CN109431855A - A kind of pearly-lustre graphene hair coloring preparation composition of chitosan-containing - Google Patents
A kind of pearly-lustre graphene hair coloring preparation composition of chitosan-containing Download PDFInfo
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- CN109431855A CN109431855A CN201811515255.6A CN201811515255A CN109431855A CN 109431855 A CN109431855 A CN 109431855A CN 201811515255 A CN201811515255 A CN 201811515255A CN 109431855 A CN109431855 A CN 109431855A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/736—Chitin; Chitosan; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/436—Interference pigments, e.g. Iridescent, Pearlescent
Abstract
The invention discloses a kind of pearly-lustre graphene hair coloring preparation compositions of chitosan-containing, are related to hair dye technical field, including first dose and second dose, in which: first dose, are made by mica iron series pearlescent pigment, graphene and chitosan;Second dose, the aqueous solution for being 2-10% by the mass concentration that boric acid and borax are made into.In the present invention, mica iron series pearlescent pigment, graphene, zinc salt and chitosan belong to green material, are free of harmful synthetics;Organosilicon synthesis process is avoided, organosilicon derivates, simple process, no pollution to the environment are not contained;It is added to boric acid in second dose, it was proved that, water resistance and detergent resistance can significantly improve, and have more practicability.
Description
Technical field
The present invention relates to a kind of combinations of the pearly-lustre graphene hair dye of hair dye technical field more particularly to chitosan-containing
Object.
Background technique
Hair dye is a kind of cosmetics for hair, and effect is to reach beauty beauty by changing hair color
The effect of hair.
The hair dye in ancient times and its method of hair dyeing have continued up to modern natural hair dye.Since they are mostly from plant
Object, it is smaller to body and hair damage, but prominent disadvantage is exactly that dyeing time is long, and technics comparing is cumbersome, it needs to smear repeatedly,
Effect not persistently, the technological deficiency of aesthetic effect difference.For example, CN2017110673105 discloses a kind of natural drug hair dye:
It is made of A hair dye, B color fixing agent, C conditioner three parts, coloring agent is by Chinese gall, Hai Naye, cape jasmine, sophora flower, turmeric, coffee
Beans, surfactant, green tea, salt composition, need to go in adhesives to hair, then impaired rotten with conditioner solution hair
Problem.CN2014104289241 discloses a kind of Natural chitosan antibacterial nutrition hair dye: by following components by shown parts by weight
Proportional region is prepared: 15~25 parts of activated ionic calcium, 8~13 parts of silicon powder, 5~10 parts of chitosan, 3~8 parts of beeswax, chitin
1~3 part, 3~8 parts of coconut oil, 3~8 parts of egg-white powder, 2~20 parts of FLOS CHRYSANTHEMI ALBA from Haizhou of China, 10~15 parts of the fleece-flower root, indigo naturalis 10~15, poly- third
2~4 parts of olefin(e) acid sodium.
In order to improve the above-mentioned deficiency for making up natural hair dye, manufacturer generally use addition p-phenylenediamine, m-phenylene diamine (MPD),
The synthetics such as m-aminophenol, hydroquinone, resorcinol, methylphenol, then with hydrogen peroxide or other oxidant oxygen
It is melted into the technology of dyestuff.So the leading role for occupying market at present is modern chemistry hair dye.Modern chemistry hair dye is by benzene
The synthetics such as diamines, m-phenylene diamine (MPD), m-aminophenol, hydroquinone, resorcinol, methylphenol are first dose, dioxygen
Water is second dose, and the used time compounds together, is applied on hair for having hair dyed, is applied on skin for tatooing.However, p-phenylenediamine
Belong to carcinogenic 3 class in the carcinogen list of international cancer association with o-phenylenediamine and its derivative, there are limited evidences
Show that it is potentially carcinogenic.Simultaneously it there is also following harm and risks:
1, carcinogenic risk: the researcher of Yale once investigated the female that hair dyeing was begun to before 1980
Property, discovery is more than that 1/3 people can suffer from lymthoma.Although whether carcinogenic to hair dyeing in the world, there are still disputes, but exist and cause
The risk of cancer is existing.
