CN108513995A - A kind of sheep hurdle summer powerful disinfectant and preparation method thereof - Google Patents
A kind of sheep hurdle summer powerful disinfectant and preparation method thereof Download PDFInfo
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
- A01N25/06—Aerosols
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/24—Lauraceae [Laurel family], e.g. laurel, avocado, sassafras, cinnamon or camphor
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/30—Polygonaceae [Buckwheat family], e.g. red-knees or rhubarb
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/34—Rosaceae [Rose family], e.g. strawberry, hawthorn, plum, cherry, peach, apricot or almond
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/36—Rutaceae [Rue family], e.g. lime, orange, lemon, corktree or pricklyash
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/304—Hydrogen sulfide
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/406—Ammonia
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
Abstract
The invention discloses a kind of sheep hurdle summer powerful disinfectants and preparation method thereof, are related to disinfectant technical field, and raw material includes by weight：30 40 parts of Chinese cassia tree, 17 25 parts of Chinese prickly ash, 23 32 parts of hypericum japonicum, 25 33 parts of folium isatidis, 27 38 parts of charred FRUCTUS CRATAEGI, 22 30 parts of cymose buckwheat rhizome, 27 34 parts of Java brucea, 32 40 parts of cactus, 18 25 parts of cape jasmine, 35 45 parts of cordate houttuynia, 13 parts of plants essential oil, 17 25 parts of zeolite powder, 8 15 parts of nano diatomite, 7 12 parts of beta cyclodextrin.Each mutual compatibility of traditional Chinese medicine ingredients in the present invention, it can be good at killing the pathogenic microorganisms such as a large amount of bacterium, virus, parasitic ovum in sheep hurdle, and the killing effect time is short, effect is lasting, it is dry after the Chinese medicine extract is blended with zeolite, realize the controlled-release function to Chinese medicine disinfection composition, and action potency is lasting；Plants essential oil is subjected to embedding treatment using cyclodextrin, makes its powdered, reduces its volatility, increase operation rate, persistently give out fragrance, improve the air quality in sheep hurdle.
Description
Technical field
The present invention relates to disinfectant technical field more particularly to a kind of sheep hurdle summer powerful disinfectant and its preparation sides
Method.
Background technology
In recent years, with the development of livestock culture industry, aquaculture has also carried out the operation of scale, to realize higher warp
Ji benefit, can generally concentrate livestock rearing, increase cultivation density, and advantage, and summer are created for the propagation of infectious disease
It is the various fowl infections susceptible stage occurred frequently.Therefore, it is to prevent epidemic disease to do pouity dwelling place disinfection well, reduces the death rate, is improved
The effective measures of poultry farming benefit.
Though at present poultry house in sterilization method there are many, respectively have disadvantage, as ultraviolet irradiation generate ozone, no
But the smell is awful, and in air ozone be more than certain content when so that people and animals is labored for breath, dermatitis, conjunctivitis even
The serious toxicities such as pulmonary edema, asphyxia occur；Chemosterilant then will produce people and animals' skin, mucous membrane certain stimulation, long
Phase using the health that can endanger flock of sheep, influences its production performance.It is a kind of economical convenient to seek, and has preferable Disinfection Effect,
And it will not be affected to poultry and uncomfortable air disinfection method becomes produce reality problem urgently to be resolved hurrily.Using Chinese medicine
The sterilization method of preparation has the characteristics that using simplicity, has no toxic side effect, and is just being increasingly subject to the attention of vast cultivation worker, but
That preceding most Chinese medicine preparation effect in terms of disinfecting, antimicrobial is not satisfactory, there are stability it is poor, bactericidal effect is not lasting the shortcomings of.
Invention content
Technical problems based on background technology, the present invention propose a kind of sheep hurdle summer powerful disinfectant and its system
The disinfectant bactericidal effect of Preparation Method, preparation is strong, and action time is lasting, effectively prevents the generation of epidemic disease.
A kind of sheep hurdle summer powerful disinfectant proposed by the present invention, raw material include by weight：30-40 parts of Chinese cassia tree,
17-25 parts of Chinese prickly ash, 23-32 parts of hypericum japonicum, 25-33 parts of folium isatidis, 27-38 parts of charred FRUCTUS CRATAEGI, 22-30 parts of cymose buckwheat rhizome, Java brucea 27-
34 parts, 32-40 parts of cactus, 18-25 parts of cape jasmine, 35-45 parts of cordate houttuynia, 1-3 parts of plants essential oil, 20-30 parts of zeolite powder, β-ring
7-12 parts of dextrin.
