CN109453046A - A kind of graphene hair coloring preparation composition of the pearlescent pigment of iron series containing mica - Google Patents
A kind of graphene hair coloring preparation composition of the pearlescent pigment of iron series containing mica Download PDFInfo
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- CN109453046A CN109453046A CN201811515254.1A CN201811515254A CN109453046A CN 109453046 A CN109453046 A CN 109453046A CN 201811515254 A CN201811515254 A CN 201811515254A CN 109453046 A CN109453046 A CN 109453046A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/733—Alginic acid; Salts thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
- A61K2800/884—Sequential application
Abstract
The invention discloses a kind of graphene hair coloring preparation compositions of pearlescent pigment of iron series containing mica, are related to hair dye technical field, including first dose and second dose, in which: first dose, are made by mica iron series pearlescent pigment, graphene and alginate；It second dose, is made by multivalent metal salt and boric acid.In the present invention, mica iron series pearlescent pigment, graphene, alginate belong to green material and belong to green material, are free of harmful synthetics；Organosilicon synthesis process is avoided, organosilicon derivates, simple process, no pollution to the environment are not contained；It is added to boric acid in second dose, it was proved that, water resistance and detergent resistance can significantly improve, and have more practicability.
Description
Technical field
The present invention relates to hair dye technical field more particularly to a kind of graphene hair dyes of iron series containing mica pearlescent pigment
Composition.
Background technique
Hair dye is a kind of cosmetics for hair, and effect is to reach beauty beauty by changing hair color
The effect of hair.
The hair dye in ancient times and its method of hair dyeing have continued up to modern natural hair dye.Since they are mostly from plant
Object, it is smaller to body and hair damage, but prominent disadvantage is exactly that dyeing time is long, and technics comparing is cumbersome, it needs to smear repeatedly,
Effect not persistently, the technological deficiency of aesthetic effect difference.For example, CN2017110673105 discloses a kind of natural drug hair dye:
It is made of A hair dye, B color fixing agent, C conditioner three parts, coloring agent is by Chinese gall, Hai Naye, cape jasmine, sophora flower, turmeric, coffee
Beans, surfactant, green tea, salt composition, need to go in adhesives to hair, then impaired rotten with conditioner solution hair
Problem.CN2014104289241 discloses a kind of Natural chitosan antibacterial nutrition hair dye: by following components by shown parts by weight
Proportional region is prepared: 15~25 parts of activated ionic calcium, 8~13 parts of silicon powder, 5~10 parts of sodium alginate, 3~8 parts of beeswax, crust
1~3 portion of element, 3~8 parts of egg-white powder, 2~20 parts of FLOS CHRYSANTHEMI ALBA from Haizhou of China, 10~15 parts of the fleece-flower root, indigo naturalis 10~15, gathers 3~8 parts of coconut oil
2~4 parts of sodium acrylate.
In order to improve the above-mentioned deficiency for making up natural hair dye, manufacturer generally use addition p-phenylenediamine, m-phenylene diamine (MPD),
The synthetics such as m-aminophenol, hydroquinone, resorcinol, methylphenol, then with hydrogen peroxide or other oxidant oxygen
It is melted into the technology of dyestuff.So the leading role for occupying market at present is modern chemistry hair dye.Modern chemistry hair dye is by benzene
The synthetics such as diamines, m-phenylene diamine (MPD), m-aminophenol, hydroquinone, resorcinol, methylphenol are first dose, dioxygen
Water is second dose, and the used time compounds together, is applied on hair for having hair dyed, is applied on skin for tatooing.However, p-phenylenediamine
Belong to carcinogenic 3 class in the carcinogen list of international cancer association with o-phenylenediamine and its derivative, there are limited evidences
Show that it is potentially carcinogenic.Simultaneously it there is also following harm and risks:
1, carcinogenic risk: the researcher of Yale once investigated the female that hair dyeing was begun to before 1980
Property, discovery is more than that 1/3 people can suffer from lymthoma.Although whether carcinogenic to hair dyeing in the world, there are still disputes, but exist and cause
The risk of cancer is existing.
