CN109304904A - A kind of flannelette Fabric structure - Google Patents

A kind of flannelette Fabric structure Download PDF

Info

Publication number
CN109304904A
CN109304904A CN201811245577.3A CN201811245577A CN109304904A CN 109304904 A CN109304904 A CN 109304904A CN 201811245577 A CN201811245577 A CN 201811245577A CN 109304904 A CN109304904 A CN 109304904A
Authority
CN
China
Prior art keywords
parts
flannelette
added
flannelette fabric
complex antimicrobials
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201811245577.3A
Other languages
Chinese (zh)
Other versions
CN109304904B (en
Inventor
石向阳
孙晓丹
余炜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Semir Garment Co Ltd
Original Assignee
Zhejiang Semir Garment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Semir Garment Co Ltd filed Critical Zhejiang Semir Garment Co Ltd
Priority to CN201811245577.3A priority Critical patent/CN109304904B/en
Publication of CN109304904A publication Critical patent/CN109304904A/en
Application granted granted Critical
Publication of CN109304904B publication Critical patent/CN109304904B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/02—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic System; Aluminates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D06M15/572—Reaction products of isocyanates with polyesters or polyesteramides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0276—Polyester fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0292—Polyurethane fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/38—Polyurethanes

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Ceramic Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The invention discloses a kind of flannelette Fabric structures, its key points of the technical solution are that including the flannelette Fabric of eiderdown shell fabric and the eiderdown shell fabric adjacent for connecting two pieces, the flannelette Fabric includes following material composition: polyester fiber, polyurethane fiber, complex antimicrobials, impregnation, beneficial effects of the present invention, polyester sea-island type superfine fibre and polyurethane fiber has been selected to be made into composite fibre, polyester sea-island type superfine fibre makes fabric surface that can form dense villus, nappiness is good, and villus washable and wearable, various colors can be dyed, and polyurethane fiber elasticity is excellent, rebound degree is high, it can restore to the original state rapidly, and resistance to acid and alkali, sweat proof, dry cleaning resistance is preferable, composite fibre passes through dipping again, complex antimicrobials are immersed into fibr tissue, to improve antibacterial ability of the invention.