Preferably, the essential oil be Peppermint essential oil, lemon, thyme essential oil, chamomile essential oil, needle pine essential oil,
It is one or more in Rosemary Oil.
Preferably, the plants essential oil is Peppermint essential oil, lemon, needle pine essential oil according to 2-3：4-6：The weight of 1-2
Amount is than composition.
Preferably, the zeolite powder is modified zeolite powder, and preparation process is as follows：It by zeolite ball mill grinding, is sieved, is added
Lye is stirred to react, and is filtered, and is washed, dry, and glucose solution is added, and stirring is placed in Muffle furnace in inert gas shielding
Lower calcining, it is cooling, the aqueous solution of chloride containing calcium, magnesium chloride, sodium chloride is added thereto, stirs, stands, it is dry to get.
Preferably, the preparation process of the modified zeolite is as follows：By zeolite ball mill grinding, 200 mesh sieve is crossed, 5-8% is added
Sodium hydroxide solution, solid-liquid ratio 1：3-5 is stirred to react 2-4h at 50-60 DEG C, filters, and washs, dry, adds thereto
Enter the aqueous solution of 4-7% glucose, solid-liquid ratio 1：2-3 is stirred 30-40min at 40-50 DEG C, is placed in Muffle furnace
1-2h is calcined at 800-900 DEG C under inert gas protection, it is cooling, calcium chloride containing 7-10%, 5-8% chlorinations are added thereto
The aqueous solution of magnesium, 2-4% sodium chloride, solid-liquid ratio 1：5-8 stirs 60-80min at 40-50 DEG C, stands, it is dry to get.
The invention also provides the preparation methods of above-mentioned sheep hurdle summer powerful disinfectant, include the following steps：
S1, Chinese cassia tree, Chinese prickly ash, Java brucea, cape jasmine being mixed, is crushed, 70% ethanol solution is added, refluxing extraction filters,
Obtain filtrate a and filter residue b；
S2, hypericum japonicum, folium isatidis, charred FRUCTUS CRATAEGI, cymose buckwheat rhizome, cactus, cordate houttuynia are mixed, crushes, filter residue b is added, mixes
It closes, adds water to cook extraction, filter, obtain filtrate c；
S3, filtrate a and filtrate c are mixed, recycles ethyl alcohol, be concentrated under reduced pressure, zeolite powder is added, stirred, vacuum drying, powder
It is broken, obtain powder d；
S4, plants essential oil is added in absolute ethyl alcohol, prepares essential oil ethanol solution, add it to beta-cyclodextrin saturation
In aqueous solution, stirring stands refrigeration, filters, and washs, and dries, and crushes, obtains powder e；
S5, by powder d and powder e be uniformly mixed to get.
Preferably, include the following steps：
S1, Chinese cassia tree, Chinese prickly ash, Java brucea, cape jasmine are mixed, crushes, 5-7 times of 70% ethanol solution is added, reflux carries
2-3h is taken, filters, obtains filtrate a and filter residue b；
S2, hypericum japonicum, folium isatidis, charred FRUCTUS CRATAEGI, cymose buckwheat rhizome, cactus, cordate houttuynia are mixed, crushes, filter residue b is added, mixes
It closes, 6-10 times of water is added, decoct extraction 2-3h, filtering obtains filtrate c；
S3, filtrate a and filtrate c are mixed, recycles ethyl alcohol, the concentrate at relative density 0.98-1.05 is concentrated under reduced pressure, adds
Enter zeolite powder, stir 40-60min, be dried in vacuo, crushes, obtain powder d；
S4, plants essential oil is added in absolute ethyl alcohol, volume ratio 1：1, essential oil ethanol solution is prepared, is added it to
In beta-cyclodextrin saturated aqueous solution, 1-3h is stirred at 50-60 DEG C, stands refrigerated overnight, is filtered, is washed, is dried, and is crushed, is obtained
Powder e；
S5, by powder d and powder e be uniformly mixed to get.
Preferably, in S3, speed of agitator 300-500r/min.
Preferably, in S4, speed of agitator 200-300r/min.
