CN114775275B - Quilting-imitating jacquard fabric and manufacturing method thereof - Google Patents
Quilting-imitating jacquard fabric and manufacturing method thereof Download PDFInfo
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- CN114775275B CN114775275B CN202210383268.2A CN202210383268A CN114775275B CN 114775275 B CN114775275 B CN 114775275B CN 202210383268 A CN202210383268 A CN 202210383268A CN 114775275 B CN114775275 B CN 114775275B
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- antibacterial
- fabric
- quilting
- mite
- agent
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- 239000004744 fabric Substances 0.000 title claims abstract description 132
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 130
- 239000010410 layer Substances 0.000 claims abstract description 60
- 239000007788 liquid Substances 0.000 claims abstract description 52
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 42
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 239000002344 surface layer Substances 0.000 claims abstract description 15
- 239000002270 dispersing agent Substances 0.000 claims abstract description 11
- 239000000853 adhesive Substances 0.000 claims abstract description 10
- 230000001070 adhesive effect Effects 0.000 claims abstract description 9
- 125000006850 spacer group Chemical group 0.000 claims abstract description 8
- 238000009998 heat setting Methods 0.000 claims abstract description 4
- 238000009941 weaving Methods 0.000 claims abstract description 4
- 238000002360 preparation method Methods 0.000 claims description 130
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 claims description 50
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 31
- 239000005844 Thymol Substances 0.000 claims description 25
- 229960000790 thymol Drugs 0.000 claims description 25
- 239000012744 reinforcing agent Substances 0.000 claims description 21
- 230000000694 effects Effects 0.000 claims description 16
- 239000011347 resin Substances 0.000 claims description 16
- 229920005989 resin Polymers 0.000 claims description 16
- OPGYRRGJRBEUFK-UHFFFAOYSA-L disodium;diacetate Chemical compound [Na+].[Na+].CC([O-])=O.CC([O-])=O OPGYRRGJRBEUFK-UHFFFAOYSA-L 0.000 claims description 15
- 239000001632 sodium acetate Substances 0.000 claims description 15
- 235000017454 sodium diacetate Nutrition 0.000 claims description 15
- 229920001577 copolymer Polymers 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 12
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 claims description 10
- 229920000858 Cyclodextrin Polymers 0.000 claims description 10
- 239000001116 FEMA 4028 Substances 0.000 claims description 10
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims description 10
- 235000011175 beta-cyclodextrine Nutrition 0.000 claims description 10
- 229960004853 betadex Drugs 0.000 claims description 10
- 239000012948 isocyanate Substances 0.000 claims description 10
- 150000002513 isocyanates Chemical class 0.000 claims description 10
- 229940117986 sulfobetaine Drugs 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 8
- -1 N-dodecyl-amino Chemical group 0.000 claims description 7
- PZNOBXVHZYGUEX-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine;hydrochloride Chemical compound Cl.C=CCNCC=C PZNOBXVHZYGUEX-UHFFFAOYSA-N 0.000 claims description 7
- 125000003639 thymyl group Chemical class C1(=CC(C)=CC=C1C(C)C)* 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000010634 clove oil Substances 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 229910021485 fumed silica Inorganic materials 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 230000006835 compression Effects 0.000 claims description 3
- 238000007906 compression Methods 0.000 claims description 3
- 239000011162 core material Substances 0.000 claims description 3
- 230000000149 penetrating effect Effects 0.000 claims description 3
- 238000001694 spray drying Methods 0.000 claims description 3
- 238000002791 soaking Methods 0.000 claims description 2
- 239000003623 enhancer Substances 0.000 abstract description 2
- 230000035699 permeability Effects 0.000 abstract description 2
- 238000009954 braiding Methods 0.000 abstract 1
- 238000009940 knitting Methods 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 23
- 230000000052 comparative effect Effects 0.000 description 20
- 239000000243 solution Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- 230000000845 anti-microbial effect Effects 0.000 description 7
- 238000001179 sorption measurement Methods 0.000 description 7
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 4
- 230000009471 action Effects 0.000 description 4
- 238000001514 detection method Methods 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 239000012466 permeate Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 235000019270 ammonium chloride Nutrition 0.000 description 3
- 230000001580 bacterial effect Effects 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- 241000238876 Acari Species 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 240000006891 Artemisia vulgaris Species 0.000 description 2
- 235000003261 Artemisia vulgaris Nutrition 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical group [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 239000004599 antimicrobial Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 2
- 235000019345 sodium thiosulphate Nutrition 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- PJZDODDUSMVLPX-YRNVUSSQSA-N COC(C=C(/C=C/C(NC1(CCCC1)C(O)=O)=O)C=C1)=C1OCC1=CC=C(C(F)(F)F)C=C1 Chemical compound COC(C=C(/C=C/C(NC1(CCCC1)C(O)=O)=O)C=C1)=C1OCC1=CC=C(C(F)(F)F)C=C1 PJZDODDUSMVLPX-YRNVUSSQSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- LEVWYRKDKASIDU-QWWZWVQMSA-N D-cystine Chemical compound OC(=O)[C@H](N)CSSC[C@@H](N)C(O)=O LEVWYRKDKASIDU-QWWZWVQMSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 1
- 229910008051 Si-OH Inorganic materials 0.000 description 1
- 229910006358 Si—OH Inorganic materials 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 229960003067 cystine Drugs 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000675 fabric finishing Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 238000009962 finishing (textile) Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000003834 intracellular effect Effects 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229940068918 polyethylene glycol 400 Drugs 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000012966 redox initiator Substances 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D21/00—Lappet- or swivel-woven fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
- D06M15/248—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing chlorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
- D06M15/3562—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The quilting-imitating jacquard fabric is sequentially distributed into an upper layer, a spacer layer and a lower layer from top to bottom, each surface layer is woven by yarns, the antibacterial and anti-mite yarns are finished by the yarns through antibacterial finishing liquid, and the antibacterial finishing liquid is mainly prepared from the following raw materials: an antibacterial agent, an anti-mite agent, water, an enhancer, a dispersant, and an adhesive; the manufacturing method comprises the following steps: immersing the yarn in the antibacterial finishing liquid to obtain antibacterial and anti-mite yarn; weaving the upper layer; braiding the lower layer; knitting products on the front needle bed and the back needle bed respectively, and arranging a spacing layer; weaving quilting areas, and carrying out jacquard operation on quilting-free areas of an upper layer and a lower layer of the fabric to obtain quilted fabrics; and (5) performing heat setting on the quilted fabric to obtain the quilted fabric. The quilting-imitating jacquard fabric has the advantages that the arrangement of the multiple layers of the quilting-imitating jacquard fabric is convenient for improving the three-dimensional property and the air permeability of the fabric, jacquard operation is carried out, the patterns of the fabric are more abundant and attractive, the cost is lower, and meanwhile, the antibacterial and anti-mite performances of the fabric are better.
