CN105498687A - Environment-friendly livestock and poultry farm environment improving agent and preparation method and application thereof - Google Patents
Environment-friendly livestock and poultry farm environment improving agent and preparation method and application thereof Download PDFInfo
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- CN105498687A CN105498687A CN201510944059.0A CN201510944059A CN105498687A CN 105498687 A CN105498687 A CN 105498687A CN 201510944059 A CN201510944059 A CN 201510944059A CN 105498687 A CN105498687 A CN 105498687A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/26—Drying gases or vapours
- B01D53/261—Drying gases or vapours by adsorption
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
- B01J20/0229—Compounds of Fe
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/041—Oxides or hydroxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
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Abstract
The invention relates to an environment-friendly livestock and poultry farm environment improving agent. The environment-friendly livestock and poultry farm environment improving agent is prepared from, by weight, titanium dioxide1-3%, aluminum silicate 60-85%, alkali metal silicate 5-12%, alkaline earth metal silicate 0-7%, iron-containing salt 0-5%, lime1-5% and a pH regulator 3-8%. The environment improving agent can simultaneously eliminate ammonia smell and improve a damp environment, makes the farm environment always dry, prevents volatile organic compounds from appearing again, meanwhile has anti-bacterial anti-viral functions, can effectively improve the immunity of poultry, enhance disease resistance, prevent various diseases and reduce the dose for disease prevention and control and enables livestock and poultry to always grow in a good growth environment.
Description
Technical field
The present invention relates to a kind of environment-friendly type livestock and poultry farm environmental improvement agent, livestock and poultry cultivation technical field.
Background technology
The poultry that current China takes/poultry intensive farm pattern produces a large amount of animal welfare issues, causes livestock and poultry to occur and popular, especially the generation of zoonosis and popular, serious threat human health and sustainable development of animal husbandry.Animal welfare obtains the attention of the numerous common people and government department day by day, and OIE (OIE) even includes animal welfare " terrestrial animal health codes " in.
Intensive livestock and poultry farms is, pernicious gas excessive along with raising humidity often, and particularly ammonia taste is too high, and pathogen excessive number, causes the problems such as fowl poultry immune resistance reduction.The conventional use liquid disinfection liquid that adopts and add antibiotic all bring series of problems in drinking-water and feed.
Summary of the invention
For the deficiencies in the prior art, the invention provides a kind of environment-friendly type livestock and poultry farm environmental improvement agent, this modifying agent changes breeding environment pH value, eliminates ammonia taste, reduces the generation of breathing problem; Improve wet environment, suppress also kill bacteria, fungi, virus, parasitic ovum; Reduce fly, mosquito infectious disease, improve animal immunizing power, reduce expenses for medicine, improve comprehensive benefit.
The present invention is achieved by the following technical solutions:
A kind of environment-friendly type livestock and poultry farm environmental improvement agent, raw material components and percentage by weight composed as follows:
The present invention is preferred, and described titanium dioxide is sharp titanium or rutile titanium dioxide, and particle diameter is 0.1nm ~ 100nm.
The present invention is preferred, and described aluminium silicate salt is alumina silicate and/or metasilicic acid aluminium class material, and particle diameter is 0.1nm ~ 100nm.
The present invention is preferred, and described alkali silicate is sodium metasilicate, and sodium metasilicate or potassium silicate be one or more mixing wherein, and particle diameter is 0.1nm ~ 100nm.
The present invention is preferred, and described alkaline-earth-metal silicate is calcium silicates and/or magnesium silicate, and particle diameter is 0.1nm ~ 100nm.
The present invention is preferred, and described is wherein one or more mixing of iron oxide red, iron oxide yellow, iron chloride or ferric sulfate containing molysite, and particle diameter is 0.1nm ~ 100nm.
The present invention is preferred, and described lime is quick lime, white lime or lime stone.
The present invention is preferred, and described pH adjusting agent is wherein one or more mixing of citric acid, amino acid, ascorbic acid, salicylic acid, benzoic acid, gluconic acid, tartaric acid, oxalic acid.