Advantageous effect：Plurality of Chinese compatibility is selected in the present invention, wherein the cinnaldehydrum contained in Chinese cassia tree has killing for wide spectrum
Bacterium acts on, and has significant inhibiting effect to common gram-positive bacteria, Gram-negative bacteria, there is very strong antifungal work
With, expelling parasite, sterilization, mould proof；Chinese prickly ash water decoction is to streptococcus, staphylococcus, pneumococcus, bacillus anthracis, hay bacillus, cholera
Vibrios, paratyphosum Bacterium and Pseudomonas aeruginosa have inhibiting effect, contained volatile oil that can make roundworm, pinworm poisoning；Hypericum japonicum has anti-
Bacterium antivirus action has not bacillus tuberculosis bovis, pneumococcus, staphylococcus aureus, hog cholera bacillus and shigella dysenteriae
With the antibacterial and bactericidal effect of degree；Folium isatidis has good bacteriostasis property to bacterium and mould, effectively kills golden yellow Portugal
Grape coccus also has inhibiting effect, antimycotic antiseptic for mould, aspergillus flavus；Charred FRUCTUS CRATAEGI decoction is to various shigella dysenteriaes and green pus bar
Bacterium, Escherichia coli, golden yellow coccus, bacillus anthracis etc. have apparent inhibiting effect；Cymose buckwheat rhizome is to staphylococcus aureus, lung
The bacillus such as scorching coccus and dysentery, typhoid fever, green pus have inhibiting effect；Java brucea master has heat-clearing, dry containing alkaloid, glucoside etc.
Wet, desinsection, removing toxic substances effect；Cactus is to staphylococcus aureus, Escherichia coli, bacillus subtilis, saccharomycete, Penicillium notatum
There are certain inhibiting effect, infected by influenza, Respiratory Syncytial Virus(RSV) also to have certain effect；Cape jasmine has broad-spectrum antibacterial action,
There is inhibiting effect to the pathogenic moss bacterium of Pseudomonas aeruginosa, staphylococcus aureus and various skins；Cordate houttuynia has antibacterial, antiviral work
With, or even have direct killing effect to drug-fast bacteria such as methicillin-resistant staphylococcus aureus；The mutual compatibility of medicine phases among the above, energy
It is enough to kill the pathogenic microorganisms such as a large amount of bacterium, virus, parasitic ovum in sheep hurdle well, and the killing effect time is short, effect
It is good, to prevent the generation of epidemic disease, the death rate is reduced, it is dry after which is blended with zeolite, compare table using zeolite
Area is big and pore structure, realizes the controlled-release function to Chinese medicine disinfection composition, improves its stability, and zeolite itself also have compared with
Strong suction-operated has preferable adsorption capacity to bacterium, virus, pernicious gas etc., uses it for load disinfection of Chinese drug ingredient,
Disinfection Effect can be improved, and action potency is lasting；Essential oil is subjected to embedding treatment using cyclodextrin, makes plants essential oil powder
Change, reduce its volatility, improve its utilization rate, persistently give out fragrance, improves the air quality in sheep hurdle.It can be direct when use
The disinfectant is sprayed into pouity dwelling place, it is easy to use, and the disinfectant bactericidal effect is strong, action potency is lasting, and pouity dwelling place gives up one entirely
Week sprays once sterilizing.
In prepared by modified zeolite powder, sized zeolite particles become smaller after ball milling, and specific surface area increases, then carries out alkali leaching processing, can
Remove the impurity in zeolite interior duct, aperture increases, the more microcellular structures of exposure, specific surface area increase, improvement zeolite suction
Attached performance, is entered in glucose solution, and glucose molecule enters zeolite pores and its surface, in inert gas shielding
Lower calcining, one side zeolite its specific surface area after calcining increase, and the performances such as ion exchangeable, adsorptivity significantly improve, another
Aspect, the glucose molecule being adsorbed in zeolite pore are carbonized into amorphous carbon, control the concentration and dosage of glucose solution, make
The amorphous carbon of carbonization is dispersed in zeolite cavity and surface, is in loose porous shape, and unplugged pore structure, the composite junction
Structure significantly improves the absorption property of zeolite, can be good at adsorbing a large amount of ammonia in sheep hurdle, hydrogen sulfide and other harmful poisonous
Gas improves the environment of sheep hurdle, prevents and control the generation of breathing problem in sheep cultivation, then is added and contains into the composite material
The inorganic salt solution of calcium chloride, magnesium chloride, sodium chloride enhances the humidity of modified zeolite, makes it by ion exchange
The air humidity in sheep hurdle can be improved, avoid the growth of mould；Modified zeolite is mixed with above-mentioned Chinese medicine extract so that in
Active ingredient in medicine can be good at being supported on modified zeolite, improve its stability, release rate, and effect is lasting, due to changing
The high-specific surface area of property zeolite being capable of potent absorption environment to improve the contact area of active Chinese drug component substance and harmful substance
In pathogen, moisture and pernicious gas, improve breeding environment.
