CN108477228B - Antibacterial and anti-mite agent for bedding and preparation method thereof - Google Patents
Antibacterial and anti-mite agent for bedding and preparation method thereof Download PDFInfo
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- CN108477228B CN108477228B CN201810367906.5A CN201810367906A CN108477228B CN 108477228 B CN108477228 B CN 108477228B CN 201810367906 A CN201810367906 A CN 201810367906A CN 108477228 B CN108477228 B CN 108477228B
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/12—Asteraceae or Compositae [Aster or Sunflower family], e.g. daisy, pyrethrum, artichoke, lettuce, sunflower, wormwood or tarragon
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/34—Rosaceae [Rose family], e.g. strawberry, hawthorn, plum, cherry, peach, apricot or almond
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Abstract
The invention discloses an antibacterial and acarid-proof agent for bedding and a preparation method thereof. The antibacterial and acarid-proof agent for bedding comprises the following raw materials in percentage by weight: 0.5-8% of an antibacterial agent, 1-10% of an anti-mite agent, 0.3-1% of an emulsifier, 0.2-0.4% of a dispersant, 0.1-0.3% of a cross-linking agent and the balance of water; wherein the antimicrobial agent comprises an extract of Caryopteridis Incanae, an extract of Eriobotrya japonica; the mite preventing agent is one or two of folium artemisiae argyi volatile oil and stemonine. The preparation process of the antibacterial and acaricidal agent for bedding is simple and convenient, is safe and environment-friendly, does not produce toxic substances influencing the safety of human bodies and environment, can effectively inhibit and kill bacteria, prevents mites from breeding and multiplying, and reduces the harm risk of the mites and the bacteria to the health of human bodies, thereby playing a role in preventing diseases and having very important significance and wide application prospect.
Description
Technical Field
The invention relates to the technical field of antibiosis and mite prevention, and particularly relates to an antibiosis and mite prevention agent for bedding and a preparation method thereof
Background
With the improvement of living standard, people pay more and more attention to their health care, and the requirements for home environment are also continuously improved. In particular, multifunctional bedding which has the effects of preventing bacteria breeding, mite breeding and the like and is safe and environment-friendly is more and more popular. Therefore, the bedding can obtain the health and health care functions by researching and preparing the finishing agent with the antibacterial and anti-mite functions, thereby playing the role of preventing diseases and having very important significance and wide application prospect.
Bacteria and mites are all micro-organisms invisible to the naked eye, and under appropriate circumstances they can rapidly multiply with sweat, secretions and shed dander secreted by humans as nutrients. The figure is used in household articles and environments such as mattresses, bedding, plush toys, carpets, sofas, kitchens, bathrooms and the like. Secretion, metabolite and corpse of mites are allergens which can cause diseases, and allergic dermatitis and respiratory diseases are easily caused. If some germs are brought in by dust mites, respiratory tract infection or inflammation of human body is also easy to cause. According to the world health organization, 70% of asthma is caused by dust mites.
In the hot and humid quilt, bacteria and mites can breed and propagate quickly, so that the skin of a human body is infected, and the fabric stained with sweat and human secretion generates foul smell, which has great harm to the sleep quality and health of people. Therefore, bedding has antibacterial, anti-mite and deodorizing functions, and becomes one of the research hotspots of the current multifunctional antibacterial and anti-mite agent. In the current research on anti-bacteria and anti-mite, most of the main substances for anti-mite sterilization are artificially synthesized and have high toxicity, which seriously damages the health of human bodies.
Therefore, there is a need to provide an antibacterial and acaricidal agent, which can be widely used in bedding, can effectively sterilize and acarid, has no irritation to human skin, is safe and environment-friendly, and improves the living environment of people.