Description
Technical Field
The application relates to the technical field of quilting-imitating fabric preparation, in particular to quilting-imitating jacquard fabric and a manufacturing method thereof.
Background
Along with the improvement of living standard, the requirements of people on the comfort and the aesthetic property of the bedding fabric are higher and higher, and the jacquard fabric is a cotton fabric or chemical fiber blended fabric with a weave pattern, so that the requirements of people on the bedding fabric are generally met.
The bed cover is the most with human contact in the day, and the bed cover surface fabric is closely contacted with the human body, not only to skin, still has very big influence to breathing, therefore, the travelling comfort and the functional of bedding surface fabric, and is great to human health influence, and current bed cover adopts imitative quilting jacquard fabric more to make the bed cover not only satisfy pleasing to the eye demand but also satisfy comfortable demand. The traditional jacquard fabric has poor three-dimensional effect, and the quilted jacquard fabric can realize batch production of quilted products, but has low production efficiency.
The bed cover fabric can leave sweat and the like on the surface due to contact with people, and meanwhile, the bed cover fabric is made of cotton-flax fibers, and the main components of the bed cover fabric are cellulose, protein and the like, and the components can provide nutrition sources for growth of bacteria and mites.
At present, in order to facilitate the bed cover fabric to have an antibacterial effect, the cloth for preparing the bed cover fabric is generally soaked in an antibacterial finishing agent, so that the antibacterial finishing agent is adhered to the cloth, and the bed cover fabric has a certain antibacterial effect.
In view of the above related art, the inventors believe that the fabric is soaked in the antibacterial finishing agent, which can play a better role in antibacterial at the initial stage, but the antibacterial performance of the bedding fabric gradually decreases with the increase of the washing times, so that the requirement on the antibacterial performance of the bedding fabric cannot be met, and meanwhile, the prepared bedding fabric has poor stereoscopic impression.
Disclosure of Invention
In order to improve the antibacterial performance of the bed cover fabric, the quilting-imitating jacquard fabric and the manufacturing method thereof are provided, the yarns are reasonably selected to be combined, meanwhile, antibacterial finishing is carried out on the yarns, the multi-layer fabric is manufactured by adopting a jacquard loom, so that the three-dimensional effect of the quilting-imitating jacquard fabric is improved, the quilting-imitating jacquard fabric has good plumpness, the surface of the quilting-imitating jacquard fabric has uniform quilting stitch effect of a quilting-imitating product, and meanwhile, the antibacterial performance of the quilting-imitating jacquard fabric is improved.
In a first aspect, the present application provides a quilting-simulated jacquard fabric, which adopts the following technical scheme:
the quilting-imitating jacquard fabric comprises a plurality of surface layers, wherein the surface layers are sequentially distributed into an upper layer, a spacing layer and a lower layer from top to bottom, the surface layers are formed by weaving warps and wefts, the warps and the wefts are formed by combining antibacterial anti-mite yarns and elastic yarns, the antibacterial anti-mite yarns are finished by yarns through antibacterial finishing liquid, and the antibacterial finishing liquid is mainly prepared from the following raw materials in parts by weight: 30-50 parts of antibacterial agent, 5-10 parts of anti-mite agent, 20-30 parts of water, 2-5 parts of reinforcing agent, 1-2 parts of dispersing agent and 5-8 parts of adhesive; the antibacterial agent is at least two of sodium diacetate, thymol and isocyanate sulfobetaine, and the reinforcing agent consists of acrylic acid-hydroxypropyl acrylate copolymer, toluene-2, 4-diisocyanate and polydimethyl diallyl ammonium chloride according to the mass ratio of (1-2) to (3-4).
Preferably, the anti-mite agent is mugwort leaf volatile oil.
Preferably, the dispersant is sodium tripolyphosphate.
Preferably, the binder is polyvinyl acetate.