The present invention is preferred, environment-friendly type livestock and poultry farm environmental improvement agent, raw material components and percentage by weight composed as follows:
The present invention is preferred, environment-friendly type livestock and poultry farm environmental improvement agent, raw material components and percentage by weight composed as follows:
The present invention is preferred, environment-friendly type livestock and poultry farm environmental improvement agent, raw material components and percentage by weight composed as follows:
The titanium dioxide that the present invention uses is a kind of Chinese white generally used, and is widely used in the emulsion paint coating of interior room, its hygroscopicity and the organic ability of adsorb volatile; Aluminium silicate salt is the aluminosilicate that a class contains the crystallization water, is a kind of efficient selective adsorbent, can be used for divided gas flow or liquid, with certain proportion mixing, dehydrates and obtains molecular sieve; Alkali silicate and alkaline-earth-metal silicate quasi-mineral mesolite molecular sieve analog (Na simultaneously
2oAl
2o
32SiO
2nH
2o), feldspar (K
2oAl
2o
36SiO
2), mica (K
2o2Al
2o
36SiO
22H
2o), kaolin (Al
2o
32SiO
22H
2o), garnet (3CaOAl
2o
33SiO
2) etc., major part has natural cellular structure, the pollutant such as steam, volatile organic matter in a large amount of absorbed air of energy, has excellent dehumidifying, goes the effects such as peculiar smell, with weak organic acid acting in conjunction, removes the ammonia taste in plant.
The present inventor surprisingly finds, the livestock and poultry farm environmental improvement agent that the present invention is made up of titanium dioxide, aluminium silicate salt, alkali silicate, lime, pH adjusting agent can eliminate ammonia taste simultaneously, improve wet environment, plant's environment is made to be in dry environment all the time, reduce the generation of breathing problem, suppress also kill bacteria, fungi, virus, parasitic ovum, in use, titanium dioxide has hygroscopicity, adsorb the volatile organic matter distributed in plant's environment simultaneously, adding of aluminium silicate salt is assisted moisture absorption and adsorbs the volatile organic matter distributed in plant's environment, alkali silicate and alkaline-earth-metal silicate quasi-mineral have larger surface area, namely have larger surface energy, play suction-operated, carry out coated to the volatile organic matter after absorption, prevent volatile organic matter from appearing again, after lime and above-mentioned formula are arranged in pairs or groups, can be combined rapidly with the optimum strength of place of arrival, produce polyphenoils, eliminate oxidation material, eliminate corrupt, suppress pathogen, can effectively protect from infection, suppress growing and developing of germ virus, the generation of prevention bird various diseases, form good ecological environment, strengthen immunity of livestock, premunition, effectively can prevent the various diseases of livestock and poultry, for fowl poultry kind growth provides a good growing environment, the pH adjusting agent that the present invention uses makes product pH remain on about 4 ~ 5, simultaneously with above-mentioned formula acting in conjunction, remove the ammonia taste in plant, substantially increase the effect that livestock and poultry farm removes ammonia taste, titanium dioxide of the present invention, aluminium silicate salt, alkali silicate, lime, the proportion of composing of each material of pH adjusting agent is that those skilled in the art gropes to obtain through long-term experiment, especially titanium dioxide, aluminium silicate salt, the ratio of alkali silicate, ammonia taste can be eliminated simultaneously, improve wet environment, plant's environment is made to be in dry environment all the time, prevent volatile organic matter from appearing again, there is anti-bacteria and anti-virus function simultaneously, effectively can improve poultry immunity, strengthen premunition, prevent various disease, reduce disease prevention and cure dosage, fowl poultry kind is grown and is in a good growing environment all the time, reduce livestock and poultry M & M and can reduce by more than 95%, survival rate more than 99%, therefore bird output can be improved, reduce cost, modifying agent of the present invention is safe and harmless simultaneously, without the resistance to the action of a drug, noresidue, have no side effect, preparation method is simple, with low cost, stable performance, easy to use, safe and reliable.
Raw material of the present invention are all nano level industrial powders, but heavy metal etc. have the constituent content of harmfulness should be not too high to domestic animal.Raw material, after mechanical mixture is even, can use after product pH is adjusted to about 4 ~ 5.
Formula of the present invention, raw material major part material all derives from natural crystal, under definitely harmless prerequisite, ensures the drying of livestock and poultry cultivation, totally, for animal builds better growing environment, improves the individual productivity ratio of livestock and poultry and product quality.
The preparation method of above-mentioned environment-friendly type livestock and poultry farm environmental improvement agent, comprises step as follows:
(1) by titanium dioxide, aluminium silicate salt, alkali silicate, alkaline-earth-metal silicate, be ground to particle diameter 0.1nm ~ 100nm respectively containing molysite, lime, pH adjusting agent is ground to particle diameter 10 ~ 50 μm;
(2) get the titanium dioxide after grinding, aluminium silicate salt, alkali silicate, alkaline-earth-metal silicate by proportioning, mix containing molysite, lime, obtain composite ore stone flour;
(3) pH adjusting agent after grinding is added in composite ore stone flour and mixes, obtain environment-friendly type livestock and poultry farm environmental improvement agent.
The application of above-mentioned environment-friendly type livestock and poultry farm environmental improvement agent, eliminate ammonia taste for livestock and poultry farm, improve wet environment and sterilizing, can directly spray in environment during use, fountain height be 5 ~ 20g/ square.