Disclosure of Invention
The technical problem to be solved by the invention is to provide the antibacterial and mite-proof agent for bedding and the preparation method thereof, the preparation process of the antibacterial and mite-proof agent for bedding is simple and convenient, the agent is safe and environment-friendly, toxic substances influencing the safety of human bodies and the environment are not generated, bacteria can be effectively inhibited and killed, mites are prevented from breeding and multiplying, and the harm risk of the mites and the bacteria to the health of the human bodies is reduced, so that the agent plays a role in preventing diseases, and has very important significance and wide application prospect.
In order to solve the technical problems, the technical scheme of the invention is as follows:
in a first aspect, the present invention provides an antibacterial and acarid-preventing agent for bedding, which comprises the following raw materials, by weight: 0.5-8% of an antibacterial agent, 1-10% of an anti-mite agent, 0.3-1% of an emulsifier, 0.2-0.4% of a dispersant, 0.1-0.3% of a cross-linking agent and the balance of water;
wherein the antibacterial agent is selected from one or more of herba Caryopteridis Incanae extract, folium Eriobotryae extract, and folium Myricae Rubrae extract;
the mite preventing agent is one or two of folium artemisiae argyi volatile oil and stemonine.
Preferably, the cymbopogon flexuosus extract is prepared by any one of water extraction and alcohol extraction; the extract of the batch leaf is prepared by any one of a water extraction method and an alcohol extraction method; the extract of the waxberry leaves is prepared by any one of a water extraction method and an alcohol extraction method.
Preferably, the extract of the cymbopogon flexuosus is prepared by the following method:
after smashing the common bluegrass, taking water as a solvent, performing oscillation extraction for 1-3 hours under the conditions that the ratio of the material to the water is 1: 5-20 g/mL and the temperature is 60-80 ℃, filtering to obtain filtrate, re-extracting filter residues once according to the steps, combining and concentrating the extracting solutions obtained twice to obtain the common bluegrass extract;
the extract of the loquat leaves is prepared by the following method:
pulverizing loquat leaves, taking water as a solvent, carrying out constant-temperature oscillation extraction for 1-3 hours at the temperature of 60-80 ℃ at the material-water ratio of 1: 5-20 g/mL, filtering to obtain a filtrate, re-extracting filter residues once according to the steps, and combining the extracting solutions obtained twice to concentrate an extract of the loquat leaves;
the waxberry leaf extract is prepared by adopting the following method:
crushing the waxberry leaves, taking water as a solvent, carrying out constant-temperature oscillation extraction for 1-3 hours at the temperature of 60-80 ℃ according to the material-water ratio of 1: 5-20 g/mL, filtering to obtain filtrate, re-extracting filter residues once according to the steps, and combining the extracting solutions obtained twice to concentrate the extract of the loquat leaves.
Preferably, the antibacterial agent comprises an extract of common bluebeard herb and an extract of loquat leaves, wherein the weight ratio of the extract of common bluebeard herb to the extract of loquat leaves is 0.5-3: 1.
Preferably, the anti-mite agent comprises folium artemisiae argyi volatile oil and stemonine, wherein the weight ratio of the folium artemisiae argyi volatile oil to the stemonine is 0.5-3: 1.
Preferably, the emulsifier is one or more selected from caprylic capric acid glyceride and glyceryl monostearate.
Preferably, the dispersing agent is one or more selected from sodium tripolyphosphate and sodium hexametaphosphate.
Preferably, the cross-linking agent is a waterborne polyurethane.
Preferably, the antibacterial and acarid-proof agent for bedding comprises the following raw materials in percentage by weight: 4-8% of an antibacterial agent, 5-10% of an anti-mite agent, 0.8-1% of an emulsifier, 0.35-0.4% of a dispersant, 0.25-0.3% of a cross-linking agent and the balance of water.
In a second aspect, the present invention provides a method for preparing the antibacterial and acaricidal agent for bedding in the first aspect, comprising the following steps:
according to the weight percentage, the antibacterial agent, the anti-mite agent, the emulsifier, the dispersant, the cross-linking agent and the water are stirred and mixed evenly at 1200-1800 rpm to obtain the antibacterial anti-mite agent.
