CN111114038A - Antibacterial sportswear fabric - Google Patents

Antibacterial sportswear fabric Download PDF

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Publication number
CN111114038A
CN111114038A CN201911326425.0A CN201911326425A CN111114038A CN 111114038 A CN111114038 A CN 111114038A CN 201911326425 A CN201911326425 A CN 201911326425A CN 111114038 A CN111114038 A CN 111114038A
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CN
China
Prior art keywords
parts
fiber
fibers
protein
chitosan
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201911326425.0A
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Chinese (zh)
Inventor
张凤
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Individual
Original Assignee
Individual
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Publication date
Application filed by Individual filed Critical Individual
Priority to CN201911326425.0A priority Critical patent/CN111114038A/en
Publication of CN111114038A publication Critical patent/CN111114038A/en
Withdrawn legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
    • A41D13/0015—Sports garments other than provided for in groups A41D13/0007 - A41D13/088
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/12—Hygroscopic; Water retaining
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/24—Resistant to mechanical stress, e.g. pierce-proof
    • A41D31/245—Resistant to mechanical stress, e.g. pierce-proof using layered materials
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/30—Antimicrobial, e.g. antibacterial
    • A41D31/305—Antimicrobial, e.g. antibacterial using layered materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0013—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using multilayer webs
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0036—Polyester fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/047—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D—TEXTILES; PAPER
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    • D—TEXTILES; PAPER
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    • D06N2209/00—Properties of the materials
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    • D06N2209/1671—Resistance to bacteria, mildew, mould, fungi
    • D—TEXTILES; PAPER
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    • D06N2211/00—Specially adapted uses
    • D06N2211/10—Clothing

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Physical Education & Sports Medicine (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses an antibacterial sportswear fabric which comprises the following raw materials in parts by weight: 30-50 parts of bamboo fiber, 15-30 parts of protein fiber, 30-50 parts of modal fiber, 10-40 parts of Shengma fiber, 15-25 parts of soybean fiber, 15-25 parts of polyester fiber, 5-10 parts of chitosan, 2-8 parts of quaternary ammonium salt compound, 10-30 parts of deionized water, 12-16 parts of water-soluble silane coupling agent, 5-10 parts of organosilane, 2-8 parts of ethanol, 7-12 parts of polytetrafluoroethylene and 8-10 parts of graphite, and the invention relates to the technical field of garment fabric. This antibiotic sports wear surface fabric, bamboo fiber, albumen fiber and modal fiber have good antibacterial property and moisture absorption performance, play and disinfect and antibacterial effect, all adopt natural material to go on, environmental protection safety, with low costs, the grade is high, and the comfort level is good, and modal fiber has improved comfort level and compliance, has reached the quick-drying and comfortable wear-resisting requirement of moisture absorption, dissolves in the organosilane with the surface fabric and carries out the dipping treatment, improves textile fabric's bacterinertness.

Description

Antibacterial sportswear fabric
Technical Field
The invention relates to the technical field of garment materials, in particular to an antibacterial sportswear fabric.
Background
The garment is made of fabric, the fabric is used for making the garment and is one of three elements of the garment, the fabric can explain the style and the characteristics of the garment, the expression effects of color and shape of the garment are directly controlled, the garment presents noble and perfect self and soft hand feeling, the fabric of the garment is different in every day and in every month in the world of the garment, but the high-quality and high-grade fabric has the characteristics of wearing comfort, sweat absorption and air permeability, suspension and stiffness, high and noble vision, soft touch feeling and the like on the whole The characteristics of softness and comfort are absorbed, the advantages of firmness, wear resistance, stiff and smooth hanging, good luster, bright color and the like of the chemical fiber fabric are also absorbed, a large amount of high-grade and high-quality blended fabric is developed every year, sometimes, the clothing made of pure leather is worn, the allowance is also provided, and the general clothing fabric is divided into two series: weaving the fabric: mainly used for outerwear and shirt of clothes; knitting the fabric: underwear and sports-series garments; however, due to the development of science and technology, knitted fabrics are also developed to be thick and stiff, the knitted underwear is gradually externalized, and the knitted fabric tatting method becomes the supplement of the outer garment.
Most sportswear surface fabric generally can all consider its wear resistance earlier on the existing market, can influence the comfort that the sportswear was worn, on the other hand, the sportswear has waterproof effect, in waterproof, the gas permeability of surface fabric has been reduced, lead to the perspire not smooth, and this surface fabric hydroscopicity is relatively poor, be difficult to wash, can breed more bacterium on the perspire not smooth lead to the clothing, and have more dust absorption, be difficult for washing, bacterium on the clothing increases day by day, influence the health of wearer.
