CN108451780A - A kind of washable hair dye and preparation method thereof - Google Patents
A kind of washable hair dye and preparation method thereof Download PDFInfo
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- CN108451780A CN108451780A CN201810254105.8A CN201810254105A CN108451780A CN 108451780 A CN108451780 A CN 108451780A CN 201810254105 A CN201810254105 A CN 201810254105A CN 108451780 A CN108451780 A CN 108451780A
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- graphene
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/368—Carboxylic acids; Salts or anhydrides thereof with carboxyl groups directly bound to carbon atoms of aromatic rings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
Abstract
The invention discloses a kind of washable hair dyes and preparation method thereof, belong to cosmetics preparation field, including I dose and II dose, wherein I dose is made of the following components by mass percentage：Graphene 0.25~5%, graphene stabilizer 5~10%, ascorbic acid 0.5~2.5%, propylgallate 1~3%, glycerine 5%, thickener 2~5%, surplus are water；Wherein II dose is made of the following components by mass percentage：Ferrous sulfate 5~10%, ascorbic acid 0.1~0.5%, glycerine 5%, alkaline agent 1~5%, thickener 2~5%, surplus is water.The beneficial effects of the invention are as follows：It is acted synergistically using the dyestuffs such as graphene and graphene stabilizer, and by the proportioning of reasonable design, obtained hair dye has the characteristics that good color fastness, not fugitive color and antistatic.Through experiment test, hair can also still keep bright black after 70 washings.
Description
Technical field
The present invention relates to cosmetics preparation fields more particularly to a kind of washable hair dye and preparation method thereof.
Background technology
Hair dyeing is modern one of most common means of making up, generally require using plant (such as avocado fruit, nail grass, what
Tuber of multiflower knotweed etc.) or chemical pigment, the color of hair is dyed desired color.As the improvement of people's living standards, hair dyeing
As widely known fashion simple makeup mode again.Hair dyeing can make color development back to nature, make up due to heredity, metabolism,
Nutrition or disease, year are waited for a long time white hair caused by factor, embody the mental attitude of more aobvious youth, recurrence oriental traditional is with natural dark hair
For beautiful purpose.Meanwhile China comes into quick ageing stage, hair dye has prodigious as the hair care articles of the elderly
Market.In addition, being the epoch for showing individual character now, originally pitch-black hair is dyed colorful color development by people, when pursuing
Still, show charisma；From grizzled old man to the youth to follow the fashion, the number and frequency of hair dyeing are increasing rapidly
Add, hair dyeing has become one of world pop fashion.
However, presently commercially available various hair dyes, ingredient is mostly containing harmful heavy metal such as lead, chromium etc., more sternly
Weight is that p-phenylenediamine and other band benzene ring type compounds are added in hair dye.It is a large amount of studies have shown that p-phenylenediamine and
Its band being irritating to the skin property of benzene ring type compounds, causes anaphylaxis, and be easy to be absorbed by the skin, and accumulation causes to be poisoned in vivo,
And various cancers can be induced.In recent years, natural dyeing agent is environmentally protective due to safe and non-toxic, and the features such as derive from a wealth of sources,
Increasingly favored by consumers in general.For example, the Chinese invention patent of Patent No. 200710173282.5 discloses one
Kind is using cloves as bleeding agent, Chinese gall, Ke Zi, the natural hair dye that nutgall is pigment；Recently, document (Chem 4,1-11,
April 12,2018：Multifunctional Graphene Hair Dye) it reports using grapheme material, develop one
Kind is nontoxic, does not hinder hair quality and can help the hair dyeing liquor of hair antistatic, and repeatedly washing will not fade.Traditional chemical dyes material
The active ingredient of material is " spherical particle ", therefore is easier to be washed out when hair washing, and new material can be as " hygenic towelette " head
Feel nervous and wraps tightly.But still there is a problem of that color fastness is inadequate with hair dye prepared by the method for document report, it can only be through
It is washed by 30 times, the main reason is that the polymeric adhesive in the document is chitosan, does not participate in hair dye
Reaction.