Specific implementation mode
In the following, technical scheme of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of sheep hurdle summer powerful disinfectant proposed by the present invention, raw material include by weight：30 parts of Chinese cassia tree, Chinese prickly ash
17 parts, 32 parts of hypericum japonicum, 25 parts of folium isatidis, 27 parts of charred FRUCTUS CRATAEGI, 30 parts of cymose buckwheat rhizome, 34 parts of Java brucea, 32 parts of cactus, cape jasmine 25
Part, 45 parts of cordate houttuynia, 1 part of plants essential oil, 20 parts of zeolite powder, 7 parts of beta-cyclodextrin；
Wherein, essential oil is Peppermint essential oil and thyme essential oil according to 1：1 weight ratio composition.
The invention also provides the preparation methods of above-mentioned sheep hurdle summer powerful disinfectant, include the following steps：
S1, Chinese cassia tree, Chinese prickly ash, Java brucea, cape jasmine are mixed, crushes, 5 times of 70% ethanol solution, refluxing extraction is added
2h, filtering, obtains filtrate a and filter residue b；
S2, hypericum japonicum, folium isatidis, charred FRUCTUS CRATAEGI, cymose buckwheat rhizome, cactus, cordate houttuynia are mixed, crushes, filter residue b is added, mixes
It closes, 6 times of water is added, decoct extraction 2h, filtering obtains filtrate c；
S3, filtrate a and filtrate c are mixed, recycles ethyl alcohol, the concentrate at relative density 0.98 is concentrated under reduced pressure, boiling is added
Mountain flour stirs 40min, is dried in vacuo, and crushes, obtains powder d；
S4, plants essential oil is added in absolute ethyl alcohol, volume ratio 1：1, essential oil ethanol solution is prepared, is added it to
In beta-cyclodextrin saturated aqueous solution, 1h is stirred at 50 DEG C, stands refrigerated overnight, is filtered, is washed, is dried, and is crushed, is obtained powder e；
S5, by powder d and powder e be uniformly mixed to get.
Embodiment 2
A kind of sheep hurdle summer powerful disinfectant proposed by the present invention, raw material include by weight：40 parts of Chinese cassia tree, Chinese prickly ash
25 parts, 23 parts of hypericum japonicum, 33 parts of folium isatidis, 38 parts of charred FRUCTUS CRATAEGI, 22 parts of cymose buckwheat rhizome, 27 parts of Java brucea, 40 parts of cactus, cape jasmine 18
Part, 35 parts of cordate houttuynia, 3 parts of needle pine essential oil, 30 parts of zeolite powder, 12 parts of beta-cyclodextrin.
The invention also provides the preparation methods of above-mentioned sheep hurdle summer powerful disinfectant, include the following steps：
S1, Chinese cassia tree, Chinese prickly ash, Java brucea, cape jasmine are mixed, crushes, 7 times of 70% ethanol solution, refluxing extraction is added
3h, filtering, obtains filtrate a and filter residue b；
S2, hypericum japonicum, folium isatidis, charred FRUCTUS CRATAEGI, cymose buckwheat rhizome, cactus, cordate houttuynia are mixed, crushes, filter residue b is added, mixes
It closes, 10 times of water is added, decoct extraction 3h, filtering obtains filtrate c；
S3, filtrate a and filtrate c are mixed, recycles ethyl alcohol, the concentrate at relative density 1.05 is concentrated under reduced pressure, boiling is added
Mountain flour stirs 60min, is dried in vacuo, and crushes, obtains powder d；
S4, needle pine essential oil is added in absolute ethyl alcohol, volume ratio 1：1, needle pine essential oil ethanol solution is prepared, it will
It is added in beta-cyclodextrin saturated aqueous solution, and 3h is stirred at 60 DEG C, stands refrigerated overnight, filters, and washs, and dries, and crushes,
Obtain powder e；
S5, by powder d and powder e be uniformly mixed to get.
