CN108097005A - Multi-functional dry powder environmental improvement agent and its preparation method and application - Google Patents

Multi-functional dry powder environmental improvement agent and its preparation method and application Download PDF

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Publication number
CN108097005A
CN108097005A CN201810022231.0A CN201810022231A CN108097005A CN 108097005 A CN108097005 A CN 108097005A CN 201810022231 A CN201810022231 A CN 201810022231A CN 108097005 A CN108097005 A CN 108097005A
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CN
China
Prior art keywords
dry powder
environmental improvement
improvement agent
montmorillonite
vitamin
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Pending
Application number
CN201810022231.0A
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Chinese (zh)
Inventor
尹曲平
郑庆禄
许详
冷淑珍
刘露
吴兴玉
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GUANGZHOU HIGH-STEP CHEMICAL Co Ltd
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GUANGZHOU HIGH-STEP CHEMICAL Co Ltd
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Priority to CN201810022231.0A priority Critical patent/CN108097005A/en
Publication of CN108097005A publication Critical patent/CN108097005A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/26Drying gases or vapours
    • B01D53/28Selection of materials for use as drying agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/58Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/70Organic acids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/106Silica or silicates
    • B01D2253/108Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/80Water
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/91Bacteria; Microorganisms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0266Other waste gases from animal farms

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fodder In General (AREA)

Abstract

The invention discloses a kind of multi-functional dry powder environmental improvement agents, it is characterised in that:Count by weight percentage, formula includes:Montmorillonite 70~75%, zeolite powder 20~25%, vitamin C 1~2%, silica 1~3%, organic acid 2~5%.The dry powder environmental improvement agent of the present invention is used for the improvement of fowl and livestock farm environment, reduces ambient humidity, absorption pernicious gas (such as ammonia, sulfurous gas), while reduces Animal stress power.

