剂正丁基锂0.3份、水130份。
4.根据权利要求1-3任一项所述的一种纺织品用无氟防水剂，其特征在于：所述的催化剂为正丁基锂。
5.权利要求1-3任一项所述的一种纺织品用无氟防水剂的制备方法，其特征在于，包括以下步骤：
(1)按照所述重量份数备取原料；
(2)将气相二氧化钛、六水合硝酸锌和聚醚硅油置于容器中搅拌1～1.5h，得匀混物料；
(3)将丙烯酸正丁酯、高级脂肪醇丙烯酸酯、聚乙烯蜡、二丁基萘磺酸钠、烷基甘油醚磺酸盐、硬脂酸和占水总量三分之二的水与步骤(2)得到的匀混物料混合，并在75～85℃下保温搅拌40～50min，得匀混液；
(4)将步骤(3)得到的匀混液温度降至55～65℃，并保温滴加催化剂与剩余水的共混液，滴加时间控制在50～70min，滴加完毕后继续保温搅拌2～2.5h；
(5)将步骤(4)得到的混合液体冷却到室温，用剪切机进行剪切处理，剪切机转速为5000rpm，剪切时间为10～20min，剪切后过滤，即得到本发明的纺织品用无氟防水剂。
CN201810302285.2A 2018-04-04 2018-04-04 一种纺织品用无氟防水剂及其制备方法 Pending CN108468205A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810302285.2A CN108468205A (zh) 2018-04-04 2018-04-04 一种纺织品用无氟防水剂及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810302285.2A CN108468205A (zh) 2018-04-04 2018-04-04 一种纺织品用无氟防水剂及其制备方法

Publications (1)

Publication Number Publication Date
CN108468205A true CN108468205A (zh) 2018-08-31

Family

ID=63262522

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810302285.2A Pending CN108468205A (zh) 2018-04-04 2018-04-04 一种纺织品用无氟防水剂及其制备方法

Country Status (1)

Country Link
CN (1) CN108468205A (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111996800A (zh) * 2020-09-09 2020-11-27 浙江氟信新材料科技有限公司 一种持久性良好的纺织品用防水剂及制备方法
CN115594853A (zh) * 2021-07-07 2023-01-13 佳化化学（上海）有限公司（Cn） 一种非氟聚合物及其制备方法和应用

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1066091A (zh) * 1991-04-23 1992-11-11 阎锡禄 一次浸轧成型强力防水无纺布和工艺
CN1218389A (zh) * 1996-03-15 1999-06-02 普罗克特和甘保尔公司 包含具有憎水碳基接枝物的共聚物的个人护理组合物
CN101148825A (zh) * 2007-09-04 2008-03-26 山东东岳高分子材料有限公司 一种有机氟拒水拒油整理剂及其制备
CN103572602A (zh) * 2013-10-24 2014-02-12 广东德美精细化工股份有限公司 无氟防水剂及制备方法、纺织品
CN103572603A (zh) * 2013-10-24 2014-02-12 广东德美精细化工股份有限公司 纺织品无氟防水剂及其制备方法、纺织品
CN105369621A (zh) * 2015-10-30 2016-03-02 无锡市长安曙光手套厂 纺织品无氟防水剂及其制备方法、纺织品
CN106087420A (zh) * 2016-06-07 2016-11-09 苏州联胜化学有限公司 一种无氟防水剂及其制备方法
CN106884327A (zh) * 2017-03-09 2017-06-23 浙江康德新材料有限公司 织物防水处理用组合物分散液
CN107815875A (zh) * 2017-11-14 2018-03-20 湖州泰鑫无纺布有限公司 一种无纺布用的防水剂

