CN108670879A - A kind of melanin hair dye and preparation method thereof - Google Patents
A kind of melanin hair dye and preparation method thereof Download PDFInfo
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- CN108670879A CN108670879A CN201810385629.0A CN201810385629A CN108670879A CN 108670879 A CN108670879 A CN 108670879A CN 201810385629 A CN201810385629 A CN 201810385629A CN 108670879 A CN108670879 A CN 108670879A
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- hair dye
- melanin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
- A61K8/492—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid having condensed rings, e.g. indol
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
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Abstract
A kind of melanin hair dye of present invention offer and preparation method thereof, belongs to field of hairdye.The constituent of the melanin hair dye includes melanin, thickener, pH adjusting agent and water.It is 0.01%~20% that the melanin, which accounts for hair dye total weight percent, and it is 0.2%~2% that thickener, which accounts for hair dye total weight percent, and it is 0.2%~10% that pH adjusting agent, which accounts for hair dye total weight percent, remaining is water.Constituent of the present invention is simple, preparation method is easy, natural safety, is not all damaged to health and hair quality, and has excellent ultraviolet absorption effect.
Description
Technical field
The present invention relates to a kind of melanin hair dyes and preparation method thereof, belong to field of hairdye.Specifically it is utilized in water
It is to help with water, thickener and PH conditioning agents based on the natural black pigment of middle favorable dispersibility or artificial synthesized Melanoidins
Agent prepares a kind of melanin hair dye.
Background technology
In recent years, as population structure steps into aging, silver hair consumer group is also expanding therewith, and people are for hair dye
Demand it is also higher and higher.Existing hair dye product is mostly oxidative hair dyes currently on the market, it is to utilize low molecular weight
The effect of oxidized dose of dyestuff intermediate after form coloured macromolecular compound.However, a variety of research shows that this chemistry closes
At hair dye in containing carcinogenic and force quick property chemical staining ingredient (such as phenylenediamine) and some harmful components (such as mistakes
Hydrogen oxide, ammonium hydroxide etc.).The U.S. was found after once doing experiment to the 169 kinds of permanent hairdyes sold in the market, wherein 150 kinds
There are different degrees of carcinogenesis, about 89%.Which greatly limits the development of hair dye and the strong of people is seriously endangered
Health.
Hair is mainly made of epidermis, cortical layer and medullary substance layer, and normal hair epidermis is one layer of regular arrangement of tiles
Scale layer, enemy hair play a protective role.However, most of hair dye is required for carrying out pre-treatment at present, that is, pass through
Alkaline matter makes hair keratin generate expansion, and hair scale piece opens that small molecule dyes is enable to penetrate into hair fiber structure
It is internal.Therefore after the effect of this hair dye, scale can not be returned to original compact state again and scale layer will appear
Slight degrades phenomenon, and this point is can be hurtful to hair quality.Meanwhile another kind of hair dye is less than using molecular weight
500 organic matter, these organic matters easily propagate through skin barrier, and cause a series of problems, such as allergy is even carcinogenic.Therefore exist
Once there are small molecule harmful substances to be remained in hair dye, it is likely to move in the contact process long-term with scalp
It moves, to pass through skin effects people's health.
Based on problems above, more and more people attempt to look for a kind of more natural safety, nontoxic, have hair dyed simultaneously
Effect can be more lasting hair dye substitute traditional oxidative hair dyes.CN101164528A is mentioned with phytochrome
The method that tea phenol prepares natural hair dye, but the catechol extracted from Chinese medicine seriously limits source and the raising of hair dye
The price of product, and catechol still falls within small-molecule substance, still may penetrate skin barrier, there are security risks.
A kind of edible mushroom enzyme solution is utilized in CN106038411A, and amino acid substrate is converted to natural black pigment precursor substance, and by its
It is prepared into multi-form biology hair dye.But this hair dye formulas is sufficiently complex, preparation process is cumbersome, needs out of edible mushroom
Extract complex enzyme.Meanwhile main component melanin precursor such as 5, the 6- dihydroxy indoles in formula still fall within small point before polymerization
Sub- substance still may penetrate skin barrier, and there are security risks.
The present invention uses based on the natural black pigment of favorable dispersibility in water or artificial synthesized Melanoidins, with
Water, thickener and PH conditioning agents are auxiliary agent, prepare a kind of melanin hair dye.Although two kinds of melanin sources as main body are not
Together, it but belongs to non-toxic to humans, and macromolecular substances into the human body can not be migrated into, while source is extensive
Reduce the price of product.In addition to this, inventive formulation is simple, and preparation method is easy, and thickener and PH conditioning agents use
Nantural non-toxic substance, moieties are even usually used in medicine and cosmetics, so will not have an impact to health.
Invention content
To solve technical problem present in existing hair dye, the purpose of the present invention is to provide a kind of melanin hair dyes
And preparation method thereof, the hair dye is naturally safe, cheap, while the hair dye that hair dyeing effect can be more lasting.
Technical scheme of the present invention：
A kind of melanin hair dye, including melanin, thickener, pH adjusting agent and water；The melanin accounts for hair dye
Total weight percent is 0.01%~20%, and it is 0.2%~2% that thickener, which accounts for hair dye total weight percent, pH adjusting agent
It is 0.2%~10% to account for hair dye total weight percent, remaining is water.
Further feature, the percentage of the hair dye be melanin account for hair dye total weight percent be 0.025%~
0.25%, it is 0.2%~2% that thickener, which accounts for hair dye total weight percent, and pH adjusting agent accounts for hair dye total weight percent
It is 0.2%~2%.