Description

Multi-functional dry powder environmental improvement agent and its preparation method and application
Technical field
The present invention relates to aquaculture fields, the particularly multi-functional dry powder environmental improvement agent for farm.
Background technology
It is moist, dirty it is smelly, it is sultry or it is clammy in winter-spring season be a great problem for perplexing China's pig raising dealer, it is while moist And pernicious gas is not only the hotbed of pathogenic microorganism breeding, and animal is also easily allowed to generate stress reaction and reduce resistance.It is special It is not Large-scale pig farm, since cultivation density is big, more a large amount of pathogens can be caused to be bred in colony house, and then influences animal and be good for Health reduces culture benefit.And farm largely uses disinfectant spray disinfectant as reduction pathogen major measure at present, and into One step adds the humidity in cultivation place, causes a kind of vicious circle.
For this purpose, pig farm is mostly used greatly montmorillonite as moisture absorption functional product at present, but its moisture absorption ability is weaker, and base This is without suction ammonia ability.
The content of the invention
To solve the above problems, it is an object of the invention to provide a kind of multi-functional dry powder environmental improvement agent, for changing The ambient humidity on kind pig farm, absorption pernicious gas (such as ammonia, sulfurous gas), while Animal stress power is reduced, and ensure Animal health improves culture benefit.
The object of the present invention is achieved like this:A kind of multifunctionality dry powder environmental improvement agent, it is characterised in that:By weight Percentage calculation, formula include:Montmorillonite 70~75%, zeolite powder 20~25%, vitamin C 1~2%, silica 1~ 3%, organic acid 2~5%.
The formula includes:Montmorillonite 70%, zeolite powder 25%, vitamin C 1%, silica 1 %, organic acid 3%.
The organic acid is selected from least one of citric acid, oxalic acid or malic acid.
The specific surface area of the silica is 200~300m2/g。
The preparation method of above-mentioned multifunctionality dry powder environmental improvement agent, it is characterised in that including following sequential steps:(1) exist The montmorillonite of 1/5~1/4 formula ratio is added in mixing arrangement, the silica, vitamin C and organic acid of formula ratio is added in, mixes It closes 8~12 minutes;(2) remaining montmorillonite and whole amount zeolite powder are added, is mixed 25~35 minutes, prepares and completes.
Above-mentioned multifunctionality dry powder environmental improvement agent is applied to fowl and livestock farm.
The multifunctionality dry powder environmental improvement agent is applied to fowl and livestock farm, is spread with hand or air blower sprays, made for the first time Use 45-55g/m2, routine use 25-35g/m2, 1 week 1~2 time, appropriate dosage during wet weather.
The dry powder environmental improvement agent of the present invention is used for the improvement of fowl and livestock farm environment, reduces ambient humidity, and absorption is harmful Gas (such as ammonia, sulfurous gas), while reduce Animal stress power.
Specific embodiment
The present invention is a kind of multi-functional dry powder environmental improvement agent, and count by weight percentage, formula includes:Montmorillonite 70 ~75%, zeolite powder 20~25%, vitamin C 1~2%, silica 1~3%, organic acid 2~5%.
The organic acid is selected from least one of citric acid, oxalic acid or malic acid.
The silica is amorphous silica, and specific surface area is preferably 200~300m2/g。
Montmorillonite and silica in formula can effectively improve the humidity on animal house ground, be provided to livestock and poultry comfortable raw Environment living inhibits animal house pathogen and multiplies, pathogen sum is dropped under infection risk line.Zeolite powder in formula has absorption The function of ammonia in addition the chemical substances such as organic acid and ammonia, sulphur make acid-base neutralization, has the function that reduce pernicious gas, reaches and disappear The effect of removing and harmful gas.Vitamin C in formula can effectively reduce Animal stress, improve animal resistance.Environmental stress meeting The synthesis and utilization of pig body ascorbic acid are influenced, so as to cause hypovitaminosis C in pig body.This formula is by adding vitamin C Can effectively slow down stress, reduce the morbidity chance of swinery, while vitamin C can reduce body capillary during heat stress and lead to Permeability enhances body's resistance to disease, mitigates hepatic cell fattydegeneration, reduces the death rate.