Beneficial effect of the present invention is as follows:
1, livestock and poultry farm environmental improvement agent of the present invention can eliminate ammonia taste simultaneously, improve wet environment, make plant's environment be in dry environment all the time, reduce the generation of breathing problem, suppress also kill bacteria, fungi, virus, parasitic ovum, fowl poultry kind is grown and is in a good growing environment all the time, reduce livestock and poultry M & M and can reduce by more than 95%, survival rate more than 99%, improve bird output, reduce cost.
2, livestock and poultry farm environmental improvement agent of the present invention safe and harmless, without the resistance to the action of a drug, noresidue, have no side effect, preparation method is simple, with low cost, and stable performance is esy to use, safe and reliable.
Detailed description of the invention
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.Described embodiment is only a part of example of invention, instead of whole case study on implementation.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
The raw material used in embodiment is prior art, and market is buied.
Embodiment 1
One environment-friendly type livestock and poultry farm environmental improvement agent, raw material components and percentage by weight composed as follows:
Preparation method, step is as follows:
(1) by titanium dioxide, aluminium silicate salt, alkali silicate, alkaline-earth-metal silicate, be ground to particle diameter 10nm respectively containing molysite, lime, pH adjusting agent is ground to particle diameter 10 μm;
(2) get the titanium dioxide after grinding, aluminium silicate salt, alkali silicate, alkaline-earth-metal silicate by proportioning, mix containing molysite, lime, obtain composite ore stone flour;
(3) pH adjusting agent after grinding is added in composite ore stone flour and mixes, obtain environment-friendly type livestock and poultry farm environmental improvement agent.
Embodiment 2
One environment-friendly type livestock and poultry farm environmental improvement agent, raw material components and percentage by weight composed as follows:
Preparation method is with embodiment 1.
Embodiment 3
Environment-friendly type livestock and poultry farm environmental improvement agent, raw material components and percentage by weight composed as follows:
Preparation method is with embodiment 1.
Comparative example 1
One ring livestock and poultry farm environmental improvement agent, raw material components and percentage by weight composed as follows:
Comparative example 2
One ring livestock and poultry farm environmental improvement agent, raw material components and percentage by weight composed as follows:
Experimental example
By site test in the duck plant of the livestock and poultry farm environmental improvement agent of embodiment 1-3 and comparative example 1-2 under same environment, use amount 10g/ square/day, with not applying environment modifying agent for control group, long run test 10 days, duck plant space humidity, ammonia concentration and clump count result after environment for use modifying agent are as shown in table 1 below:
Table 1
Group | Breeding spaces humidity (%) | Ammonia concentration (mg/m 3) | Clump count (CFU) |
Embodiment 1 | 60±2 | 1.1±0.1 | 105±10 |
Embodiment 2 | 50±1 | 0.9±0.1 | 100±10 |
Embodiment 3 | 58±2 | 1.1±0.1 | 103±10 |
Comparative example 1 | 70±1 | 9.7±0.1 | 150±20 |
Comparative example 2 | 82±5 | 8.7±0.1 | |
Contrast | 85±5 | 10.0±2.0 | 175±20 |
Contrast known by upper table 1, environmental improvement agent of the present invention can eliminate ammonia taste simultaneously, improve wet environment, make plant's environment be in dry environment all the time, prevent volatile organic matter from appearing again, there is anti-bacteria and anti-virus function simultaneously, effectively can improve poultry immunity, strengthen premunition, prevent various disease, reduce disease prevention and cure dosages, fowl poultry kind is grown be in all the time the growing environment that good.
Foregoing be only the present invention conceive under basic explanation, and according to any equivalent transformation that technical scheme of the present invention is done, all should protection scope of the present invention be belonged to.
Claims (10)
1. an environment-friendly type livestock and poultry farm environmental improvement agent, raw material components and percentage by weight composed as follows:
2. environment-friendly type livestock and poultry farm environmental improvement agent according to claim 1, it is characterized in that, described titanium dioxide is sharp titanium or rutile titanium dioxide, and particle diameter is 0.1nm ~ 100nm.
3. environment-friendly type livestock and poultry farm environmental improvement agent according to claim 1, is characterized in that, described aluminium silicate salt is alumina silicate and/or metasilicic acid aluminium class material, and particle diameter is 0.1nm ~ 100nm.
4. environment-friendly type livestock and poultry farm environmental improvement agent according to claim 1, it is characterized in that, described alkali silicate is sodium metasilicate, and sodium metasilicate or potassium silicate be one or more mixing wherein, and particle diameter is 0.1nm ~ 100nm; Described alkaline-earth-metal silicate is calcium silicates and/or magnesium silicate, and particle diameter is 0.1nm ~ 100nm; Described is wherein one or more mixing of iron oxide red, iron oxide yellow, iron chloride or ferric sulfate containing molysite, and particle diameter is 0.1nm ~ 100nm; Described lime is quick lime, white lime or lime stone.