Disclosure of Invention
Aiming at the defects of the prior art, the invention provides an antibacterial sportswear fabric, and solves the problems that most sportswear fabrics in the existing market generally consider the wear resistance firstly, so that the wearing comfort of the sportswear is influenced, on the other hand, the sportswear has a waterproof effect, the air permeability of the fabrics is reduced when the sportswear is waterproof, the perspiration is not smooth, the fabric has poor water absorption, the washing is not easy, the perspiration is not smooth, so that more bacteria can be bred on clothes, more dust can be adsorbed, the clothes are not easy to wash, the bacteria on the clothes are increased increasingly, and the health of wearers is influenced.
In order to achieve the purpose, the invention is realized by the following technical scheme: an antibacterial sportswear fabric comprises the following raw materials in parts by weight: 30-50 parts of bamboo fiber, 15-30 parts of protein fiber, 30-50 parts of modal fiber, 10-40 parts of Shengma fiber, 15-25 parts of soybean fiber, 15-25 parts of polyester fiber, 5-10 parts of chitosan, 2-8 parts of quaternary ammonium salt compound, 10-30 parts of deionized water, 12-16 parts of water-soluble silane coupling agent, 5-10 parts of organosilane and 2-8 parts of
Ethanol, 7-12 parts of polytetrafluoroethylene and 8-10 parts of graphite.
Preferably, the raw materials comprise the following components: 40 parts of bamboo fiber, 22 parts of protein fiber, 40 parts of modal fiber, 25 parts of Shengma fiber, 20 parts of soybean fiber, 20 parts of polyester fiber, 7 parts of chitosan, 5 parts of quaternary ammonium salt compound, 20 parts of deionized water, 14 parts of water-soluble silane coupling agent, 7 parts of organosilane, 5 parts of ethanol, 10 parts of polytetrafluoroethylene and 9 parts of graphite.
Preferably, the raw materials comprise the following components: 30 parts of bamboo fiber, 15 parts of protein fiber, 30 parts of modal fiber, 10 parts of Shengma fiber, 15 parts of soybean fiber, 15 parts of polyester fiber, 5 parts of chitosan, 2 parts of quaternary ammonium salt compound, 10 parts of deionized water, 12 parts of water-soluble silane coupling agent, 5 parts of organosilane, 2 parts of ethanol, 7 parts of polytetrafluoroethylene and 8 parts of graphite.
Preferably, the raw materials comprise the following components: 50 parts of bamboo fiber, 30 parts of protein fiber, 50 parts of modal fiber, 40 parts of Shengma fiber, 25 parts of soybean fiber, 25 parts of polyester fiber, 10 parts of chitosan, 8 parts of quaternary ammonium salt compound, 30 parts of deionized water, 16 parts of water-soluble silane coupling agent, 10 parts of organosilane, 8 parts of ethanol, 12 parts of polytetrafluoroethylene and 10 parts of graphite.
Preferably, the water-soluble silane coupling agent has a chemical structural formula: wherein Me is-CH 3, X is-OCH 2CH3 or-OCH 3, Y is-CH ═ CH2, Z is-OH, and the molecular weight is 0.5-1.0 ten thousand.
Preferably, the protein fiber is soybean protein fiber, milk protein fiber, corn protein fiber, casein protein fiber or peanut protein fiber.
Preferably, the chitosan is N, N-trimethyl chitosan and/or diethyl methyl chitosan.