The preparation method of above-mentioned multifunctionality dry powder environmental improvement agent, including following sequential steps:(1) in mixing arrangement The montmorillonite of 1/5~1/4 formula ratio is added in, adds in the silica, vitamin C and organic acid of formula ratio, mixes 2~12 points Clock;(2) remaining montmorillonite and whole amount zeolite powder are added, is mixed 25~35 minutes, prepares and completes.This method is by small content Ingredient is first pre-mixed, then is mixed with other big content ingredients, so can guarantee that small content ingredient can be uniformly mixed.
Above-mentioned multifunctionality dry powder environmental improvement agent is applied to fowl and livestock farm (such as pig farm column home).In application, with Hand is spread or air blower sprinkling, for the first time using 45-55g/m2, routine use 25-35g/m2, it is preferred that for the first time using 50g/m2, day Often use 30g/m2, 1 week 1~2 time, appropriate dosage during wet weather.
Below by way of specific example, the present invention is further elaborated, but the present invention is simultaneously limited to this specific examples in portion.
Embodiment 1
Formula:Montmorillonite:700g, zeolite powder:250g, vitamin C:10g, silica:10g, citric acid:30g.
Preparation method:The montmorillonite of 1/5 formula ratio is added in mixing arrangement, adds in silica, the dimension life of formula ratio Plain C and citric acid mix 10 minutes;(2) remaining montmorillonite and whole amount zeolite powder are added, mixes 30 minutes, has prepared Into.
Comparative example 1
Formula:Montmorillonite:710g, zeolite powder:250g, vitamin C:10g, silica:0g, citric acid:30g.It prepares Method is the same as embodiment 1.
Comparative example 1 is on the basis of the formula of embodiment 1, does not add silica, and increases 10g montmorillonites, investigates two " Absorbance ratio-derivative method " of group of formula.In general, Absorbance ratio-derivative method value is bigger, and physical absorption ability is stronger, to moisture in air, gas, The adsorption capacities such as microorganism are also stronger.Method is using GB/T 20973-2007 detection methods.As a result it is as follows:
Index Comparative example 1 Embodiment 1 It is opposite to improve (%)
Absorbance ratio-derivative method (g/100g) 32.46 43.10 32.8%
Comparative example 2
Formula:Montmorillonite:700g, zeolite powder:280g, vitamin C:10g, silica:10g, citric acid:0g.It prepares Method is the same as embodiment 1.
Comparative example 2 is on the basis of upper embodiment 1 formula, does not add organic acid, and increases 30g zeolite powders, investigates two " the suction ammonia amount " of group of formula.In general, absorbability of the product to ammonia in air can be embodied indirectly by inhaling ammonia amount, and value is got over Greatly, it is stronger to inhale ammonia ability.Method is using GBT 21695-2008 detection methods.As a result it is as follows:
Index Comparative example 2 Embodiment 1 It is opposite to improve (%)
Inhale ammonia amount (mmol/100g) 89.32 114.65 28.4%
Comparative example 3
Certain existing commercially available product, mark ingredient are:Montmorillonite, zeolite powder, antimicrobial component, usage amount 30g~50g/m2
Do practical effect control on Jieyang pig farm, using using before product with investigating three respectively after using product Index, air humidity (being detected using hygrometer), air ammonia concentration (being detected using ammonia detector), ground total number of bacteria (separately sampled after before use and when use 24 is small, the sampling of surface smear method, the culture of laboratory cultures base).As a result such as table 1, table 2.
Table 1. is compareed using each index of certain commercially available product
Index Before use Behind commercial product
Air humidity (%RH) 76 59
Air ammonia concentration (mg/m3) 19 14
Ground total number of bacteria (a/cm2) 3.2×106 2.7×105
Table 2. is compareed using each index of this dry powder environmental improvement agent formulation product
Index Before use After 1 product of embodiment
Air humidity (%RH) 77 51
Air ammonia concentration (mg/m3) 17 6
Ground total number of bacteria (a/cm2) 4.6×106 6.9×104
Embodiment 2
Formula:Montmorillonite:700g, zeolite powder:200g, vitamin C:20g, silica:30g, malic acid:50g.It prepares Method is the same as embodiment 1.
Embodiment 3
Formula:Montmorillonite:750g, zeolite powder:200g, vitamin C:10g, silica:20g, citric acid and oxalic acid: 20g.Preparation method is the same as embodiment 1.
Embodiment 4
Formula:Montmorillonite:730g, zeolite powder:220g, vitamin C:20g, silica:10g, oxalic acid:20g.Preparation side Method is the same as embodiment 1.