By adopting the technical scheme, the arrangement of the upper layer, the spacing layer and the lower layer is convenient for enabling the quilting-imitating jacquard fabric to have better plumpness and improving the stereoscopic impression of the quilting-imitating jacquard fabric; the yarns are put into an antibacterial finishing liquid for finishing, so that the antibacterial performance of the quilting-imitating jacquard fabric is improved; sodium diacetate in the antibacterial agent conveniently penetrates through the cell wall of the microorganism, enters the microorganism cell, interferes with biosynthesis of intracellular enzymes, can effectively inhibit division, propagation and spread of bacteria, and simultaneously, is convenient for reacting with hydroxyl groups on fibers, so that the adsorption strength of the sodium diacetate on yarns is improved; thymol in the antibacterial agent is convenient for interacting with proteins in cell membranes to cause backflow of transmembrane protons, so that cell activity powered by proton drive is affected, and the thymol can be combined with substances necessary for bacterial growth, so that the antibacterial property of the fabric is improved; the isocyanate sulfobetaine is convenient for inhibiting the adsorption of bacteria on the surface of the fabric, preventing the formation of a biological film, and Si-OH formed by hydrolysis is convenient for reacting with-OH on the fiber, so that a stable antibacterial coating is formed, meanwhile, -NCO is chemically bonded with-OH, so that the retention time of the antibacterial agent on the fiber is improved; the acrylic acid-hydroxypropyl acrylate copolymer is easy to diffuse into the fiber, cross-linking and bridging reaction is carried out between the acrylic acid-hydroxypropyl acrylate copolymer and hydroxyl groups in the fiber, and meanwhile, the components of the antibacterial agent are convenient to dissolve in gaps among molecular chains of the acrylic acid-hydroxypropyl acrylate copolymer, so that an antibacterial film layer is formed; toluene-2, 4-diisocyanate is convenient to permeate to the surface of the fabric and combine with fiber molecules to form a washable film layer, so that the adsorption strength of an antibacterial agent in the fiber is improved, and meanwhile, the wool effect and wettability of the fabric are improved, so that the diffusion rate of water in the fabric is improved, the breeding of bacteria is reduced, and the antibacterial performance of the bed cover fabric is further improved; the polydimethyl diallyl ammonium chloride contains the quaternary ammonium salt component, so that the antibacterial property is convenient to further improve, and meanwhile, the polydimethyl diallyl ammonium chloride is convenient to react with the fibers, so that bridging effect is convenient to be equivalent between the fibers and the antibacterial agent, the washability of the antibacterial agent in the fabric is improved, and the antibacterial agent is convenient to improve the antibacterial property of the bed cover fabric; the anti-mite agent is convenient to improve the resistance strength of the bedding fabric to mites, and the antibacterial agent and the anti-mite agent are convenient to further improve the antibacterial property and the anti-mite property of the fabric under the action of the reinforcing agent.
Preferably, the mass ratio of the antibacterial agent to the anti-mite agent to the reinforcing agent is (35-45): 6-8): 3-4.
By adopting the technical scheme, the mass ratio of the antibacterial agent, the anti-mite agent and the reinforcing agent is optimized, so that the mixture ratio of the three raw materials is optimal, the antibacterial agent and the anti-mite agent interact to jointly improve the antibacterial performance of the bedding cover fabric, the reinforcing agent is used for improving the washability of the antibacterial agent and the anti-mite agent in the bedding cover fabric on one hand, and the polydimethyl diallyl ammonium chloride in the reinforcing agent also has the antibacterial effect and is convenient to jointly cooperate with the antibacterial agent and the anti-mite agent to improve the antibacterial performance of the bedding cover fabric on the other hand.
Preferably, the antibacterial agent consists of sodium diacetate, thymol and isocyanate sulfobetaine according to the mass ratio of (2-3) (4-5).
By adopting the technical scheme, the antibacterial agent is obtained by compounding a plurality of components, the proportion of the components of the antibacterial agent is adjusted, so that the proportion of the components is optimal, sodium diacetate is convenient to react with hydroxyl groups on the fibers, thymol is convenient to combine with substances required by bacterial growth, si-OH formed by hydrolysis of isocyanate sulfobetaine is convenient to react with-OH on the fibers, so that a stable antibacterial coating is formed, meanwhile, -NCO is chemically bonded with-OH, the adsorption strength of sodium diacetate and thymol on the fibers is improved, the washability of the antibacterial agent in yarns is further improved, and the antibacterial performance of the bed cover fabric is further improved.
Preferably, the thymol is modified thymol, and the preparation method of the modified thymol comprises the following steps: mixing beta-cyclodextrin, water and ethanol solution, heating to dissolve, cooling to 50-55deg.C, adding thymol, clathrating under stirring, maintaining the system temperature at 50-55deg.C, stirring for 50-60min, naturally cooling to room temperature, and spray drying thymol clathrate solution.
By adopting the technical scheme, the beta-cyclodextrin is coated outside the thymol, the beta-cyclodextrin has antibacterial property, the beta-cyclodextrin has better compatibility with the beta-cyclodextrin, the beta-cyclodextrin is convenient for the beta-cyclodextrin to play an antibacterial role firstly, then the thymol is slowly released, the antibacterial property of the bedding cover fabric is improved, the modified thymol is uniformly distributed in the reticular structure of the acrylic acid-hydroxypropyl acrylate copolymer and the toluene-2, 4-diisocyanate, and the antibacterial property of the bedding cover fabric is further improved.
Preferably, the anti-mite agent is N-dodecyl-amino betaine-2-mercaptoethylamine hydrochloride.
By adopting the technical scheme, the N-dodecyl-amino betaine-2-mercaptoethylamine hydrochloride can react with cystine to generate asymmetric disulfide bonds, has good adsorption capacity with yarns, and is convenient to be preferentially adsorbed on the surfaces of the yarns, thereby improving the antibacterial performance and the stability of the bed cover fabric.
Preferably, the toluene-2, 4-diisocyanate is modified toluene-2, 4-diisocyanate, and the modified toluene-2, 4-diisocyanate uses toluene-2, 4-diisocyanate as a wall material and clove oil as a core material.