Preferably, the preparation method of the antibacterial sportswear fabric specifically comprises the following steps:
s1, preparing an inner layer fabric: firstly, selecting bamboo fibers, protein fibers and modal fibers in corresponding parts respectively, then sequentially carrying out scouring, bleaching and mercerizing pretreatment on the selected bamboo fibers, protein fibers and modal fibers, then dyeing the cotton fibers, soybean protein fibers, graphite carbon fibers and bamboo fibers after the pretreatment is finished, then cleaning the dyed fibers, then placing the fibers in a dryer for drying at the drying temperature of 75-85 ℃ so that the moisture content in the fibers is 3% -8%, controlling the drying time to be 30-50 minutes, then carrying out spinning treatment on the dried fibers through a spinning machine to obtain the bamboo fibers, protein fibers and modal fibers with required colors, and then spinning the bamboo fibers, protein fibers and modal fibers through a blending machine to obtain an inner layer fabric;
s2, preparing outer-layer fabric: firstly, selecting corresponding parts of Shengma fiber, soybean fiber and polyester fiber, then sequentially carrying out scouring, bleaching and mercerizing pretreatment on the selected Shengma fiber, soybean fiber and polyester fiber, then dyeing the Shengma fiber, soybean fiber and polyester fiber after the pretreatment is finished, cleaning the dyed fiber, then placing the dyed fiber in a dryer for drying at the drying temperature of 75-85 ℃ so that the moisture content in the fiber is less than 3%, then carrying out spinning treatment on the dried fiber through a spinning machine to obtain the Shengma fiber, soybean fiber and polyester fiber with required colors, and then spinning the Shengma fiber, soybean fiber and polyester fiber through a blending machine to obtain an outer-layer fabric;
s3, preparation of a steeping liquid: putting a proper amount of organosilane into a stirrer, then pouring a certain amount of ethanol, starting the stirrer, setting the stirring temperature at 40-60 ℃, and controlling the stirring time at 10-20 minutes to ensure that the organosilane is completely dissolved in the ethanol to form an impregnation liquid;
s4, preparation of the antibacterial finishing agent: selecting a proper amount of chitosan and quaternary ammonium salt compound in parts by weight, putting the chitosan and quaternary ammonium salt compound into a stirrer, starting the stirrer to mix the chitosan and quaternary ammonium salt compound at normal temperature, setting the mixing time to be 15-20 minutes, the stirring speed to be 58 revolutions per minute, then pouring a proper amount of deionized water and a water-soluble silane coupling agent, and stirring the mixture for 20-30 minutes at the stirring speed to be 120 revolutions per minute to obtain the antibacterial finishing agent;
s5, preparing the wear-resistant coating: selecting polytetrafluoroethylene and graphite with corresponding proportions, putting the polytetrafluoroethylene and the graphite into a mixer for mixing, wherein the stirring speed is 300-400 rpm, and the stirring time is 20-30 minutes, so as to prepare the wear-resistant coating;
s6, processing of finished products: respectively adding the antibacterial finishing agent into the inner-layer fabric prepared in the step S1 and the outer-layer fabric prepared in the step S2 for soaking for 1-2 hours, then putting the fabrics into a spinning machine, starting the spinning machine to cut the inner-layer fabric and the outer-layer fabric together, then putting the finished product into a soaking solution, treating the finished product at the temperature of 40-90 ℃ for 20-50 minutes, then taking the finished product out and putting the finished product into a drying oven for drying, spreading the finished product on a platform after drying, uniformly coating the prepared wear-resistant coating on the surface of the finished product, and then drying the finished product to obtain the antibacterial sportswear fabric.
Advantageous effects
The invention provides an antibacterial sportswear fabric. Compared with the prior art, the method has the following beneficial effects: the antibacterial sportswear fabric comprises the following raw materials in parts by weight: 30-50 parts of bamboo fiber, 15-30 parts of protein fiber, 30-50 parts of modal fiber, 10-40 parts of Shengma fiber, 15-25 parts of soybean fiber, 15-25 parts of polyester fiber, 5-10 parts of chitosan, 2-8 parts of quaternary ammonium salt compound, 10-30 parts of deionized water, 12-16 parts of water-soluble silane coupling agent, 5-10 parts of organosilane, 2-8 parts of ethanol, 7-12 parts of polytetrafluoroethylene and 8-10 parts of graphite, wherein the chemical structural formula of the water-soluble silane coupling agent is as follows: wherein Me is-CH 3, X is-OCH 2CH3 or-OCH 3, Y is-CH ═ CH2, Z is-OH, the molecular weight is 0.5-1.0 ten thousand, the protein fiber is soybean protein fiber, milk protein fiber, corn protein fiber, casein fiber or peanut protein fiber, the chitosan is N, N, N-trimethyl chitosan and/or diethyl methyl chitosan, the bamboo fiber, the protein fiber and the modal fiber have good antibacterial performance and moisture absorption performance, the sterilization and bacteriostasis effects are achieved, natural materials are adopted, the environment is protected, the safety is achieved, the cost is low, the grade is high, the comfort level is good, the comfort level and the softness are improved through the modal fiber, the requirements of moisture absorption, quick drying, comfort and wear resistance are met, the clothing fabric is dissolved in organic silane for dipping treatment, the antibacterial property of the textile fabric is improved, and the integral antibacterial property and the wear resistance are enhanced.