2, cause skin allergy: verified evidence for the sensitization of p-phenylenediamine (PPD).Before 20th century, people, which are known that, to be contained
Contact hypersensitivity can be caused by having the hair dye of PPD.With will appear the puffiness of the eyes after hair dye, there is erythema, small in skin
Rash, serious to play blister, surprise is itched unbearably, especially painful.2006, PPD was classified as current year by contact dermatitis association, the U.S.
The disease incidence of contactant, PPD contact allergy increases trend in continuous.The European Union member countries such as France, Germany are prohibited by explicit order
Only p-phenylenediamine is added in hair dye.
3, damage liver kidney: some products are enhancing dyeing effect in the market, can add the heavy metals such as lead, mercury, arsenic, and is produced from part
Lead tolerance in product even paints 5-10 times of lead tolerance, and long-time service can cause chronic lesion to body, it is not only possible to go out
The lead poisonings symptoms such as existing giddy, numb limb, abdominal pain, it is also possible to damage the function of the internal organs such as liver, kidney.
4, hair is impaired: hair dye is redox chemistry reaction, will affect moisture imbalance in hair, leads to a large amount of eggs
Denaturation and reduction of white matter etc..Make a slit or vent, become fragile so as to cause hair, fibrous fracture, make hair lose natural soft, toughness and
The aesthetic feeling of gloss.
5, infiltration is poisoned: hair dye not only contacts hair, can't avoid contact with scalp.Scalp be human body hair follicle at most,
Most intensive position, its meeting chemical component enter the channel of human body.So as long as phenyl amines hair dye contacts scalp, not only
It can be made to colour, and chemical toxicant can be entered in human body by the numerous hair follicle channels on scalp, or even be followed by micro-
Loop system enters blood, causes to systemic organs potentially hazardous.
6, ammonium hydroxide pollutes: phenyl amines hair dye, also containing volatility and the very strong ammonium hydroxide of alkalinity, leads to expand human hair
It crosses respiratory system to do harm to huamn body, and causes environmental pollution.
In order to increase the bright property and flexibility of hair dye, existing technology can add organic silicon-type column synthetics,
But exists and be difficult to biodegrade, there is the defect of pollution to environment.For example, the 3- chloropropyl first of patent application 201810975949.1
Base dialkoxy silicane and N, N- dimethyl C6-C16 tertiary amine are reacted to obtain quaternized methyl dioxane oxysilane；By eight first
Basic ring tetrasiloxane, dialkoxy silicane containing amino methyl and quaternized methyl dioxane oxysilane are balanced reaction and are contained
The quaternized silicone oil of amino is added in hair dye；The dialkoxy silicane containing amino methyl of patent application 201810975961.2,
Mercapto hydroxypropyl methyl dialkoxy silicane, octamethylcy-clotetrasiloxane and closure agent are balanced reaction, obtain amino mercapto silicone oil；
By amino mercapto silicone oil, methacrylic acid N, N- dialkylamino ethyl and isopropanol under photoinitiator and ultraviolet light into
Row sulfydryl-alkene clicking chemistry reacts to obtain amino copolymerization silicone oil；Amino copolymerization silicone oil and quaternizing agent are carried out quaternized anti-
It answers, obtains the quaternized silicone oil containing amino and be added in graphene.This kind of technology not only can only obtain single yellow, but also make
It can cause environmental pollution in standby and use process.
Summary of the invention
In order to solve the above technical problems, the invention discloses a kind of graphene hair dye groups of pearlescent pigment of iron series containing mica
Close object.
To achieve the above object, the present invention adopts the following technical solutions:
A kind of graphene hair coloring preparation composition of the pearlescent pigment of iron series containing mica, including first dose and second dose, in which: the
It is one, it is made by mica iron series pearlescent pigment, graphene and alginate；It second dose, is made by multivalent metal salt and boric acid.
Further, first dose of the preparation process includes:
(1) alginate is first dissolved in water, adjusting solution ph is 7-10, is made into alginate；
(2) a certain amount of mica iron series pearlescent pigment and graphene are added into alginate, and dedicated with mill base
Three-roll grinder homogeneous, as first dose.
Further, the graphene selects pure graphene (GO) or reduced graphene (RGO), and alginate selects seaweed
One of sour sodium, potassium alginate and ammonium alginate.