Description

A kind of flannelette Fabric structure
Technical field
The present invention relates to a kind of fabric structure, more particularly to a kind of flannelette Fabric structure.
Background technique
Eiderdown shell fabric elasticity is low, for convenience of wearing, comfort level is improved, often at the cuff of cotton clothes jacket or natural feather Flexible fabric is sewed in trousers side at seam, in order to not influence the thermal property of cotton clothes, often selects resilience villous good Fabric.
Due to easily leading to filler unevenness after cotton clothes washing, influencing beautiful and reducing warmth retention property, most of cotton clothess are used Part is cleaned, and if things go on like this, is difficult to clean in place with connection cloth villous, and bacterium easy to breed, to influence human body body Body health.
Summary of the invention
In view of the deficiencies of the prior art, the present invention intends to provide a kind of high-elastic face of the flannelette that anti-microbial property is strong Expect structure.
To achieve the above object, the present invention provides the following technical scheme that a kind of flannelette Fabric structure, including natural feather The flannelette Fabric of fabric and the eiderdown shell fabric adjacent for connecting two pieces, the flannelette Fabric include following parts by weight Material composition:
70-80 parts of polyester fiber；
65-80 parts of polyurethane fiber；
5-10 parts of complex antimicrobials；
10-15 parts of impregnation；
The production technology following steps of the flannelette Fabric:
S1: polyester fiber and polyurethane fiber are subjected to shredding, mixing, smart shredding, filtering and combing, it is fine to obtain mixing Dimension；
S2: complex antimicrobials being uniformly mixed with impregnation, obtain maceration extract, carries out impregnation 3-5h to composite fibre；
S3: fabric obtained in S2 is dried, is fluffed, soft treatment, is formed again, hot light and cropping.
The complex antimicrobials include following parts by weight material composition:
2-10 parts of loaded article；
1-2 parts of carrier；
The loaded article includes inorganic antiseptic and organic antibacterial agent；
Wherein the ratio between parts by weight of inorganic antiseptic and organic antibacterial agent are 2:1；
The inorganic antiseptic is rare earth oxide, and the rare earth oxide is in cerium oxide, praseodymium oxide and neodymia Mixture, the ratio between parts by weight are 1:1:1；
Organic antibacterial agent is 5-Chloro-2-methyl-4-isothiazolin-3-one, the double octyl ammonium chlorides of dimethyl, polyhexamethylene The mixture of biguanide hydrochloride, the ratio between parts by weight are 1:3:1；
The carrier is chitosan porous microsphere；
The complex antimicrobials manufacturing process is as follows:
A1: cerium oxide, praseodymium oxide, neodymia being added into 100 parts of hydrochloric acid, stirring and dissolving 5min, and 2-3 parts of silane are added Coupling agent and 5-Chloro-2-methyl-4-isothiazolin-3-one, dimethyl double octyl ammonium chlorides, hexamethylene Mixture stirs evenly 0.5h, adds 3-4 parts of emulsifiers, and 3-5 parts of modified polyurethane adhesives, stirring is added in high speed dispersion It is formed and stablizes antimicrobial emulsion；
Chitosan porous microsphere is added in antimicrobial emulsion obtained in a2:a1, by being uniformly mixed, is put into 90 DEG C Baking oven is heat-treated 4 hours, obtains complex antimicrobials.
The silane coupling agent is silane resin acceptor kh-550, in silane coupling agent KH-560, Silane coupling reagent KH-570 Any one.
The emulsifier is any one in fatty alcohol polyoxyethylene ether or alkyl phenol polyoxyethylene ether.
The synthesis step of the modified polyurethane adhesive is as follows:
B1: 50 toluene di-isocyanate(TDI)s and 100 parts of polyadipate -1,4- butyl glycol ester diols are put into reflux unit Heating stirring machine in, be warming up to 70-80 DEG C, add 2 parts of modifying agent, react 2-3h, obtain performed polymer；2 parts of chain extensions are added Agent reacts 1-2h, adds 4 parts of sealers, be warming up to 100-110 DEG C of reaction 1-2h；1 part of acetone viscosity reduction is added to glue to required Degree；
B2: being cooled to 40-50 DEG C, and 4 parts of gamma-aminopropyl-triethoxy-silanes are added dropwise, and reacts 1-2h；
B3: 3 parts of modifying agent, 1 part of triethylamine and 90 parts of deionized waters are added, above-mentioned mixed solution is put into kneading machine In, revolving speed translates 2000r/min, and time 20-30min is to get modified polyurethane adhesive；
The sealer is one of phenol, ethanethio, hydrogen cyanide or combination.
The chain extender is one of 1,4- butanediol, diglycol, ethylenediamine or combination.
The modifying agent is lignin, N- acetyl group aziridine, ferrous sulfate, ammonium sulfate, and the ratio between parts by weight are 2:1:1:1。
The polyester fiber is polyester sea-island type superfine fibre.