Compared with the prior art, the invention has the beneficial effects that:
(1) the antibacterial and anti-mite agent for bedding is made of natural, safe and environment-friendly materials and has no skin irritation.
(2) The antibacterial and anti-mite agent for bedding has good antibacterial and anti-mite effects: the antibacterial and anti-mite agent is a compound antibacterial and anti-mite agent, can play a role in inhibiting bacteria and preventing mites, and has the inhibiting rate of over 99 percent on staphylococcus aureus and escherichia coli and the inhibiting rate of over 99 percent on mites.
(3) The bedding antibacterial and acarid-proof agent has wide application range: can be used in textiles, sofas, bedding, bathrooms, pet nests and the like, does not change color after being sprayed or soaked with articles, and does not reduce the use value or the appearance of products.
(4) The antibacterial and acarid-proof agent for bedding has high cost performance: the raw materials used are common, the cost is low, the price advantage is achieved, the production operation steps are few, and the production period is short.
(5) The antibacterial and acarid-proof agent for bedding has the advantages of certain persistence: washing resistance and difficult loss.
Detailed Description
The following further describes the embodiments of the present invention. It should be noted that the description of the embodiments is provided to help understanding of the present invention, but the present invention is not limited thereto. In addition, the technical features involved in the embodiments of the present invention described below may be combined with each other as long as they do not conflict with each other.
In a first aspect, the present invention provides an antibacterial and acarid-preventing agent for bedding, which comprises the following raw materials, by weight: 0.5-8% of an antibacterial agent, 1-10% of an anti-mite agent, 0.3-1% of an emulsifier, 0.2-0.4% of a dispersant, 0.1-0.3% of a cross-linking agent and the balance of water;
wherein the antibacterial agent is selected from one or more of herba Caryopteridis Incanae extract, folium Eriobotryae extract, and folium Myricae Rubrae extract;
the mite preventing agent is one or two of folium artemisiae argyi volatile oil and stemonine.
In one embodiment of the present invention, the extract of the cymbopogon flexuosus is prepared by any one of water extraction and alcohol extraction; the extract of the batch leaf is prepared by any one of a water extraction method and an alcohol extraction method; the extract of the waxberry leaves is prepared by any one of a water extraction method and an alcohol extraction method.
In one embodiment of the present invention, the extract of the cymbopogon flexuosus is prepared by the following method:
after smashing the common bluegrass herb, taking water as a solvent, performing oscillation extraction for 1-3 hours under the conditions that the ratio of the material to the water is 1: 5-20 (g/mL) and the temperature is 60-80 ℃, filtering to obtain filtrate, re-extracting filter residues once according to the steps, combining and concentrating the extracting solutions obtained twice to obtain the common bluegrass herb extract;
the extract of the loquat leaves is prepared by the following method:
pulverizing loquat leaves, taking water as a solvent, carrying out constant-temperature oscillation extraction for 1-3 h at the temperature of 60-80 ℃ at a material-water ratio of 1: 5-20 (g/mL), filtering to obtain a filtrate, re-extracting filter residues once according to the steps, and combining the extracting solutions obtained in the two steps to concentrate an extract of the loquat leaves;
the waxberry leaf extract is prepared by adopting the following method:
crushing the waxberry leaves, taking water as a solvent, carrying out constant-temperature oscillation extraction for 1-3 h at the temperature of 60-80 ℃ in a material-water ratio of 1: 5-20 (g/mL), filtering to obtain a filtrate, re-extracting filter residues once according to the steps, and combining the extracting solutions obtained twice to concentrate the extract of the loquat leaves.
The vanilla of the invention contains an antibacterial active ingredient of sodium vanillic aldehyde, the content of which in root, stem, leaf, flower and whole grass is 1, 5, 10.4, 5.5 and 4.7 g respectively, and the vanilla is light yellow or yellow green powder, has no odor, slightly bitter taste and is easy to dissolve in water. The vanillic acid sodium has effect in resisting Staphylococcus aureus, typhoid fever, paratyphoid A and B, pyocyania, large intestine, dysentery (Freund) bacillus and hemolytic streptococcus.