By adopting the technical scheme, the toluene-2, 4-diisocyanate is convenient to permeate into fiber molecules, the sodium diacetate and the thymol are convenient to permeate into long-chain molecules of the toluene-2, 4-diisocyanate, and then the toluene-2, 4-diisocyanate is adsorbed on the fiber molecules under the action of the toluene-2, 4-diisocyanate, and meanwhile, the toluene-2, 4-diisocyanate is internally coated with clove oil, so that the clove oil has the sterilization effect, and further antibacterial components are conveniently introduced into the fibers, and further the antibacterial performance of the fabric is conveniently improved.
Preferably, the antibacterial finishing liquid also comprises 2-5 parts by weight of filler, wherein the filler consists of PVC paste resin, PVC blending resin and fumed silica according to the mass ratio of (1-3) (2-4).
Preferably, the particle size of the PVC paste resin is 0.1-0.5 μm.
Preferably, the particle size of the PVC blending resin is 10-20 μm.
By adopting the technical scheme, the filler is mixed by adopting the PVC paste resin and the PVC blending resin, so that a good filling effect is obtained, the PVC paste resin is filled in gaps among PVC blending resin particles, the fluidity of the PVC paste resin particles and the PVC blending resin particles is improved, the fumed silica has a higher specific surface area, and the fumed silica is matched with the PVC paste resin and the PVC blending resin to form a three-dimensional cross-linked network in the fiber, so that the tensile strength of the yarn is improved, the distribution stability of the antibacterial agent in the bed cover fabric is improved, and the antibacterial performance of the bed cover fabric is improved.
In a second aspect, the present application provides a method for manufacturing quilting-simulated jacquard fabric, which adopts the following technical scheme: a method for manufacturing quilting-imitating jacquard fabric comprises the following steps,
(1) Preparation of antibacterial and anti-mite yarns: soaking the yarn in the antibacterial finishing liquid, and drying to obtain the antibacterial anti-mite yarn;
(2) Preparing warps and wefts: combining the elastic yarn and the antibacterial and anti-mite yarn obtained in the step (1) to obtain warps and wefts;
(3) Preparing an upper layer: the warp and the weft are fully penetrated by the ground comb joints, and the upper surface layer is woven on the front needle bed;
(4) Preparation of the following layers: the warp and the weft are fully penetrated by the ground comb joints, and the ground comb joints are woven into a lower layer on the back needle bed;
(5) Preparing a spacer layer: the warp and the weft are penetrated by using a ground comb joint, products are respectively woven on a front needle bed and a back needle bed, and a spacing layer with a monofilament structure and a strain characteristic value of more than 4kpa is arranged at a forty percent compression stress position;
(6) Three-dimensional quilted fabric: the jacquard comb is used for fully penetrating warp yarns and weft yarns, quilting effect areas with three-dimensional sense are respectively woven on the front needle bed and the back needle bed, and jacquard operation is carried out on the quilting effect areas without the upper layer and the lower layer of the fabric according to the designed patterns, so that the three-dimensional quilted fabric is obtained;
(7) Preparation of quilting-simulated jacquard fabric: and (3) performing heat setting on the three-dimensional quilted fabric prepared in the step (6) to obtain the quilting-imitating jacquard fabric.
By adopting the technical scheme, after the yarns are subjected to the antibacterial finishing liquid dipping treatment, the antibacterial agent and the anti-mite agent are adsorbed on the yarns under the action of the reinforcing agent, so that the washability of the antibacterial agent on the fibers is improved, the antibacterial property of the yarns is further improved, and the antibacterial property of quilting-imitating jacquard fabric made of the yarns is better; the arrangement of the upper layer, the spacer layer and the lower layer in the quilting-imitating jacquard fabric is convenient for improving the stereoscopic impression of the quilting-imitating jacquard fabric, so that the quilting-imitating jacquard fabric has better plumpness, and the jacquard operation is convenient for enriching the expression form of the quilting-imitating jacquard fabric, thereby ensuring that the quilting-imitating jacquard fabric has better antibacterial performance and better stereoscopic impression.
In summary, the present application has the following beneficial effects:
1. the quilting-imitating jacquard fabric is prepared by performing antibacterial finishing on yarns for preparing the fabric, so that the yarns have antibacterial and mite-preventing performances, meanwhile, antibacterial finishing liquid performs antibacterial finishing on the yarns, so that antibacterial washability of the fabric is improved, antibacterial performance of the fabric is improved, the quilting-imitating jacquard fabric is composed of an upper layer, a spacer layer and a plurality of surface layers of a lower layer, the surface layers are made of the yarns processed by the antibacterial finishing liquid, and the quilting-imitating jacquard fabric is convenient to improve and has better stereoscopic impression and antibacterial performance.
2. According to the quilting-imitating jacquard fabric, yarns are finished through the antibacterial finishing liquid, and in the antibacterial finishing liquid, the antibacterial performance of the yarns is improved through interaction of the antibacterial agent and the anti-mite agent, and meanwhile, under the action of the reinforcing agent, the adsorption strength of the antibacterial agent and the anti-mite agent on the yarns is increased, so that after multiple times of washing, the fabric still has the better antibacterial performance.
3. The quilting-imitating jacquard fabric is convenient to improve the three-dimensional property of the quilting-imitating jacquard fabric through the arrangement of the upper layer, the spacing layer and the lower layer, and simultaneously improves the aesthetic property and the air permeability of the quilting-imitating jacquard fabric.
Detailed Description
The present application is described in further detail below with reference to examples.