Beneficial effects of the present invention have selected polyester sea-island type superfine fibre and polyurethane fiber to be made into composite fibre, gather Ester sea-island composite fiber makes fabric surface that can form dense villus, and nappiness is good, and villus washable and wearable, can dye each Kind color, and polyurethane fiber elasticity is excellent, rebound degree is high, can restore to the original state rapidly, and resistance to acid and alkali, sweat proof, dry cleaning resistance Preferably, composite fibre passes through dipping again, complex antimicrobials is immersed fibr tissue, to improve antibacterial ability of the invention.
As one of new wound point of the invention, which is by mixing inorganic antiseptic and organic antibacterial agent It loads on chitosan porous microsphere later, wherein inorganic antibacterial object selects rare earth compound, and there is rare earth compound sterilization to make With outer, also have the characteristics that wide spectrum, long-acting and without side-effects, compare silver ion antimicrobial agent, security performance is high, but its antibiotic property Can not be strong, to constrain rare earth in the development in antibacterial field.Three kinds of rare earth-iron-borons are selected in the present invention, are respectively aoxidized Cerium, praseodymium oxide, neodymia under three kinds of substance collective effects, expand the range of antibacterial, and anti-microbial property is more lasting, and organic Antibacterial selects the double octyl ammonium chlorides of 5-Chloro-2-methyl-4-isothiazolin-3-one, dimethyl, cosmocil stearate acid Salt, it is mutual in 5-Chloro-2-methyl-4-isothiazolin-3-one, the double octyl ammonium chlorides of dimethyl, hexamethylene Under cooperation, anti-microbial property is enhanced.Carrier selects chitosan porous microsphere, and chitosan has polymolecularity and Large ratio surface Product, is the carrier material that a clock is had excellent performance, in addition to this, chitosan itself has certain antibacterial ability, and anti-microbial property obtains To further enhancing.
As another new wound point of the invention, in preparing complex antimicrobials, in order to keep complex antimicrobials long-term Stability is added adhesive during the preparation process to solve the loss of inorganic antiseptic or organic antibacterial agent and fall off, but bonds Agent reduces the antibacterial effect of complex antimicrobials, modified polyurethane adhesive is selected in the present invention, in the process of synthesis performed polymer In, it joined modifying agent, modifying agent is lignin, N- acetyl group aziridine, ferrous sulfate, ammonium sulfate, is made in above-mentioned substance Under, the antibacterial effect of complex antimicrobials is not influenced by adhesive, and the water resistance of adhesive is improved, and the present invention is more After secondary washing, still there is preferable antibacterial ability.
Detailed description of the invention
Fig. 1 is application schematic diagram of the present invention.
Fig. 2 is schematic structural view of the invention.
In figure: 1, flannelette Fabric；2, eiderdown shell fabric.
Specific embodiment
Below with reference to embodiment, the present invention is described in more detail.Substance used in the present invention without specified otherwise, It purchases to obtain by market.
Embodiment one:
70-80 parts of polyester fiber；
65-80 parts of polyurethane fiber；
5-10 parts of complex antimicrobials；
10-15 parts of impregnation；
The production technology following steps of the flannelette Fabric:
S1: polyester fiber and polyurethane fiber are subjected to shredding, mixing, smart shredding, filtering and combing, it is fine to obtain mixing Dimension；
S2: complex antimicrobials being uniformly mixed with impregnation, obtain maceration extract, carries out impregnation 3-5h to composite fibre；
S3: fabric obtained in S2 is dried, is fluffed, soft treatment, is formed again, hot light and cropping.
The complex antimicrobials include following parts by weight material composition:
2-10 parts of loaded article；
1-2 parts of carrier；
The loaded article includes inorganic antiseptic and organic antibacterial agent；
Wherein the ratio between parts by weight of inorganic antiseptic and organic antibacterial agent are 2:1；
The inorganic antiseptic is rare earth oxide, and the rare earth oxide is in cerium oxide, praseodymium oxide and neodymia Mixture, the ratio between parts by weight are 1:1:1；
Organic antibacterial agent is 5-Chloro-2-methyl-4-isothiazolin-3-one, the double octyl ammonium chlorides of dimethyl, polyhexamethylene The mixture of biguanide hydrochloride, the ratio between parts by weight are 1:3:1；
The carrier is chitosan porous microsphere.
The complex antimicrobials manufacturing process is as follows:
