CN108097005A - Multi-functional dry powder environmental improvement agent and its preparation method and application - Google Patents
Multi-functional dry powder environmental improvement agent and its preparation method and application Download PDFInfo
- Publication number
- CN108097005A CN108097005A CN201810022231.0A CN201810022231A CN108097005A CN 108097005 A CN108097005 A CN 108097005A CN 201810022231 A CN201810022231 A CN 201810022231A CN 108097005 A CN108097005 A CN 108097005A
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- dry powder
- environmental improvement
- improvement agent
- montmorillonite
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/26—Drying gases or vapours
- B01D53/28—Selection of materials for use as drying agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/58—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/70—Organic acids
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/80—Water
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/91—Bacteria; Microorganisms
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0266—Other waste gases from animal farms
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- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Fodder In General (AREA)
Abstract
The invention discloses a kind of multi-functional dry powder environmental improvement agents, it is characterised in that:Count by weight percentage, formula includes:Montmorillonite 70~75%, zeolite powder 20~25%, vitamin C 1~2%, silica 1~3%, organic acid 2~5%.The dry powder environmental improvement agent of the present invention is used for the improvement of fowl and livestock farm environment, reduces ambient humidity, absorption pernicious gas (such as ammonia, sulfurous gas), while reduces Animal stress power.
Description
Technical field
The present invention relates to aquaculture fields, the particularly multi-functional dry powder environmental improvement agent for farm.
Background technology
It is moist, dirty it is smelly, it is sultry or it is clammy in winter-spring season be a great problem for perplexing China's pig raising dealer, it is while moist
And pernicious gas is not only the hotbed of pathogenic microorganism breeding, and animal is also easily allowed to generate stress reaction and reduce resistance.It is special
It is not Large-scale pig farm, since cultivation density is big, more a large amount of pathogens can be caused to be bred in colony house, and then influences animal and be good for
Health reduces culture benefit.And farm largely uses disinfectant spray disinfectant as reduction pathogen major measure at present, and into
One step adds the humidity in cultivation place, causes a kind of vicious circle.
For this purpose, pig farm is mostly used greatly montmorillonite as moisture absorption functional product at present, but its moisture absorption ability is weaker, and base
This is without suction ammonia ability.
The content of the invention
To solve the above problems, it is an object of the invention to provide a kind of multi-functional dry powder environmental improvement agent, for changing
The ambient humidity on kind pig farm, absorption pernicious gas (such as ammonia, sulfurous gas), while Animal stress power is reduced, and ensure
Animal health improves culture benefit.
The object of the present invention is achieved like this:A kind of multifunctionality dry powder environmental improvement agent, it is characterised in that:By weight
Percentage calculation, formula include:Montmorillonite 70~75%, zeolite powder 20~25%, vitamin C 1~2%, silica 1~
3%, organic acid 2~5%.
The formula includes:Montmorillonite 70%, zeolite powder 25%, vitamin C 1%, silica 1 %, organic acid
3%.
The organic acid is selected from least one of citric acid, oxalic acid or malic acid.
The specific surface area of the silica is 200~300m2/g。
The preparation method of above-mentioned multifunctionality dry powder environmental improvement agent, it is characterised in that including following sequential steps:(1) exist
The montmorillonite of 1/5~1/4 formula ratio is added in mixing arrangement, the silica, vitamin C and organic acid of formula ratio is added in, mixes
It closes 8~12 minutes;(2) remaining montmorillonite and whole amount zeolite powder are added, is mixed 25~35 minutes, prepares and completes.
Above-mentioned multifunctionality dry powder environmental improvement agent is applied to fowl and livestock farm.
The multifunctionality dry powder environmental improvement agent is applied to fowl and livestock farm, is spread with hand or air blower sprays, made for the first time
Use 45-55g/m2, routine use 25-35g/m2, 1 week 1~2 time, appropriate dosage during wet weather.
The dry powder environmental improvement agent of the present invention is used for the improvement of fowl and livestock farm environment, reduces ambient humidity, and absorption is harmful
Gas (such as ammonia, sulfurous gas), while reduce Animal stress power.
Specific embodiment
The present invention is a kind of multi-functional dry powder environmental improvement agent, and count by weight percentage, formula includes:Montmorillonite 70
~75%, zeolite powder 20~25%, vitamin C 1~2%, silica 1~3%, organic acid 2~5%.
The organic acid is selected from least one of citric acid, oxalic acid or malic acid.