The quilting-imitating jacquard fabric is characterized in that the upper layer, the spacer layer and the lower layer are designed, the three-dimensional sense of the jacquard fabric is improved by the design of the multi-layer, meanwhile, the quilting-imitating jacquard fabric is combined with quilting-imitating technology, so that the quilting-imitating jacquard fabric has good plumpness, the quilting-imitating jacquard fabric surface has uniform quilting stitch effect of a quilting product imitating the stitch, the patterns and the attractiveness of the quilting-imitating jacquard fabric are enriched, the cost is low, and meanwhile, yarns woven into the quilting-imitating jacquard fabric are finished by the antibacterial finishing liquid, so that the quilting-imitating jacquard fabric has attractive and rich patterns and antibacterial properties.
The preparation method of the isocyanate sulfobetaine comprises the following steps: 44.46g of isophorone diisocyanate, 11.91g of N-methyldiethanolamine and 56.37g of N, N-dimethylformamide are mixed and stirred uniformly, and reacted for 2 hours under the protection of nitrogen at 90 ℃ to prepare tertiary amine intermediate solution containing isocyanate groups; after 12.21g of 1, 3-sulfobutyrolactone is dissolved in 12.21g of N, N, N-dimethylformamide, the mixture is added into the prepared tertiary amine intermediate solution containing isocyanate groups, and the reaction is continued for 10 hours under the protection of nitrogen at the temperature of 100 ℃; after the reaction was completed, the product was precipitated with 137.16g of acetone, filtered and washed, and finally dried in a vacuum oven at 25 ℃ for 48 hours to obtain the product.
The preparation method of the polydimethyldiallyl ammonium chloride comprises the following steps: 20mL of 65% dimethyldiallylammonium chloride monomer solution was injected into a 250mL three-necked flask, and subsequently ethylenediamine tetraacetic acid was added in an amount of 0.1% by mass of the monomer. After stirring for 10min, the amine persulfate and sodium thiosulfate redox initiators were added rapidly, with the amounts of amine persulfate and sodium thiosulfate both being 0.2% of the mass of the monomer. Negative pressure is pumped at room temperature, and then N is slowly introduced 2 Repeating for 3 times, reacting at 60deg.C for 5 hr to obtain white solid product, placing the product into dialysis bag, dialyzing with distilled water for 3d, rotary evaporating, and drying at 40deg.C for 3 d. Wherein, the manufacturer of the dimethyldiallylammonium chloride monomer solution is Wohan Jiang Run fine chemical company.
The preparation method of the modified toluene-2, 4-diisocyanate comprises the following steps: adding 0.075g sodium alginate and 1.0g polyvinyl alcohol into 200 mL distilled water, heating, stirring to dissolve the sodium alginate and the polyvinyl alcohol near boiling, pouring the mixture into a 500mL three-port bottle, stirring, cooling to 30 ℃, adding 3.08g polyethylene glycol-400, and emulsifying and stirring in a water bath at 30 ℃ at a rotating speed of 1500r/min for 10min; then evenly mixing 4.05g of toluene-2, 4-diisocyanate and 4.0g of clove oil, then dropwise adding the mixture into a three-mouth bottle, stirring the mixture while dropwise adding 0.15g of dibutyltin dilaurate after dropwise adding, stirring the mixture in a constant-temperature water bath at 30 ℃ for reaction for 1h, heating the mixture to 70 ℃, adding 50ml of 30% volume fraction ethylene glycol aqueous solution, stirring the mixture in a constant-temperature water bath at 70 ℃ for reaction for 1h, and cooling the mixture to room temperature to obtain the modified toluene-2, 4-diisocyanate which is spherical and has the particle size of 1 mu m.
Preparation example of antibacterial anti-mite finishing agent
Preparation example 1
The antibacterial finishing liquid of the preparation example is prepared from the following raw materials in parts by weight: 30kg of antibacterial agent, 5kg of anti-mite agent, 20kg of water, 2kg of reinforcing agent, 1kg of dispersing agent and 5kg of adhesive, wherein the antibacterial agent consists of sodium diacetate and thymol according to the mass ratio of 1:1, the anti-mite agent is mugwort leaf volatile oil, the reinforcing agent consists of acrylic acid-hydroxypropyl acrylate copolymer, toluene-2, 4-diisocyanate and polydimethyl diallyl ammonium chloride according to the mass ratio of 1:1:3, the dispersing agent is sodium tripolyphosphate, and the adhesive is polyvinyl acetate.
The preparation method of the antibacterial finishing liquid comprises the following steps: the antibacterial finishing liquid is prepared by mixing an antibacterial agent, an anti-mite agent, water, an enhancer, a dispersing agent and an adhesive.
PREPARATION EXAMPLES 2 to 5
Preparation examples 2-5 are antibacterial finishing solutions with different raw material component ratios, the raw material ratio of each antibacterial finishing solution corresponding to each preparation example is shown in table 1, and the raw material ratio unit is kg.
TABLE 1 preparation examples 1-5 ratio of raw material components of antibacterial finishing liquid
| Raw materials | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 |
| Antibacterial agent | 30 | 35 | 50 | 40 | 45 |
| Mite-proof agent | 5 | 6 | 10 | 7 | 8 |
| Water and its preparation method | 20 | 25 | 30 | 25 | 25 |
| Reinforcing agent | 2 | 3 | 5 | 3 | 4 |
| Dispersing agent | 1 | 1 | 2 | 2 | 2 |
| Adhesive agent | 5 | 7 | 8 | 7 | 7 |
The preparation examples 2 to 5 differ from the preparation example 1 in that: the antibacterial finishing liquid has different raw material proportions, and the other materials are completely the same as those in preparation example 1.
Preparation examples 2 to 5 the preparation method of the antibacterial finishing liquid is exactly the same as that of preparation example 1.