A1: cerium oxide, praseodymium oxide, neodymia being added into 100 parts of hydrochloric acid, stirring and dissolving 5min, and 2-3 parts of silane are added Coupling agent and 5-Chloro-2-methyl-4-isothiazolin-3-one, dimethyl double octyl ammonium chlorides, hexamethylene Mixture stirs evenly 0.5h, adds 3-4 parts of emulsifiers, and 3-5 parts of modified polyurethane adhesives, stirring is added in high speed dispersion It is formed and stablizes antimicrobial emulsion；
Chitosan porous microsphere is added in antimicrobial emulsion obtained in a2:a1, by being uniformly mixed, is put into 90 DEG C Baking oven is heat-treated 4 hours, obtains complex antimicrobials.
The silane coupling agent is silane resin acceptor kh-550.
The emulsifier is fatty alcohol polyoxyethylene ether.
The synthesis step of the modified polyurethane adhesive is as follows:
B1: 50 parts of toluene di-isocyanate(TDI)s and 100 parts of polyadipate -1,4- butyl glycol ester diols are put into reflux dress In the heating stirring machine set, it is warming up to 70-80 DEG C, adds 2 parts of modifying agent, 2-3h is reacted, obtains performed polymer；2 parts of expansions are added Chain agent reacts 1-2h, adds 4 parts of sealers, be warming up to 100-110 DEG C of reaction 1-2h；1 part of acetone viscosity reduction is added to glue to required Degree；
B2: being cooled to 40-50 DEG C, and 4 parts of gamma-aminopropyl-triethoxy-silanes are added dropwise, and reacts 1-2h；
B3: 3 parts of modifying agent, 1 part of triethylamine and 90 parts of deionized waters are added, above-mentioned mixed solution is put into kneading machine In, revolving speed translates 2000r/min, and time 20-30min is to get modified polyurethane adhesive.
The sealer is phenol.
The chain extender is 1,4-butanediol, diglycol, and parts by weight are to than for 1:1.
The modifying agent is lignin, N- acetyl group aziridine, ferrous sulfate, ammonium sulfate, and the ratio between parts by weight are 2:1:1:1。
The polyester fiber is polyester sea-island type superfine fibre.
Comparative example one:
70-80 parts of polyester fiber；
65-80 parts of polyurethane fiber；
5-10 parts of complex antimicrobials；
10-15 parts of impregnation；
The production technology following steps of the flannelette Fabric:
S1: polyester sea-island type superfine fibre and polyurethane fiber are subjected to shredding, mixing, smart shredding, filtering and combing, obtained To composite fibre；
S2: complex antimicrobials being uniformly mixed with impregnation, obtain maceration extract, carries out impregnation 3-5h to composite fibre；
S3: fabric obtained in S2 is dried, is fluffed, soft treatment, is formed again, hot light and cropping.
The complex antimicrobials include following parts by weight material composition:
2-10 parts of loaded article；
1-2 parts of carrier；
The loaded article is inorganic antiseptic；
The inorganic antiseptic is rare earth oxide, and the rare earth oxide is in cerium oxide, praseodymium oxide and neodymia Mixture, the ratio between parts by weight are 1:1:1；
The carrier is chitosan porous microsphere.
The complex antimicrobials manufacturing process is as follows:
A1: cerium oxide, praseodymium oxide, neodymia being added into 100 parts of hydrochloric acid, stirring and dissolving 5min, and 2-3 parts of silane are added Coupling agent stirs evenly 0.5h, adds 3-4 parts of emulsifiers, and 3-5 parts of modified polyurethane adhesives, stirring is added in high speed dispersion It is formed and stablizes antimicrobial emulsion；
Chitosan porous microsphere is added in antimicrobial emulsion obtained in a2:a1, by being uniformly mixed, is put into 90 DEG C Baking oven is heat-treated 4 hours, obtains complex antimicrobials.
The silane coupling agent is silane resin acceptor kh-550.
The emulsifier is fatty alcohol polyoxyethylene ether.
The synthesis step of modified polyurethane adhesive is as follows:
B1: 50 parts of toluene di-isocyanate(TDI)s and 100 parts of polyadipate -1,4- butyl glycol ester diols are put into reflux dress In the heating stirring machine set, it is warming up to 70-80 DEG C, adds 2 parts of modifying agent, 2-3h is reacted, obtains performed polymer；2 parts of expansions are added Chain agent reacts 1-2h, adds 4 parts of sealers, be warming up to 100-110 DEG C of reaction 1-2h；1 part of acetone viscosity reduction is added to glue to required Degree；
B2: being cooled to 40-50 DEG C, and 4 parts of gamma-aminopropyl-triethoxy-silanes are added dropwise, and reacts 1-2h；
B3: 3 parts of modifying agent, 1 part of triethylamine and 90 parts of deionized waters are added, above-mentioned mixed solution is put into kneading machine In, revolving speed translates 2000r/min, and time 20-30min is to get modified polyurethane adhesive.
The sealer is phenol.
The chain extender is 1,4-butanediol, diglycol, and parts by weight are to than for 1:1.
The modifying agent is lignin, N- acetyl group aziridine, ferrous sulfate, ammonium sulfate, and the ratio between parts by weight are 2:1:1:1。
The polyester fiber is polyester sea-island type superfine fibre.
Comparative example two:
70-80 parts of polyester fiber；
65-80 parts of polyurethane fiber；