Claims (7)

1. a kind of multifunctionality dry powder environmental improvement agent, it is characterised in that:Count by weight percentage, formula includes:Montmorillonite 70~75%, zeolite powder 20~25%, vitamin C 1~2%, silica 1~3%, organic acid 2~5%.
2. multifunctionality dry powder environmental improvement agent according to claim 1, it is characterised in that:The formula includes:It covers De- stone 70%, zeolite powder 25%, vitamin C 1%, silica 1 %, organic acid 3%.
3. multifunctionality dry powder environmental improvement agent according to claim 1, it is characterised in that:The organic acid is selected from lemon At least one of lemon acid, oxalic acid or malic acid.
4. multifunctionality dry powder environmental improvement agent according to claim 1, it is characterised in that:The ratio of the silica Surface area is 200~300m2/g。
5. the preparation method of multi-functional dry powder environmental improvement agent described in the arbitrary claims of claim 1-4, it is characterised in that Including following sequential steps:(1) montmorillonite of 1/5~1/4 formula ratio is added in mixing arrangement, adds in the titanium dioxide of formula ratio Silicon, vitamin C and organic acid mix 8~12 minutes;(2) remaining montmorillonite and whole amount zeolite powder are added, mixing 25~ It 35 minutes, prepares and completes.
6. the above-mentioned multi-functional dry powder environmental improvement agent of the arbitrary claim institutes of claim 1-4 is applied to fowl and livestock farm.
7. multi-functional dry powder environmental improvement agent is applied to fowl and livestock farm according to claim 6, spread with hand or air blower Sprinkling, for the first time using 45-55g/m2, routine use 25-35g/m2, 1 week 1~2 time, appropriate dosage during wet weather.
CN201810022231.0A 2018-01-10 2018-01-10 Multi-functional dry powder environmental improvement agent and its preparation method and application Pending CN108097005A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110367193A (en) * 2019-08-13 2019-10-25 北京桃古图生物科技有限公司 It is a kind of for improve cultivation colony house environment improver and its preparation method and application
CN111888929A (en) * 2020-08-04 2020-11-06 广东海大集团股份有限公司 Dry powder type environment improver for livestock and poultry breeding and preparation method and application thereof
CN117427481A (en) * 2023-08-24 2024-01-23 葫芦岛康达环保工贸有限公司 Deodorant based on nano silicon dioxide modification and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4366511B2 (en) * 2004-08-13 2009-11-18 株式会社アマテラ Container for dehumidification, defensive and deodorizing
CN101703072A (en) * 2009-11-19 2010-05-12 张同兵 Environment modifier for disinfection with dry powder
CN105052917A (en) * 2015-08-14 2015-11-18 湖南新南方养殖服务有限公司 Dry powder modified disinfection agent
CN105498687A (en) * 2015-12-16 2016-04-20 潍坊学院 Environment-friendly livestock and poultry farm environment improving agent and preparation method and application thereof
CN106430873A (en) * 2016-11-01 2017-02-22 中国海洋大学 High-efficiency compound type substrate improver and preparation method
CN106535625A (en) * 2014-06-20 2017-03-22 Gp 纤维素股份有限公司 Animal litter having improved odor control and absorbency
CN107279688A (en) * 2017-07-01 2017-10-24 河北工业大学 A kind of complex mineral takes off mould dose and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4366511B2 (en) * 2004-08-13 2009-11-18 株式会社アマテラ Container for dehumidification, defensive and deodorizing
CN101703072A (en) * 2009-11-19 2010-05-12 张同兵 Environment modifier for disinfection with dry powder
CN106535625A (en) * 2014-06-20 2017-03-22 Gp 纤维素股份有限公司 Animal litter having improved odor control and absorbency
CN105052917A (en) * 2015-08-14 2015-11-18 湖南新南方养殖服务有限公司 Dry powder modified disinfection agent
CN105498687A (en) * 2015-12-16 2016-04-20 潍坊学院 Environment-friendly livestock and poultry farm environment improving agent and preparation method and application thereof
CN106430873A (en) * 2016-11-01 2017-02-22 中国海洋大学 High-efficiency compound type substrate improver and preparation method
CN107279688A (en) * 2017-07-01 2017-10-24 河北工业大学 A kind of complex mineral takes off mould dose and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110367193A (en) * 2019-08-13 2019-10-25 北京桃古图生物科技有限公司 It is a kind of for improve cultivation colony house environment improver and its preparation method and application
CN111888929A (en) * 2020-08-04 2020-11-06 广东海大集团股份有限公司 Dry powder type environment improver for livestock and poultry breeding and preparation method and application thereof
CN117427481A (en) * 2023-08-24 2024-01-23 葫芦岛康达环保工贸有限公司 Deodorant based on nano silicon dioxide modification and preparation method thereof
CN117427481B (en) * 2023-08-24 2024-04-09 葫芦岛康达环保工贸有限公司 Deodorant based on nano silicon dioxide modification and preparation method thereof

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Application publication date: 20180601

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