Invention content
The problems such as to overcome harmful, being irritating to the skin property existing for prior art hair dye, being easy to fade, this
The first purpose of invention is to provide a kind of washable hair dye, using this new material of graphene oxide as primary raw material, is added few
The graphene stabilizer that can participate in hair dyeing reaction is added in hair dye made of the auxiliary material of amount in graphene oxide reduction process,
The hair dye being prepared still keeps black glossy, concrete scheme as follows by 120 washings：
A kind of washable hair dye, including I dose and II dose：
Wherein I dose is made of the following components by mass percentage：Graphene 0.25~5%, graphene stabilizer 5~
10%, ascorbic acid 0.5~2.5%, propylgallate 1~3%, glycerine 5%, thickener 2~5%, surplus are water；
Wherein II dose is made of the following components by mass percentage：Ferrous sulfate 5~10%, ascorbic acid 0.1~
0.5%, glycerine 5%, alkaline agent 1~5%, thickener 2~5%, surplus is water.
Preferably, the graphene is graphene oxide or the graphene oxide by reduction.
Preferably, the graphene stabilizer is tannic acid or gallic acid.
Preferably, the alkaline agent is edible alkaline matter.
Preferably, the edible alkaline matter is sodium pyrophosphate, sodium bicarbonate, sodium tripolyphosphate or sodium citrate.
Preferably, the thickener is sodium carboxymethylcellulose, hydroxyethyl cellulose, methylcellulose, xanthans, gelatin
With the mixture of one or more of anti-jelly thickener.
Preferably, I agent and II dose of weight ratio are 1 when the hair dye uses：1.
The second object of the present invention is to provide a kind of preparation method of above-mentioned washable hair dye, include the following steps：
Step 1:It prepares graphene dispersing solution, is added ascorbic acid and graphene stabilizer, heating stirring 1 at 90 DEG C~
4h makes graphene restore, and then obtains graphene by filtering or centrifuging；
Step 2：I agent is prepared, 60~65 DEG C is heated water to, is proportionally added into I agent each component raw materials, after stirring evenly,
Graphene dispersing solution is added, is again stirring for uniformly, postcooling is to 45 DEG C or less；
Step 3：II dose is prepared, weighs II dose of each component raw material in proportion, after heating water to 60~65 DEG C, is added II
Agent each component raw material, is cooled to 45 DEG C or less.
Preferably, the graphene stabilizer is added in two portions, when in step 1 prepared by graphene dispersing solution for the first time
It is added, is added when preparing I agent in step 2 for the second time.
Preferably, the weight ratio that graphene stabilizer is added in step 1 and step 2 is 1：1.
The application method of washable hair dye is in the present invention：I dose is equably combed on hair with comb, it, will after 10min
II dose is uniformly combed onto hair, clean with warm water washing after keeping 10min.
Compared with prior art, the beneficial effects of the invention are as follows：
(1) it uses the dyestuffs such as graphene and graphene stabilizer to act synergistically, and by the proportioning of reasonable design, obtains
Hair dye has the characteristics that good color fastness, not fugitive color and antistatic.Through experiment test, hair still can also after 70 washings
Keep bright black；
(2) hair dye preparation process is simple, environmental requirement is low, less energy consumption in the present invention, is suitable for industrialization production, and make
The hair dye obtained can have damaged hair good protective effect；
(3) in terms of safety, the graphene of the larger bigger of graphene size cannot be introduced into vivo, will not be small point as chemistry
Son is easy to be absorbed by the skin and have an impact human body like that, and graphene, using graphene oxide, additive amount is few,
At low cost, target user is extensive.
Description of the drawings
Fig. 1 is the present invention preferably graphene coated hair electron microscope；
Fig. 2 is the electron microscope of graphene oxide used in the present invention.
Specific implementation mode
Below in conjunction with drawings and examples, the present invention will be described in further detail.It should be appreciated that described herein
Specific examples are only used to explain the present invention, is not intended to limit the present invention.
Present embodiments provide for a kind of washable hair dyes, using this new material of graphene oxide as primary raw material, are added
The graphene stabilization that can participate in hair dyeing reaction is added in hair dye made of a small amount of auxiliary material in graphene oxide reduction process
Agent, the hair dye being prepared still keep black glossy by 120 washings, specifically include I dose and II dose：
Wherein I dose is made of the following components by mass percentage：Graphene 0.25~5%, graphene stabilizer 5~
10%, ascorbic acid 0.5~2.5%, propylgallate 1~3%, glycerine 5%, thickener 2~5%, surplus are water；
Wherein II dose is made of the following components by mass percentage：Ferrous sulfate 5~10%, ascorbic acid 0.1~
0.5%, glycerine 5%, alkaline agent 1~5%, thickener 2~5%, surplus is water.If Fig. 1 is graphene coated hair electron microscope,
It can be seen that graphene uniform is coated on hair surface, enemy's hair plays good protective effect.