Further, in first dose of preparation process, mica iron series pearlescent pigment, graphene, alginate three matter
Amount percentage is 1-10%:1-5%:85-98%.
Further, the fineness of mica iron series pearlescent pigment is having a size of 0.1-200 μm
Further, described second dose is that the mass concentration being made into is mixed with boric acid is 10- to soluble polyvalent metal salt
The mass percent of 25% aqueous solution, metal salt and boric acid is 50-70%:30-50%.
Further, soluble polyvalent metal salt selects at least one of calcium salt, zinc salt.
A kind of hair colouring methods use above-mentioned hair coloring preparation composition, which is characterized in that hair dyeing sequence are as follows: first by first dose
After being uniformly applied to hair, then second dose is uniformly applied on hair, reacts 5-15min, to mica iron series pearlescent pigment with
Graphene is fixed on hair, then is washed, dried with clear water.
The invention has the advantages that
1, mica iron series pearlescent pigment, graphene, alginate belong to green material and belong to green material, due to not
Contain p-phenylenediamine, the m-phenylene diamine (MPD), m-aminophenol, hydroquinone, resorcinol, methylbenzene in current chemical hair dye
The synthetics such as phenol, organic silicone oil, so eliminating seven big harm existing for traditional hair dye: (1) carcinogenic risk, (2) skin
Skin allergy, (3) damage liver kidney, (4) hair are impaired, (5) infiltration is poisoned, the pollution of (6) ammonium hydroxide, (7) organic silicone oil.
2, mica iron series pearlescent pigment is relatively complete with nonhazardous, high temperature resistant, light shine, acid and alkali-resistance, chromatography, discoloration etc. is not excellent
Point can especially obtain pearly-lustre aesthetic effect.
3, exempt thickener, traditional hair dye needs to add thickener, and the alginate in the present invention is soluble high score
Sub- material, ontology thickening, and react and moment the graphene oxide of brown can be bonded on hair with metal ion, it is no different
Taste, hair dyeing aesthetic effect be good, the washing of resistance to shampoo.
4, boric acid is added in second dose, it was proved that, water resistance and detergent resistance can significantly improve, and have more
Practicability.
5, the invention avoids organosilicon synthesis processes, do not contain organosilicon derivates, simple process, to environment without dirt
Dye.
6, graphene specific surface is big, be in lamellar structure, it is big with the scale layer contact area of hair, cohesive force with regard to strong, just between
The cohesive force increased to mica iron series pearlescent pigment is connect, tests prove that washability effect has humidification.
Specific embodiment
In order to clearly illustrate the technical characterstic of this programme, the present invention is made further below with reference to embodiment
It is bright.
Embodiment 1
A kind of graphene hair coloring preparation composition of the pearlescent pigment of iron series containing mica, preparation process include:
(1) it weighs sodium alginate 90g to be dissolved in water 500g distilled water, adjusts pH value 9.5, be made into sodium alginate gel；
(2) the red pearl powder 10g and pure graphene 1g of mica iron series is added into sodium alginate gel, with dedicated three roller of mill base
To get first dose after grinder homogeneous；
(3) calcium chloride and boric acid are made into the water that mass concentration is 20% according to the ratio of mass percent 70%:30%
Solution 500mL, as second dose；
Above-mentioned first dose is first first applied in white hair by a kind of hair colouring methods, then is uniformly applied to hair for second dose
On, it reacts 15 minutes, just mica iron series pearlescent pigment and pure graphene is fixed on hair, become rufous head to hair
Hair, clear water washing, drying.
Embodiment 2
A kind of graphene hair coloring preparation composition of the pearlescent pigment of iron series containing mica, preparation process include:
(1) it weighs sodium alginate 93g to be dissolved in water 500g distilled water, adjusts pH value 9.0, be made into sodium alginate gel；
(2) mica iron series indigo plant pearl powder 5g and reduced graphene 2g are added into sodium alginate gel, with mill base dedicated three
To get first dose after roller mill homogeneous；
(3) zinc chloride and boric acid are made into the water that mass concentration is 15% according to the ratio of mass percent 50%:50%
Solution 500mL, as second dose；
Above-mentioned first dose is first first applied in white hair by a kind of hair colouring methods, then is uniformly applied to hair for second dose
On, it reacts 10 minutes, just mica iron series pearlescent pigment, reduced graphene is fixed on hair, become dark brown to hair, clearly
Water washing, drying.