Embodiment 3
A kind of sheep hurdle summer powerful disinfectant proposed by the present invention, raw material include by weight：32 parts of Chinese cassia tree, Chinese prickly ash
20 parts, 30 parts of hypericum japonicum, 28 parts of folium isatidis, 35 parts of charred FRUCTUS CRATAEGI, 27 parts of cymose buckwheat rhizome, 30 parts of Java brucea, 37 parts of cactus, cape jasmine 19
Part, 38 parts of cordate houttuynia, 1.5 parts of plants essential oil, 23 parts of zeolite powder, 8 parts of beta-cyclodextrin；
Wherein, essential oil is Peppermint essential oil, lemon according to 1：2 weight ratio composition；
Wherein, zeolite powder is modified zeolite powder, and preparation process is as follows：By zeolite ball mill grinding, 200 mesh sieve is crossed, is added
5% sodium hydroxide solution, solid-liquid ratio 1：5, it is stirred to react 2h at 50 DEG C, filters, washs, it is dry, 4% is added thereto
The aqueous solution of glucose, solid-liquid ratio 1：2, it is stirred 30min at 40 DEG C, is placed in Muffle furnace under inert gas protection
1h is calcined at 800 DEG C, it is cooling, the aqueous solution containing 7% calcium chloride, 5% magnesium chloride, 4% sodium chloride, solid-liquid ratio are added thereto
It is 1：5,60min is stirred at 40 DEG C, is stood, it is dry to get.
The invention also provides the preparation methods of above-mentioned sheep hurdle summer powerful disinfectant, include the following steps：
S1, Chinese cassia tree, Chinese prickly ash, Java brucea, cape jasmine are mixed, crushes, 5 times of 70% ethanol solution, refluxing extraction is added
2.5h, filtering, obtains filtrate a and filter residue b；
S2, hypericum japonicum, folium isatidis, charred FRUCTUS CRATAEGI, cymose buckwheat rhizome, cactus, cordate houttuynia are mixed, crushes, filter residue b is added, mixes
It closes, 7 times of water is added, decoct extraction 2h, filtering obtains filtrate c；
S3, filtrate a and filtrate c are mixed, recycles ethyl alcohol, the concentrate at relative density 0.10 is concentrated under reduced pressure, boiling is added
Mountain flour stirs 45min, speed of agitator 300r/min, is dried in vacuo, and crushes, obtains powder d；
S4, plants essential oil is added in absolute ethyl alcohol, volume ratio 1：1, essential oil ethanol solution is prepared, is added it to
In beta-cyclodextrin saturated aqueous solution, 1.5h, speed of agitator 200r/min are stirred at 50 DEG C, stands refrigerated overnight, are filtered, are washed
It washs, dries, crush, obtain powder e；
S5, by powder d and powder e be uniformly mixed to get.
Embodiment 4
A kind of sheep hurdle summer powerful disinfectant proposed by the present invention, raw material include by weight：37 parts of Chinese cassia tree, Chinese prickly ash
24 parts, 25 parts of hypericum japonicum, 31 parts of folium isatidis, 30 parts of charred FRUCTUS CRATAEGI, 24 parts of cymose buckwheat rhizome, 28 parts of Java brucea, 33 parts of cactus, cape jasmine 24
Part, 40 parts of cordate houttuynia, 2.5 parts of plants essential oil, 25 parts of zeolite powder, 9 parts of beta-cyclodextrin；
Wherein, plants essential oil is Peppermint essential oil, lemon, needle pine essential oil according to 2：6：2 weight ratio composition；
Wherein, zeolite powder is modified zeolite powder, and preparation process is as follows：By zeolite ball mill grinding, 200 mesh sieve is crossed, is added
8% sodium hydroxide solution, solid-liquid ratio 1：3, it is stirred to react 4h at 60 DEG C, filters, washs, it is dry, 7% is added thereto
The aqueous solution of glucose, solid-liquid ratio 1：3, it is stirred 40min at 50 DEG C, is placed in Muffle furnace under inert gas protection
2h is calcined at 900 DEG C, it is cooling, the aqueous solution containing 10% calcium chloride, 8% magnesium chloride, 2% sodium chloride, feed liquid are added thereto
Than being 1：8,80min is stirred at 50 DEG C, is stood, it is dry to get.
