CN110367193A - It is a kind of for improve cultivation colony house environment improver and its preparation method and application - Google Patents
It is a kind of for improve cultivation colony house environment improver and its preparation method and application Download PDFInfo
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- CN110367193A CN110367193A CN201910744966.9A CN201910744966A CN110367193A CN 110367193 A CN110367193 A CN 110367193A CN 201910744966 A CN201910744966 A CN 201910744966A CN 110367193 A CN110367193 A CN 110367193A
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- montmorillonite
- colony house
- adjusting agent
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- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 52
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical class O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 47
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 28
- 239000011707 mineral Substances 0.000 claims abstract description 28
- 239000002594 sorbent Substances 0.000 claims abstract description 28
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 27
- 239000003463 adsorbent Substances 0.000 claims abstract description 26
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 26
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 239000000341 volatile oil Substances 0.000 claims abstract description 12
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 27
- 239000007788 liquid Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 15
- 238000012216 screening Methods 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 10
- 125000001453 quaternary ammonium group Chemical class 0.000 claims description 7
- 239000003337 fertilizer Substances 0.000 claims description 6
- 238000009830 intercalation Methods 0.000 claims description 6
- 230000002687 intercalation Effects 0.000 claims description 6
- 230000028327 secretion Effects 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 5
- 239000004317 sodium nitrate Substances 0.000 claims description 5
- 235000010344 sodium nitrate Nutrition 0.000 claims description 5
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical group OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 3
- 238000000527 sonication Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 14
- 241001465754 Metazoa Species 0.000 abstract description 11
- 229910021529 ammonia Inorganic materials 0.000 abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- 230000003670 easy-to-clean Effects 0.000 abstract description 3
- 230000036541 health Effects 0.000 abstract description 3
- 235000019645 odor Nutrition 0.000 abstract description 3
- 244000052769 pathogen Species 0.000 abstract description 3
- 230000001717 pathogenic effect Effects 0.000 abstract description 3
- 239000007858 starting material Substances 0.000 abstract description 3
- 241000196324 Embryophyta Species 0.000 description 34
- 235000010755 mineral Nutrition 0.000 description 23
- 239000000243 solution Substances 0.000 description 14
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 10
- 230000006872 improvement Effects 0.000 description 9
- 239000000292 calcium oxide Substances 0.000 description 5
- 235000012255 calcium oxide Nutrition 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 230000007480 spreading Effects 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 241000737241 Cocos Species 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 229960000892 attapulgite Drugs 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000013270 controlled release Methods 0.000 description 2
- 238000004332 deodorization Methods 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 229910052625 palygorskite Inorganic materials 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 241000283690 Bos taurus Species 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- 241000258920 Chilopoda Species 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- 235000009262 Dracaena angustifolia Nutrition 0.000 description 1
- 240000007833 Dracaena angustifolia Species 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- 206010030113 Oedema Diseases 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 241000239226 Scorpiones Species 0.000 description 1
- 241000282887 Suidae Species 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 208000025865 Ulcer Diseases 0.000 description 1
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000009360 aquaculture Methods 0.000 description 1
- 244000144974 aquaculture Species 0.000 description 1
- HRHBQGBPZWNGHV-UHFFFAOYSA-N azane;bromomethane Chemical compound N.BrC HRHBQGBPZWNGHV-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000012258 culturing Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- XJWSAJYUBXQQDR-UHFFFAOYSA-M dodecyltrimethylammonium bromide Chemical compound [Br-].CCCCCCCCCCCC[N+](C)(C)C XJWSAJYUBXQQDR-UHFFFAOYSA-M 0.000 description 1
- 230000029142 excretion Effects 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 238000009374 poultry farming Methods 0.000 description 1
- 208000023504 respiratory system disease Diseases 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 231100000397 ulcer Toxicity 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K67/00—Rearing or breeding animals, not otherwise provided for; New or modified breeds of animals
- A01K67/02—Breeding vertebrates
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K67/00—Rearing or breeding animals, not otherwise provided for; New or modified breeds of animals
- A01K67/033—Rearing or breeding invertebrates; New breeds of invertebrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/26—Drying gases or vapours
- B01D53/263—Drying gases or vapours by absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/406—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/80—Water
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Environmental Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Animal Behavior & Ethology (AREA)
- Zoology (AREA)
- Animal Husbandry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Engineering & Computer Science (AREA)
- Fertilizers (AREA)
Abstract
The embodiment of the invention discloses a kind of for improving the improver and its preparation method and application of cultivation colony house environment, and the improver is by including that following raw material is made: 70-75 parts modified montmorillonite used, 8-12 parts of mineral adsorbent, 6-10 parts of plant sorbent, 1.5-2 parts of titanium dioxide, 4-5 parts of natural plant essential oils and 3-4 parts of pH adjusting agent;The present invention passes through the above-mentioned specific selection with content of starting materials, it can be realized the moisture and ammonia quickly absorbed in colony house, achieve the purpose that rapid draing place and removes odors, it is effectively improved colony house environment, and above-mentioned improver by specified raw material select meet water it is non-sticky stick it is easy to clean, in addition, improver of the present invention can effectively inhibit pathogen growth and propagation, and to domestic animal non-stress, it is conducive to improve domestic animal health.