Embodiment 3
A kind of graphene hair coloring preparation composition of the pearlescent pigment of iron series containing mica, preparation process include:
(1) it weighs sodium alginate 94g to be dissolved in water 500g distilled water, adjusts pH value 8.5, be made into sodium alginate gel；
(2) the green pearlescent pigment 1g and pure graphene 5g of mica iron series is added into sodium alginate gel, with mill base dedicated three
To get first dose after roller mill homogeneous；
(3) zinc chloride is made into the aqueous solution 500mL that mass concentration is 1%, as second dose；
Above-mentioned first dose is first first applied in white hair by a kind of hair colouring methods, then is uniformly applied to hair for second dose
On, it reacts 10 minutes, just mica iron series pearlescent pigment, pure graphene is fixed on hair, allow hair light brown, clear water is washed
It washs, dry.
Embodiment 4
A kind of graphene hair coloring preparation composition of the pearlescent pigment of iron series containing mica, preparation process include:
(1) it weighs sodium alginate 98g to be dissolved in water 500g distilled water, adjusts pH value 10.0, be made into sodium alginate gel；
(2) mica iron series orange pearlescent pigment 1g and reduced graphene 1g is added into sodium alginate gel, it is dedicated with mill base
To get first dose after three-roll grinder homogeneous；
(3) calcium chloride is made into the aqueous solution 500mL that mass concentration is 30%, as second dose；
Above-mentioned first dose is first first applied in white hair by a kind of hair colouring methods, then is uniformly applied to hair for second dose
On, it reacts 10 minutes, just mica iron series pearlescent pigment, reduced graphene is fixed on hair, become dark brown to hair,
Clear water washing, drying.
Embodiment 5
A kind of graphene hair coloring preparation composition of the pearlescent pigment of iron series containing mica, preparation process include:
(1) it weighs sodium alginate 90g to be dissolved in water 500g distilled water, adjusts pH value 8.0, be made into sodium alginate gel；
(2) mica iron series Huang pearlescent pigment 7g and pure graphene 3g is added into sodium alginate gel, with mill base dedicated three
To get first dose after roller mill homogeneous；
(3) calcium chloride and zinc chloride are made into the aqueous solution that mass concentration is 20% according to mass percent 50%:50%
500mL, as second dose；
Above-mentioned first dose is first first applied in white hair by a kind of hair colouring methods, then is uniformly applied to hair for second dose
On, it reacts 10 minutes, just mica iron series pearlescent pigment, pure graphene is fixed on hair, become dark brown to hair, clearly
Water washing, drying.
Embodiment 6
A kind of graphene hair coloring preparation composition of the pearlescent pigment of iron series containing mica, preparation process include:
(1) it weighs sodium alginate 85g to be dissolved in water 500g distilled water, adjusts pH value 7.0, be made into sodium alginate gel；
(2) the black pearlescent pigment 10g and pure graphene 5g of mica iron series is added into sodium alginate gel, with mill base dedicated three
To get first dose after roller mill homogeneous；
(3) zinc chloride and boric acid are made into the water that mass concentration is 10% according to the ratio of mass percent 60%:40%
Solution 500mL, as second dose；
Above-mentioned first dose is first first applied on white hair by a kind of hair colouring methods, then second dose is uniformly applied on hair,
Reaction 5 minutes, just mica iron series pearlescent pigment, pure graphene are fixed on hair, to hair become in red chestnut color of the leather, clearly
Water washing, drying.
Embodiment 7
A kind of graphene hair coloring preparation composition of the pearlescent pigment of iron series containing mica, preparation process include:
(1) it weighs sodium alginate 90g to be dissolved in water 500g distilled water, adjusts pH value 9.5, be made into sodium alginate gel；
(2) mica iron series ash pearl powder 10g and pure graphene 0g is added into sodium alginate gel, with dedicated three roller of mill base
To get first dose after grinder homogeneous；
(3) calcium chloride and boric acid are made into the water that mass concentration is 20% according to the ratio of mass percent 70%:30%
Solution 500mL, as second dose；
Above-mentioned first dose is first first applied on white hair by a kind of hair colouring methods, then second dose is uniformly applied on hair,
Mica iron series pearlescent pigment, pure graphene, are just fixed on hair, become rufous, clear water to hair by reaction 10 minutes
Washing, drying.