2, cause skin allergy: verified evidence for the sensitization of p-phenylenediamine (PPD).Before 20th century, people, which are known that, to be contained
Contact hypersensitivity can be caused by having the hair dye of PPD.With will appear the puffiness of the eyes after hair dye, there is erythema, small in skin
Rash, serious to play blister, surprise is itched unbearably, especially painful.2006, PPD was classified as current year by contact dermatitis association, the U.S.
The disease incidence of contactant, PPD contact allergy increases trend in continuous.The European Union member countries such as France, Germany are prohibited by explicit order
Only p-phenylenediamine is added in hair dye.
3, damage liver kidney: some products are enhancing dyeing effect in the market, can add the heavy metals such as lead, mercury, arsenic, and is produced from part
Lead tolerance in product even paints 5-10 times of lead tolerance, and long-time service can cause chronic lesion to body, it is not only possible to go out
The lead poisonings symptoms such as existing giddy, numb limb, abdominal pain, it is also possible to damage the function of the internal organs such as liver, kidney.
4, hair is impaired: hair dye is redox chemistry reaction, will affect moisture imbalance in hair, leads to a large amount of eggs
Denaturation and reduction of white matter etc..Make a slit or vent, become fragile so as to cause hair, fibrous fracture, make hair lose natural soft, toughness and
The aesthetic feeling of gloss.
5, infiltration is poisoned: hair dye not only contacts hair, can't avoid contact with scalp.Scalp be human body hair follicle at most,
Most intensive position, its meeting chemical component enter the channel of human body.So as long as phenyl amines hair dye contacts scalp, not only
It can be made to colour, and chemical toxicant can be entered in human body by the numerous hair follicle channels on scalp, or even be followed by micro-
Loop system enters blood, causes to systemic organs potentially hazardous.
6, ammonium hydroxide pollutes: phenyl amines hair dye, also containing volatility and the very strong ammonium hydroxide of alkalinity, leads to expand human hair
It crosses respiratory system to do harm to huamn body, and causes environmental pollution.
In order to increase the bright property and flexibility of hair dye, existing technology can add organic silicon-type column synthetics,
But exists and be difficult to biodegrade, there is the defect of pollution to environment.For example, the 3- chloropropyl first of patent application 201810975949.1
Base dialkoxy silicane and N, N- dimethyl C6-C16 tertiary amine are reacted to obtain quaternized methyl dioxane oxysilane;By eight first
Basic ring tetrasiloxane, dialkoxy silicane containing amino methyl and quaternized methyl dioxane oxysilane are balanced reaction and are contained
The quaternized silicone oil of amino is added in hair dye;The dialkoxy silicane containing amino methyl of patent application 201810975961.2,
Mercapto hydroxypropyl methyl dialkoxy silicane, octamethylcy-clotetrasiloxane and closure agent are balanced reaction, obtain amino mercapto silicone oil;
By amino mercapto silicone oil, methacrylic acid N, N- dialkylamino ethyl and isopropanol under photoinitiator and ultraviolet light into
Row sulfydryl-alkene clicking chemistry reacts to obtain amino copolymerization silicone oil;Amino copolymerization silicone oil and quaternizing agent are carried out quaternized anti-
It answers, obtains the quaternized silicone oil containing amino and be added in graphene.This kind of technology not only can only obtain single yellow, but also make
It can cause environmental pollution in standby and use process.
Summary of the invention
In order to solve the above technical problems, the invention discloses a kind of pearly-lustre graphene hair coloring preparation compositions of chitosan-containing.
To achieve the above object, the present invention adopts the following technical solutions:
A kind of pearly-lustre graphene hair coloring preparation composition of chitosan-containing, including first dose and second dose, in which: first dose,
It is made by mica iron series pearlescent pigment, graphene and chitosan;It second dose, is made by boric acid and borax.
Further, first dose of the preparation process includes:
(1) chitosan is first dissolved in the acetic acid aqueous solution that mass concentration is 1-10%, water-soluble zinc salt is added, it is poly- that shell is made
Sugared gel of zinc;
(2) a certain amount of mica iron series pearlescent pigment and graphene are added into chitosan-zn gel, and dedicated with mill base
Three-roll grinder homogeneous, as first dose.