Detailed Description
The following will clearly and completely describe the technical solutions in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention provides three technical schemes: an antibacterial sportswear fabric comprises the following raw materials in parts by weight: 30-50 parts of bamboo fiber, 15-30 parts of protein fiber, 30-50 parts of modal fiber, 10-40 parts of Shengma fiber, 15-25 parts of soybean fiber, 15-25 parts of polyester fiber, 5-10 parts of chitosan, 2-8 parts of quaternary ammonium salt compound, 10-30 parts of deionized water, 12-16 parts of water-soluble silane coupling agent, 5-10 parts of organosilane, 2-8 parts of ethanol, 7-12 parts of polytetrafluoroethylene and 8-10 parts of graphite.
In the invention, the raw materials comprise the following components in parts by weight: 30-50 parts of bamboo fiber, 15-30 parts of protein fiber, 30-50 parts of modal fiber, 10-40 parts of Shengma fiber, 15-25 parts of soybean fiber, 15-25 parts of polyester fiber, 5-10 parts of chitosan, 2-8 parts of quaternary ammonium salt compound, 10-30 parts of deionized water, 12-16 parts of water-soluble silane coupling agent, 5-10 parts of organosilane and 2-8 parts of
Ethanol, 7-12 parts of polytetrafluoroethylene and 8-10 parts of graphite.
In the invention, the raw materials comprise the following components: 30 parts of bamboo fiber, 15 parts of protein fiber, 30 parts of modal fiber, 10 parts of Shengma fiber, 15 parts of soybean fiber, 15 parts of polyester fiber, 5 parts of chitosan, 2 parts of quaternary ammonium salt compound, 10 parts of deionized water, 12 parts of water-soluble silane coupling agent, 5 parts of organosilane, 2 parts of ethanol, 7 parts of polytetrafluoroethylene and 8 parts of graphite.
In the invention, the raw materials comprise the following components: 50 parts of bamboo fiber, 30 parts of protein fiber, 50 parts of modal fiber, 40 parts of Shengma fiber, 25 parts of soybean fiber, 25 parts of polyester fiber, 10 parts of chitosan, 8 parts of quaternary ammonium salt compound, 30 parts of deionized water, 16 parts of water-soluble silane coupling agent, 10 parts of organosilane, 8 parts of ethanol, 12 parts of polytetrafluoroethylene and 10 parts of graphite.
In the invention, the chemical structural formula of the water-soluble silane coupling agent is as follows: wherein Me is-CH 3, X is-OCH 2CH3 or-OCH 3, Y is-CH ═ CH2, Z is-OH, and the molecular weight is 0.5-1.0 ten thousand.
In the invention, the protein fiber is soybean protein fiber, milk protein fiber, corn protein fiber, casein fiber or peanut protein fiber.
In the invention, the chitosan is N, N, N-trimethyl chitosan and/or diethyl methyl chitosan.
A preparation method of an antibacterial sportswear fabric specifically comprises the following embodiments:
example 1
S1, preparing an inner layer fabric: firstly, respectively selecting 40 parts of bamboo fibers, 22 parts of protein fibers and 40 parts of modal fibers, then sequentially carrying out scouring, bleaching and mercerizing pretreatment on the selected bamboo fibers, protein fibers and modal fibers, then dyeing the cotton fibers, soybean protein fibers, graphite carbon fibers and bamboo fibers after the pretreatment is finished, then cleaning the dyed fibers, then placing the fibers in a dryer for drying at the drying temperature of 80 ℃, controlling the moisture content in the fibers to be 5% and the drying time to be 40 minutes, then carrying out spinning treatment on the dried fibers through a spinning machine to obtain the bamboo fibers, protein fibers and modal fibers with required colors, and then spinning the bamboo fibers, protein fibers and modal fibers through a blending machine to obtain an inner layer fabric;
s2, preparing outer-layer fabric: firstly, respectively selecting 25 parts of Shengma fiber, 20 parts of soybean fiber and 20 parts of polyester fiber, then sequentially carrying out scouring, bleaching and mercerizing pretreatment on the selected Shengma fiber, soybean fiber and polyester fiber, then dyeing the Shengma fiber, soybean fiber and polyester fiber after the pretreatment is finished, cleaning the dyed fiber, then placing the dyed fiber in a dryer for drying at the drying temperature of 80 ℃ so that the moisture content in the fiber is less than 3%, then carrying out spinning treatment on the dried fiber through a spinning machine to obtain the Shengma fiber, soybean fiber and polyester fiber with the required color, and then spinning the Shengma fiber, soybean fiber and polyester fiber through a blending machine to obtain an outer-layer fabric;
s3, preparation of a steeping liquid: putting 7 parts of organosilane into a stirrer, then pouring 5 parts of ethanol, starting the stirrer, setting the stirring temperature at 50 ℃, and controlling the stirring time at 15 minutes to ensure that the organosilane is completely dissolved in the ethanol to form a steeping fluid;
s4, preparation of the antibacterial finishing agent: selecting 7 parts of chitosan and 5 parts of quaternary ammonium salt compound, putting the chitosan and the quaternary ammonium salt compound into a stirrer, starting the stirrer to mix the chitosan and the quaternary ammonium salt compound at normal temperature, setting the mixing time to be 17 minutes, and the stirring speed to be 58 revolutions per minute, then pouring 20 parts of deionized water and 14 parts of water-soluble silane coupling agent, and stirring the mixture for 25 minutes at the stirring speed to be 120 revolutions per minute to obtain the antibacterial finishing agent;