Embodiment 8
In addition to sodium alginate is replaced by potassium alginate, remaining is the same as embodiment 1.
Embodiment 9
In addition to sodium alginate is replaced by ammonium alginate, remaining is the same as embodiment 1.
Embodiment 10
In addition to the red pearl powder of mica iron series to be replaced with to mica iron series Callicarpa bodinieri Levl. light powder, remaining is the same as embodiment 1.
Embodiment 11
In addition to the red pearl powder of mica iron series is replaced with the white pearl powder of mica iron series, remaining is the same as embodiment 1.
In the above embodiments, wherein embodiment 3, embodiment 4 do not add boric acid in second dose in embodiment 5,
Graphene is not added in embodiment 7, test is used as a comparison.
Using hair dye obtained in embodiment, the effect experiment evaluation for hairdressing of having hair dyed is as follows:
Experimental material: white hair, the embodiment hair coloring preparation composition of people, commercially available Head&Shoulders board shampoo.
First dose in embodiment hair coloring preparation composition: being first applied on white hair by test method, then uniformly by second dose
It smears on white hair, reacts 15 minutes, then smear commercially available Head&Shoulders board shampoo simultaneously, rub 2 minutes, wash three with clear water
It is secondary.
Evaluation effect: evaluating white hair hiding rares with 5 grades of evaluation assessments, each+number a rank is represented, 5+number effects are most
Good, a+number effect is worst；Pearl effect ocular estimate, with it is excellent, good, in, poor level Four objectively evaluates.
Washable experiment: being washed several times with above-mentioned washing methods, evaluates white hair hiding rare with 5 grades of evaluation assessments, and rank is higher,
Washability is better, conversely, washability is poorer.
According to above-mentioned test method and evaluation method, the experimental results are shown inthe following table by embodiment 1-8:
Evaluation effect: evaluating white hair hiding rares with 5 grades of evaluation assessments, each+number a rank is represented, 5+number effects are most
Good, a+number effect is worst.
Washable experiment: being washed several times with above-mentioned washing methods, evaluates white hair hiding rare with 5 grades of evaluation assessments, and rank is higher,
Washability is better, conversely, washability is poorer.
According to above-mentioned test method and evaluation method, the experimental result of embodiment 1-5 is as follows:
+++ ++ it is completely covered by white hair, becomes this hair dyeing hair cosmetic agent true qualities, evenness has pearly-lustre, soft glossy, but
For outstanding standard；
++++cover white hair, becomes this hair dyeing hair cosmetic agent true qualities, and coloration is substantially uniform, has pearly-lustre, soft glossy general,
It but is good standard；
+++ covering white hair substantially becomes this hair dyeing hair cosmetic agent true qualities, color evenness is general, has pearly-lustre, but have grey
It adjusts, can be considered qualified standard；
++ it cannot be completely covered by white hair, this hair dyeing hair cosmetic agent true qualities become gray tone, and pearl effect does not protrude；
+ white hair, this hair dyeing hair cosmetic agent true qualities and white alternate appearance, no pearly-lustre cannot be covered.
It can be seen that the present invention, which can satisfy, covers technical effect, the soft beauty of color primary, that pearly-lustre hairdressing is presented,
It is minimum to remain to reach criterion of acceptability for wash resistant 3 times；Embodiment 1,2,6,9,10,11 can be 10 times washable, illustrates boric acid
It is added, water resistance and detergent resistance can significantly improve.Embodiment 7 is not added with graphene, washable effect decline.
Certainly, the above description is not a limitation of the present invention, and the present invention is also not limited to the example above, this technology neck
The variations, modifications, additions or substitutions that the technical staff in domain is made within the essential scope of the present invention also should belong to of the invention
Protection scope.
Claims (8)
1. a kind of graphene hair coloring preparation composition of the pearlescent pigment of iron series containing mica, which is characterized in that including first dose and second
Agent, in which: first dose, be made by mica iron series pearlescent pigment, graphene and alginate；Second dose, by multivalent metal salt and
Boric acid is made into.