The silica is amorphous silica, and specific surface area is preferably 200~300m2/g。
Montmorillonite and silica in formula can effectively improve the humidity on animal house ground, be provided to livestock and poultry comfortable raw
Environment living inhibits animal house pathogen and multiplies, pathogen sum is dropped under infection risk line.Zeolite powder in formula has absorption
The function of ammonia in addition the chemical substances such as organic acid and ammonia, sulphur make acid-base neutralization, has the function that reduce pernicious gas, reaches and disappear
The effect of removing and harmful gas.Vitamin C in formula can effectively reduce Animal stress, improve animal resistance.Environmental stress meeting
The synthesis and utilization of pig body ascorbic acid are influenced, so as to cause hypovitaminosis C in pig body.This formula is by adding vitamin C
Can effectively slow down stress, reduce the morbidity chance of swinery, while vitamin C can reduce body capillary during heat stress and lead to
Permeability enhances body's resistance to disease, mitigates hepatic cell fattydegeneration, reduces the death rate.
The preparation method of above-mentioned multifunctionality dry powder environmental improvement agent, including following sequential steps:(1) in mixing arrangement
The montmorillonite of 1/5~1/4 formula ratio is added in, adds in the silica, vitamin C and organic acid of formula ratio, mixes 2~12 points
Clock;(2) remaining montmorillonite and whole amount zeolite powder are added, is mixed 25~35 minutes, prepares and completes.This method is by small content
Ingredient is first pre-mixed, then is mixed with other big content ingredients, so can guarantee that small content ingredient can be uniformly mixed.
Above-mentioned multifunctionality dry powder environmental improvement agent is applied to fowl and livestock farm (such as pig farm column home).In application, with
Hand is spread or air blower sprinkling, for the first time using 45-55g/m2, routine use 25-35g/m2, it is preferred that for the first time using 50g/m2, day
Often use 30g/m2, 1 week 1~2 time, appropriate dosage during wet weather.
Below by way of specific example, the present invention is further elaborated, but the present invention is simultaneously limited to this specific examples in portion.
Embodiment 1
Formula:Montmorillonite:700g, zeolite powder:250g, vitamin C:10g, silica:10g, citric acid:30g.
Preparation method:The montmorillonite of 1/5 formula ratio is added in mixing arrangement, adds in silica, the dimension life of formula ratio
Plain C and citric acid mix 10 minutes;(2) remaining montmorillonite and whole amount zeolite powder are added, mixes 30 minutes, has prepared
Into.
Comparative example 1
Formula:Montmorillonite:710g, zeolite powder:250g, vitamin C:10g, silica:0g, citric acid:30g.It prepares
Method is the same as embodiment 1.
Comparative example 1 is on the basis of the formula of embodiment 1, does not add silica, and increases 10g montmorillonites, investigates two
" Absorbance ratio-derivative method " of group of formula.In general, Absorbance ratio-derivative method value is bigger, and physical absorption ability is stronger, to moisture in air, gas,
The adsorption capacities such as microorganism are also stronger.Method is using GB/T 20973-2007 detection methods.As a result it is as follows:
Index | Comparative example 1 | Embodiment 1 | It is opposite to improve (%) |
Absorbance ratio-derivative method (g/100g) | 32.46 | 43.10 | 32.8% |
Comparative example 2
Formula:Montmorillonite:700g, zeolite powder:280g, vitamin C:10g, silica:10g, citric acid:0g.It prepares
Method is the same as embodiment 1.
Comparative example 2 is on the basis of upper embodiment 1 formula, does not add organic acid, and increases 30g zeolite powders, investigates two
" the suction ammonia amount " of group of formula.In general, absorbability of the product to ammonia in air can be embodied indirectly by inhaling ammonia amount, and value is got over
Greatly, it is stronger to inhale ammonia ability.Method is using GBT 21695-2008 detection methods.As a result it is as follows:
Index | Comparative example 2 | Embodiment 1 | It is opposite to improve (%) |
Inhale ammonia amount (mmol/100g) | 89.32 | 114.65 | 28.4% |
Comparative example 3
Certain existing commercially available product, mark ingredient are:Montmorillonite, zeolite powder, antimicrobial component, usage amount 30g~50g/m2。
Do practical effect control on Jieyang pig farm, using using before product with investigating three respectively after using product
Index, air humidity (being detected using hygrometer), air ammonia concentration (being detected using ammonia detector), ground total number of bacteria
(separately sampled after before use and when use 24 is small, the sampling of surface smear method, the culture of laboratory cultures base).As a result such as table 1, table 2.