5-10 parts of complex antimicrobials；
10-15 parts of impregnation；
The production technology following steps of the flannelette Fabric:
S1: polyester sea-island type superfine fibre and polyurethane fiber are subjected to shredding, mixing, smart shredding, filtering and combing, obtained To composite fibre；
S2: complex antimicrobials being uniformly mixed with fabric impregnation, obtain maceration extract, carries out impregnation 3- to composite fibre 5h；
S3: fabric obtained in S2 is dried, is fluffed, soft treatment, is formed again, hot light and cropping.
The complex antimicrobials include following parts by weight material composition:
2-10 parts of loaded article；
1-2 parts of carrier；
The loaded article is organic antibacterial agent；
Organic antibacterial agent is 5-Chloro-2-methyl-4-isothiazolin-3-one, the double octyl ammonium chlorides of dimethyl, polyhexamethylene The mixture of biguanide hydrochloride, the ratio between parts by weight are 1:3:1.
The carrier is chitosan porous microsphere.
The complex antimicrobials manufacturing process is as follows:
A1: in 100 parts of hydrochloric acid, 2-3 parts of silane coupling agents and 5-Chloro-2-methyl-4-isothiazolin-3-one, two is added The mixture of the double octyl ammonium chlorides of methyl, hexamethylene, stirs evenly 0.5h, adds 3-4 parts of emulsifiers, 3-5 parts of modified polyurethane adhesives are added in high speed dispersion, and stirring, which is formed, stablizes antimicrobial emulsion；
Chitosan porous microsphere is added in antimicrobial emulsion obtained in a2:a1, by being uniformly mixed, is put into 90 DEG C Baking oven is heat-treated 4 hours, obtains complex antimicrobials.
The silane coupling agent is silane resin acceptor kh-550.
The emulsifier is fatty alcohol polyoxyethylene ether.
The synthesis step of modified polyurethane adhesive is as follows:
B1: 50 parts of toluene di-isocyanate(TDI)s and 100 parts of polyadipate -1,4- butyl glycol ester diols are put into reflux dress In the heating stirring machine set, it is warming up to 70-80 DEG C, adds 2 parts of modifying agent, 2-3h is reacted, obtains performed polymer；2 parts of expansions are added Chain agent reacts 1-2h, adds 4 parts of sealers, be warming up to 100-110 DEG C of reaction 1-2h；1 part of acetone viscosity reduction is added to glue to required Degree；
B2: being cooled to 40-50 DEG C, and 4 parts of gamma-aminopropyl-triethoxy-silanes are added dropwise, and reacts 1-2h；
B3: 3 parts of modifying agent, 1 part of triethylamine and 90 parts of deionized waters are added, above-mentioned mixed solution is put into kneading machine In, revolving speed translates 2000r/min, and time 20-30min is to get modified polyurethane adhesive.
The sealer is phenol.
The chain extender is 1,4-butanediol, diglycol, and parts by weight are to than for 1:1.
The modifying agent is lignin, N- acetyl group aziridine, ferrous sulfate, ammonium sulfate, and the ratio between parts by weight are 2:1:1:1。
The polyester fiber is polyester sea-island type superfine fibre.
Comparative example three:
70-80 parts of polyester fiber；
65-80 parts of polyurethane fiber；
5-10 parts of complex antimicrobials；
10-15 parts of impregnation；
The production technology following steps of the flannelette Fabric:
S1: polyester fiber and polyurethane fiber are subjected to shredding, mixing, smart shredding, filtering and combing, it is fine to obtain mixing Dimension；
S2: complex antimicrobials being uniformly mixed with fabric impregnation, obtain maceration extract, carries out impregnation 3- to composite fibre 5h；
S3: fabric obtained in S2 is dried, is fluffed, soft treatment, is formed again, hot light and cropping.
The complex antimicrobials include following parts by weight material composition:
2-10 parts of loaded article；
1-2 parts of carrier；
The loaded article includes inorganic antiseptic and organic antibacterial agent；
Wherein the ratio between parts by weight of inorganic antiseptic and organic antibacterial agent are 2:1；
The inorganic antiseptic is rare earth oxide, and the rare earth oxide is in cerium oxide, praseodymium oxide and neodymia Mixture, the ratio between parts by weight are 1:1:1；
Organic antibacterial agent is 5-Chloro-2-methyl-4-isothiazolin-3-one, the double octyl ammonium chlorides of dimethyl, polyhexamethylene The mixture of biguanide hydrochloride, the ratio between parts by weight are 1:3:1.
The carrier is chitosan porous microsphere.
The complex antimicrobials manufacturing process is as follows:
S1: cerium oxide, praseodymium oxide, neodymia being added into 100 parts of hydrochloric acid, stirring and dissolving 5min, and 2-3 parts of silane are added Coupling agent and 5-Chloro-2-methyl-4-isothiazolin-3-one, dimethyl double octyl ammonium chlorides, hexamethylene Mixture stirs evenly 0.5h, adds 3-4 parts of fatty alcohol polyoxyethylene ether emulsifiers, and 3-5 parts of poly- ammonia are added in high speed dispersion Ester adhesive, stirring, which is formed, stablizes antimicrobial emulsion；