5. environment-friendly type livestock and poultry farm environmental improvement agent according to claim 1, it is characterized in that, described pH adjusting agent is wherein one or more mixing of citric acid, amino acid, ascorbic acid, salicylic acid, benzoic acid, gluconic acid, tartaric acid, oxalic acid.
6. environment-friendly type livestock and poultry farm environmental improvement agent according to claim 1, is characterized in that, raw material components and percentage by weight composed as follows:
7. environment-friendly type livestock and poultry farm environmental improvement agent according to claim 1, is characterized in that, raw material components and percentage by weight composed as follows:
8. environment-friendly type livestock and poultry farm environmental improvement agent according to claim 1, is characterized in that, raw material components and percentage by weight composed as follows:
9. the preparation method of environment-friendly type livestock and poultry farm environmental improvement agent according to claim 1, comprises step as follows:
(1) by titanium dioxide, aluminium silicate salt, alkali silicate, alkaline-earth-metal silicate, be ground to particle diameter 0.1nm ~ 100nm respectively containing molysite, lime, pH adjusting agent is ground to particle diameter 10 ~ 50 μm;
(2) get the titanium dioxide after grinding, aluminium silicate salt, alkali silicate, alkaline-earth-metal silicate by proportioning, mix containing molysite, lime, obtain composite ore stone flour;
(3) pH adjusting agent after grinding is added in composite ore stone flour and mixes, obtain environment-friendly type livestock and poultry farm environmental improvement agent.
10. the application of environment-friendly type livestock and poultry farm environmental improvement agent according to claim 1, eliminate ammonia taste for livestock and poultry farm, improve wet environment and sterilizing, can directly spray in environment during use, fountain height be 5 ~ 20g/ square.
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CN105498687B CN105498687B (en) | 2018-03-20 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106359450A (en) * | 2016-08-23 | 2017-02-01 | 北京老哈默国际农业科技发展有限公司 | Livestock and poultry farm environment improver and preparation method thereof |
CN108097005A (en) * | 2018-01-10 | 2018-06-01 | 广州迈高化学有限公司 | Multi-functional dry powder environmental improvement agent and its preparation method and application |
CN109370270A (en) * | 2018-10-09 | 2019-02-22 | 合肥斯姆雷品牌管理有限公司 | Functional coating and preparation method thereof for livestock and poultry farm inner wall |
CN111013314A (en) * | 2019-08-14 | 2020-04-17 | 长沙创西生物科技有限公司 | Environment improver for animal house |
CN112353049A (en) * | 2020-10-29 | 2021-02-12 | 杭州憬鸿科技有限公司 | Modified fine-pore silica-alumina gel deodorization material, polyurethane foam insole and preparation method thereof |
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CN102814161A (en) * | 2012-08-09 | 2012-12-12 | 南京农业大学 | Attapulgite-powder containing environment improver for delivery room of sows and preparation method thereof |
CN103548874A (en) * | 2013-10-25 | 2014-02-05 | 龙口市海盛农牧有限公司 | Environment cleaning agent for cultivation |
CN204466539U (en) * | 2014-12-31 | 2015-07-15 | 张荣幸 | A kind of Novel pig house |
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CN1689408A (en) * | 2004-04-29 | 2005-11-02 | 周娟 | Nano modified bamboo charcoal capable of resisting and eliminating bacteria |
CN101264434A (en) * | 2008-05-05 | 2008-09-17 | 中国农业大学 | Drying agent for absorbing ammonia |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106359450A (en) * | 2016-08-23 | 2017-02-01 | 北京老哈默国际农业科技发展有限公司 | Livestock and poultry farm environment improver and preparation method thereof |
CN108097005A (en) * | 2018-01-10 | 2018-06-01 | 广州迈高化学有限公司 | Multi-functional dry powder environmental improvement agent and its preparation method and application |
CN109370270A (en) * | 2018-10-09 | 2019-02-22 | 合肥斯姆雷品牌管理有限公司 | Functional coating and preparation method thereof for livestock and poultry farm inner wall |
CN111013314A (en) * | 2019-08-14 | 2020-04-17 | 长沙创西生物科技有限公司 | Environment improver for animal house |
CN112353049A (en) * | 2020-10-29 | 2021-02-12 | 杭州憬鸿科技有限公司 | Modified fine-pore silica-alumina gel deodorization material, polyurethane foam insole and preparation method thereof |
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