The folium artemisiae argyi is the leaf of the plant folium artemisiae argyi of the Compositae, has long medicinal history and is originally recorded in the famous medical records. The chemical components of the folium artemisiae argyi mainly comprise volatile oil, flavone, eudesmane and triterpenes, the folium artemisiae argyi has good antibacterial effect, the water decoction has good antibacterial effect, and the bacterial colony reduction rate of the wound surface of a burn patient is 74.64% after the wound surface is smoked by the moxa stick; the folium artemisiae argyi is used for fumigating and disinfecting the sickroom, so that the reduction rate of the total number of bacteria in the air can reach 73.04%.
In one embodiment of the invention, the antibacterial agent comprises an extract of Caryopteris incana and an extract of loquat leaves, wherein the weight ratio of the extract of Caryopteris incana to the extract of loquat leaves is 0.5-3: 1.
Further preferably, in this embodiment, the weight ratio of the cymbopogon extract to the loquat leaf extract is 2: 1.
In one embodiment of the invention, the mite preventing agent comprises folium artemisiae argyi volatile oil and stemonine, wherein the weight ratio of the folium artemisiae argyi volatile oil to the stemonine is 0.5-3: 1.
Further preferably, in this embodiment, the weight ratio of the folium artemisiae argyi volatile oil to the stemonine is 2: 1.
In one embodiment of the present invention, the emulsifier is one or more selected from glyceryl caprylate/caprate and glyceryl monostearate.
Further, in this embodiment, the emulsifier is caprylic capric glyceride.
In one embodiment of the present invention, the dispersant is one or more selected from sodium tripolyphosphate and sodium hexametaphosphate.
Further, in this embodiment, the dispersant is sodium tripolyphosphate.
In one embodiment of the present invention, the crosslinking agent is a waterborne polyurethane.
In one embodiment of the present invention, the antibacterial and acaricidal agent for bedding comprises the following raw materials by weight: 4-8% of an antibacterial agent, 5-10% of an anti-mite agent, 0.8-1% of an emulsifier, 0.35-0.4% of a dispersant, 0.25-0.3% of a cross-linking agent and the balance of water.
In a second aspect, the present invention provides a method for preparing the antibacterial and acaricidal agent for bedding in the first aspect, comprising the following steps:
according to the weight percentage, the antibacterial agent, the anti-mite agent, the emulsifier, the dispersant, the cross-linking agent and the water are stirred and mixed evenly at 1200-1800 rpm to obtain the antibacterial anti-mite agent.
In the following examples, the extracts of the cymbopogon flexuosus were prepared as follows:
putting the common bluegrass into a high-speed grinder, uniformly grinding the common bluegrass, taking water as a solvent, carrying out constant-temperature oscillation extraction for 2 hours at the temperature of 70 ℃ at the material-water ratio of 1:10(g/mL), filtering to obtain a filtrate, re-extracting filter residues once according to the steps, and combining and concentrating the extracting solutions obtained twice to obtain the water extract of the common bluegrass.
In the following examples, the extract of loquat leaves was prepared by the following method:
pulverizing folium Eriobotryae in a high speed pulverizer, extracting with water as solvent at constant temperature of 70 deg.C at a ratio of water to material of 1:10(g/mL) for 2 hr under shaking, filtering to obtain filtrate, re-extracting the residue according to the above steps, and mixing the extractive solutions obtained in the two steps to obtain concentrated aqueous extract of folium Eriobotryae.
In the following examples, the extract of the bayberry leaves was prepared by the following method:
crushing the waxberry leaves uniformly in a high-speed crusher, taking water as a solvent, carrying out constant-temperature oscillation extraction for 2 hours at the temperature of 70 ℃ at a material-water ratio of 1:12(g/mL), filtering to obtain a filtrate, re-extracting the filter residue once according to the steps, and combining the extracting solutions obtained twice to concentrate the extract of the loquat leaves.