Further, the zinc salt selects zinc sulfate or boric acid.
Further, in first dose of preparation process, mica iron series pearlescent pigments, graphene, zinc salt, chitosan
Mass percent is 3-10%:0.3%-2%:15-25%:63%-81.7%.
Further, the fineness of mica iron series pearlescent pigment is having a size of 0.1-200 μm
Further, described second dose is that boric acid mixes the aqueous solution that the mass concentration being made into is 10-25%, boron with borax
The mass percent of acid and borax is 5-15%:85-95%.
A kind of hair colouring methods use above-mentioned hair coloring preparation composition, which is characterized in that hair dyeing sequence are as follows: first by first dose
After being uniformly applied to hair, then second dose is uniformly applied on hair, reacts 5-15min, to mica iron series pearlescent pigment with
Graphene is fixed on hair, then is washed, dried with clear water.
The invention has the advantages that
1, mica iron series pearlescent pigment, graphene, zinc salt and chitosan belong to green material, due to not containing currentization
Learn p-phenylenediamine, the m-phenylene diamine (MPD), m-aminophenol, hydroquinone, resorcinol, methylphenol, organic silicone oil in hair dye
Equal synthetics, so eliminating seven big harm existing for traditional hair dye: (1) carcinogenic risk, (2) skin allergy, (3)
Damage liver kidney, (4) hair is damaged, (5) infiltration is poisoned, the pollution of (6) ammonium hydroxide, (7) organic silicone oil.
2, mica iron series pearlescent pigment has relatively full nonhazardous, high temperature resistant, light shine, acid and alkali-resistance, chromatography, light shine, no
The advantages that discoloration, can especially obtain pearly-lustre aesthetic effect.
3, graphene specific surface is big, be in lamellar structure, it is big with the scale layer contact area of hair, cohesive force with regard to strong, just between
The cohesive force increased to mica iron series pearlescent pigment is connect, tests prove that washability effect has humidification.
4, exempt thickener, traditional hair dye needs to add thickener, and the chitosan in the present invention is soluble high-molecular
Material, ontology thickening, and react and moment the graphene oxide of brown can be bonded on hair with metal ion, it is no different
Taste, hair dyeing aesthetic effect be good, the washing of resistance to shampoo.
5, boric acid is added in second dose, it was proved that, water resistance and detergent resistance can significantly improve, and have more
Practicability.
6, the invention avoids organosilicon synthesis processes, do not contain organosilicon derivates, simple process, to environment without dirt
Dye.
Specific embodiment
In order to clearly illustrate the technical characterstic of this programme, the present invention is made further below with reference to embodiment
It is bright.
Embodiment 1
A kind of pearly-lustre graphene hair coloring preparation composition of chitosan-containing, preparation process include:
(1) it weighs chitosan 72g and is dissolved in the acetic acid aqueous solution that 1000g concentration is 5%, 20g zinc sulfate is added, it is poly- that shell is made
Sugared gel of zinc;
(2) the red pearlescent pigment 7g and pure graphene 1g of mica iron series is added into chitosan-zn gel, with mill base dedicated three
To get first dose after roller mill homogeneous;
(3) by boric acid and borax according to the ratio of mass percent 10%:90%, be made into mass concentration be 6% it is water-soluble
Liquid 600mL, as second dose;
Above-mentioned first dose is first first applied in white hair by a kind of hair colouring methods, then is uniformly applied to hair for second dose
On, it reacts 15 minutes, just mica iron series pearlescent pigment and pure graphene is fixed on hair, it is reddish brown to become pearly-lustre to hair
Color hair, clear water washing, drying.
Embodiment 2
A kind of pearly-lustre graphene hair coloring preparation composition of chitosan-containing, preparation process include:
(1) it weighs chitosan 81.7g and is dissolved in the acetic acid aqueous solution that 1000g concentration is 10%, 15g zinc sulfate is added, is made
Chitosan-zn gel;
(2) mica iron series indigo plant pearl powder 3g and graphene 0.3g are added into chitosan-zn gel, with dedicated three roller of mill base
To get first dose after grinder homogeneous;
(3) by boric acid and boric acid according to the ratio of mass percent 5%:95%, be made into mass concentration be 10% it is water-soluble
Liquid 600mL, as second dose;
Above-mentioned first dose is first first applied in white hair by a kind of hair colouring methods, then is uniformly applied to hair for second dose
On, it reacts 10 minutes, just mica iron series pearlescent pigment, graphene is fixed on hair, become pearly-lustre blue, clear water to hair
Washing, drying.