As a preferred embodiment, the graphene is graphene oxide or the graphite oxide by reduction
Alkene.As shown in Fig. 2, wherein the size of graphene oxide in the micron-scale, can form fine and close protective layer in hair surface in this way.
As a preferred embodiment, the graphene stabilizer is tannic acid or gallic acid.
As a preferred embodiment, the alkaline agent is edible alkaline matter.
As a preferred embodiment, the edible alkaline matter is sodium pyrophosphate, sodium bicarbonate, trimerization phosphorus
Sour sodium or sodium citrate.
As a preferred embodiment, the thickener is sodium carboxymethylcellulose, hydroxyethyl cellulose, methyl fibre
Tie up the mixture of one or more of element, xanthans, gelatin and anti-jelly thickener.
As a preferred embodiment, I agent and II dose of weight ratio are 1 when the hair dye uses：1.
Present embodiment additionally provides a kind of preparation method of above-mentioned washable hair dye, includes the following steps：
Step 1:It prepares graphene dispersing solution, is added ascorbic acid and graphene stabilizer, heating stirring 1 at 90 DEG C~
4h makes graphene restore, and then obtains graphene by filtering or centrifuging；
Step 2：I agent is prepared, 60~65 DEG C is heated water to, is proportionally added into I agent each component raw materials, after stirring evenly,
Graphene dispersing solution is added, is again stirring for uniformly, postcooling is to 45 DEG C or less；
Step 3：II dose is prepared, weighs II dose of each component raw material in proportion, after heating water to 60~65 DEG C, is added II
Agent each component raw material, is cooled to 45 DEG C or less.
As a preferred embodiment, the graphene stabilizer is added in two portions, the stone in step 1 for the first time
Black alkene dispersion liquid is added when preparing, and is added when preparing I agent in step 2 for the second time.
As a preferred embodiment, the weight ratio that graphene stabilizer is added in step 1 and step 2 is 1：1.
Embodiment one：
Washable hair dye in the present embodiment, including I dose and II dose：
Wherein I dose, 100% meter, is made of following composition by weight percent：Graphene 0.25%, graphene stabilizer
5%, ascorbic acid 2%, propylgallate 1%, glycerine 5%, thickener 2%, surplus are water；
Described II dose, 100% meter, is made of the following components by weight percent：Ferrous sulfate 5%, ascorbic acid
0.1, glycerine 5%, thickener 2%, surplus are water, and the additive amount of alkaline agent is to keep II dose of pH value to be advisable.
Embodiment two：
Washable hair dye in the present embodiment, including I dose and II dose：
Wherein I dose, 100% meter, is made of following composition by weight percent：Graphene 5%, graphene stabilizer 5%,
Ascorbic acid 1.5%, ascorbic acid 0.5~2.5%, propylgallate 3%, glycerine 5%, thickener 5%, surplus are water；
II dose, 100% meter, is made of the following components by weight percent：It is ferrous sulfate 10%, ascorbic acid 0.5%, sweet
Oil 5%, thickener 2%, surplus is water, and the additive amount of alkaline agent is to keep II dose of pH value to be advisable.
Embodiment three：
Washable hair dye in the present embodiment, including I dose and II dose：
Wherein I dose, 100% meter, is made of following composition by weight percent：Graphene 1%, graphene stabilizer 8%,
Ascorbic acid 1%, propylgallate 2%, glycerine 5%, thickener 3%, surplus are water；
II dose, 100% meter, is made of the following components by weight percent：It is ferrous sulfate 5%, ascorbic acid 0.1%, sweet
Oil 5%, thickener 2%, surplus is water, and the additive amount of alkaline agent is to keep II dose of pH value to be advisable.
Comparative example one：
Washable hair dye in this comparative example, including I dose and II dose：
Wherein I dose, 100% meter, is made of following composition by weight percent：Graphene 5%, graphene stabilizer 5%,
Ascorbic acid 2%, propylgallate 1%, glycerine 5%, thickener 2%, surplus are water；
II dose, 100% meter, is made of the following components by weight percent：It is ferrous sulfate 5%, ascorbic acid 0.1%, sweet
Oil 5%, thickener 2%, surplus is water, and the additive amount of alkaline agent is to keep II dose of pH value to be advisable.