Preparation example 6
The present preparation example differs from preparation example 4 in that: the reinforcing agent consists of acrylic acid-hydroxypropyl acrylate copolymer, toluene-2, 4-diisocyanate and polydimethyl diallyl ammonium chloride according to the mass ratio of 2:2:4, and the anti-mite agent is N-dodecyl-amino betaine-2-mercaptoethylamine hydrochloride, and the other components are completely the same as in preparation example 4.
The preparation method of the antibacterial finishing liquid of the preparation example is exactly the same as that of the preparation example 4.
Preparation example 7
The present preparation example differs from preparation example 4 in that: the antibacterial agent consists of sodium diacetate, thymol and isocyanate sulfobetaine according to the mass ratio of 1:1:1, and the other components are exactly the same as in preparation example 1.
The preparation method of the antibacterial finishing liquid of the preparation example is exactly the same as that of the preparation example 4.
Preparation example 8
The present preparation example differs from preparation example 4 in that: the antibacterial agent consists of sodium diacetate, thymol and isocyanate sulfobetaine according to the mass ratio of 2:2:4, and the other components are exactly the same as in preparation example 4.
The preparation method of the antibacterial finishing liquid of the preparation example is exactly the same as that of the preparation example 4.
Preparation example 9
The present preparation example differs from preparation example 4 in that: the antibacterial agent consists of sodium diacetate, thymol and isocyanate sulfobetaine according to the mass ratio of 3:3:5, and the other components are exactly the same as in preparation example 4.
The preparation method of the antibacterial finishing liquid of the preparation example is exactly the same as that of the preparation example 4.
Preparation example 10
This preparation differs from preparation 9 in that: the thymol is modified thymol, and the preparation method of the modified thymol comprises the following steps: mixing 11g of beta-cyclodextrin, 80g of water and 2g of ethanol solution with the concentration of 95%, heating to 70 ℃ for dissolution, cooling to 55 ℃, adding 1g of thymol, stirring at 5000r/min by using a shearing machine for inclusion, keeping the system temperature between 50 ℃, shearing for 60 minutes, performing quality inspection on the inclusion compound to be qualified, naturally cooling to room temperature, and spray-drying the thymol inclusion compound solution to obtain the beta-cyclodextrin. The other steps are exactly the same as in preparation example 9.
The preparation method of the antibacterial finishing liquid of the preparation example is exactly the same as that of the preparation example 9.
PREPARATION EXAMPLE 11
The present preparation example differs from preparation example 10 in that: the toluene-2, 4-diisocyanate is modified toluene-2, 4-diisocyanate, the modified toluene-2, 4-diisocyanate takes toluene-2, 4-diisocyanate as a wall material and clove oil as a core material. The other steps are exactly the same as in preparation example 10.
The preparation method of the antibacterial finishing liquid of the preparation example is exactly the same as that of the preparation example 10.
Preparation example 12
The antibacterial finishing liquid of the preparation example is prepared from the following raw materials in parts by weight: 40kg of antibacterial agent, 7kg of anti-mite agent, 25kg of water, 3kg of reinforcing agent, 2kg of dispersing agent, 7kg of adhesive and 3kg of filler, wherein the filler consists of PVC paste resin, PVC blending resin and fumed silica according to the mass ratio of 3:3:4, and the other components are completely the same as in preparation example 11.
The preparation method of the antibacterial finishing liquid of the preparation example is exactly the same as that of the preparation example 11.
Preparation example 13
The antibacterial finishing liquid of this preparation example is different from that of preparation example 1 in that: the antibacterial agent is nano silver, the average grain diameter of the nano silver is 20nm, the other components are exactly the same as the preparation example 1,
the preparation method of the antibacterial finishing liquid of the preparation example is exactly the same as that of the preparation example 1.
PREPARATION EXAMPLE 14
The antibacterial finishing liquid of this preparation example is different from that of preparation example 1 in that: the antimicrobial agent was sodium diacetate, and the other components were identical to those of preparation example 1.
The preparation method of the antibacterial finishing liquid of the preparation example is exactly the same as that of the preparation example 1.
Preparation example 15
The antibacterial finishing liquid of the preparation example is prepared from the following raw materials in parts by weight: 30kg of an antibacterial agent, 5kg of an anti-mite agent, 20kg of water, 1kg of a dispersing agent, and 5kg of an adhesive, and the same procedure as in preparation example 1 was repeated.
The preparation method of the antibacterial finishing liquid of the preparation example is exactly the same as that of the preparation example 1.
PREPARATION EXAMPLE 16
The antibacterial finishing liquid of this preparation example is different from that of preparation example 1 in that: the reinforcing agent was an acrylic acid-hydroxypropyl acrylate copolymer, and the other was identical to that of preparation example 1.
The preparation method of the antibacterial finishing liquid of the preparation example is exactly the same as that of the preparation example 1.
Preparation example 17
The antibacterial finishing liquid of this preparation example is different from that of preparation example 1 in that: the reinforcing agent consists of acrylic acid-hydroxypropyl acrylate copolymer and toluene-2, 4-diisocyanate according to the mass ratio of 1:1, and the other components are exactly the same as in preparation example 1.
The preparation method of the antibacterial finishing liquid of the preparation example is exactly the same as that of the preparation example 1.
PREPARATION EXAMPLE 18
The antibacterial finishing liquid of this preparation example is different from that of preparation example 1 in that: 15kg of an antibacterial agent, 3kg of an anti-mite agent, 20kg of water, 8kg of a reinforcing agent, 1kg of a dispersing agent, and 5kg of an adhesive, and the same procedure as in preparation example 1 was repeated.
The preparation method of the antibacterial finishing liquid of the preparation example is exactly the same as that of the preparation example 1.
