CN114775275A - Quilting-imitating jacquard fabric and manufacturing method thereof - Google Patents
Quilting-imitating jacquard fabric and manufacturing method thereof Download PDFInfo
- Publication number
- CN114775275A CN114775275A CN202210383268.2A CN202210383268A CN114775275A CN 114775275 A CN114775275 A CN 114775275A CN 202210383268 A CN202210383268 A CN 202210383268A CN 114775275 A CN114775275 A CN 114775275A
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- CN
- China
- Prior art keywords
- fabric
- antibacterial
- agent
- quilting
- mite
- Prior art date
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- 239000004744 fabric Substances 0.000 title claims abstract description 135
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 121
- 239000007788 liquid Substances 0.000 claims abstract description 52
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 46
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 29
- 239000010410 layer Substances 0.000 claims abstract description 29
- 239000002344 surface layer Substances 0.000 claims abstract description 26
- 239000012744 reinforcing agent Substances 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 230000003115 biocidal effect Effects 0.000 claims abstract description 13
- 238000009941 weaving Methods 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 239000002270 dispersing agent Substances 0.000 claims abstract description 11
- 239000000853 adhesive Substances 0.000 claims abstract description 8
- 230000001070 adhesive effect Effects 0.000 claims abstract description 7
- 238000009998 heat setting Methods 0.000 claims abstract description 4
- 238000002360 preparation method Methods 0.000 claims description 122
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 claims description 52
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 30
- 239000005844 Thymol Substances 0.000 claims description 26
- 229960000790 thymol Drugs 0.000 claims description 26
- OPGYRRGJRBEUFK-UHFFFAOYSA-L disodium;diacetate Chemical compound [Na+].[Na+].CC([O-])=O.CC([O-])=O OPGYRRGJRBEUFK-UHFFFAOYSA-L 0.000 claims description 16
- 239000011347 resin Substances 0.000 claims description 16
- 229920005989 resin Polymers 0.000 claims description 16
- 239000001632 sodium acetate Substances 0.000 claims description 16
- 235000017454 sodium diacetate Nutrition 0.000 claims description 16
- 230000000694 effects Effects 0.000 claims description 15
- 229920001577 copolymer Polymers 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 12
- 239000012948 isocyanate Substances 0.000 claims description 11
- 150000002513 isocyanates Chemical class 0.000 claims description 11
- 238000001816 cooling Methods 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 8
- 229920000858 Cyclodextrin Polymers 0.000 claims description 7
- 239000001116 FEMA 4028 Substances 0.000 claims description 7
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims description 7
- 235000011175 beta-cyclodextrine Nutrition 0.000 claims description 7
- 229960004853 betadex Drugs 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims description 6
- 229960003237 betaine Drugs 0.000 claims description 6
- 125000003639 thymyl group Chemical class C1(=CC(C)=CC=C1C(C)C)* 0.000 claims description 6
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 claims description 5
- 239000010634 clove oil Substances 0.000 claims description 5
- 229940117986 sulfobetaine Drugs 0.000 claims description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 229910021485 fumed silica Inorganic materials 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- -1 N-dodecyl-amino Chemical group 0.000 claims description 3
- 230000006835 compression Effects 0.000 claims description 3
- 238000007906 compression Methods 0.000 claims description 3
- 239000011162 core material Substances 0.000 claims description 3
- 238000009940 knitting Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 238000001694 spray drying Methods 0.000 claims description 3
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- 238000002791 soaking Methods 0.000 claims description 2
- 125000006850 spacer group Chemical group 0.000 abstract description 7
- 238000007598 dipping method Methods 0.000 abstract description 5
- 230000035699 permeability Effects 0.000 abstract description 2
- 239000000835 fiber Substances 0.000 description 22
- 230000000052 comparative effect Effects 0.000 description 20
- 239000000243 solution Substances 0.000 description 14
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 230000000845 anti-microbial effect Effects 0.000 description 6
- 238000001514 detection method Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000001179 sorption measurement Methods 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 4
- 230000009471 action Effects 0.000 description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
- 238000013329 compounding Methods 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 239000012466 permeate Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 229910008051 Si-OH Inorganic materials 0.000 description 3
- 229910006358 Si—OH Inorganic materials 0.000 description 3
- 230000001580 bacterial effect Effects 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 210000004027 cell Anatomy 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- 241000238876 Acari Species 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical group [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- 239000004599 antimicrobial Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 2
- 235000019345 sodium thiosulphate Nutrition 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- LEVWYRKDKASIDU-QWWZWVQMSA-N D-cystine Chemical compound OC(=O)[C@H](N)CSSC[C@@H](N)C(O)=O LEVWYRKDKASIDU-QWWZWVQMSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- GSCLMSFRWBPUSK-UHFFFAOYSA-N beta-Butyrolactone Chemical compound CC1CC(=O)O1 GSCLMSFRWBPUSK-UHFFFAOYSA-N 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 229960003067 cystine Drugs 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229940068918 polyethylene glycol 400 Drugs 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000012966 redox initiator Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000002390 rotary evaporation Methods 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D21/00—Lappet- or swivel-woven fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
- D06M15/248—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing chlorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
- D06M15/3562—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The application discloses imitative quilting jacquard fabric from top to bottom distributes in proper order and is upper strata, wall and lower surface course, and every surface course is woven by the yarn and is formed, and antibiotic anti-mite yarn is put in order through antibiotic finishing liquor by the yarn, and antibiotic finishing liquor mainly is made by following raw materials: antibacterial agent, acarid-proof agent, water, reinforcing agent, dispersing agent and adhesive; the manufacturing method comprises the following steps: dipping the yarn in the antibacterial finishing liquid to obtain the antibacterial anti-mite yarn; weaving the upper surface layer; weaving the lower surface layer; respectively weaving products on the front needle bed and the back needle bed, and arranging a spacer layer; weaving quilting seam regions, and carrying out jacquard weaving operation on non-quilting seam regions of an upper surface layer and a lower surface layer of the fabric to obtain the quilted fabric; and (4) performing heat setting on the quilted fabric to obtain the quilted fabric. The quilting-imitating jacquard fabric multi-surface layer is convenient to improve the three-dimensional property and the air permeability of the fabric, and the jacquard operation enables the pattern of the fabric to be richer and more attractive, the cost to be lower, and meanwhile the fabric has better antibacterial and anti-mite performance.