2. a kind of graphene hair coloring preparation composition of the pearlescent pigment of iron series containing mica as described in claim 1, which is characterized in that
First dose of the preparation process includes:
(1) alginate is first dissolved in water, adjusting solution ph is 7-10, is made into alginate；
(2) a certain amount of mica iron series pearlescent pigment and graphene are added into alginate, and with dedicated three roller of mill base
Grinder homogeneous, as first dose.
3. a kind of graphene hair coloring preparation composition of the pearlescent pigment of iron series containing mica as claimed in claim 2, which is characterized in that
The graphene selects pure graphene (GO) or reduced graphene (RGO), and alginate selects sodium alginate, potassium alginate and sea
One of ammonium alginate.
4. a kind of graphene hair coloring preparation composition of the pearlescent pigment of iron series containing mica as described in claim 1, which is characterized in that
In first dose of preparation process, mica iron series pearlescent pigment, graphene, alginate three mass percent be 1-10%:
1-5%:85-98%.
5. a kind of graphene hair coloring preparation composition of the pearlescent pigment of iron series containing mica as claimed in claim 4, which is characterized in that
The fineness of mica iron series pearlescent pigment is having a size of 0.1-200 μm.
6. a kind of graphene hair coloring preparation composition of the pearlescent pigment of iron series containing mica as described in claim 1, which is characterized in that
Described second dose is that soluble polyvalent metal salt mixes the aqueous solution that the mass concentration being made into is 10-25%, metal salt with boric acid
Mass percent with boric acid is 50-70%:30-50%.
7. a kind of graphene hair coloring preparation composition of the pearlescent pigment of iron series containing mica as claimed in claim 5, which is characterized in that
Soluble polyvalent metal salt selects at least one of calcium salt, zinc salt.
8. a kind of hair colouring methods use hair coloring preparation composition as claimed in claim 1, which is characterized in that hair dyeing is suitable
Sequence are as follows: after being first uniformly applied to hair for first dose, then second dose is uniformly applied on hair, reaction 5-15min, to mica
Iron series pearlescent pigment and graphene are fixed on hair, then are washed, dried with clear water.
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| CN201811515254.1A CN109453046A (en) | 2018-12-12 | 2018-12-12 | A kind of graphene hair coloring preparation composition of the pearlescent pigment of iron series containing mica |
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| CN201811515254.1A CN109453046A (en) | 2018-12-12 | 2018-12-12 | A kind of graphene hair coloring preparation composition of the pearlescent pigment of iron series containing mica |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102338053B1 (en) * | 2021-07-16 | 2021-12-13 | 한국콜마주식회사 | Hair coloring leave-on cosmetics containing graphene oxide |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06248581A (en) * | 1993-02-22 | 1994-09-06 | Mitsui Petrochem Ind Ltd | Method for dyeing fiber substance with shikonin-based dye |
| CN108030704A (en) * | 2017-12-21 | 2018-05-15 | 北京工商大学 | Botanical hair dye and preparation method using graphene oxide as dyeing auxiliaries |
| CN108451780A (en) * | 2018-03-26 | 2018-08-28 | 郑小华 | A kind of washable hair dye and preparation method thereof |
-
2018
- 2018-12-12 CN CN201811515254.1A patent/CN109453046A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06248581A (en) * | 1993-02-22 | 1994-09-06 | Mitsui Petrochem Ind Ltd | Method for dyeing fiber substance with shikonin-based dye |
| CN108030704A (en) * | 2017-12-21 | 2018-05-15 | 北京工商大学 | Botanical hair dye and preparation method using graphene oxide as dyeing auxiliaries |
| CN108451780A (en) * | 2018-03-26 | 2018-08-28 | 郑小华 | A kind of washable hair dye and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102338053B1 (en) * | 2021-07-16 | 2021-12-13 | 한국콜마주식회사 | Hair coloring leave-on cosmetics containing graphene oxide |
| WO2023286976A1 (en) * | 2021-07-16 | 2023-01-19 | 한국콜마주식회사 | Hair coloring leave-on cosmetic containing graphene oxide |
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Application publication date: 20190312 |