Embodiment 3
A kind of pearly-lustre graphene hair coloring preparation composition of chitosan-containing, preparation process include:
(1) it weighs chitosan 81.7g and is dissolved in the acetic acid aqueous solution that 1000g concentration is 10%, 25g zinc sulfate is added, is made
Chitosan-zn gel;
(2) the green pearlescent pigment 10g and pure graphene 2g of mica iron series is added into chitosan-zn gel, with mill base dedicated three
To get first dose after roller mill homogeneous;
(3) by boric acid and boric acid according to the ratio of mass percent 15%:85%, be made into mass concentration be 2% it is water-soluble
Liquid 600mL, as second dose;
Above-mentioned first dose is first first applied in white hair by a kind of hair colouring methods, then is uniformly applied to hair for second dose
On, it reacts 5 minutes, just mica iron series pearlescent pigment, pure graphene is fixed on hair, hair is allowed to become pearly-lustre green,
Clear water washing, drying.
Embodiment 4
A kind of pearly-lustre graphene hair coloring preparation composition of chitosan-containing, preparation process include:
(1) it weighs chitosan 72g and is dissolved in the acetic acid aqueous solution that 1000g concentration is 5%, 17.5g zinc sulfate is added, shell is made
Glycan gel of zinc;
(2) mica iron series Callicarpa bodinieri Levl. delustering pigment 5g and graphene 1.5g are added into chitosan-zn gel, with mill base dedicated three
To get first dose after roller mill homogeneous;
(3) boric acid and boric acid are made into the aqueous solution that mass concentration is 4% according to the ratio of mass percent 7%:93%
600mL, as second dose.
Above-mentioned first dose is first first applied in white hair by a kind of hair colouring methods, then is uniformly applied to hair for second dose
On, it reacts 10 minutes, just mica iron series pearlescent pigment, graphene is fixed on hair, to hair pearly-lustre purple, clear water is washed
It washs, dry.
Embodiment 5
The red pearl powder of mica iron series is only replaced with into mica iron series Huang pearlescent pigment, obtains pearly-lustre yellow hair, remaining is same
Embodiment 1.
Embodiment 6
The red pearl powder of mica iron series is only replaced with into the black pearlescent pigment of mica iron series, obtains pearly-lustre black hair, remaining is same
Embodiment 1.
Embodiment 7
The red pearl powder of mica iron series is only replaced with into mica iron series ash pearlescent pigment, obtains pearly-lustre grey hair, remaining is same
Embodiment 1.
Embodiment 8
The red pearl powder of mica iron series is only replaced with into mica iron series orange pearlescent pigment, obtains the orange hair of pearly-lustre, remaining is same
Embodiment 1.
Embodiment 9
The red pearl powder of mica iron series is only replaced with into the white pearlescent pigment of mica iron series, obtains pearlescent white hair, remaining is same
Embodiment 1.
Embodiment 10
Graphene is not only added, remaining is the same as embodiment 1.
Embodiment 11
Zinc sulfate is not only added, remaining is the same as embodiment 1.
Embodiment 12
By second dose in embodiment 1,6% boric acid aqueous solution 600mL is replaced with, remaining is the same as embodiment 1.
Embodiment 13
By second dose in embodiment 1,6% borax solution 600mL is replaced with, remaining is the same as embodiment 1.
In the above embodiments, embodiment 10-13 is comparative test: embodiment 10 be do not add graphene to having a competition
It tests;Embodiment 11 is not add the comparative test of zinc salt;Embodiment 12 is not add the comparative test of borax;Embodiment 13 is not
Add the comparative test of boric acid.
Using hair dye obtained in embodiment, the effect experiment evaluation for hairdressing of having hair dyed is as follows:
Experimental material: white hair, the embodiment hair coloring preparation composition of people, commercially available Head&Shoulders board shampoo.