Description
Technical Field
The application relates to the technical field of quilting-imitated fabric preparation, in particular to a quilting-imitated jacquard fabric and a manufacturing method thereof.
Background
Along with the improvement of living standard, the requirements of people on the comfort and the aesthetic property of the bed cover fabric are higher and higher, and the jacquard fabric is a cotton fabric or chemical fiber blended fabric with woven patterns, and generally meets the requirements of people on the bed cover fabric.
The bed cover is most contacted with a human body in one day, the fabric of the bed cover is in close contact with the human body, and not only has great influence on skin but also on respiration, so that the comfort and the functionality of the fabric of the bedding are greatly influenced on the health of the human body, and the conventional bed cover mostly adopts quilting-imitating jacquard fabrics, so that the bed cover not only meets the aesthetic requirement, but also meets the comfortable requirement. Traditional jacquard fabric stereoscopic effect is not good, quilting formula jacquard fabric can realize the batch production of quilting product, but production efficiency is low.
Some sweat and the like can be remained on the surface of the bed cover fabric due to contact with people, meanwhile, the bed cover fabric is made of cotton and hemp fibers, the main components of the bed cover fabric are cellulose, protein and the like, and the components can provide nutrient sources for the growth of bacteria and mites.
At present, in order to enable a bed cover fabric to have an antibacterial effect, the fabric for preparing the bed cover fabric is usually soaked in an antibacterial finishing agent, so that the antibacterial finishing agent is adhered to the fabric, and the bed cover fabric has a certain antibacterial effect.
In view of the above-mentioned related technologies, the inventor believes that the fabric soaked in the antibacterial finishing agent can play a better antibacterial role in the initial stage, but as the number of washing times increases, the antibacterial performance of the mattress cover fabric gradually decreases, and the requirement for the antibacterial performance of the mattress cover fabric cannot be met, and meanwhile, the prepared mattress cover fabric has poor stereoscopic impression.
Disclosure of Invention
In order to improve the antibacterial performance of the bed cover fabric, the application provides an imitation quilting jacquard fabric and a manufacturing method thereof, yarn combination is reasonably selected, meanwhile, antibacterial finishing is carried out on the yarns, a skillful tying structure design is adopted, and a jacquard loom is adopted to manufacture a multilayer fabric, so that the stereoscopic impression of the imitation quilting jacquard fabric is improved, the imitation quilting jacquard fabric has better plumpness, the surface of the imitation quilting jacquard fabric has an even quilting line stitch effect of a stitch imitation quilted product, and meanwhile, the antibacterial performance of the imitation quilting jacquard fabric is improved.
In a first aspect, the present application provides a quilting-imitated jacquard fabric, which adopts the following technical scheme:
the utility model provides an imitative quilting jacquard fabric, includes a plurality of surface courses, and is a plurality of the surface course from top to bottom distributes in proper order and is upper surface course, wall and lower surface course, the surface course is woven by warp and weft and forms, warp and weft are formed by antibiotic anti-mite yarn, the combination of elasticity yarn, antibiotic anti-mite yarn is put in order through antibiotic finishing liquor by the yarn, antibiotic finishing liquor is mainly made by following parts by weight's raw materials: 30-50 parts of an antibacterial agent, 5-10 parts of a mite-proof agent, 20-30 parts of water, 2-5 parts of a reinforcing agent, 1-2 parts of a dispersing agent and 5-8 parts of an adhesive; the antibacterial agent is at least two of sodium diacetate, thymol and isocyanate sulfobetaine, and the reinforcing agent is composed of acrylic acid-hydroxypropyl acrylate copolymer, toluene-2, 4-diisocyanate and poly dimethyl diallyl ammonium chloride according to the mass ratio of (1-2) to (3-4).
Preferably, the mite-resistant agent is folium artemisiae argyi volatile oil.
Preferably, the dispersant is sodium tripolyphosphate.
Preferably, the binder is polyvinyl acetate.