Example 1
Taking the following raw materials in percentage by weight: 0.5% of cymbopogon extract, 1% of argy wormwood leaf volatile oil, 0.3% of caprylic capric glyceride, 0.2% of sodium tripolyphosphate, 0.1% of waterborne polyurethane and the balance of distilled water, and the raw materials are added into a stirrer and stirred and mixed uniformly at 1600rpm to obtain the antibacterial and acaricidal agent.
Example 2
Taking the following raw materials in percentage by weight: 0.5% of cymbidium lancifolium extract, 1% of stemonine, 0.3% of caprylic/capric glyceride, 0.2% of sodium tripolyphosphate, 0.1% of waterborne polyurethane and the balance of distilled water, and the raw materials are added into a stirrer and stirred and mixed uniformly at 1600rpm to obtain the antibacterial and acaricidal agent.
Example 3
Taking the following raw materials in percentage by weight: 0.25% of cymbidium lancifolium extract, 0.25% of burclover leaf extract, 0.5% of argy wormwood leaf volatile oil, 0.5% of stemonine, 0.3% of caprylic/capric glyceride, 0.2% of sodium tripolyphosphate, 0.1% of waterborne polyurethane and the balance of distilled water, and the raw materials are added into a stirrer and stirred and mixed uniformly at 1600rpm to obtain the antibacterial and acaricidal agent.
Example 4
Taking the following raw materials in percentage by weight: adding 0.5% of extract of the loquat leaves, 1% of volatile oil of the argy wormwood leaves, 0.3% of caprylic capric acid glyceride, 0.2% of sodium tripolyphosphate, 0.1% of waterborne polyurethane and the balance of distilled water into a stirrer, and uniformly stirring and mixing at 1600rpm to obtain the antibacterial and acaricidal agent.
Example 5
Taking the following raw materials in percentage by weight: adding 0.5% of extract of folium Trigonellae, 1% of stemonine, 0.3% of caprylic/capric glyceride, 0.2% of sodium tripolyphosphate, 0.1% of waterborne polyurethane and the balance of distilled water into a stirrer, and uniformly stirring and mixing at 1600rpm to obtain the antibacterial and acaricidal agent.
Example 6
Taking the following raw materials in percentage by weight: 0.33 percent of common bluebeard herb extract, 0.17 percent of burclover leaf extract, 0.66 percent of argy wormwood leaf volatile oil, 0.34 percent of stemonine, 0.3 percent of caprylic/capric glyceride, 0.2 percent of sodium tripolyphosphate, 0.1 percent of waterborne polyurethane and the balance of distilled water, and the raw materials are added into a stirrer and stirred and mixed uniformly at 1600rpm to obtain the antibacterial and anti-mite agent.
Example 7
Taking the following raw materials in percentage by weight: 0.17% of common bluebeard herb extract, 0.33% of burclover leaf extract, 0.37% of argy wormwood leaf volatile oil, 0.66% of stemonine, 0.3% of caprylic/capric glyceride, 0.2% of sodium tripolyphosphate, 0.1% of waterborne polyurethane and the balance of distilled water, and the raw materials are added into a stirrer and stirred and mixed uniformly at 1600rpm to obtain the antibacterial and anti-mite agent.
Example 8
Taking the following raw materials in percentage by weight: 5.33 percent of common bluebeard herb extract, 2.67 percent of burclover leaf extract, 6.6 percent of argy wormwood leaf volatile oil, 3.4 percent of stemonine, 1 percent of caprylic/capric glyceride, 0.4 percent of sodium tripolyphosphate, 0.3 percent of waterborne polyurethane and the balance of distilled water, and the raw materials are added into a stirrer and stirred and mixed uniformly at 1600rpm to obtain the antibacterial and anti-mite agent.