Comparative example two：
Washable hair dye in this comparative example, including I dose and II dose：
Wherein I dose, 100% meter, is made of following composition by weight percent：Graphene 0.25%, ascorbic acid 1%,
Propylgallate 1%, glycerine 5%, thickener 2%, surplus are water；
II dose, 100% meter, is made of the following components by weight percent：It is ferrous sulfate 5%, ascorbic acid 0.1%, sweet
Oil 5%, thickener 2%, surplus is water, and the additive amount of alkaline agent is to keep II dose of pH value to be advisable.
Comparative example three：
This comparative example is that business commonly uses hair dye, including I dose and II dose：
I dose composition, based on gross mass percentage 100%, cetostearyl alcohol 7%, octadecyltrimethylammonium chloride 1%,
Oleyl alcohol ether 54%, p-phenylenediamine 2.2%, resorcinol 0.6%, m-aminophenol 0.3%, sulfurous acid 0.5%, arabo-ascorbic acid
0.3%, ethanol amine 5%, surplus are water；
II dose of composition, based on gross mass percentage 100%, cetostearyl alcohol 5%, oleyl alcohol ether 53%, 50% hydrogen peroxide
12%, disodium hydrogen phosphate 0.4%, phosphoric acid 0.1%, sodium stannate 0.1%, surplus are water.
Above-described embodiment and comparative example are subjected to color fastness test, specific test process is as follows：By the hair after dyeing, put
It in the aqueous solution containing 5% shampoo, is then placed on vortex favourable turn, control rotating speed is that 40r/min is rotated.
Obtain following result：
| Project | Coloring effect | The washing times to fade for the first time |
| Embodiment one | Bright black gloss | 72 |
| Embodiment two | Bright black gloss | 124 |
| Embodiment three | Bright black gloss | 86 |
| Comparative example one | Furvous | 23 |
| Comparative example two | Furvous | 36 |
| Comparative example three | Black | 54 |
From experimental data it is found that the washing times of the first time colour fading of embodiment one to three are at 70 times or more, especially
Hair dye in embodiment two, the washing times that first time fades have reached 124 times, far above the test in three groups of comparative examples
As a result, having excellent color fastness.
The preferred embodiment of the present invention has shown and described in above description, as previously described, it should be understood that the present invention is not office
Be limited to form disclosed herein, be not to be taken as excluding other embodiments, and can be used for various other combinations, modification and
Environment, and can be changed by the above teachings or related fields of technology or knowledge in the scope of the invention is set forth herein
It is dynamic.And changes and modifications made by those skilled in the art do not depart from the spirit and scope of the present invention, then it all should be appended by the present invention
In scope of the claims.
Claims (10)
1. a kind of washable hair dye, which is characterized in that including I dose and II dose：
Wherein I dose is made of the following components by mass percentage：Graphene 0.25~5%, graphene stabilizer 5~10%,
Ascorbic acid 0.5~2.5%, propylgallate 1~3%, glycerine 5%, thickener 2~5%, surplus are water；
Wherein II dose is made of the following components by mass percentage：Ferrous sulfate 5~10%, ascorbic acid 0.1~0.5%,
Glycerine 5%, alkaline agent 1~5%, thickener 2~5%, surplus is water.
2. a kind of washable hair dye according to claim 1, which is characterized in that the graphene be graphene oxide or
By the graphene oxide of reduction.
3. a kind of washable hair dye according to claim 1, which is characterized in that the graphene stabilizer be tannic acid or
Person's gallic acid.
4. a kind of washable hair dye according to claim 1, which is characterized in that the alkaline agent is edible basic species
Matter.
5. a kind of washable hair dye according to claim 4, which is characterized in that the edible alkaline matter is burnt phosphorus
Sour sodium, sodium bicarbonate, sodium tripolyphosphate or sodium citrate.
6. a kind of washable hair dye according to claim 1, which is characterized in that the thickener is carboxymethyl cellulose
The mixture of one or more of sodium, hydroxyethyl cellulose, methylcellulose, xanthans, gelatin and anti-jelly thickener.
7. a kind of washable hair dye according to claim 1, which is characterized in that when the hair dye uses I agent with II dose
Weight ratio is 1：1.
8. a kind of preparation method of the washable hair dye as described in claim any one of 1-7, which is characterized in that including walking as follows
Suddenly：
Step 1:Graphene dispersing solution is prepared, ascorbic acid and graphene stabilizer is added, 1~4h of heating stirring makes at 90 DEG C
Graphene restores, and then obtains graphene by filtering or centrifuging；
Step 2：I agent is prepared, 60~65 DEG C is heated water to, is proportionally added into I agent each component raw materials, after stirring evenly, is added
Graphene dispersing solution is again stirring for uniformly, and postcooling is to 45 DEG C or less；
Step 3：II dose is prepared, weighs II dose of each component raw material in proportion, after heating water to 60~65 DEG C, is added II dose respectively
Component raw material is cooled to 45 DEG C or less.