Description
Technical field
The present embodiments relate to cultural technique fields, and in particular to a kind of for improving the improver of cultivation colony house environment
And its preparation method and application.
Background technique
Cultivation refers to cultivation and breeding animals and plants.Cultivation includes livestock culturing, poultry farming, aquaculture and special cultivation
Etc. types;The more popular several cultivation classifications of Chinese market are exactly chicken, pig, ox, sheep, scorpion, centipede etc. at present.
However, the farm of most of China, since environment is simple and crude, cattle's shed design is unreasonable to cause atmosphere draught-free, feeding
All in same place, temperature-controlled conditions are not also up to standard for excretion, cause breeding environment moist, germ easy to breed also improves simultaneously
The concentration of ammonia;For cost consideration, common solution is solved using quick lime spreading for present most of farms
The certainly above problem, but excessive quick lime can stimulate and aggravate the upper respiratory disease of domestic animal, and quick lime is in the stomach of domestic animal
It is reacted with water, generates strong base substance, be opened to big calorimetric, damage alimentary canal tissue, cause inflammation, oedema or ulcer etc., and
Domestic animal steps down on quick lime, easily causes toe burn.
Summary of the invention
For this purpose, the embodiment of the present invention provide it is a kind of for improve cultivation colony house environment improver, to solve the prior art
Middle use quick lime existing damage problems many caused by domestic animal as improver.
To achieve the goals above, the embodiment of the present invention provides the following technical solutions:
There is provided according to a first aspect of the embodiments of the present invention it is a kind of for improve cultivation colony house environment improver, it is described to change
Kind agent is by including that following raw material is made:
70-75 parts modified montmorillonite used, 8-12 parts of mineral adsorbent, 6-10 parts of plant sorbent, 1.5-2 parts of titanium dioxide,
4-5 parts and pH adjusting agent 3-4 parts of natural plant essential oils.
The present invention can be realized the moisture and ammonia quickly absorbed in colony house by the above-mentioned specific selection with content of starting materials,
Achieve the purpose that rapid draing place and remove odors, is effectively improved colony house environment, and above-mentioned improver passes through specified raw material
Selection meet water it is non-sticky stick it is easy to clean, in addition, improver of the present invention can effectively inhibit pathogen growth and propagation, and to domestic animal without
Stress reaction is conducive to improve domestic animal health.
Further, by including that following raw material is made:
Modified montmorillonite used 72 parts, 10 parts of mineral adsorbent, 8 parts of plant sorbent, 1.8 parts of titanium dioxide, natural plants essence
4.6 parts and 3.6 parts of pH adjusting agent of oil.
The present invention can preferably improve the overall performance of improver by the further restriction to each raw material dosage.
Further, the pH adjusting agent is DL-malic acid.
Further, the mineral adsorbent includes diatomite, zeolite and attapulgite.
Further, the plant sorbent is cocos active carbon.
Further, described modified montmorillonite used to be made by the following method:
(1) montmorillonite is crushed, then montmorillonite dispersion liquid is made in smashed montmorillonite;
(2) quaternary ammonium salt-modified agent solution is placed in montmorillonite dispersion liquid, ultrasonic disperse, dried to get intercalation modifying illiteracy
De- stone;
(3) intercalation modifying montmorillonite is roasted, is then placed in sodium nitrate solution, is ultrasonically treated, is dry to get institute
It states modified montmorillonite used.
Further, solid-liquid mass ratio is 1 in the montmorillonite dispersion liquid: (2.5-4.5).
Further, the montmorillonite dispersion liquid and quaternary ammonium salt-modified agent solution mass ratio are 1: (3-5);Preferably, season
Ammonium salt modifier solution is dodecyl trimethyl ammonium bromide solution, cetyl trimethylammonium bromide solution, octadecyl three
Methyl bromide ammonium salt solution or stearyl dimethyl benzyl ammonium chloride solution.