The invention also provides the preparation methods of above-mentioned sheep hurdle summer powerful disinfectant, include the following steps：
S1, Chinese cassia tree, Chinese prickly ash, Java brucea, cape jasmine are mixed, crushes, 7 times of 70% ethanol solution, refluxing extraction is added
3h, filtering, obtains filtrate a and filter residue b；
S2, hypericum japonicum, folium isatidis, charred FRUCTUS CRATAEGI, cymose buckwheat rhizome, cactus, cordate houttuynia are mixed, crushes, filter residue b is added, mixes
It closes, 9 times of water is added, decoct extraction 3h, filtering obtains filtrate c；
S3, filtrate a and filtrate c are mixed, recycles ethyl alcohol, the concentrate at relative density 1.03 is concentrated under reduced pressure, boiling is added
Mountain flour stirs 55min, speed of agitator 500r/min, is dried in vacuo, and crushes, obtains powder d；
S4, plants essential oil is added in absolute ethyl alcohol, volume ratio 1：1, essential oil ethanol solution is prepared, is added it to
In beta-cyclodextrin saturated aqueous solution, 2.5h, speed of agitator 300r/min are stirred at 55 DEG C, stands refrigerated overnight, are filtered, are washed
It washs, dries, crush, obtain powder e；
S5, by powder d and powder e be uniformly mixed to get.
Embodiment 5
A kind of sheep hurdle summer powerful disinfectant proposed by the present invention, raw material include by weight：35 parts of Chinese cassia tree, Chinese prickly ash
22 parts, 28 parts of hypericum japonicum, 30 parts of folium isatidis, 32 parts of charred FRUCTUS CRATAEGI, 26 parts of cymose buckwheat rhizome, 32 parts of Java brucea, 35 parts of cactus, cape jasmine 23
Part, 41 parts of cordate houttuynia, 2 parts of plants essential oil, 28 parts of zeolite powder, 10 parts of beta-cyclodextrin.
Wherein, essential oil is Peppermint essential oil, lemon, thyme essential oil, chamomile essential oil, needle pine essential oil, rosemary
It is one or more in essential oil.
The plants essential oil is Peppermint essential oil, lemon, needle pine essential oil according to 3：4：1 weight ratio composition.
Wherein, zeolite powder is modified zeolite powder, and preparation process is as follows：By zeolite ball mill grinding, 200 mesh sieve is crossed, is added
7% sodium hydroxide solution, solid-liquid ratio 1：4, it is stirred to react 3h at 55 DEG C, filters, washs, it is dry, 6% is added thereto
The aqueous solution of glucose, solid-liquid ratio 1：2.5, it is stirred 35min at 45 DEG C, is placed in Muffle furnace in inert gas shielding
Under 1.5h is calcined at 850 DEG C, it is cooling, the aqueous solution containing 8% calcium chloride, 6% magnesium chloride, 3% sodium chloride, material are added thereto
Liquor ratio is 1：7,70min is stirred at 45 DEG C, is stood, it is dry to get.
The invention also provides the preparation methods of above-mentioned sheep hurdle summer powerful disinfectant, include the following steps：
S1, Chinese cassia tree, Chinese prickly ash, Java brucea, cape jasmine are mixed, crushes, 6 times of 70% ethanol solution, refluxing extraction is added
2.5h, filtering, obtains filtrate a and filter residue b；
S2, hypericum japonicum, folium isatidis, charred FRUCTUS CRATAEGI, cymose buckwheat rhizome, cactus, cordate houttuynia are mixed, crushes, filter residue b is added, mixes
It closes, 8 times of water is added, decoct extraction 2.5h, filtering obtains filtrate c；
S3, filtrate a and filtrate c are mixed, recycles ethyl alcohol, the concentrate at relative density 1.02 is concentrated under reduced pressure, boiling is added
Mountain flour stirs 50min, speed of agitator 400r/min, is dried in vacuo, and crushes, obtains powder d；
S4, plants essential oil is added in absolute ethyl alcohol, volume ratio 1：1, essential oil ethanol solution is prepared, is added it to
In beta-cyclodextrin saturated aqueous solution, 2h, speed of agitator 250r/min are stirred at 55 DEG C, stands refrigerated overnight, are filtered, are washed
It washs, dries, crush, obtain powder e；
S5, by powder d and powder e be uniformly mixed to get.