s5, preparing the wear-resistant coating: selecting 10 parts of polytetrafluoroethylene and 9 parts of graphite, and putting the polytetrafluoroethylene and the graphite into a mixer for mixing, wherein the stirring speed is 350 revolutions per minute, and the stirring time is 25 minutes, so as to prepare the wear-resistant coating;
s6, processing of finished products: respectively adding the antibacterial finishing agent into the inner-layer fabric prepared in the step S1 and the outer-layer fabric prepared in the step S2 for soaking for 1.5 hours, then putting the fabrics into a spinning machine, starting the spinning machine to cut the inner-layer fabric and the outer-layer fabric together, then putting the finished product into a soaking solution, treating the finished product at the temperature of 65 ℃ for 35 minutes, then taking out the finished product, putting the finished product into a drying oven for drying, flatly paving the finished product on a platform after drying, uniformly coating the prepared wear-resistant coating on the surface of the finished product, and then drying the finished product to obtain the antibacterial sportswear fabric.
Example 2
S1, preparing an inner layer fabric: firstly, respectively selecting 30 parts of bamboo fibers, 15 parts of protein fibers and 30 parts of modal fibers, then sequentially carrying out scouring, bleaching and mercerizing pretreatment on the selected bamboo fibers, protein fibers and modal fibers, then dyeing the cotton fibers, soybean protein fibers, graphite carbon fibers and bamboo fibers after the pretreatment is finished, then cleaning the dyed fibers, then placing the fibers in a dryer for drying at the drying temperature of 75 ℃ so that the moisture content in the fibers is 3%, controlling the drying time to be 30 minutes, then carrying out spinning treatment on the dried fibers through a spinning machine to obtain the bamboo fibers, protein fibers and modal fibers with required colors, and then spinning the bamboo fibers, protein fibers and modal fibers through a blending machine to obtain an inner layer fabric;
s2, preparing outer-layer fabric: firstly, respectively selecting 10 parts of Shengma fiber, 15 parts of soybean fiber and 15 parts of polyester fiber, then sequentially carrying out scouring, bleaching and mercerizing pretreatment on the selected Shengma fiber, soybean fiber and polyester fiber, then dyeing the Shengma fiber, soybean fiber and polyester fiber after the pretreatment is finished, cleaning the dyed fiber, then placing the dyed fiber in a dryer for drying at the drying temperature of 75 ℃ to ensure that the moisture content in the fiber is less than 3%, then carrying out spinning treatment on the dried fiber through a spinning machine to obtain the Shengma fiber, soybean fiber and polyester fiber with required colors, and then spinning the Shengma fiber, soybean fiber and polyester fiber through a blending machine to obtain an outer-layer fabric;
s3, preparation of a steeping liquid: putting 5 parts of organosilane into a stirrer, then pouring 2 parts of ethanol, starting the stirrer, setting the stirring temperature at 40 ℃, and controlling the stirring time at 10 minutes to ensure that the organosilane is completely dissolved in the ethanol to form a steeping fluid;
s4, preparation of the antibacterial finishing agent: selecting 5 parts of chitosan and 2 parts of quaternary ammonium salt compound, putting the chitosan and the quaternary ammonium salt compound into a stirrer, starting the stirrer to mix the chitosan and the quaternary ammonium salt compound at normal temperature, setting the mixing time to be 15 minutes, and the stirring speed to be 58 revolutions per minute, then pouring 10 parts of deionized water and 12 parts of water-soluble silane coupling agent, and stirring the mixture for 20 minutes at the stirring speed to be 120 revolutions per minute to obtain the antibacterial finishing agent;
s5, preparing the wear-resistant coating: selecting 7 parts of polytetrafluoroethylene and 8 parts of graphite, and putting the polytetrafluoroethylene and the graphite into a mixer for mixing, wherein the stirring speed is 300 revolutions per minute, and the stirring time is 20 minutes, so as to prepare the wear-resistant coating;
s6, processing of finished products: respectively adding the antibacterial finishing agent into the inner-layer fabric prepared in the step S1 and the outer-layer fabric prepared in the step S2 for soaking for 1 hour, then putting the fabrics into a spinning machine, starting the spinning machine to cut the inner-layer fabric and the outer-layer fabric together, then putting the finished product into a soaking solution, treating the fabric at the temperature of 40 ℃ for 20 minutes, then taking out the fabric, putting the fabric into a drying oven for drying, spreading the finished product on a platform after drying, uniformly coating the prepared wear-resistant coating on the surface of the fabric, and then drying the fabric to obtain the antibacterial sportswear fabric.