By adopting the technical scheme, the upper surface layer, the spacer layer and the lower surface layer are arranged, so that the quilting-imitating jacquard fabric has better plumpness, and the stereoscopic impression of the quilting-imitating jacquard fabric is improved; putting the yarns into an antibacterial finishing liquid for finishing, so that the antibacterial performance of the quilting-like jacquard fabric is improved; the sodium diacetate in the antibacterial agent is convenient to penetrate through the cell wall of the microorganism and enter the microorganism cell to interfere the biosynthesis of enzymes in the cell, so that the division, the propagation and the spread of bacteria can be efficiently inhibited, and simultaneously, the sodium diacetate is convenient to react with hydroxyl on fibers, thereby improving the adsorption strength of the sodium diacetate on yarns; thymol in the antibacterial agent is convenient to interact with protein in a cell membrane to cause reverse flow of transmembrane protons, so that the cell activity powered by proton drive is influenced, and the thymol can be combined with substances necessary for bacterial growth, so that the antibacterial property of the fabric is improved; the isocyanate sulfobetaine is convenient for inhibiting bacteria from being adsorbed on the surface of the fabric and preventing the formation of a biological film, Si-OH formed by hydrolysis is convenient for reacting with-OH on the fiber so as to form a stable antibacterial coating, and meanwhile, -NCO is chemically bonded with-OH so as to improve the retention time of the antibacterial agent on the fiber; the acrylic acid-hydroxypropyl acrylate copolymer is easy to diffuse into the fiber and generates a cross-linking bridging reaction with hydroxyl in the fiber, and meanwhile, the components of the antibacterial agent are convenient to dissolve in the gaps among the molecular chains of the acrylic acid-hydroxypropyl acrylate copolymer to form an antibacterial film layer; the toluene-2, 4-diisocyanate is convenient to permeate the surface of the fabric and is combined with fiber molecules to form a washable film layer, so that the adsorption strength of the antibacterial agent in the fiber is improved, and meanwhile, the wool effect and the wettability of the fabric are improved, so that the diffusion rate of water in the fabric is improved, the breeding of bacteria is reduced, and the antibacterial performance of the mattress cover fabric is further improved; the poly dimethyl diallyl ammonium chloride contains the components of quaternary ammonium salt, so that the antibacterial property is further improved, and meanwhile, the poly dimethyl diallyl ammonium chloride is convenient to react with the fibers, so that the bridging effect between the fibers and the antibacterial agent is facilitated, the water washing resistance of the antibacterial agent in the fabric is improved, and the antibacterial property of the mattress cover fabric is facilitated to be improved due to the addition of the antibacterial agent; the anti-mite agent is added to improve the resistance strength of the mattress cover fabric to mites, and the antibacterial agent and the anti-mite agent are used for further improving the antibacterial property and the anti-mite property of the fabric under the action of the reinforcing agent.
Preferably, the mass ratio of the antibacterial agent to the acaricidal agent to the reinforcing agent is (35-45) to (6-8) to (3-4).
By adopting the technical scheme, the mass ratio of the antibacterial agent, the anti-mite agent and the reinforcing agent is optimized, so that the ratio of the antibacterial agent to the anti-mite agent is optimal, the antibacterial agent and the anti-mite agent interact with each other and are used for improving the antibacterial performance of the mattress cover fabric together, the reinforcing agent is used for improving the washability of the antibacterial agent and the anti-mite agent in the mattress cover fabric, and the poly dimethyl diallyl ammonium chloride in the reinforcing agent also has the antibacterial effect and is convenient to cooperate with the antibacterial agent and the anti-mite agent together to improve the antibacterial performance of the mattress cover fabric.
Preferably, the antibacterial agent consists of sodium diacetate, thymol and isocyanate sulfonic acid betaine according to the mass ratio of (2-3) to (4-5).
By adopting the technical scheme, the antibacterial agent is obtained by compounding multiple components, and the proportion of the multiple components of the antibacterial agent is adjusted, so that the proportion of the multiple components is optimal, sodium diacetate is convenient to react with hydroxyl on fibers, thymol is convenient to combine with substances required by bacterial growth, Si-OH formed by hydrolysis of isocyanate sulfobetaine is convenient to react with-OH on the fibers, and a stable antibacterial coating is formed.
Preferably, the thymol is modified thymol, and the preparation method of the modified thymol comprises the following steps: mixing beta-cyclodextrin, water and ethanol solution, heating to dissolve, cooling to 50-55 deg.C, adding thymol, clathrating under stirring, maintaining system temperature at 50-55 deg.C, stirring for 50-60min, naturally cooling to room temperature, and spray drying thymol clathrate solution.
By adopting the technical scheme, the beta-cyclodextrin is coated outside the thymol, the beta-cyclodextrin has antibacterial property, the thymol and the beta-cyclodextrin have good compatibility, the beta-cyclodextrin plays an antibacterial role firstly, then the thymol is slowly released, the antibacterial performance of the bed cover fabric is improved, and the modified thymol is uniformly distributed in the net structure of the acrylic acid-hydroxypropyl acrylate copolymer and the toluene-2, 4-diisocyanate, so that the antibacterial performance of the bed cover fabric is further improved.
Preferably, the mite-proofing agent is N-dodecyl-amino betaine-2-mercaptoethylamine hydrochloride.
By adopting the technical scheme, the N-dodecyl-aminobetaine-2-mercaptoethylamine hydrochloride can react with cystine to generate asymmetric disulfide bonds, has good adsorption capacity with yarns, and is conveniently and preferentially adsorbed on the surfaces of the yarns, so that the antibacterial performance and the stability of the mattress cover fabric are improved.
Preferably, the toluene-2, 4-diisocyanate is modified toluene-2, 4-diisocyanate, the modified toluene-2, 4-diisocyanate uses toluene-2, 4-diisocyanate as wall material, and clove oil as core material.
By adopting the technical scheme, the toluene-2, 4-diisocyanate is convenient to permeate into fiber molecules, the sodium diacetate and the thymol are convenient to permeate into long-chain molecules of the toluene-2, 4-diisocyanate and then are adsorbed on the fiber molecules under the action of the toluene-2, 4-diisocyanate, meanwhile, the clove oil is coated in the toluene-2, 4-diisocyanate and has the sterilization effect, so that the antibacterial component is convenient to further introduce into the fibers, and the antibacterial performance of the fabric is further improved.
Preferably, the antibacterial finishing liquid also comprises 2-5 parts by weight of filler, wherein the filler consists of PVC paste resin, PVC blending resin and fumed silica according to the mass ratio of (1-3) to (2-4).