Chitosan porous microsphere is added in antimicrobial emulsion obtained in S2:S1, by being uniformly mixed, is put into 90 DEG C Baking oven is heat-treated 4 hours, obtains complex antimicrobials.
One, flexibility test
Fabric tension performance test is carried out according to GB/T 3923.1-1997
Tensile strength MPa Elongation at break (%)
Embodiment one 40 272
Two: the measurement of antibiotic rate
Flannelette Fabric is cut into the fragment of about 1cmx1cm, 2.0g is taken to be fitted into the sterile conical flask of 100ml, then plus Enter the sterile saline and 0.2ml examination bacterium solution of 19.8ml, the examination bacterium solution includes staphylococcus, in 30 DEG C of water-bath oscillators 200r/min shakes 2h.0.5ml concussion 0h is taken respectively and shakes the sample liquid of 2h takes out 0.1ml after doing appropriate dilution with sterile water In aseptic flat board, viable bacteria culture is carried out using the method for plate culture count and is counted, and calculates antibiotic rate.
Three, water-wash resistance
GB8629-2001 according to national standards is found white washing powder and is made into the cleaning solution that mass concentration is 3g/L with commercially available, At normal temperature, by washings quality and cleaning solution mass ratio 1:30, flannelette Fabric is put into agitator treating in washing machine Then 15min is rinsed in clear water, wash as 1 time, after flannelette Fabric carries out 5 times and 10 times washings respectively, is then taken out It dries, test sample antibacterial effect.
In the present invention, polyester sea-island type superfine fibre and polyurethane fiber is selected to be made into composite fibre, polyester sea-island type Superfine fibre makes fabric surface that can form dense villus, and nappiness is good, and villus washable and wearable, can dye various colors, And polyurethane fiber elasticity is excellent, and rebound degree is high, it can restore to the original state rapidly, and resistance to acid and alkali, sweat proof, dry cleaning resistance are preferable, Composite fibre passes through dipping again, and complex antimicrobials are immersed fibr tissue, to improve antibacterial ability of the invention.
As one of new wound point of the invention, which is by mixing inorganic antiseptic and organic antibacterial agent It loads on chitosan porous microsphere later, wherein inorganic antibacterial object selects rare earth compound, and there is rare earth compound sterilization to make With outer, also have the characteristics that wide spectrum, long-acting and without side-effects, compare silver ion antimicrobial agent, security performance is high, but its antibiotic property Can not be strong, to constrain rare earth in the development in antibacterial field.Three kinds of rare earth-iron-borons are selected in the present invention, are respectively aoxidized Cerium, praseodymium oxide, neodymia under three kinds of substance collective effects, expand the range of antibacterial, and anti-microbial property is more lasting, and organic Antibacterial selects the double octyl ammonium chlorides of 5-Chloro-2-methyl-4-isothiazolin-3-one, dimethyl, cosmocil stearate acid Salt, it is mutual in 5-Chloro-2-methyl-4-isothiazolin-3-one, the double octyl ammonium chlorides of dimethyl, hexamethylene Under cooperation, anti-microbial property is enhanced.Carrier selects chitosan porous microsphere, and chitosan has polymolecularity and Large ratio surface Product, is the carrier material that a clock is had excellent performance, in addition to this, chitosan itself has certain antibacterial ability, and anti-microbial property obtains To further enhancing.
As another new wound point of the invention, in preparing complex antimicrobials, in order to keep complex antimicrobials long-term Stability is added adhesive during the preparation process to solve the loss of inorganic antiseptic or organic antibacterial agent and fall off, but bonds Agent reduces the antibacterial effect of complex antimicrobials, modified polyurethane adhesive is selected in the present invention, in the process of synthesis performed polymer In, it joined modifying agent, modifying agent is lignin, N- acetyl group aziridine, ferrous sulfate, ammonium sulfate, is made in above-mentioned substance Under, the antibacterial effect of complex antimicrobials is not influenced by adhesive, and the water resistance of adhesive is improved, and the present invention is more After secondary washing, still there is preferable antibacterial ability.
The above is only a preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-mentioned implementation Example, all technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It should be pointed out that for the art Those of ordinary skill for, several improvements and modifications without departing from the principles of the present invention, these improvements and modifications It should be regarded as protection scope of the present invention.