Example 3
S1, preparing an inner layer fabric: firstly, respectively selecting 50 parts of bamboo fibers, 30 parts of protein fibers and 50 parts of modal fibers, then sequentially carrying out scouring, bleaching and mercerizing pretreatment on the selected bamboo fibers, protein fibers and modal fibers, then dyeing the cotton fibers, soybean protein fibers, graphite carbon fibers and bamboo fibers after the pretreatment is finished, then cleaning the dyed fibers, then placing the fibers in a dryer for drying at the drying temperature of 85 ℃, controlling the moisture content in the fibers to be 8% and the drying time to be 50 minutes, then carrying out spinning treatment on the dried fibers through a spinning machine to obtain the bamboo fibers, protein fibers and modal fibers with required colors, and then spinning the bamboo fibers, protein fibers and modal fibers through a blending machine to obtain an inner layer fabric;
s2, preparing outer-layer fabric: firstly, respectively selecting 40 parts of Shengma fiber, 25 parts of soybean fiber and 25 parts of polyester fiber, then sequentially carrying out scouring, bleaching and mercerizing pretreatment on the selected Shengma fiber, soybean fiber and polyester fiber, then dyeing the Shengma fiber, soybean fiber and polyester fiber after the pretreatment is finished, cleaning the dyed fiber, then placing the dyed fiber in a dryer for drying at the drying temperature of 85 ℃ to ensure that the moisture content in the fiber is less than 3%, then carrying out spinning treatment on the dried fiber through a spinning machine to obtain the Shengma fiber, soybean fiber and polyester fiber with required colors, and then spinning the Shengma fiber, soybean fiber and polyester fiber through a blending machine to obtain an outer-layer fabric;
s3, preparation of a steeping liquid: putting 10 parts of organosilane into a stirrer, then pouring 8 parts of ethanol, starting the stirrer, setting the stirring temperature at 60 ℃, and controlling the stirring time at 20 minutes to ensure that the organosilane is completely dissolved in the ethanol to form a steeping fluid;
s4, preparation of the antibacterial finishing agent: selecting 10 parts of chitosan and 8 parts of quaternary ammonium salt compound, putting the chitosan and the quaternary ammonium salt compound into a stirrer, starting the stirrer to mix the chitosan and the quaternary ammonium salt compound at normal temperature, setting the mixing time to be 20 minutes, and the stirring speed to be 58 revolutions per minute, then pouring 30 parts of deionized water and 16 parts of water-soluble silane coupling agent, and stirring the mixture for 30 minutes at the stirring speed to be 120 revolutions per minute to obtain the antibacterial finishing agent;
s5, preparing the wear-resistant coating: selecting 12 parts of polytetrafluoroethylene and 10 parts of graphite, and putting the polytetrafluoroethylene and the graphite into a mixer for mixing, wherein the stirring speed is 400 revolutions per minute, and the stirring time is 30 minutes, so as to prepare the wear-resistant coating;
s6, processing of finished products: respectively adding the antibacterial finishing agent into the inner-layer fabric prepared in the step S1 and the outer-layer fabric prepared in the step S2 for soaking for 2 hours, then putting the fabrics into a spinning machine, starting the spinning machine to cut the inner-layer fabric and the outer-layer fabric together, then putting the finished product into a soaking solution, treating the fabric at the temperature of 90 ℃ for 50 minutes, then taking out the fabric, putting the fabric into a drying oven for drying, spreading the finished product on a platform after drying, uniformly coating the prepared wear-resistant coating on the surface of the fabric, and then drying the fabric to obtain the antibacterial sportswear fabric.