First dose in embodiment hair coloring preparation composition: being first applied on white hair by test method, then uniformly by second dose
It smears on white hair, reacts 15 minutes, then smear commercially available Head&Shoulders board shampoo simultaneously, rub 2 minutes, wash three with clear water
It is secondary.
Evaluation effect: evaluating white hair hiding rares with 5 grades of evaluation assessments, each+number a rank is represented, 5+number effects are most
Good, a+number effect is worst;Pearl effect ocular estimate, with it is excellent, good, in, poor level Four objectively evaluates.
Washable experiment: being washed several times with above-mentioned washing methods, evaluates white hair hiding rare with 5 grades of evaluation assessments, and rank is higher,
Washability is better, conversely, washability is poorer.
According to above-mentioned test method and evaluation method, the experimental results are shown inthe following table by embodiment 1-8:
Embodiment | Hairdressing color | Pearl effect | Washing 3 times | Washing 5 times | Washing 10 times | Washing 13 times | Washing 16 times |
1 | Pearly-lustre is red | It is excellent | +++++ | ++++ | +++ | ++ | + |
2 | Pearly-lustre blue | It is good | +++++ | +++ | ++ | + | |
3 | Pearly-lustre is blackish green | It is good | +++++ | +++ | ++ | + | |
4 | Pearly-lustre is purplish red | It is good | +++++ | +++ | ++ | + | |
5 | Pearly-lustre is deep yellow | It is good | +++++ | +++ | ++ | + | |
6 | Pearly-lustre black | It is excellent | +++++ | ++++ | +++ | ++ | + |
7 | Pearly-lustre grey | It is good | +++++ | +++ | ++ | + | |
8 | Pearly-lustre is orange | It is good | +++++ | +++ | ++ | + | |
9 | Pearlescent white | It is good | +++++ | +++ | ++ | + | |
10 | Pearly-lustre is red | Difference | +++ | ++ | + | ||
11 | Pearly-lustre is red | Difference | +++ | ++ | + | ||
12 | Pearly-lustre is red | Difference | +++ | ++ | + | ||
13 | Pearly-lustre is red | In | ++++ | +++ | ++ | + |
Evaluation effect: evaluating white hair hiding rares with 5 grades of evaluation assessments, each+number a rank is represented, 5+number effects are most
Good, a+number effect is worst.
Washable experiment: being washed several times with above-mentioned washing methods, evaluates white hair hiding rare with 5 grades of evaluation assessments, and rank is higher,
Washability is better, conversely, washability is poorer.
According to above-mentioned test method and evaluation method, the experimental result of embodiment 1-5 is as follows:
+++ ++ it is completely covered by white hair, becomes this hair cosmetic agent true qualities, evenness has pearly-lustre, soft glossy, but is excellent
Elegant standard;
++++cover white hair, becomes this hair cosmetic agent true qualities, and coloration is substantially uniform, has pearly-lustre, soft glossy general, but
For good standard;
+++ covering white hair substantially becomes this hair cosmetic agent true qualities, color evenness is general, has pearly-lustre, but have gray tone, can
It is considered as qualified standard;
++ it cannot be completely covered by white hair, this hair cosmetic agent true qualities become gray tone, and pearl effect does not protrude;
+ white hair, this hair cosmetic agent true qualities and white alternate appearance, no pearly-lustre cannot be covered.
It can be seen that the present invention, which can satisfy, covers technical effect, the soft beauty of color primary, that pearly-lustre hairdressing is presented,
It is minimum to remain to reach criterion of acceptability for wash resistant 3 times;Embodiment 2-5,7-9 can be 5 times washable, and embodiment 1,6 highests are resistant to
It washes 10 times;The washable number of embodiment 10-12 is minimum, and pearl effect is also poor, when illustrating not add graphene, zinc salt or borax,
Washing fastness is remarkably decreased, and pearl effect obviously weakens;13 washing fastness of embodiment is general, and pearl effect is general, illustrates exist
The synergistic effect of boric acid and borax.
Certainly, the above description is not a limitation of the present invention, and the present invention is also not limited to the example above, this technology neck
The variations, modifications, additions or substitutions that the technical staff in domain is made within the essential scope of the present invention also should belong to of the invention
Protection scope.