Preferably, the particle size of the PVC paste resin is 0.1 to 0.5. mu.m.
Preferably, the particle size of the PVC blending resin is 10-20 μm.
By adopting the technical scheme, the filling agent is formed by mixing the PVC paste resin and the PVC blending resin, so that a good filling effect is obtained, the PVC paste resin is filled in gaps among PVC blending resin particles, the flowability of the PVC paste resin particles and the flowability of the PVC blending resin particles are improved, the fumed silica has a higher specific surface area, and is matched with the PVC paste resin and the PVC blending resin to form a three-dimensional cross-linked network in fibers, so that the tensile strength of yarns is improved, the distribution stability of the antibacterial agent in the bed cover fabric is improved, and the antibacterial performance of the bed cover fabric is improved.
In a second aspect, the present application provides a method for manufacturing quilting-imitated jacquard fabric, which adopts the following technical scheme: a method for manufacturing quilting-imitated jacquard fabric comprises the following steps,
(1) preparing antibacterial anti-mite yarn: dipping the yarn into the antibacterial finishing liquid, and drying to obtain the antibacterial anti-mite yarn;
(2) preparing warps and wefts: combining the elastic yarn and the antibacterial and anti-mite yarn obtained in the step (1) to obtain warp and weft;
(3) preparing an upper surface layer: using a land comb node to penetrate all warps and wefts, and weaving an upper surface layer on a front needle bed;
(4) preparation of the following layers: the ground comb nodes are used to penetrate the warps and the wefts, and the lower surface layer is woven on the back needle bed;
(5) preparing a spacing layer: using a ground comb node to penetrate all warps and wefts, knitting products on a front needle bed and a back needle bed respectively, and arranging a spacing layer with a strain characteristic value larger than 4kpa in a compression stress position of forty percent;
(6) three-dimensional quilted fabric: using a jacquard comb to penetrate through warps and wefts, respectively weaving quilting effect areas with three-dimensional sense on a front needle bed and a back needle bed, and then carrying out jacquard operation on non-quilting effect areas of an upper layer and a lower layer of the fabric according to a designed pattern to obtain a three-dimensional quilted fabric;
(7) preparing the quilting-imitated jacquard fabric: and (5) performing heat setting on the three-dimensional quilted fabric prepared in the step (6) to obtain the quilting-simulated jacquard fabric.
By adopting the technical scheme, after the yarns are subjected to dipping treatment by the antibacterial finishing liquid, the antibacterial agent and the anti-mite agent are adsorbed on the yarns under the action of the reinforcing agent, so that the washability of the antibacterial agent on fibers is improved, the antibacterial property of the yarns is further improved, and the antibacterial property of the quilting-imitating jacquard fabric made of the yarns is better; the arrangement of the upper layer, the spacer layer and the lower layer in the quilting imitation jacquard fabric is convenient for improving the stereoscopic impression of the quilting imitation jacquard fabric, so that the quilting imitation jacquard fabric has better plumpness, and the jacquard operation is convenient for enriching the expression forms of the quilting imitation jacquard fabric, so that the quilting imitation jacquard fabric has better antibacterial performance and better stereoscopic impression.
In summary, the present application has the following beneficial effects:
1. the anti-bacterial finishing is carried out on the yarns for preparing the fabric, so that the yarns have anti-bacterial and anti-mite performances, meanwhile, the anti-bacterial finishing liquid carries out anti-bacterial finishing on the yarns, the anti-bacterial washability of the fabric is convenient to improve, the anti-bacterial performance of the fabric is further improved, the anti-quilting jacquard fabric is composed of an upper surface layer, a spacer layer and a lower surface layer, the surface layer is made of the yarns processed by the anti-bacterial finishing liquid, the improvement is convenient, the stereoscopic impression of the anti-quilting jacquard fabric is better, and the anti-bacterial performance is achieved.
2. According to the quilting seam imitating jacquard fabric, yarns are arranged through the antibacterial finishing liquid, and the antibacterial agent and the anti-mite agent interact with each other in the antibacterial finishing liquid, so that the antibacterial performance of the yarns is improved, meanwhile, under the action of the reinforcing agent, the adsorption strength of the antibacterial agent and the anti-mite agent on the yarns is increased, and therefore the fabric still has good antibacterial performance after being washed for many times.
3. According to the quilting-imitating jacquard fabric, the upper surface layer, the spacer layer and the lower surface layer are arranged, so that the three-dimensional performance of the quilting-imitating jacquard fabric is improved conveniently, meanwhile, the attractiveness and air permeability of the quilting-imitating jacquard fabric are improved, and compared with the quilting fabric, the quilting-imitating jacquard fabric is lower in cost and more flexible in pattern design.
Detailed Description
The present application will be described in further detail with reference to examples.
The utility model provides an imitative quilting jacquard fabric, through designing upper strata, the wall, lower surface course, the design of multiaspect layer is convenient for improve jacquard fabric's third dimension, simultaneously, adopt jacquard weave operation and imitative quilting technology to combine together, be convenient for make imitative quilting jacquard fabric have better plumpness, make imitative quilting jacquard fabric surface have the quilting line stitch effect of even "stitch" imitative quilting goods, richen imitative quilting jacquard fabric's flower type and pleasing to the eye degree, the cost is lower, simultaneously, the yarn that will weave into imitative quilting jacquard fabric is put in order through antibiotic finishing liquor, thereby make imitative quilting jacquard fabric have pleasing to the eye concurrently, abundant flower type and bacterinertness.