And those not described in detail in this specification are well within the skill of those in the art.
Effects of the embodiment
A certain garment material processing factory randomly selects 30 workers to test the garment material for sports, wherein 10 workers are selected to test the garment material manufactured by the manufacturing method of the embodiment 1 of the invention, 10 workers are selected to test the garment material manufactured by the manufacturing method of the embodiment 2 of the invention, and the remaining 10 workers test the garment material manufactured by the manufacturing method of the embodiment 3 of the invention, and after 30 workers test, the tested effect is recorded.
Experimental chart
Figure BDA0002328495050000121
Figure BDA0002328495050000131
As shown in the above table, the heat preservation effect produced in this embodiment 1 is the best, the ready-made clothes are made, after one day of wearing, the bacteria adsorption rate on the clothes is 10%, the wear resistance is good, the bamboo fiber, the protein fiber and the modal fiber have good antibacterial performance and moisture absorption performance, and the sterilization and bacteriostasis effects are achieved.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (8)

1. An antibacterial sportswear fabric is characterized in that: the raw materials comprise the following components in parts by weight: 30-50 parts of bamboo fiber, 15-30 parts of protein fiber, 30-50 parts of modal fiber, 10-40 parts of Shengma fiber, 15-25 parts of soybean fiber, 15-25 parts of polyester fiber, 5-10 parts of chitosan, 2-8 parts of quaternary ammonium salt compound, 10-30 parts of deionized water, 12-16 parts of water-soluble silane coupling agent, 5-10 parts of organosilane, 2-8 parts of ethanol, 7-12 parts of polytetrafluoroethylene and 8-10 parts of graphite.
2. The antibacterial sportswear fabric according to claim 1, characterized in that: the raw materials comprise the following components: 40 parts of bamboo fiber, 22 parts of protein fiber, 40 parts of modal fiber, 25 parts of Shengma fiber, 20 parts of soybean fiber, 20 parts of polyester fiber, 7 parts of chitosan, 5 parts of quaternary ammonium salt compound, 20 parts of deionized water, 14 parts of water-soluble silane coupling agent, 7 parts of organosilane, 5 parts of ethanol, 10 parts of polytetrafluoroethylene and 9 parts of graphite.
3. The antibacterial sportswear fabric according to claim 1, characterized in that: the raw materials comprise the following components: 30 parts of bamboo fiber, 15 parts of protein fiber, 30 parts of modal fiber, 10 parts of Shengma fiber, 15 parts of soybean fiber, 15 parts of polyester fiber, 5 parts of chitosan, 2 parts of quaternary ammonium salt compound, 10 parts of deionized water, 12 parts of water-soluble silane coupling agent, 5 parts of organosilane, 2 parts of ethanol, 7 parts of polytetrafluoroethylene and 8 parts of graphite.
4. The antibacterial sportswear fabric according to claim 1, characterized in that: the raw materials comprise the following components: 50 parts of bamboo fiber, 30 parts of protein fiber, 50 parts of modal fiber, 40 parts of Shengma fiber, 25 parts of soybean fiber, 25 parts of polyester fiber, 10 parts of chitosan, 8 parts of quaternary ammonium salt compound, 30 parts of deionized water, 16 parts of water-soluble silane coupling agent, 10 parts of organosilane, 8 parts of ethanol, 12 parts of polytetrafluoroethylene and 10 parts of graphite.
5. The antibacterial sportswear fabric according to claim 1, characterized in that: the water-soluble silane coupling agent has a chemical structural formula as follows: wherein Me is-CH 3, X is-OCH 2CH3 or-OCH 3, Y is-CH ═ CH2, Z is-OH, and the molecular weight is 0.5-1.0 ten thousand.
6. The antibacterial sportswear fabric according to claim 1, characterized in that: the protein fiber is soybean protein fiber, milk protein fiber, corn protein fiber, casein fiber or peanut protein fiber.
7. The antibacterial sportswear fabric according to claim 1, characterized in that: the chitosan is N, N, N-trimethyl chitosan and/or diethyl methyl chitosan.