Claims (7)
1. a kind of pearly-lustre graphene hair coloring preparation composition of chitosan-containing, which is characterized in that including first dose and second dose,
In: it first dose, is made by mica iron series pearlescent pigment, graphene and chitosan;It second dose, is made by boric acid and borax.
2. a kind of pearly-lustre graphene hair coloring preparation composition of chitosan-containing as described in claim 1, which is characterized in that described the
One preparation process includes:
(1) chitosan is first dissolved in the acetic acid aqueous solution that mass concentration is 1-10%, water-soluble zinc salt is added, chitosan-zn is made
Gel;
(2) a certain amount of mica iron series pearlescent pigment and graphene are added into chitosan-zn gel, and with dedicated three roller of mill base
Grinder homogeneous, as first dose.
3. a kind of pearly-lustre graphene hair coloring preparation composition of chitosan-containing as claimed in claim 2, which is characterized in that the zinc
Salt selects zinc sulfate or boric acid.
4. a kind of pearly-lustre graphene hair coloring preparation composition of chitosan-containing as described in claim 1, which is characterized in that first
In agent preparation process, mica iron series pearlescent pigment, graphene, zinc salt, chitosan mass percent be 3-10%:0.3-
2%:15-25%:63-81.7%.
5. a kind of pearly-lustre graphene hair coloring preparation composition of chitosan-containing as claimed in claim 4, which is characterized in that mica iron
It is the fineness of pearlescent pigment having a size of 0.1-200 μm.
6. a kind of pearly-lustre graphene hair coloring preparation composition of chitosan-containing as described in claim 1, which is characterized in that described the
Two doses are that boric acid mixes the aqueous solution that the mass concentration being made into is 2-10% with borax, and the mass percent of boric acid and borax is 5-
15%:85-95%.
7. a kind of hair colouring methods use the hair coloring preparation composition as described in claim 1-6 is any, which is characterized in that hair dyeing is suitable
Sequence are as follows: after being first uniformly applied to hair for first dose, then second dose is uniformly applied on hair, reaction 5-15min, to mica
Iron series pearlescent pigment and graphene are fixed on hair, then are washed, dried with clear water.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111329805A (en) * | 2020-03-24 | 2020-06-26 | 电子科技大学中山学院 | Preparation method of novel natural madder graphene hair dye |
CN111568784A (en) * | 2020-04-29 | 2020-08-25 | 东莞东阳光科研发有限公司 | A hair dye containing boron nitride |
KR102338053B1 (en) | 2021-07-16 | 2021-12-13 | 한국콜마주식회사 | Hair coloring leave-on cosmetics containing graphene oxide |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06248581A (en) * | 1993-02-22 | 1994-09-06 | Mitsui Petrochem Ind Ltd | Method for dyeing fiber substance with shikonin-based dye |
CN108030704A (en) * | 2017-12-21 | 2018-05-15 | 北京工商大学 | Botanical hair dye and preparation method using graphene oxide as dyeing auxiliaries |
CN108451780A (en) * | 2018-03-26 | 2018-08-28 | 郑小华 | A kind of washable hair dye and preparation method thereof |
-
2018
- 2018-12-12 CN CN201811515255.6A patent/CN109431855A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06248581A (en) * | 1993-02-22 | 1994-09-06 | Mitsui Petrochem Ind Ltd | Method for dyeing fiber substance with shikonin-based dye |
CN108030704A (en) * | 2017-12-21 | 2018-05-15 | 北京工商大学 | Botanical hair dye and preparation method using graphene oxide as dyeing auxiliaries |
CN108451780A (en) * | 2018-03-26 | 2018-08-28 | 郑小华 | A kind of washable hair dye and preparation method thereof |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111329805A (en) * | 2020-03-24 | 2020-06-26 | 电子科技大学中山学院 | Preparation method of novel natural madder graphene hair dye |
CN111568784A (en) * | 2020-04-29 | 2020-08-25 | 东莞东阳光科研发有限公司 | A hair dye containing boron nitride |
KR102338053B1 (en) | 2021-07-16 | 2021-12-13 | 한국콜마주식회사 | Hair coloring leave-on cosmetics containing graphene oxide |
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