Claims (10)

1. a kind of flannelette Fabric structure, it is characterised in that: the adjacent natural feather including eiderdown shell fabric (2) and for connecting two pieces The flannelette Fabric (1) of fabric, the flannelette Fabric include following parts by weight material composition:
70-80 parts of polyester fiber；
65-80 parts of polyurethane fiber；
5-10 parts of complex antimicrobials；
10-15 parts of impregnation；
The production technology following steps of the flannelette Fabric:
S1: polyester fiber and polyurethane fiber are subjected to shredding, mixing, smart shredding, filtering and combing, obtain composite fibre；
S2: complex antimicrobials being uniformly mixed with impregnation, obtain maceration extract, carries out impregnation 3-5h to composite fibre；
S3: fabric obtained in S2 is dried, is fluffed, soft treatment, is formed again, hot light and cropping.
2. a kind of flannelette Fabric structure according to claim 1, it is characterised in that: under the complex antimicrobials include Column parts by weight material composition:
2-10 parts of loaded article；
1-2 parts of carrier；
The loaded article includes inorganic antiseptic and organic antibacterial agent；
Wherein the ratio between parts by weight of inorganic antiseptic and organic antibacterial agent are 2:1；
The inorganic antiseptic is rare earth oxide, and the rare earth oxide is the mixing in cerium oxide, praseodymium oxide and neodymia Object, the ratio between parts by weight are 1:1:1；
Organic antibacterial agent is 5-Chloro-2-methyl-4-isothiazolin-3-one, the double octyl ammonium chlorides of dimethyl, poly hexamethylene biguanide The mixture of hydrochloride, the ratio between parts by weight are 1:3:1；
The carrier is chitosan porous microsphere.
3. a kind of flannelette Fabric structure according to claim 1 or 2, it is characterised in that: the complex antimicrobials system It is as follows to make process:
A1: cerium oxide, praseodymium oxide, neodymia being added into 100 parts of hydrochloric acid, stirring and dissolving 5min, and 2-3 parts of addition is silane coupled The mixing of agent and 5-Chloro-2-methyl-4-isothiazolin-3-one, dimethyl double octyl ammonium chlorides, hexamethylene Object stirs evenly 0.5h, adds 3-4 parts of emulsifiers, and 3-5 parts of modified polyurethane adhesives are added in high speed dispersion, and stirring is formed Stablize antimicrobial emulsion；
Chitosan porous microsphere is added in antimicrobial emulsion obtained in a2:a1, by being uniformly mixed, is put into 90 DEG C of baking oven Heat treatment 4 hours, obtains complex antimicrobials.
4. a kind of flannelette Fabric structure according to claim 3, it is characterised in that: the silane coupling agent is silane Coupling agent KH-550, silane coupling agent KH-560, any one in Silane coupling reagent KH-570.
5. a kind of flannelette Fabric structure according to claim 3, it is characterised in that: the emulsifier is poly alkyl alcohol Any one in ethylene oxide ether or alkyl phenol polyoxyethylene ether.
6. a kind of flannelette Fabric structure according to claim 3, it is characterised in that: the modified polyurethane adhesive Synthesis step it is as follows:
B1: 50 parts of toluene di-isocyanate(TDI)s and 100 parts of polyadipate -1,4- butyl glycol ester diols are put into reflux unit In heating stirring machine, it is warming up to 70-80 DEG C, adds 2 parts of modifying agent, 2-3h is reacted, obtains performed polymer；2 parts of chain extenders are added, 1-2h is reacted, 4 parts of sealers is added, is warming up to 100-110 DEG C of reaction 1-2h；1 part of acetone viscosity reduction is added to required viscosity；
B2: being cooled to 40-50 DEG C, and 4 parts of gamma-aminopropyl-triethoxy-silanes are added dropwise, and reacts 1-2h；
B3: adding 3 parts of modifying agent, 1 part of triethylamine and 90 parts of deionized waters, above-mentioned mixed solution be put into kneading machine, turns Speed translates 2000r/min, and time 20-30min is to get modified polyurethane adhesive.
7. a kind of flannelette Fabric structure according to claim 6, it is characterised in that: the sealer is phenol, second One of base mercaptan, hydrogen cyanide or combination.
8. a kind of flannelette Fabric structure according to claim 6, it is characterised in that: the chain extender is Isosorbide-5-Nitrae-fourth two One of alcohol, diglycol, ethylenediamine or combination.
9. a kind of flannelette Fabric structure according to claim 6, it is characterised in that: the modifying agent be lignin, N- acetyl group aziridine, ferrous sulfate, ammonium sulfate, the ratio between parts by weight are 2:1:1:1.
10. a kind of flannelette Fabric structure according to claim 1, it is characterised in that: the polyester fiber is polyester Sea-island composite fiber.
CN201811245577.3A 2018-10-24 2018-10-24 High-elastic fabric structure of matte Active CN109304904B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811245577.3A CN109304904B (en) 2018-10-24 2018-10-24 High-elastic fabric structure of matte