The preparation method of the isocyanate sulfonic acid betaine comprises the following steps: 44.46g of isophorone diisocyanate, 11.91g of N-methyldiethanolamine and 56.37g of N, N-dimethylformamide are mixed and uniformly stirred, and the mixture reacts for 2 hours under the conditions of nitrogen protection and the temperature of 90 ℃ to prepare tertiary amine intermediate solution containing isocyanate groups; dissolving 12.21g of 1, 3-butyrolactone sulfonate in 12.21g of N, N, N-dimethylformamide, adding the obtained solution into the prepared tertiary amine intermediate solution containing isocyanate groups, and continuously reacting for 10 hours under the conditions of nitrogen protection and 100 ℃; after the reaction is finished, 137.16g of acetone is used for precipitation, filtration and washing of the product, and finally the product is placed in a vacuum oven at 25 ℃ for drying for 48 hours, so that the catalyst is obtained.
The preparation method of the poly dimethyl diallyl ammonium chloride comprises the following steps: 20mL of 65% dimethyldiallylammonium chloride monomer solution was charged into a 250mL three-necked flask, followed by addition of ethylenediaminetetraacetic acid in an amount of 0.1% by mass of the monomer. After stirring for 10min, ammonium persulfate and sodium thiosulfate redox initiator were added rapidly, the amounts of ammonium persulfate and sodium thiosulfate used being 0.2% of the mass of the monomers. Pumping negative pressure at room temperature, and then slowly introducing N2And repeating the reaction for 3 times, reacting for 5h at 60 ℃ to obtain a white solid product, filling the product into a dialysis bag, dialyzing for 3d with distilled water, performing rotary evaporation, placing in a vacuum drying oven, and drying for 3d at 40 ℃ to obtain the product. Wherein the manufacturer of the dimethyl diallyl ammonium chloride monomer solution is Wuhanjiangrun fine chemical industry company.
The preparation method of the modified toluene-2, 4-diisocyanate comprises the following steps: adding 0.075g of sodium alginate and 1.0g of polyvinyl alcohol into 200 mL of distilled water, heating and stirring until the mixture is nearly boiled to dissolve the sodium alginate and the polyvinyl alcohol, pouring the mixture into a 500mL three-necked bottle, stirring, cooling to 30 ℃, adding 3.08g of polyethylene glycol-400, emulsifying and stirring in a 30 ℃ water bath at the rotating speed of 1500r/min for 10 min; then 4.05g of toluene-2, 4-diisocyanate and 4.0g of clove oil are uniformly mixed and dripped into a three-necked bottle, stirring is carried out while dripping, 0.15g of dibutyltin dilaurate is added after dripping is finished, stirring reaction is carried out in a 30 ℃ constant-temperature water bath for 1h, then the temperature is raised to 70 ℃, 50ml of 30% ethylene glycol aqueous solution in volume fraction is added, stirring reaction is carried out in a 70 ℃ constant-temperature water bath for 1h, and cooling is carried out to room temperature, thus obtaining the modified toluene-2, 4-diisocyanate, which is spherical and has the particle size of 1 mu m.
Preparation examples of antibacterial and acarid-preventing finishing agent
Preparation example 1
The antibacterial finishing liquid of the preparation example is prepared from the following raw materials in parts by weight: 30kg of an antibacterial agent, 5kg of an anti-mite agent, 20kg of water, 2kg of a reinforcing agent, 1kg of a dispersing agent and 5kg of an adhesive, wherein the antibacterial agent is composed of sodium diacetate and thymol according to the mass ratio of 1:1, the anti-mite agent is folium artemisiae argyi volatile oil, the reinforcing agent is composed of acrylic acid-hydroxypropyl acrylate copolymer, toluene-2, 4-diisocyanate and poly dimethyl diallyl ammonium chloride according to the mass ratio of 1:1:3, the dispersing agent is sodium tripolyphosphate, and the adhesive is polyvinyl acetate.
The preparation method of the antibacterial finishing liquid comprises the following steps: the antibacterial agent, the anti-mite agent, the water, the reinforcing agent, the dispersing agent and the adhesive are mixed with one another to prepare the antibacterial finishing liquid.
Preparation examples 2 to 5
Preparation examples 2 to 5 were prepared by mixing the antibacterial finishing liquids at different ratios, and the ratios of the raw materials of the antibacterial finishing liquids for each preparation example are shown in table 1, and the unit of the ratios of the raw materials is kg.
TABLE 1 PREPARATION EXAMPLES 1-5 compounding ratio of raw material components of antibacterial finishing liquid
| Starting materials | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 |
| Antimicrobial agents | 30 | 35 | 50 | 40 | 45 |
| Anti-mite agent | 5 | 6 | 10 | 7 | 8 |
| Water (I) | 20 | 25 | 30 | 25 | 25 |
| Reinforcing agent | 2 | 3 | 5 | 3 | 4 |
| Dispersing agent | 1 | 1 | 2 | 2 | 2 |
| Adhesive agent | 5 | 7 | 8 | 7 | 7 |
Preparation examples 2 to 5 differed from preparation example 1 in that: the proportions of the raw materials of the antibacterial finishing liquid are different, and the rest are completely the same as those of the preparation example 1.
Preparation examples 2 to 5 the preparation method of the antibacterial finishing liquid was completely the same as that of preparation example 1.
Preparation example 6
The difference between the preparation example and the preparation example 4 is that: the reinforcing agent consists of acrylic acid-hydroxypropyl acrylate copolymer, toluene-2, 4-diisocyanate and polydimethyldiallyl ammonium chloride according to the mass ratio of 2:2:4, the anti-mite agent is N-dodecyl-amino betaine-2-mercaptoethylamine hydrochloride, and the rest is completely the same as the preparation example 4.