Comparative example 1
Compared with Example 5, zeolite is unmodified zeolite, remaining is identical.
Comparative example 2
Compared with Example 5, zeolite is not contained, remaining is identical.
1-5 of the embodiment of the present invention disinfectants prepared and comparative example 1-2 are tested for the property.
1, sterilizing rate measures
It randomly chooses between testing sheep hurdle 3, the long 50m of sheep hurdle, width 10m, high 4.5m, quantity, the specification of breeding sheep in 3 sheep hurdles
And type is distinguished without conspicuousness.Experiment is divided into 3 groups, that is, corresponds to 3 sheep hurdles and carry out disinfection deodorizing test, is respectively adopted of the invention real
It applies the disinfectant in example 5 and comparative example 1-2 and carries out full house spraying disinfection, disinfectant usage amount is 15g/m2, before sterilizing every time, disappear
1d, 3d, 5d, 7d are sampled respectively after poison carries out Bacteria Culture.
It is promulgated according to the Ministry of Public Health《Disinfection technology standard》(2002) it requires, is sampled using plate exposure method.Every time same
One height same position is layouted, and closes ware lid inspection in culture dish exposure air after 5min.Culture dish after sampling is set 37 DEG C and is incubated
48h is cultivated in case, observes and records cultivation results on time.Plate exposure method result calculation formula：Bacteria colony count (cfu/m3)=
5000N/AT, wherein A is platen area (cm2), T is the plate exposure time (min), and N is average colony number (cfu), according to bacterium
Count results are fallen, sterilizing rate, sterilizing rate (%)=[clump count before (clump count after clump count-disinfection before disinfection)/disinfection] are calculated
× 100%, it the results are shown in Table 1.
Persistence effect of 1 disinfectant of table to the killing bacteria in sheep hurdle
From table 1 it follows that after being sterilized to sheep hurdle after 1d, the sterilizing rate in embodiment 5 will be apparently higher than 1 He of comparative example
2, and with the extension of time, the sterilizing rate in embodiment 5 is above comparative example 1 and comparative example 2, can speculate that zeolite is modified
After significantly improve its absorption property, modified zeolite and disinfection of Chinese drug ingredient collective effect, bactericidal effect are strong.In addition, with when
Between extension, Disinfection Effect decayed, but sterilized in embodiment 5 and comparative example 1 its sterilizing rate after 7d remain at 50% with
On, illustrate that bactericidal effect is lasting, this may be attributed to the fact that the slow releasing function of zeolite.The sterilizing rate of the 1d after sterilization of comparative example 2 is higher than
Comparative example 1 is the slow releasing function due to zeolite in comparative example 1, and comparative example 2, but follow-up sterilizing rate will be slightly less than by starting sterilizing rate
Obviously higher than comparative example 2.
2, monitoring harmful gases
Pernicious gas directly uses ammonia and the two-in-one portable detector of hydrogen sulfide to be monitored, and the results are shown in Table 2 and table
3。
Persistence effect of 2 disinfectant of table to the ammonia degradation in sheep hurdle
Persistence effect of 3 disinfectant of table to the hydrogen sulfide degradation in sheep hurdle
From table 2 and table 3, disinfectant obtained has good degradation effect to the pernicious gas in sheep hurdle in the present invention,
7d is held in 50% or more to the degradation rate of ammonia and hydrogen sulfide after sterilization in embodiment 5.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (9)
1. a kind of sheep hurdle summer powerful disinfectant, which is characterized in that its raw material includes by weight：30-40 parts of Chinese cassia tree, Chinese prickly ash
17-25 parts, 23-32 parts of hypericum japonicum, 25-33 parts of folium isatidis, 27-38 parts of charred FRUCTUS CRATAEGI, 22-30 parts of cymose buckwheat rhizome, Java brucea 27-34
Part, 32-40 parts of cactus, 18-25 parts of cape jasmine, 35-45 parts of cordate houttuynia, 1-3 parts of plants essential oil, 20-30 parts of zeolite powder, β-ring paste
It is 7-12 parts smart.
2. sheep hurdle summer powerful disinfectant according to claim 1, which is characterized in that the essential oil be Peppermint essential oil,
It is one or more in lemon, thyme essential oil, chamomile essential oil, needle pine essential oil, Rosemary Oil.