Further, the maturing temperature is 600-800 DEG C, time 2-3s;The concentration of the sodium nitrate solution is 7-
8mol/L;The sonication treatment time is 10-20min.
A kind of preparation method of above-mentioned improver, the preparation method packet are provided according to a second aspect of the embodiments of the present invention
Include following steps:
(a) it is ground up, sieved modified montmorillonite used, collects screenings;
(b) mineral adsorbent, plant sorbent, titanium dioxide and pH adjusting agent are ground respectively;
(c) mineral adsorbent, plant sorbent and the titanium dioxide after screenings and grinding are mixed, obtains mixture;
(d) it will mix in pH adjusting agent and natural plant essential oils merging mixture to get the improver.
The present invention, can be by polymer nano-scale material (mineral adsorbent, plant sorbent and dioxy by the above method
Change titanium) it is embedded between the gap of montmorillonite molecule, nano-high molecule joint product is formed, the suction for preparing improver is effectively improved
The wet moisture absorption and deodorization and bacteriostasis property, and can preferably play its controlled release and slow-release function.
Further, the screenings partial size is not more than 500 mesh, preferably 400-500 mesh.
Further, it is 8-12nm that the mineral adsorbent, plant sorbent and titanium dioxide secretion, which are ground to partial size,.
Further, it is 8-12 μm that the pH adjusting agent, which is ground to partial size,.
A kind of method of improvement pig cultivation colony house environment is provided according to a third aspect of the embodiments of the present invention, and the method is
Improver made from above-mentioned improver or above-mentioned preparation method is uniformly spread fertilizer over the fields on the ground of cultivation colony house.
Further, the amount of spreading fertilizer over the fields of the improver is 6-10g/m2。
The embodiment of the present invention has the advantages that
(1) present invention can be realized the moisture and ammonia quickly absorbed in colony house by the above-mentioned specific selection with content of starting materials
Gas achievees the purpose that rapid draing place and removes odors, is effectively improved colony house environment, and above-mentioned improver passes through specific original
Material selection meet water it is non-sticky stick it is easy to clean, in addition, improver of the present invention can effectively inhibit pathogen growth and propagation, and to domestic animal
Non-stress is conducive to improve domestic animal health.
(2) preparation method of the present invention can be by polymer nano-scale material (mineral adsorbent, plant sorbent and titanium dioxide
Titanium) it is embedded between the gap of montmorillonite molecule, nano-high molecule joint product is formed, the moisture absorption for preparing improver is effectively improved
The moisture absorption and deodorization and bacteriostasis property, and can preferably play its controlled release and slow-release function.
Specific embodiment
Embodiments of the present invention are illustrated by particular specific embodiment below, those skilled in the art can be by this explanation
Content disclosed by book is understood other advantages and efficacy of the present invention easily, it is clear that described embodiment is the present invention one
Section Example, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not doing
Every other embodiment obtained under the premise of creative work out, shall fall within the protection scope of the present invention.
The raw material that following embodiment uses is as follows:
Mineral adsorbent: it is mixed to prepare by diatomite, zeolite and attapulgite according to mass ratio for 3: 5: 2;
Plant sorbent: cocos active carbon;The source green from Henan;
Titanium dioxide: Shanghai Jiang Hu Industrial Co., Ltd. is derived from;
Natural plant essential oils: composite plant essential oil;From Britain baseformula;
PH adjusting agent: DL-malic acid;From Nanjing Guohai Biology Engineering Co., Ltd;
Montmorillonite: it adopts in Inner Mongol Ningcheng County mining area.
It is modified montmorillonite used: it is made by the following method:
(1) montmorillonite is crushed, then montmorillonite dispersion liquid is made in smashed montmorillonite, wherein in montmorillonite dispersion liquid
Solid-liquid mass ratio is 1: 3;
(2) quaternary ammonium salt-modified agent solution is placed in montmorillonite dispersion liquid, ultrasonic disperse, dried to get intercalation modifying illiteracy
De- stone, wherein montmorillonite dispersion liquid and quaternary ammonium salt-modified agent solution mass ratio are 1: 4, wherein quaternary ammonium salt-modified agent solution is 18
Alkyl trimethyl ammonium bromide solution;
(3) intercalation modifying montmorillonite is subjected to roasting 3s at 700 DEG C, being then placed in concentration is that 7.5mol/L sodium nitrate is molten
In liquid, it is ultrasonically treated 15min, is dry to get modified montmorillonite used.