Examples
Example 1
The quilting-imitating jacquard fabric comprises a plurality of surface layers, and is characterized in that the surface layers are sequentially distributed into an upper layer, a spacing layer and a lower layer from top to bottom, the surface layers are woven by warps and wefts, the warps and the wefts are formed by combining antibacterial and anti-mite yarns and elastic yarns, and the antibacterial and anti-mite yarns are finished by the antibacterial finishing liquid prepared by the yarns through the preparation example 1.
The quilting-simulated jacquard fabric manufacturing method of the embodiment comprises the following steps:
(1) Preparation of antibacterial and anti-mite yarns: immersing the yarn in the antibacterial finishing liquid prepared in preparation example 1, and drying to obtain the antibacterial and anti-mite yarn;
(2) Preparing warps and wefts: combining the elastic yarn and the antibacterial and anti-mite yarn obtained in the step (1) to obtain warps and wefts;
(3) Preparing an upper layer: the warp and the weft are fully penetrated by the ground comb joints, and the upper surface layer is woven on the front needle bed;
(4) Preparation of the following layers: the warp and the weft are fully penetrated by the ground comb joints, and the ground comb joints are woven into a lower layer on the back needle bed;
(5) Preparing a spacer layer: the warp and the weft are penetrated by using a ground comb joint, products are respectively woven on a front needle bed and a back needle bed, and a spacing layer with a monofilament structure and a strain characteristic value of more than 4kpa is arranged at a forty percent compression stress position;
(6) Three-dimensional quilted fabric: the jacquard comb is used for fully penetrating warp yarns and weft yarns, quilting effect areas with three-dimensional sense are respectively woven on the front needle bed and the back needle bed, and jacquard operation is carried out on the quilting effect areas without the upper layer and the lower layer of the fabric according to the designed patterns, so that the three-dimensional quilted fabric is obtained;
(7) Preparation of quilting-simulated jacquard fabric: and (5) performing heat setting on the three-dimensional quilted fabric prepared in the step (6) to obtain the quilted fabric.
Examples 2 to 12
Examples 2-12 are quilted-simulated jacquard fabrics that were antimicrobial treated with different antimicrobial finishes, each of which is shown in table 2.
Table 2 examples 1-12 quilting-simulated jacquard fabric finishing antibacterial finishing liquor
Examples 2-12 differ from example 1 in that: the antibacterial and anti-mite yarn is finished by the yarn through the corresponding antibacterial finishing liquid, and the other steps are exactly the same as those of the embodiment 1.
The quilting-simulated jacquard fabric of examples 2-12 was produced in a manner different from that of example 1 in that: the preparation of the antibacterial and anti-mite yarn comprises the following steps: immersing the yarn in the antibacterial finishing liquid corresponding to the embodiment 2-12, and drying to obtain the antibacterial and anti-mite yarn; the other is exactly the same as in example 1.
Comparative example
Comparative examples 1 to 6
Comparative examples 1-6 are quilted-simulated jacquard fabrics treated with different antimicrobial finishes, each representative of which is shown in table 3.
Table 3 comparative examples 1-6 quilting-pattern-fabric-simulating antimicrobial finish
| Sequence number | Antibacterial finishing liquid |
| Comparative example 1 | Preparation example 13 |
| Comparative example 2 | PREPARATION EXAMPLE 14 |
| Comparative example 3 | Preparation example 15 |
| Comparative example 4 | PREPARATION EXAMPLE 16 |
| Comparative example 5 | Preparation example 17 |
| Comparative example 6 | PREPARATION EXAMPLE 18 |
Comparative examples 1 to 6 differ from example 1 in that: the antibacterial finishing liquid used was different and the other was exactly the same as in example 1.
The process for preparing quilting-simulated jacquard fabrics of comparative examples 1-6 is different from example 1 in that: the preparation of the antibacterial and anti-mite yarn comprises the following steps: immersing the yarn in the antibacterial finishing liquid corresponding to the comparative examples 1-6, and drying to obtain the antibacterial and anti-mite yarn; the other is exactly the same as in example 1.
Performance test
The antibacterial detection method comprises the following steps: quilting-imitating jacquard fabrics prepared in examples 1 to 12 and comparative examples 1 to 6 were taken, and were subjected to water washing for 0 and 50 times respectively according to the detection method in GB/T20944-2007 evaluation of antibacterial Properties of textiles, with E.coli and Staphylococcus aureus as detection criteria, and the detection results are shown in Table 4.
And (3) detecting mite-preventing performance: quilting-imitating jacquard fabrics prepared in examples 1 to 12 and comparative examples 1 to 6 were subjected to mite repellency test according to the test method in GB/T24253-2009 evaluation of anti-mite Properties of textiles, and the test results are shown in Table 4.
Table 4 results of the quilting-simulated jacquard fabrics of examples 1-12 and comparative examples 1-6
In combination with examples 1 and comparative examples 1-2 and with Table 4, it can be seen that, relative to comparative examples 1-2, the antimicrobial agent of example 1 is obtained by compounding various components, sodium diacetate is convenient to react with hydroxyl groups on the fibers, thymol is convenient to combine with substances required by bacterial growth, si-OH formed by isocyanate sulfobetaine is convenient to react with-OH on the fibers, simultaneously, -NCO is chemically bonded with-OH, the adsorption strength of sodium diacetate and thymol on the fibers is improved, the three components are mutually matched, and thus the antimicrobial performance of the quilting-imitating jacquard fabric is improved, and the distribution of the upper layer, the spacer layer and the lower layer is convenient to improve the three-dimensional performance of the quilting-imitating jacquard fabric.