Example 9
Taking the following raw materials in percentage by weight: 2.66 percent of common bluebeard herb extract, 1.34 percent of loquat leaf extract, 3.3 percent of argy wormwood leaf volatile oil, 1.7 percent of stemonine, 1 percent of caprylic/capric glyceride, 0.4 percent of sodium tripolyphosphate, 0.3 percent of waterborne polyurethane and the balance of distilled water, and the raw materials are added into a stirrer and stirred and mixed uniformly at 1600rpm to obtain the antibacterial and anti-mite agent.
Example 10
Taking the following raw materials in percentage by weight: 2.66 percent of common bluebeard herb extract, 1.34 percent of loquat leaf extract, 3.3 percent of argy wormwood leaf volatile oil, 1.7 percent of stemonine, 0.3 percent of caprylic/capric glyceride, 0.2 percent of sodium tripolyphosphate, 0.1 percent of waterborne polyurethane and the balance of distilled water, and the raw materials are added into a stirrer and stirred and mixed uniformly at 1600rpm to obtain the antibacterial and acaricidal agent.
Example 11
Taking the following raw materials in percentage by weight: 3% of common bluebeard herb extract, 1% of loquat leaf extract, 3.3% of argy wormwood leaf volatile oil, 1.7% of stemonine, 1% of caprylic capric glyceride, 0.4% of sodium tripolyphosphate, 0.3% of waterborne polyurethane and the balance of distilled water, and the raw materials are added into a stirrer and stirred and mixed uniformly at 1600rpm to obtain the antibacterial and anti-mite agent.
Example 12
Taking the following raw materials in percentage by weight: 3% of common bluebeard herb extract, 1% of loquat leaf extract, 3.75% of argy wormwood leaf volatile oil, 1.25% of stemonine, 1% of caprylic capric glyceride, 0.4% of sodium tripolyphosphate, 0.3% of waterborne polyurethane and the balance of distilled water, and the raw materials are added into a stirrer and stirred and mixed uniformly at 1600rpm to obtain the antibacterial and anti-mite agent.
Example 13
Taking the following raw materials in percentage by weight: 2.66 percent of common bluebeard herb extract, 1.34 percent of loquat leaf extract, 3.3 percent of argy wormwood leaf volatile oil, 1.7 percent of stemonine, 0.8 percent of caprylic/capric glyceride, 0.35 percent of sodium tripolyphosphate, 0.25 percent of waterborne polyurethane and the balance of distilled water, and the raw materials are added into a stirrer and stirred and mixed uniformly at 1600rpm to obtain the antibacterial and acaricidal agent.
Example 14
Taking the following raw materials in percentage by weight: 0.66% of common bluebeard herb extract, 0.34% of burclover leaf extract, 1.33% of argy wormwood leaf volatile oil, 0.67% of stemonine, 0.3% of caprylic/capric glyceride, 0.2% of sodium tripolyphosphate, 0.1% of waterborne polyurethane and the balance of distilled water, and the raw materials are added into a stirrer and stirred and mixed uniformly at 1600rpm to obtain the antibacterial and anti-mite agent.
Example 15
Taking the following raw materials in percentage by weight: 6.66 percent of common bluebeard herb extract, 3.34 percent of loquat leaf extract, 9.9 percent of argy wormwood leaf volatile oil, 5.1 percent of stemonine, 1 percent of caprylic/capric glyceride, 0.4 percent of sodium tripolyphosphate, 0.3 percent of waterborne polyurethane and the balance of distilled water, and the raw materials are added into a stirrer and stirred and mixed uniformly at 1600rpm to obtain the antibacterial and anti-mite agent.
The antibacterial and acaricidal agent prepared by the embodiment of the invention is 5g/m2Spraying on bedding surface, and naturally drying. Textile articles can also be directly soaked in 10% of the antibacterial and anti-mite agent prepared by the embodiment of the invention for 15-20 minutes, and then washed and dried conventionally.
In order to further illustrate the beneficial effects of the invention, the following method is adopted to perform effect test on the product prepared by the embodiment of the invention:
(1) acute transdermal toxicity test: skin irritation/corrosion experiments were performed according to technical safety regulations for cosmetics (2015 edition) chapter vi toxicology experimental method 4.