8. The antibacterial sportswear fabric according to claim 1, characterized in that: the preparation method specifically comprises the following steps:
s1, preparing an inner layer fabric: firstly, selecting bamboo fibers, protein fibers and modal fibers in corresponding parts respectively, then sequentially carrying out scouring, bleaching and mercerizing pretreatment on the selected bamboo fibers, protein fibers and modal fibers, then dyeing the cotton fibers, soybean protein fibers, graphite carbon fibers and bamboo fibers after the pretreatment is finished, then cleaning the dyed fibers, then placing the fibers in a dryer for drying at the drying temperature of 75-85 ℃ so that the moisture content in the fibers is 3% -8%, controlling the drying time to be 30-50 minutes, then carrying out spinning treatment on the dried fibers through a spinning machine to obtain the bamboo fibers, protein fibers and modal fibers with required colors, and then spinning the bamboo fibers, protein fibers and modal fibers through a blending machine to obtain an inner layer fabric;
s2, preparing outer-layer fabric: firstly, selecting corresponding parts of Shengma fiber, soybean fiber and polyester fiber, then sequentially carrying out scouring, bleaching and mercerizing pretreatment on the selected Shengma fiber, soybean fiber and polyester fiber, then dyeing the Shengma fiber, soybean fiber and polyester fiber after the pretreatment is finished, cleaning the dyed fiber, then placing the dyed fiber in a dryer for drying at the drying temperature of 75-85 ℃ so that the moisture content in the fiber is less than 3%, then carrying out spinning treatment on the dried fiber through a spinning machine to obtain the Shengma fiber, soybean fiber and polyester fiber with required colors, and then spinning the Shengma fiber, soybean fiber and polyester fiber through a blending machine to obtain an outer-layer fabric;
s3, preparation of a steeping liquid: putting a proper amount of organosilane into a stirrer, then pouring a certain amount of ethanol, starting the stirrer, setting the stirring temperature at 40-60 ℃, and controlling the stirring time at 10-20 minutes to ensure that the organosilane is completely dissolved in the ethanol to form an impregnation liquid;
s4, preparation of the antibacterial finishing agent: selecting a proper amount of chitosan and quaternary ammonium salt compound in parts by weight, putting the chitosan and quaternary ammonium salt compound into a stirrer, starting the stirrer to mix the chitosan and quaternary ammonium salt compound at normal temperature, setting the mixing time to be 15-20 minutes, the stirring speed to be 58 revolutions per minute, then pouring a proper amount of deionized water and a water-soluble silane coupling agent, and stirring the mixture for 20-30 minutes at the stirring speed to be 120 revolutions per minute to obtain the antibacterial finishing agent;
s5, preparing the wear-resistant coating: selecting polytetrafluoroethylene and graphite with corresponding proportions, putting the polytetrafluoroethylene and the graphite into a mixer for mixing, wherein the stirring speed is 300-400 rpm, and the stirring time is 20-30 minutes, so as to prepare the wear-resistant coating;
s6, processing of finished products: respectively adding the antibacterial finishing agent into the inner-layer fabric prepared in the step S1 and the outer-layer fabric prepared in the step S2 for soaking for 1-2 hours, then putting the fabrics into a spinning machine, starting the spinning machine to cut the inner-layer fabric and the outer-layer fabric together, then putting the finished product into a soaking solution, treating the finished product at the temperature of 40-90 ℃ for 20-50 minutes, then taking the finished product out and putting the finished product into a drying oven for drying, spreading the finished product on a platform after drying, uniformly coating the prepared wear-resistant coating on the surface of the finished product, and then drying the finished product to obtain the antibacterial sportswear fabric.
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CN113403739A (en) * 2021-06-16 2021-09-17 红豆集团无锡红豆童装有限公司 Organic cotton chitosan fiber blended yarn knitted fabric and preparation method thereof
CN114032632A (en) * 2021-11-29 2022-02-11 福建长源纺织有限公司 Antibacterial blended yarn, fabric and preparation method thereof
CN115474807A (en) * 2022-07-25 2022-12-16 浙江蚕缘家纺股份有限公司 High-fluffiness silk quilt manufacturing process

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CN108486878A (en) * 2018-04-13 2018-09-04 浙江肯特科技股份有限公司 A kind of preparation method of antibacterial functions bedclothes fabric
CN109868546A (en) * 2019-01-21 2019-06-11 杭州锦绣工坊工艺品有限公司 A kind of environment-friendly type graphene nano textile fabric and its preparation process
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CN113403739A (en) * 2021-06-16 2021-09-17 红豆集团无锡红豆童装有限公司 Organic cotton chitosan fiber blended yarn knitted fabric and preparation method thereof
CN114032632A (en) * 2021-11-29 2022-02-11 福建长源纺织有限公司 Antibacterial blended yarn, fabric and preparation method thereof
CN115474807A (en) * 2022-07-25 2022-12-16 浙江蚕缘家纺股份有限公司 High-fluffiness silk quilt manufacturing process

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