The preparation method of the antibacterial finishing liquid of the preparation example is completely the same as that of the preparation example 4.
Preparation example 7
The difference between the preparation example and the preparation example 4 is that: the antibacterial agent consists of sodium diacetate, thymol and isocyanate sulfonic acid betaine according to the mass ratio of 1:1:1, and the rest is completely the same as the preparation example 1.
The preparation method of the antibacterial finishing liquid of the preparation example is completely the same as that of the preparation example 4.
Preparation example 8
The difference between the preparation example and the preparation example 4 is that: the antibacterial agent consists of sodium diacetate, thymol and isocyanate sulfonic acid betaine according to the mass ratio of 2:2:4, and the rest is completely the same as the preparation example 4.
The preparation method of the antibacterial finishing liquid of the preparation example is completely the same as that of the preparation example 4.
Preparation example 9
The difference between the preparation example and the preparation example 4 is that: the antibacterial agent consists of sodium diacetate, thymol and isocyanate sulfonic acid betaine according to the mass ratio of 3:3:5, and the rest is completely the same as the preparation example 4.
The preparation method of the antibacterial finishing liquid of the preparation example is completely the same as that of the preparation example 4.
Preparation example 10
The difference between the preparation example and the preparation example 9 is that: the preparation method of the modified thymol comprises the following steps: mixing 11g of beta-cyclodextrin, 80g of water and 2g of 95% ethanol solution, heating to 70 ℃ for dissolving, cooling to 55 ℃, adding 1g of thymol, performing inclusion by a shearing machine under the stirring of 5000r/min, keeping the system temperature between 50 ℃, shearing for 60 minutes, performing quality inspection on the inclusion compound, naturally cooling to room temperature, and performing spray drying on the thymol inclusion compound solution to obtain the thymol inclusion compound. The rest was exactly the same as in preparation example 9.
The preparation method of the antibacterial finishing liquid of the preparation example is completely the same as that of the preparation example 9.
Preparation example 11
The difference between the present preparation example and preparation example 10 is that: the toluene-2, 4-diisocyanate is modified toluene-2, 4-diisocyanate, the modified toluene-2, 4-diisocyanate is toluene-2, 4-diisocyanate serving as a wall material, and the clove oil serving as a core material. The rest was exactly the same as in preparation example 10.
The preparation method of the antibacterial finishing liquid of the preparation example is completely the same as that of the preparation example 10.
Preparation example 12
The antibacterial finishing liquid of the preparation example is prepared from the following raw materials in parts by weight: 40kg of an antibacterial agent, 7kg of an anti-mite agent, 25kg of water, 3kg of a reinforcing agent, 2kg of a dispersing agent, 7kg of an adhesive and 3kg of a filler, wherein the filler comprises PVC paste resin, PVC blending resin and fumed silica in a mass ratio of 3:3:4, and the rest is completely the same as that in preparation example 11.
The preparation method of the antibacterial finishing liquid of the preparation example is completely the same as that of the preparation example 11.
Preparation example 13
The antibacterial finishing liquid of the preparation example is different from the antibacterial finishing liquid of the preparation example 1 in that: the antibacterial agent is nano silver, the average grain diameter of the nano silver is 20nm, the rest is completely the same as the preparation example 1,
the preparation method of the antibacterial finishing liquid of the preparation example is completely the same as that of the preparation example 1.
Preparation example 14
The antibacterial finishing liquid of the preparation example is different from that of the preparation example 1 in that: the antibacterial agent is sodium diacetate, and the rest is completely the same as the preparation example 1.
The preparation method of the antibacterial finishing liquid of the preparation example is completely the same as that of the preparation example 1.
Preparation example 15
The antibacterial finishing liquid of the preparation example is prepared from the following raw materials in parts by weight: 30kg of an antibacterial agent, 5kg of an anti-mite agent, 20kg of water, 1kg of a dispersant and 5kg of a binder, and the rest are exactly the same as those in preparation example 1.
The preparation method of the antibacterial finishing liquid of the preparation example is completely the same as that of the preparation example 1.
Preparation example 16
The antibacterial finishing liquid of the preparation example is different from the antibacterial finishing liquid of the preparation example 1 in that: the reinforcing agent is acrylic acid-hydroxypropyl acrylate copolymer, and the other parts are the same as the preparation example 1.
The preparation method of the antibacterial finishing liquid of the preparation example is completely the same as that of the preparation example 1.
Preparation example 17
The antibacterial finishing liquid of the preparation example is different from the antibacterial finishing liquid of the preparation example 1 in that: the reinforcing agent consists of acrylic acid-hydroxypropyl acrylate copolymer and toluene-2, 4-diisocyanate in a mass ratio of 1:1, and the rest is completely the same as that of preparation example 1.
The preparation method of the antibacterial finishing liquid of the preparation example is completely the same as that of the preparation example 1.
Preparation example 18
The antibacterial finishing liquid of the preparation example is different from that of the preparation example 1 in that: 15kg of an antibacterial agent, 3kg of a miticide, 20kg of water, 8kg of a reinforcing agent, 1kg of a dispersant, and 5kg of a binder, and the rest were the same as in preparation example 1.
The preparation method of the antibacterial finishing liquid of the preparation example is completely the same as that of the preparation example 1.
Examples
Example 1
The quilting-imitated jacquard fabric comprises a plurality of surface layers and is characterized in that the surface layers are sequentially distributed into an upper surface layer, a spacer layer and a lower surface layer from top to bottom, the surface layers are formed by weaving warps and wefts, the warps and the wefts are formed by combining antibacterial anti-mite yarns and elastic yarns, and the antibacterial anti-mite yarns are finished by antibacterial finishing liquid prepared by the yarns through preparation example 1.