(2) Acute eye irritation test: the test was carried out according to the second part of the technical Specification for cosmetic safety (2015 edition).
(3) Antibacterial ability test: the antibacterial and anti-mite agent treated cloth is tested by using a shaking culture method, and the used strains are staphylococcus aureus and escherichia coli, and the specific reference standard is ASTM E2149.
(4) And (3) antibacterial durability test: the antibacterial and anti-mite treated cloth after being washed for 5 times by the antibacterial and anti-mite agent is tested according to the standard ASTM E2149.
(5) Testing the anti-mite capability: and (3) detecting the effect of the antibacterial and anti-mite agent on treating the cloth to repel mites, specifically referring to the evaluation of the anti-mite performance of the textile with GB/T24253 laid-open material 2009.
(6) Testing the anti-mite endurance capacity: and testing the antibacterial and anti-mite finished cloth after the antibacterial and anti-mite agent treated cloth is washed for 5 times according to the standard GB/T24253-containing 2009.
The detection results are as follows:
TABLE 1 statistical table of test results of products manufactured in each example
And (3) analyzing a test result:
comparing and analyzing the detection results of the products of examples 1 to 7 in table 1, it can be seen that the mixture of the extracts of the cymbopogon flexuosus and the extracts of the loquat leaves as the antibacterial agent has a synergistic antibacterial effect, and the antibacterial efficiency is significantly higher than that of the single extract of the cymbopogon flexuosus or the single extract of the loquat leaves; the folium artemisiae argyi volatile oil and the stemonine are mixed to be used as the anti-mite agent, so that the anti-mite effect is synergistic, and the anti-mite rate is obviously higher than that of the single folium artemisiae argyi volatile oil or the single stemonine.
Comparing the results of the tests of the products of examples 3, 6, 7, 9, 11 and 12 in table 1, it can be seen that the antibacterial efficiency is significantly better than other ratios when the weight ratio of the vanilla extract to the loquat leaf extract is 2: 1. The weight ratio of the folium artemisiae argyi volatile oil to the stemonine which are used as the anti-mite agent components is 2:1, and the anti-mite effect is obviously better than that of other mixture ratios.
Comparing and analyzing the product detection results of examples 6, 9, 10, 13 and 14 in table 1, it is known that when the dosage of the antibacterial agent is higher than 1% and the dosage of the anti-mite agent is higher than 2%, the dosages of the emulsifier, the dispersant and the cross-linking agent should be increased correspondingly, the emulsifier caprylic-capric glyceride is preferably not lower than 0.8%, the dispersant sodium tripolyphosphate is preferably not lower than 0.35%, and the cross-linking agent waterborne polyurethane is preferably not lower than 0.25, which is mainly because when the dosages of the emulsifier, the dispersant and the cross-linking agent are too low, the adsorption between the antibacterial agent and the anti-mite agent and the bedding surface is insufficient, thereby affecting the antibacterial and anti-mite effects of the product. The use amount of the emulsifier, the dispersant and the cross-linking agent is too high, so that adverse effects are brought, and the emulsifier, the dispersant and the cross-linking agent are mainly interacted, so that the antibacterial agent and the anti-mite agent are easily wrapped, and the antibacterial agent and the anti-mite agent cannot fully play a role; therefore, in the present invention, the amount of the emulsifier is preferably 0.8 to 1%, the amount of the dispersant is preferably 0.35 to 0.4%, and the amount of the crosslinking agent is preferably 0.25 to 0.3%.
Comparing and analyzing the detection results of the products of examples 6, 8, 9, 14 and 15 in table 1, it can be seen that when the dosage of the antibacterial agent is 0.5-8% and the dosage of the anti-mite agent is 1-10%, the antibacterial and anti-mite effects of the product are enhanced along with the increase of the dosages of the antibacterial agent and the anti-mite agent; when the using amount of the antibacterial agent is more than 8 percent and the using amount of the anti-mite agent is more than 10 percent, the antibacterial and anti-mite effects of the product are almost unchanged, and from the aspects of economic cost and antibacterial and anti-mite effects, the using amount of the antibacterial agent is preferably 4-8 percent and the using amount of the anti-mite agent is preferably 5-10 percent.