Embodiment 1
One, for improving the improver of cultivation colony house environment
The above-mentioned improver for improving cultivation colony house environment is by including that following raw material is made:
Modified montmorillonite used 70 parts, 12 parts of mineral adsorbent, 6 parts of plant sorbent, 2 parts of titanium dioxide, natural plant essential oils 4
Part and 4 parts of pH adjusting agent.
Two, preparation method
The preparation method of the above-mentioned improver for being used to improve cultivation colony house environment, includes the following steps:
(a) by it is modified montmorillonite used ground, cross 500 meshes, collect screenings;
(b) mineral adsorbent, plant sorbent, titanium dioxide and pH adjusting agent are ground respectively, Minerals are inhaled
It is 8-12nm that attached dose, plant sorbent and titanium dioxide secretion, which are ground to partial size,;It is 8-12 μm that pH adjusting agent, which is ground to partial size,;
(c) mineral adsorbent, plant sorbent and the titanium dioxide after screenings and grinding are mixed, obtains mixture;
(d) it will mix in pH adjusting agent and natural plant essential oils merging mixture to get improver.
Embodiment 2
One, for improving the improver of cultivation colony house environment
The above-mentioned improver for improving cultivation colony house environment is by including that following raw material is made:
Modified montmorillonite used 75 parts, 8 parts of mineral adsorbent, 10 parts of plant sorbent, 1.5 parts of titanium dioxide, natural plants essence
5 parts and 3 parts of pH adjusting agent of oil.
Two, preparation method
The preparation method of the above-mentioned improver for being used to improve cultivation colony house environment, includes the following steps:
(a) by it is modified montmorillonite used ground, cross 400-500 mesh, collect screenings;
(b) mineral adsorbent, plant sorbent, titanium dioxide and pH adjusting agent are ground respectively, Minerals are inhaled
It is 8-12nm that attached dose, plant sorbent and titanium dioxide secretion, which are ground to partial size,;It is 8-12 μm that pH adjusting agent, which is ground to partial size,;
(c) mineral adsorbent, plant sorbent and the titanium dioxide after screenings and grinding are mixed, obtains mixture;
(d) it will mix in pH adjusting agent and natural plant essential oils merging mixture to get improver.
Embodiment 3
One, for improving the improver of cultivation colony house environment
The above-mentioned improver for improving cultivation colony house environment is by including that following raw material is made:
Modified montmorillonite used 72 parts, 10 parts of mineral adsorbent, 8 parts of plant sorbent, 1.8 parts of titanium dioxide, natural plants essence
4.6 parts and 3.6 parts of pH adjusting agent of oil.
Two, preparation method
The preparation method of the above-mentioned improver for being used to improve cultivation colony house environment, includes the following steps:
(a) by it is modified montmorillonite used ground, cross 400-500 mesh, collect screenings;
(b) mineral adsorbent, plant sorbent, titanium dioxide and pH adjusting agent are ground respectively, Minerals are inhaled
It is 8-12nm that attached dose, plant sorbent and titanium dioxide secretion, which are ground to partial size,;It is 8-12 μm that pH adjusting agent, which is ground to partial size,;
(c) mineral adsorbent, plant sorbent and the titanium dioxide after screenings and grinding are mixed, obtains mixture;
(d) it will mix in pH adjusting agent and natural plant essential oils merging mixture to get improver.
Embodiment 4
The present embodiment is a kind of method that improvement pig cultivates colony house environment, and this method is uniform on the ground of cultivation colony house
The improver in above-mentioned improver or above-described embodiment 3 is spread fertilizer over the fields, wherein the amount of spreading fertilizer over the fields of improver is 8g/m2。
Reference examples 1
This reference examples is a kind of improvement for improving the improver of cultivation colony house environment, in the improver and embodiment 3
The essentially identical difference of agent is only that the mineral adsorbent that titanium dioxide is replaced with to same number;It is above-mentioned to cultivate colony house for improving
The preparation method of the improver of environment is the same as the preparation method in embodiment 3.
Reference examples 2
This reference examples is a kind of improvement for improving the improver of cultivation colony house environment, in the improver and embodiment 3
The essentially identical difference of agent, which is only that, replaces with montmorillonite for modified montmorillonite used;The above-mentioned improver for being used to improve cultivation colony house environment
Preparation method with the preparation method in embodiment 3.
Reference examples 3
This reference examples is a kind of improvement for improving the improver of cultivation colony house environment, in the improver and embodiment 3
Agent component is identical, and the preparation method and the preparation method in embodiment 3 of above-mentioned improver are essentially identical, and difference is only that step
(a) for by it is modified montmorillonite used ground, cross 600 meshes, collect screenings.