The method for manufacturing the quilting-imitated jacquard fabric comprises the following steps of:
(1) preparing the antibacterial anti-mite yarn: soaking the yarn in the antibacterial finishing liquid prepared in the preparation example 1, and drying to obtain the antibacterial and anti-mite yarn;
(2) preparing warps and wefts: combining the elastic yarn and the antibacterial and anti-mite yarn obtained in the step (1) to obtain warp and weft;
(3) preparing an upper surface layer: using a land comb node to fully penetrate warps and wefts, and weaving an upper surface layer on a front needle bed;
(4) preparation of the following layers: using a land comb node to penetrate with warps and wefts, and weaving a back needle bed into a lower surface layer;
(5) preparing a spacing layer: using a ground comb node to penetrate all warps and wefts, knitting products on a front needle bed and a back needle bed respectively, and arranging a spacing layer with a strain characteristic value larger than 4kpa in a compression stress position of forty percent;
(6) three-dimensional quilted fabric: using a jacquard comb to penetrate through warps and wefts, respectively weaving quilting effect areas with stereoscopic impression on a front needle bed and a rear needle bed, and then carrying out jacquard operation on non-quilting effect areas of an upper layer and a lower layer of the fabric according to a designed pattern to obtain a stereoscopic quilted fabric;
(7) preparing quilting-imitated jacquard fabric: and (5) performing heat setting on the three-dimensional quilted fabric prepared in the step (6).
Examples 2 to 12
Examples 2-12 are simulated quilted jacquard fabrics that were treated with different antimicrobial finishing solutions for antimicrobial treatment, the antimicrobial finishing solutions used in each example being shown in table 2.
Table 2 examples 1-12 finishing antimicrobial finishing liquids for imitation quilted jacquard fabrics
Examples 2-12 differ from example 1 in that: the antibacterial and anti-mite yarn is finished by the corresponding antibacterial finishing liquid, and the rest is completely the same as the example 1.
The quilting simulated jacquard production method of the embodiments 2-12 is different from the embodiment 1 in that: step (1), preparing antibacterial and anti-mite yarn: dipping the yarn into the antibacterial finishing liquid corresponding to the embodiment 2-12, and drying to obtain the antibacterial and anti-mite yarn; the rest is exactly the same as in example 1.
Comparative example
Comparative examples 1 to 6
Comparative examples 1-6 are quilted-like jacquard fabrics treated with different antimicrobial finishing solutions, each of which represents an antimicrobial finishing solution as shown in table 3.
Table 3 comparative examples 1-6 antibiotic finishing solutions for quilting-imitating jacquard fabrics
| Serial number | Antibacterial finishing liquid |
| Comparative example 1 | Preparation example 13 |
| Comparative example 2 | Preparation example 14 |
| Comparative example 3 | Preparation example 15 |
| Comparative example 4 | Preparation example 16 |
| Comparative example 5 | Preparation example 17 |
| Comparative example 6 | Preparation example 18 |
Comparative examples 1 to 6 differ from example 1 in that: the procedure of example 1 was repeated except that the antibacterial finishing liquid used was different.
The quilting simulated jacquard fabric of comparative examples 1-6 was prepared in a manner different from that of example 1 in that: step (1), preparation of antibacterial and anti-mite yarn: dipping the yarn into the antibacterial finishing liquid corresponding to the comparative examples 1-6, and drying to obtain the antibacterial anti-mite yarn; the rest is exactly the same as in example 1.
Performance test
The antibacterial detection method comprises the following steps: the quilting-imitated jacquard fabrics prepared in the embodiments 1-12 and the comparative examples 1-6 are taken, and are respectively washed by water for 0 and 50 times by taking escherichia coli and staphylococcus aureus as detection standards according to a detection method in GB/T20944-2007 evaluation on antibacterial performance of textiles, and detection results are shown in Table 4.
And (3) detecting the anti-mite performance: the quilting-imitated jacquard fabrics prepared in examples 1 to 12 and comparative examples 1 to 6 were subjected to a mite avoidance test according to the detection method in GB/T24253-2009 evaluation of anti-mite performance of textiles, and the detection results are shown in table 4.
Table 4 performance results of the quilted jacquard-like fabrics of examples 1-12 and comparative examples 1-6
In combination with the embodiment 1 and the comparative examples 1-2 and the table 4, it can be seen that, compared with the comparative examples 1-2, the antibacterial agent in the embodiment 1 is obtained by compounding a plurality of components, sodium diacetate is convenient to react with hydroxyl on the fibers, thymol is convenient to combine with substances required by bacterial growth, Si-OH formed by hydrolysis of isocyanate sulfobetaine is convenient to react with-OH on the fibers, and simultaneously, -NCO is chemically bonded with-OH to improve the adsorption strength of the sodium diacetate and the thymol on the fibers, the three components are mutually matched to further improve the antibacterial performance of the quilting-simulated jacquard fabric, and the distribution of an upper layer, a spacer layer and a lower layer is convenient to improve the three-dimensional property of the quilting-simulated jacquard fabric.
By combining the example 1 and the comparative examples 3-5, and combining the table 4, it can be seen that the reinforcing agent is obtained by compounding the acrylic acid-hydroxypropyl acrylate copolymer, the toluene-2, 4-diisocyanate and the polydimethyldiallylammonium chloride, the antibacterial agent is convenient to dissolve in the gaps of molecular chains of the acrylic acid-hydroxypropyl acrylate copolymer and the toluene-2, 4-diisocyanate, the acrylic acid-hydroxypropyl acrylate copolymer and the toluene-2, 4-diisocyanate are convenient to permeate into fibers, and the polydimethyldiallylammonium chloride is matched with the acrylic acid-hydroxypropyl acrylate copolymer and the toluene-2, 4-diisocyanate, so that the antibacterial performance of the quilted-imitated fabric and the antibacterial performance after multiple times of water washing are improved.