In order to further illustrate the beneficial effects of the invention, the invention also adopts the red bayberry leaf extract to replace the loquat leaf extract in the embodiments 1-14 of the invention to prepare the antibacterial and anti-mite agent, and finally the measured antibacterial and anti-mite performance of the product is obviously inferior to that of the products obtained in the embodiments 1-15 of the invention.
The embodiments of the present invention have been described in detail, but the present invention is not limited to the described embodiments. It will be apparent to those skilled in the art that various changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, and the scope of protection is still within the scope of the invention.
Claims (8)
1. An antibacterial and acarid-proof agent for bedding, which is characterized in that: the composite material comprises the following raw materials in percentage by weight: 0.5-8% of an antibacterial agent, 1-10% of an anti-mite agent, 0.3-1% of an emulsifier, 0.2-0.4% of a dispersant, 0.1-0.3% of a cross-linking agent and the balance of water;
the antibacterial agent comprises an extract of common bluebeard herb and an extract of loquat leaves, wherein the weight ratio of the extract of common bluebeard herb to the extract of loquat leaves is 0.5-3: 1; the anti-mite agent comprises folium artemisiae argyi volatile oil and stemonine, wherein the weight ratio of the folium artemisiae argyi volatile oil to the stemonine is 0.5-3: 1.
2. The antibacterial and acaricidal agent for bedding according to claim 1, wherein: the cymbopogon extract is prepared by any one of water extraction and alcohol extraction; the extract of the loquat leaf is prepared by any one of a water extraction method and an alcohol extraction method.
3. The antibacterial and acaricidal agent for bedding according to claim 1, wherein: the extract of the common bluebeard herb is prepared by the following method:
after smashing the common bluegrass, taking water as a solvent, performing oscillation extraction for 1-3 hours under the conditions that the ratio of the material to the water is 1: 5-20 g/mL and the temperature is 60-80 ℃, filtering to obtain filtrate, re-extracting filter residues once according to the steps, combining and concentrating the extracting solutions obtained twice to obtain the common bluegrass extract;
the extract of the loquat leaves is prepared by the following method:
pulverizing loquat leaves, taking water as a solvent, carrying out constant-temperature oscillation extraction for 1-3 hours at the temperature of 60-80 ℃ at the material-water ratio of 1: 5-20 g/mL, filtering to obtain filtrate, re-extracting filter residues once according to the steps, and combining the extracting solutions obtained in the two steps to concentrate the extract of the loquat leaves.
4. The antibacterial and acaricidal agent for bedding according to claim 1, wherein: the emulsifier is one or more of caprylic capric acid glyceride and glyceryl monostearate.
5. The antibacterial and acaricidal agent for bedding according to claim 1, wherein: the dispersing agent is selected from one or more of sodium tripolyphosphate and sodium hexametaphosphate.
6. The antibacterial and acaricidal agent for bedding according to claim 1, wherein: the cross-linking agent is waterborne polyurethane.
7. The antibacterial and acaricidal agent for bedding according to claim 1, wherein: the antibacterial and acarid-proof agent for bedding comprises the following raw materials in percentage by weight: 4-8% of an antibacterial agent, 5-10% of an anti-mite agent, 0.8-1% of an emulsifier, 0.35-0.4% of a dispersant, 0.25-0.3% of a cross-linking agent and the balance of water.
8. A method for preparing the antibacterial and acaricidal agent for bedding according to any one of claims 1 to 7, which comprises: the method comprises the following steps:
according to the weight percentage, the antibacterial agent, the anti-mite agent, the emulsifier, the dispersant, the cross-linking agent and the water are stirred and mixed evenly at 1200-1800 rpm to obtain the antibacterial anti-mite agent.
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