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811245577.3A CN109304904B (en) 2018-10-24 2018-10-24 High-elastic fabric structure of matte

Publications (2)

Publication Number Publication Date
CN109304904A true CN109304904A (en) 2019-02-05
CN109304904B CN109304904B (en) 2020-05-29

Family

ID=65225397

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811245577.3A Active CN109304904B (en) 2018-10-24 2018-10-24 High-elastic fabric structure of matte

Country Status (1)

Country Link
CN (1) CN109304904B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110093704A (en) * 2019-04-28 2019-08-06 福建润博实业有限公司 A kind of comfortable school uniform of pro-skin and preparation method thereof
CN112853765A (en) * 2021-02-03 2021-05-28 百事基材料（青岛）股份有限公司 Down feather macrofiber containing active ingredients of tangerine peel, orange and pomelo and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN203058462U (en) * 2012-12-28 2013-07-17 上海林展贸易发展有限公司 Bidirectional elasticity elastic ribbon
CN206025317U (en) * 2016-08-30 2017-03-22 浙江众华家纺集团有限公司 Elastic fabric
CN108342808A (en) * 2018-02-05 2018-07-31 海宁市纵达新材料有限公司 A kind of manufacturing process of anti-microbial elastomeric fabric

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN203058462U (en) * 2012-12-28 2013-07-17 上海林展贸易发展有限公司 Bidirectional elasticity elastic ribbon
CN206025317U (en) * 2016-08-30 2017-03-22 浙江众华家纺集团有限公司 Elastic fabric
CN108342808A (en) * 2018-02-05 2018-07-31 海宁市纵达新材料有限公司 A kind of manufacturing process of anti-microbial elastomeric fabric

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110093704A (en) * 2019-04-28 2019-08-06 福建润博实业有限公司 A kind of comfortable school uniform of pro-skin and preparation method thereof
CN112853765A (en) * 2021-02-03 2021-05-28 百事基材料（青岛）股份有限公司 Down feather macrofiber containing active ingredients of tangerine peel, orange and pomelo and preparation method thereof

Also Published As

Publication number Publication date
CN109304904B (en) 2020-05-29

Similar Documents

Publication Publication Date Title
CN105544210B (en) A kind of preparation method of the fabric step treating reagent based on modified fibroin protein solution
CN104389099B (en) A kind of uvioresistant Anti-static textile fabric and preparation method thereof
CN105239389B (en) A kind of dedicated antibacterial textile fabric of baby
CN104047099B (en) The production technology of health blended knitted fabric
CN112878041A (en) High-breathability antibacterial anti-mite fabric and preparation process thereof
CN109385729A (en) A kind of antimicrobial form blended fabric and its preparation process
CN106592223A (en) Water-proofing, oil-proofing and antifouling type easy-care finishing liquid of shirt and finishing method of water-proofing, oil-proofing and antifouling type easy-care finishing liquid
CN109304904A (en) A kind of flannelette Fabric structure
CN106592104B (en) A kind of tea polyphenols cellulose fibre spunlace non-woven cloth and its production method
CN110273218A (en) A kind of Wormwood fiber bedding and preparation method thereof
CN113172956A (en) Antibacterial crease-resistant knitted fabric and preparation method thereof
CN111114038A (en) Antibacterial sportswear fabric
CN104250931B (en) A kind of mulberry Tsumugi silk silk oxford and preparation method thereof
CN108903104A (en) Intelligent waistband with microcirculation physical therapy function
CN107475861A (en) A kind of preparation method of the stretch-proof fabric containing chitosan
CN105780233A (en) Textile material and manufacture method thereof
CN108851260A (en) Intelligent brassiere with microcirculation physical therapy function
CN105887276B (en) A kind of Yoga takes the preparation method of fabric
CN106758200A (en) The uvioresistant protection type noniron finish liquid and its method for sorting of a kind of shirt
CN115679706A (en) Preparation method of insect-proof antibacterial garment fabric
CN107584835A (en) A kind of anti-bacterial flame-retardant fabric
CN107675481A (en) A kind of preparation method of fabric antibiotic finishing solution
CN102828395A (en) Manufacturing method of mould-proof and mothproof cashmere overcoat
CN114318876A (en) Medical antibacterial spinning fabric and preparation method thereof
CN106436017B (en) A kind of chitosan oligosaccharide cellulose fibre spunlace non-woven cloth and its production method

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB03 Change of inventor or designer information
CB03 Change of inventor or designer information

Inventor after: Shi Xiangyang

Inventor after: Sun Xiaodan

Inventor after: Tang Feng

Inventor after: Wu Ling

Inventor after: Wu Xiangfu

Inventor before: Shi Xiangyang

Inventor before: Sun Xiaodan

Inventor before: Yu Wei

GR01 Patent grant
GR01 Patent grant