By combining examples 1-6 and comparative example 6 and table 4, it can be seen that the ratio of the raw materials of the anti-bacterial finishing liquid is adjusted, and the anti-bacterial performance of the quilting-imitated jacquard fabric and the anti-bacterial performance after washing are greatly different from each other by the raw materials with different ratios.
By combining the examples 4 and 7 to 11 and the table 4, it can be seen that the ratios of the multiple components of the antibacterial agent are adjusted, so that the multiple components are matched with each other, the effect of the antibacterial agent in the antibacterial finishing liquid is further improved, and the antibacterial performance of the quilting-simulated jacquard fabric is further improved.
In combination with examples 11 to 12 and table 4, it can be seen that the addition of the filler facilitates the improvement of the tensile strength of the yarn, thereby improving the stability of the antibacterial agent in the imitation quilted jacquard fabric and further improving the antibacterial performance of the imitation quilted jacquard fabric.
The specific embodiments are only for explaining the present application and are not limiting to the present application, and those skilled in the art can make modifications to the embodiments without inventive contribution as required after reading the present specification, but all the embodiments are protected by patent law within the scope of the claims of the present application.
Claims (8)
1. The utility model provides an imitative quilting jacquard fabric, includes a plurality of surface courses, its characterized in that, a plurality of the surface course from top to bottom distributes in proper order and is upper strata, wall and lower surface course, the surface course is woven by warp and weft and forms, warp and weft are formed by antibiotic anti-mite yarn, elasticity yarn combination, antibiotic anti-mite yarn is put in order through antibiotic finishing liquor by the yarn, antibiotic finishing liquor is mainly made by following parts by weight's raw materials: 30-50 parts of an antibacterial agent, 5-10 parts of a mite-proof agent, 20-30 parts of water, 2-5 parts of a reinforcing agent, 1-2 parts of a dispersing agent and 5-8 parts of an adhesive; the antibacterial agent is at least two of sodium diacetate, thymol and isocyanate sulfobetaine, and the reinforcing agent is composed of acrylic acid-hydroxypropyl acrylate copolymer, toluene-2, 4-diisocyanate and polydimethyldiallyl ammonium chloride according to the mass ratio of (1-2) to (3-4).
2. The imitation quilted jacquard fabric of claim 1, wherein: the mass ratio of the antibacterial agent to the anti-mite agent to the reinforcing agent is (35-45) to (6-8) to (3-4).
3. The imitation quilted jacquard fabric of claim 1, wherein: the antibacterial agent consists of sodium diacetate, thymol and isocyanate sulfonic acid betaine according to the mass ratio of (2-3) to (4-5).
4. The imitation quilted jacquard fabric of claim 3, wherein: the thymol is modified thymol, and the preparation method of the modified thymol comprises the following steps: mixing beta-cyclodextrin, water and ethanol solution, heating to dissolve, cooling to 50-55 deg.C, adding thymol, clathrating under stirring, keeping the temperature of system at 50-55 deg.C, stirring for 50-60min, naturally cooling to room temperature, and spray drying thymol clathrate solution.
5. The imitation quilted jacquard fabric of claim 1, wherein: the anti-mite agent is N-dodecyl-amino betaine-2-mercaptoethylamine hydrochloride.
6. The imitation quilted jacquard fabric of claim 1, wherein: the toluene-2, 4-diisocyanate is modified toluene-2, 4-diisocyanate, the modified toluene-2, 4-diisocyanate takes the toluene-2, 4-diisocyanate as a wall material, and the clove oil is a core material.
7. The imitation quilted jacquard fabric of claim 1, wherein: the antibacterial finishing liquid also comprises 2-5 parts by weight of filler, wherein the filler consists of PVC paste resin, PVC blending resin and fumed silica according to the mass ratio of (1-3) to (2-4).
8. A method of making a simulated quilted jacquard fabric as claimed in any one of claims 1-7, wherein: comprises the following steps of (a) carrying out,
(1) preparing antibacterial anti-mite yarn: soaking the yarn in the antibacterial finishing liquid, and drying to obtain the antibacterial anti-mite yarn;
(2) preparing warp and weft: combining the elastic yarns and the antibacterial and anti-mite yarns obtained in the step (1) to obtain warps and wefts;
(3) preparing an upper surface layer: using a land comb node to penetrate all warps and wefts, and weaving an upper surface layer on a front needle bed;
(4) preparation of the following layers: the ground comb nodes are used to penetrate the warps and the wefts, and the lower surface layer is woven on the back needle bed;
(5) preparing a spacing layer: using a ground comb node to penetrate all warps and wefts, knitting products on a front needle bed and a back needle bed respectively, and arranging a spacing layer with a strain characteristic value larger than 4kpa in a compression stress position of forty percent;
(6) three-dimensional quilted fabric: using a jacquard comb to penetrate through warps and wefts, respectively weaving quilting effect areas with stereoscopic impression on a front needle bed and a rear needle bed, and then carrying out jacquard operation on non-quilting effect areas of an upper layer and a lower layer of the fabric according to a designed pattern to obtain a stereoscopic quilted fabric;
(7) preparing quilting-imitated jacquard fabric: and (5) performing heat setting on the three-dimensional quilted fabric prepared in the step (6) to obtain the quilting-simulated jacquard fabric.
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