In combination with example 1 and comparative examples 3 to 5, and in combination with Table 4, it can be seen that the reinforcing agent is compounded from three components of acrylic acid-hydroxypropyl acrylate copolymer, toluene-2, 4-diisocyanate and polydimethyldiallyl ammonium chloride, and the antibacterial agent is convenient to dissolve in gaps of molecular chains of acrylic acid-hydroxypropyl acrylate copolymer and toluene-2, 4-diisocyanate, and the acrylic acid-hydroxypropyl acrylate copolymer and the toluene-2, 4-diisocyanate are convenient to permeate into fibers, and the polydimethyldiallyl ammonium chloride and the acrylic acid-hydroxypropyl acrylate copolymer and the toluene-2, 4-diisocyanate are mutually matched, so that the antibacterial performance of the quilted-simulated jacquard fabric and the antibacterial performance after washing for a plurality of times are improved.
As can be seen from the combination of examples 1 to 6 and comparative example 6 and the combination of Table 4, the antibacterial properties of the quilted jacquard fabric obtained by adjusting the proportions of the various raw materials of the antibacterial finishing liquid and the raw materials of different proportions and the antibacterial properties after washing were greatly different.
By combining the embodiment 4 and the embodiments 7-11 and combining the table 4, it can be seen that the proportion of the components of the antibacterial agent is adjusted, so that the components are mutually matched, the effect of the antibacterial agent in the antibacterial finishing liquid is further improved, and the antibacterial performance of the quilting-imitating jacquard fabric is further improved.
As can be seen from the combination of examples 11-12 and Table 4, the addition of the filler facilitates the improvement of the tensile strength of the yarn, thereby improving the stability of the antimicrobial in the quilted-simulated jacquard fabric and, at the same time, further improving the antimicrobial properties of the quilted-simulated jacquard fabric.
The present embodiment is merely illustrative of the present application and is not intended to be limiting, and those skilled in the art, after having read the present specification, may make modifications to the present embodiment without creative contribution as required, but is protected by patent laws within the scope of the claims of the present application.
Claims (3)
1. The quilting-imitating jacquard fabric comprises a plurality of surface layers, and is characterized in that the surface layers are sequentially distributed into an upper layer, a spacing layer and a lower layer from top to bottom, wherein the surface layers are formed by weaving warps and wefts, the warps and the wefts are formed by combining antibacterial and anti-mite yarns and elastic yarns, the antibacterial and anti-mite yarns are finished by yarns through antibacterial finishing liquid, and the antibacterial finishing liquid is mainly prepared from the following raw materials in parts by weight: 30-50 parts of antibacterial agent, 5-10 parts of anti-mite agent, 20-30 parts of water, 2-5 parts of reinforcing agent, 1-2 parts of dispersing agent, 5-8 parts of adhesive and 2-5 parts of filler; the antibacterial agent is at least two of sodium diacetate, thymol and isocyanate sulfobetaine; the reinforcing agent consists of acrylic acid-hydroxypropyl acrylate copolymer, toluene-2, 4-diisocyanate and polydimethyl diallyl ammonium chloride according to the mass ratio of (1-2) to (3-4); the anti-mite agent is N-dodecyl-amino betaine-2-mercaptoethylamine hydrochloride; the filler consists of PVC paste resin, PVC blending resin and fumed silica according to the mass ratio of (1-3) (2-4);
the thymol is modified thymol, and the preparation method of the modified thymol comprises the following steps: mixing beta-cyclodextrin, water and ethanol solution, heating to dissolve, cooling to 50-55deg.C, adding thymol, clathrating under stirring, maintaining the system temperature at 50-55deg.C, stirring for 50-60min, naturally cooling to room temperature, and spray drying thymol clathrate solution;
the toluene-2, 4-diisocyanate is modified toluene-2, 4-diisocyanate, the modified toluene-2, 4-diisocyanate takes toluene-2, 4-diisocyanate as a wall material and clove oil as a core material.
2. The quilted pattern fabric of claim 1 wherein: the mass ratio of the antibacterial agent to the anti-mite agent to the reinforcing agent is (35-45)/(6-8)/(3-4).
3. A method of making a quilted-simulated jacquard fabric of any one of claims 1-2, characterized by: comprises the following steps of the method,
(1) Preparation of antibacterial and anti-mite yarns: soaking the yarn in the antibacterial finishing liquid, and drying to obtain the antibacterial anti-mite yarn;
(2) Preparing warps and wefts: combining the elastic yarn and the antibacterial and anti-mite yarn obtained in the step (1) to obtain warps and wefts;
(3) Preparing an upper layer: the warp and the weft are fully penetrated by the ground comb joints, and the upper surface layer is woven on the front needle bed;
(4) Preparation of the following layers: the warp and the weft are fully penetrated by the ground comb joints, and the ground comb joints are woven into a lower layer on the back needle bed;
(5) Preparing a spacer layer: the warp and the weft are penetrated by using a ground comb joint, products are respectively woven on a front needle bed and a back needle bed, and a spacing layer with a monofilament structure and a strain characteristic value of more than 4kpa is arranged at a forty percent compression stress position;
(6) Three-dimensional quilted fabric: the jacquard comb is used for fully penetrating warp yarns and weft yarns, quilting effect areas with three-dimensional sense are respectively woven on the front needle bed and the back needle bed, and jacquard operation is carried out on the quilting effect areas without the upper layer and the lower layer of the fabric according to the designed patterns, so that the three-dimensional quilted fabric is obtained;
(7) Preparation of quilting-simulated jacquard fabric: and (3) performing heat setting on the three-dimensional quilted fabric prepared in the step (6) to obtain the quilting-imitating jacquard fabric.
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