3. sheep hurdle summer powerful disinfectant according to claim 1 or 2, which is characterized in that the plants essential oil is thin
Lotus essential oil, lemon, needle pine essential oil are according to 2-3：4-6：The weight ratio composition of 1-2.
4. according to any sheep hurdle summer powerful disinfectants of claim 1-3, which is characterized in that the zeolite powder is to change
Property zeolite powder, preparation process are as follows：By zeolite ball mill grinding, sieving is added lye, is stirred to react, and filters, and washs, dry,
Glucose solution is added, stirring is placed in Muffle furnace and calcines under inert gas protection, cooling, and chloride containing is added thereto
The aqueous solution of calcium, magnesium chloride, sodium chloride stirs, and stands, it is dry to get.
5. according to any sheep hurdle summer powerful disinfectants of claim 1-4, which is characterized in that the modified zeolite
Preparation process is as follows：By zeolite ball mill grinding, 200 mesh sieve is crossed, the sodium hydroxide solution of 5-8%, solid-liquid ratio 1 is added：3-5,
It is stirred to react 2-4h at 50-60 DEG C, filters, washs, it is dry, the aqueous solution of 4-7% glucose is added thereto, solid-liquid ratio is
1：2-3 is stirred 30-40min at 40-50 DEG C, is placed in Muffle furnace and is forged at 800-900 DEG C under inert gas protection
1-2h is burnt, it is cooling, the aqueous solution of calcium chloride containing 7-10%, 5-8% magnesium chlorides, 2-4% sodium chloride is added thereto, solid-liquid ratio is
1：5-8 stirs 60-80min at 40-50 DEG C, stands, it is dry to get.
6. a kind of preparation method based on any sheep hurdle summer powerful disinfectants of claim 1-5, which is characterized in that
Include the following steps：
S1, Chinese cassia tree, Chinese prickly ash, Java brucea, cape jasmine are mixed, is crushed, 70% ethanol solution, refluxing extraction is added, filtering must filter
Liquid a and filter residue b；
S2, hypericum japonicum, folium isatidis, charred FRUCTUS CRATAEGI, cymose buckwheat rhizome, cactus, cordate houttuynia are mixed, is crushed, filter residue b is added, mixing adds
Water boiling and extraction, filtering, obtains filtrate c；
S3, filtrate a and filtrate c are mixed, recycles ethyl alcohol, be concentrated under reduced pressure, zeolite powder is added, stirred, is dried in vacuo, crushed, obtain
Powder d；
S4, plants essential oil is added in absolute ethyl alcohol, prepares essential oil ethanol solution, it is water-soluble to add it to beta-cyclodextrin saturation
In liquid, stirring stands refrigeration, filters, and washs, and dries, and crushes, obtains powder e；
S5, by powder d and powder e be uniformly mixed to get.
7. the preparation method of sheep hurdle summer powerful disinfectant according to claim 6, which is characterized in that including following step
Suddenly：
S1, Chinese cassia tree, Chinese prickly ash, Java brucea, cape jasmine are mixed, crushes, 5-7 times of 70% ethanol solution, refluxing extraction 2- is added
3h, filtering, obtains filtrate a and filter residue b；
S2, hypericum japonicum, folium isatidis, charred FRUCTUS CRATAEGI, cymose buckwheat rhizome, cactus, cordate houttuynia are mixed, is crushed, filter residue b is added, mixing adds
Enter 6-10 times of water, decoct extraction 2-3h, filtering obtains filtrate c；
S3, filtrate a and filtrate c are mixed, recycles ethyl alcohol, the concentrate at relative density 0.98-1.05 is concentrated under reduced pressure, boiling is added
Mountain flour stirs 40-60min, is dried in vacuo, and crushes, obtains powder d；
S4, plants essential oil is added in absolute ethyl alcohol, volume ratio 1：1, essential oil ethanol solution is prepared, β-ring is added it to
In dextrin saturated aqueous solution, 1-3h is stirred at 50-60 DEG C, stands refrigerated overnight, is filtered, is washed, is dried, and is crushed, is obtained powder
e；
S5, by powder d and powder e be uniformly mixed to get.
8. the preparation method of sheep hurdle summer powerful disinfectant according to claim 6, which is characterized in that in S3, stirring
Rotating speed is 300-500r/min.
9. the preparation method of sheep hurdle summer powerful disinfectant according to claim 6, which is characterized in that in S4, stirring
Rotating speed is 200-300r/min.
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Application publication date: 20180911 |