Reference examples 4
This reference examples is a kind of improvement for improving the improver of cultivation colony house environment, in the improver and embodiment 3
Agent component is identical, and the preparation method and the preparation method in embodiment 3 of above-mentioned improver are essentially identical, and difference is only that step
(b) it is 15-18nm that Minerals adsorbent, plant sorbent and titanium dioxide secretion, which are ground to partial size,;PH adjusting agent is ground to grain
Diameter is 8-12 μm.
Experimental example 1
It is tested in certain pig farm of Henan Hebi, in same a collection of colony house, chooses the identical colony house of five structures, and
50 pigs are cultivated in colony house, the weight of each pig is 70 ± 2kg;Each colony house is respectively adopted in embodiment 3 and reference examples 1-4
Improver is improved, and ameliorative way uniformly spreads fertilizer over the fields improver according to 8g/m2, once a day;
Detect the humidity improved in each colony house in front and back, ammonia concentration respectively using hygrometer, ammonia detector;Before improvement
And ground total number of bacteria is sampled respectively after improving 24 hours, culture medium training is carried out in laboratory using after the sampling of surface semar technique
It supports, to detect clump count, above-mentioned testing result is as shown in table 1:
Table 1
As shown in Table 1:
The improver that the embodiment of the present invention is prepared can be reduced preferably compared with reference examples to the humidity in colony house
And ammonia concentration, cowshed environment, and can preferably print the growth of bacterium.
Although above having used general explanation and specific embodiment, the present invention is described in detail, at this
On the basis of invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Therefore,
These modifications or improvements without departing from theon the basis of the spirit of the present invention are fallen within the scope of the claimed invention.
Claims (10)
1. a kind of for improving the improver of cultivation colony house environment, which is characterized in that by including that following raw material is made:
It is 70-75 parts modified montmorillonite used, 8-12 parts of mineral adsorbent, 6-10 parts of plant sorbent, 1.5-2 parts of titanium dioxide, natural
4-5 parts and pH adjusting agent 3-4 parts of plants essential oil.
2. improver according to claim 1, which is characterized in that by including that following raw material is made:
Modified montmorillonite used 72 parts, 10 parts of mineral adsorbent, 8 parts of plant sorbent, 1.8 parts of titanium dioxide, natural plant essential oils 4.6
Part and 3.6 parts of pH adjusting agent.
3. improver according to claim 1 or 2, which is characterized in that the pH adjusting agent is DL-malic acid.
4. improver according to claim 1 or 2, which is characterized in that described modified montmorillonite used to be made by the following method:
(1) montmorillonite is crushed, then montmorillonite dispersion liquid is made in smashed montmorillonite;
(2) quaternary ammonium salt-modified agent solution is placed in montmorillonite dispersion liquid, ultrasonic disperse, dried to get intercalation modifying montmorillonite;
(3) intercalation modifying montmorillonite is roasted, is then placed in sodium nitrate solution, is ultrasonically treated, drying changes to get described
Property montmorillonite.
5. improver according to claim 4, which is characterized in that solid-liquid mass ratio is 1 in the montmorillonite dispersion liquid:
(2.5-4.5)。
6. improver according to claim 4, which is characterized in that the montmorillonite dispersion liquid and quaternary ammonium salt-modified agent solution
Mass ratio is 1: (3-5).
7. improver according to claim 4, which is characterized in that the maturing temperature is 600-800 DEG C, time 2-
3s;The concentration of the sodium nitrate solution is 7-8mol/L;The sonication treatment time is 10-20min.
8. the preparation method of improver as claimed in claim 1 to 7, which comprises the steps of:
(a) it is ground up, sieved modified montmorillonite used, collects screenings;
(b) mineral adsorbent, plant sorbent, titanium dioxide and pH adjusting agent are ground respectively;
(c) mineral adsorbent, plant sorbent and the titanium dioxide after screenings and grinding are mixed, obtains mixture;
(d) it will mix in pH adjusting agent and natural plant essential oils merging mixture to get the improver.
9. preparation method according to claim 5, which is characterized in that the screenings partial size is not more than 500 mesh;The mine
It is 8-12nm that object adsorbent, plant sorbent and titanium dioxide secretion, which are ground to partial size,;The pH adjusting agent is ground to partial size
8-12μm。
10. a kind of method for improving pig cultivation colony house environment, which is characterized in that uniformly spread fertilizer over the fields right on the ground of cultivation colony house
It is required that improver made from any any preparation method of the improver or claim 5-8 of 1-4.
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Application publication date: 20191025 |