Table 1. is compareed using each index of certain commercially available product
Index | Before use | Behind commercial product |
Air humidity (%RH) | 76 | 59 |
Air ammonia concentration (mg/m3) | 19 | 14 |
Ground total number of bacteria (a/cm2) | 3.2×106 | 2.7×105 |
Table 2. is compareed using each index of this dry powder environmental improvement agent formulation product
Index | Before use | After 1 product of embodiment |
Air humidity (%RH) | 77 | 51 |
Air ammonia concentration (mg/m3) | 17 | 6 |
Ground total number of bacteria (a/cm2) | 4.6×106 | 6.9×104 |
Embodiment 2
Formula:Montmorillonite:700g, zeolite powder:200g, vitamin C:20g, silica:30g, malic acid:50g.It prepares
Method is the same as embodiment 1.
Embodiment 3
Formula:Montmorillonite:750g, zeolite powder:200g, vitamin C:10g, silica:20g, citric acid and oxalic acid:
20g.Preparation method is the same as embodiment 1.
Embodiment 4
Formula:Montmorillonite:730g, zeolite powder:220g, vitamin C:20g, silica:10g, oxalic acid:20g.Preparation side
Method is the same as embodiment 1.
Claims (7)
1. a kind of multifunctionality dry powder environmental improvement agent, it is characterised in that:Count by weight percentage, formula includes:Montmorillonite
70~75%, zeolite powder 20~25%, vitamin C 1~2%, silica 1~3%, organic acid 2~5%.
2. multifunctionality dry powder environmental improvement agent according to claim 1, it is characterised in that:The formula includes:It covers
De- stone 70%, zeolite powder 25%, vitamin C 1%, silica 1 %, organic acid 3%.
3. multifunctionality dry powder environmental improvement agent according to claim 1, it is characterised in that:The organic acid is selected from lemon
At least one of lemon acid, oxalic acid or malic acid.
4. multifunctionality dry powder environmental improvement agent according to claim 1, it is characterised in that:The ratio of the silica
Surface area is 200~300m2/g。
5. the preparation method of multi-functional dry powder environmental improvement agent described in the arbitrary claims of claim 1-4, it is characterised in that
Including following sequential steps:(1) montmorillonite of 1/5~1/4 formula ratio is added in mixing arrangement, adds in the titanium dioxide of formula ratio
Silicon, vitamin C and organic acid mix 8~12 minutes;(2) remaining montmorillonite and whole amount zeolite powder are added, mixing 25~
It 35 minutes, prepares and completes.
6. the above-mentioned multi-functional dry powder environmental improvement agent of the arbitrary claim institutes of claim 1-4 is applied to fowl and livestock farm.
7. multi-functional dry powder environmental improvement agent is applied to fowl and livestock farm according to claim 6, spread with hand or air blower
Sprinkling, for the first time using 45-55g/m2, routine use 25-35g/m2, 1 week 1~2 time, appropriate dosage during wet weather.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110367193A (en) * | 2019-08-13 | 2019-10-25 | 北京桃古图生物科技有限公司 | It is a kind of for improve cultivation colony house environment improver and its preparation method and application |
CN111888929A (en) * | 2020-08-04 | 2020-11-06 | 广东海大集团股份有限公司 | Dry powder type environment improver for livestock and poultry breeding and preparation method and application thereof |
CN117427481A (en) * | 2023-08-24 | 2024-01-23 | 葫芦岛康达环保工贸有限公司 | Deodorant based on nano silicon dioxide modification and preparation method thereof |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110367193A (en) * | 2019-08-13 | 2019-10-25 | 北京桃古图生物科技有限公司 | It is a kind of for improve cultivation colony house environment improver and its preparation method and application |
CN111888929A (en) * | 2020-08-04 | 2020-11-06 | 广东海大集团股份有限公司 | Dry powder type environment improver for livestock and poultry breeding and preparation method and application thereof |
CN117427481A (en) * | 2023-08-24 | 2024-01-23 | 葫芦岛康达环保工贸有限公司 | Deodorant based on nano silicon dioxide modification and preparation method thereof |
CN117427481B (en) * | 2023-08-24 | 2024-04-09 | 葫芦岛康达环保工贸有限公司 | Deodorant based on nano silicon dioxide modification and preparation method thereof |
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