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1066091A (zh) * 1991-04-23 1992-11-11 阎锡禄 一次浸轧成型强力防水无纺布和工艺
CN1218389A (zh) * 1996-03-15 1999-06-02 普罗克特和甘保尔公司 包含具有憎水碳基接枝物的共聚物的个人护理组合物
CN101148825A (zh) * 2007-09-04 2008-03-26 山东东岳高分子材料有限公司 一种有机氟拒水拒油整理剂及其制备
CN103572602A (zh) * 2013-10-24 2014-02-12 广东德美精细化工股份有限公司 无氟防水剂及制备方法、纺织品
CN103572603A (zh) * 2013-10-24 2014-02-12 广东德美精细化工股份有限公司 纺织品无氟防水剂及其制备方法、纺织品
CN105369621A (zh) * 2015-10-30 2016-03-02 无锡市长安曙光手套厂 纺织品无氟防水剂及其制备方法、纺织品
CN106087420A (zh) * 2016-06-07 2016-11-09 苏州联胜化学有限公司 一种无氟防水剂及其制备方法
CN106884327A (zh) * 2017-03-09 2017-06-23 浙江康德新材料有限公司 织物防水处理用组合物分散液
CN107815875A (zh) * 2017-11-14 2018-03-20 湖州泰鑫无纺布有限公司 一种无纺布用的防水剂

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
张建春 等: "《化纤仿毛技术原理与生产实践》", 30 September 2003, 中国纺织出版社 *
路艳华 等: "《壳聚糖及纳米材料在柞蚕丝功能改性中的应用》", 31 August 2012, 中国纺织出版社 *
邱建辉: "《高分子合成化学实验》", 31 August 2008, 国防工业出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111996800A (zh) * 2020-09-09 2020-11-27 浙江氟信新材料科技有限公司 一种持久性良好的纺织品用防水剂及制备方法
CN115594853A (zh) * 2021-07-07 2023-01-13 佳化化学（上海）有限公司（Cn） 一种非氟聚合物及其制备方法和应用
CN115594853B (zh) * 2021-07-07 2023-10-31 佳化化学(上海)有限公司 一种非氟聚合物及其制备方法和应用

Similar Documents

Publication Publication Date Title
CN108468205A (zh) 一种纺织品用无氟防水剂及其制备方法
CN104017920B (zh) 一种无甲醛氨基树脂复鞣剂
CN103571291B (zh) 一种防水涂料
CN110409183A (zh) 一种无氟防水整理剂及其制备和应用方法
CN104674562A (zh) 使用添加型三防整理剂制备海岛超细纤维pu革基布的方法
CN103102447A (zh) 一种织物三防整理剂的制备方法
CN102492789B (zh) 皮革油润剂及皮革油润剂制备方法
CN101284937A (zh) 一种湿法合成革用泡孔调节剂
CN105421068A (zh) 一种环保防水布料及其制备方法
CN110424160A (zh) 一种成衣免烫三防整理方法
CN101050321B (zh) 芦荟涂饰剂及其应用
CN108570854A (zh) 一种耐强洗涤的纺织品用防水剂及其制备方法
CN102965945A (zh) 一种织物耐久拒水整理剂及其制备方法
CN108486874A (zh) 一种纺织品用无氟防水涂层胶粘整理剂及其制备方法
CN108611858A (zh) 一种耐强洗涤的纺织品用防水涂层胶粘整理剂及其制备方法
CN105088800A (zh) 一种低温水性防水剂及其生产工艺
CN107083682B (zh) 一种通气透湿纺织用防水整理剂及其制备方法
CN101603102A (zh) 一种复合型防水皮革加脂剂的制备方法
CN108998592A (zh) 有色羊皮漂白工艺
CN104313206A (zh) 一种常温加脂的加脂剂
CN107189532A (zh) 一种石墨烯除醛壁纸、墙布以及制备方法
CN102330342A (zh) 一种粘棉织物用防水剂
CN101948714A (zh) 一种阳离子合成鲸蜡油加脂剂的制备方法
CN102677469B (zh) 一种超微粒子三防整理剂及制备方法
CN109837755A (zh) 一种雾面肤感处理剂及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20180831

RJ01 Rejection of invention patent application after publication