9. the preparation method of washable hair dye according to claim 8, which is characterized in that the graphene stabilizer is at twice
It is added, is added when in step 1 prepared by graphene dispersing solution for the first time, is added when preparing I agent in step 2 for the second time.
10. the preparation method of washable hair dye according to claim 9, which is characterized in that be added in step 1 and step 2
The weight ratio of graphene stabilizer is 1：1.
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| CN201810254105.8A CN108451780A (en) | 2018-03-26 | 2018-03-26 | A kind of washable hair dye and preparation method thereof |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109010126A (en) * | 2018-10-08 | 2018-12-18 | 齐鲁工业大学 | A kind of method of photochemical treatment graphene-silk-fibroin composite material |
| CN109350550A (en) * | 2018-12-12 | 2019-02-19 | 青岛大学 | A kind of graphene hair coloring preparation composition of the iron oxide red containing nanometer |
| CN109350549A (en) * | 2018-12-12 | 2019-02-19 | 青岛大学 | A kind of black graphene hair coloring preparation composition |
| CN109431855A (en) * | 2018-12-12 | 2019-03-08 | 青岛大学 | A kind of pearly-lustre graphene hair coloring preparation composition of chitosan-containing |
| CN109453046A (en) * | 2018-12-12 | 2019-03-12 | 青岛大学 | A kind of graphene hair coloring preparation composition of the pearlescent pigment of iron series containing mica |
| CN109453045A (en) * | 2018-12-12 | 2019-03-12 | 青岛大学 | A kind of brown graphene hair coloring preparation composition |
| CN111329805A (en) * | 2020-03-24 | 2020-06-26 | 电子科技大学中山学院 | Preparation method of novel natural madder graphene hair dye |
| CN112545929A (en) * | 2019-09-10 | 2021-03-26 | 陈飞 | Edible hair dye without allergy |
| CN113398009A (en) * | 2021-05-26 | 2021-09-17 | 马宋 | Natural plant hair dye capable of filtering extract and preparation method thereof |
| WO2024059971A1 (en) * | 2022-09-19 | 2024-03-28 | Jmm Limited | Hair dye composition having improved viscosity |
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| WO2014002669A1 (en) * | 2012-06-27 | 2014-01-03 | 富士フイルム株式会社 | Hair-dye composition |
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| WO2014002669A1 (en) * | 2012-06-27 | 2014-01-03 | 富士フイルム株式会社 | Hair-dye composition |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109010126A (en) * | 2018-10-08 | 2018-12-18 | 齐鲁工业大学 | A kind of method of photochemical treatment graphene-silk-fibroin composite material |
| CN109350550A (en) * | 2018-12-12 | 2019-02-19 | 青岛大学 | A kind of graphene hair coloring preparation composition of the iron oxide red containing nanometer |
| CN109350549A (en) * | 2018-12-12 | 2019-02-19 | 青岛大学 | A kind of black graphene hair coloring preparation composition |
| CN109431855A (en) * | 2018-12-12 | 2019-03-08 | 青岛大学 | A kind of pearly-lustre graphene hair coloring preparation composition of chitosan-containing |
| CN109453046A (en) * | 2018-12-12 | 2019-03-12 | 青岛大学 | A kind of graphene hair coloring preparation composition of the pearlescent pigment of iron series containing mica |
| CN109453045A (en) * | 2018-12-12 | 2019-03-12 | 青岛大学 | A kind of brown graphene hair coloring preparation composition |
| CN112545929A (en) * | 2019-09-10 | 2021-03-26 | 陈飞 | Edible hair dye without allergy |
| CN111329805A (en) * | 2020-03-24 | 2020-06-26 | 电子科技大学中山学院 | Preparation method of novel natural madder graphene hair dye |
| CN113398009A (en) * | 2021-05-26 | 2021-09-17 | 马宋 | Natural plant hair dye capable of filtering extract and preparation method thereof |
| WO2024059971A1 (en) * | 2022-09-19 | 2024-03-28 | Jmm Limited | Hair dye composition having improved viscosity |
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Application publication date: 20180828 |