The melanin includes the mixing of one or both of natural black pigment or artificial synthesized Melanoidins, natural black
The source of element includes being extracted from various animals and plants, and the source of artificial synthesized Melanoidins includes enzymatic clarification and chemical synthesis
Method.
The thickener include chitosan, chitin, sodium alginate, glucan, hyaluronic acid, sodium carboxymethylcellulose,
Carboxymethyl chitin, carboxymethyl chitosan, starch, gelatin, guar gum, agar, soybean protein glue, hyaluronic acid sodium, xanthans
One or more of mixing.
The pH adjusting agent includes that one or more of ascorbic acid, lysine, arginine, sodium bicarbonate are mixed
It closes.
The preparation method of above-mentioned melanin hair dye：PH adjusting agent and thickener are dissolved in the water respectively, added
Melanin is uniformly mixed.
The best composition of the hair dye is natural black pigment, chitosan, ascorbic acid and water.
The hair colouring methods for the melanin hair dye that the present invention is prepared include the following steps：(1) after hair wash clean
Melanin hair dye is uniformly applied on hair；(2) have hair dyed 30~50min at normal temperatures；(3) hair is cleaned into drying.
Beneficial effects of the present invention：
1) melanin hair dye constituent of the present invention is simple, and preparation method is easy, and is derived from a wealth of sources and cheap, this hair
It is avoided in bright using p-PDA, resorcinol, hydrogen peroxide and ammonium hydroxide etc. to body harmful substance, it is safe and non-toxic；
2) the melanin hair dye being prepared using the method for the present invention, before need not being carried out in hair dye processing and
Without heating, it is only necessary to uniformly be applied to melanin hair dye on hair, operation is simple, saves the time；
3) small molecule melanin precursor substance is free of in melanin hair dye of the present invention, so being migrated without small molecule hidden
Suffer from, skin barrier will not be penetrated, and melanin macromolecular has the excellent performance such as uvioresistant and heat conduction, to scalp and
Hair can play a protective role.
Description of the drawings
Fig. 1 is the ultra-violet absorption spectrum comparison diagram of hair dye 1 and the commercially available hair dye containing hydrogen peroxide.
Fig. 2 is the ultra-violet absorption spectrum comparison diagram of hair dye 2 and the commercially available hair dye containing hydrogen peroxide.
Fig. 3 is the ultra-violet absorption spectrum comparison diagram of hair dye 3 and the commercially available hair dye containing hydrogen peroxide.
Fig. 4 is the ultra-violet absorption spectrum comparison diagram of hair dye 4 and the commercially available hair dye containing hydrogen peroxide.
Fig. 5 is the ultra-violet absorption spectrum comparison diagram of hair dye 5 and the commercially available hair dye containing hydrogen peroxide.
Fig. 6 is the ultra-violet absorption spectrum comparison diagram of hair dye 6 and the commercially available hair dye containing hydrogen peroxide.
Fig. 7 is the ultra-violet absorption spectrum comparison diagram of hair dye 7 and the commercially available hair dye containing hydrogen peroxide.
Fig. 8 is the ultra-violet absorption spectrum comparison diagram of hair dye 8 and the commercially available hair dye containing hydrogen peroxide.
Specific implementation mode
With reference to embodiment, further illustrate the present invention.Raw materials used in embodiment is commercially available.
Embodiment 1
First respectively by chitosan and dissolution of ascorbic acid in water, adds natural black pigment and be uniformly mixing to obtain hair dyeing
Agent 1.It is as follows that each component accounts for hair dye total weight percent：Natural black pigment 0.25%, chitosan 2%, ascorbic acid 2%,
Yu Weishui.Hair dye 1 is uniformly applied to hair surface after white hair wash clean, then have hair dyed 30~50min at normal temperatures, most
Hair is cleaned into drying afterwards, hair is presented natural brownish black and has excellent uv absorption property, protects to a certain extent
Head protector skin is not injured by ultraviolet light.
For normal hair, there is apparent scale knot on the either surface of the white hair of people or natural dark hair
Structure, this is the epidermis of hair, is played a protective role at hair scale sheet enemy hair, and arranged regular.And it has hair dyed through the present invention
After agent 1 is handled, still arranged regular is not destroyed the Microstructure of epidermal scale of hair surface, while the melanin hair dyeing of smooth even
Hair is integrally wrapped up covering by agent coating, and natural brownish black and the still smooth flexible of hair is presented in hair.
Embodiment 2
First respectively by chitosan and dissolution of ascorbic acid in water, adds natural black pigment and be uniformly mixing to obtain hair dyeing
Agent 2.It is as follows that each component accounts for hair dye total weight percent：Natural black pigment 0.025%, chitosan 0.2%, ascorbic acid
0.2%, remaining is water.Hair dye 2 is uniformly applied to hair surface after white hair wash clean, then at normal temperatures hair dyeing 30~
Hair is finally cleaned drying by 50min, and hair is presented natural brownish black and has excellent uv absorption property, certain
Scalp is protected not injured by ultraviolet light in degree.
Embodiment 3
First respectively by sodium alginate and dissolution of ascorbic acid in water, it is black to add the artificial synthesized class obtained by enzyme process
Pigment is simultaneously uniformly mixing to obtain hair dye 3.It is as follows that each component accounts for hair dye total weight percent：Artificial synthesized Melanoidins
0.25%, sodium alginate 0.2%, ascorbic acid 0.2%, remaining is water.Hair dye 3 is uniformly applied to after white hair wash clean
Hair surface, then have hair dyed 30~50min at normal temperatures, and hair is finally cleaned drying, hair present natural brownish black and
With excellent uv absorption property, scalp is protected not injured by ultraviolet light to a certain extent.
Embodiment 4
First respectively by sodium alginate and dissolution of ascorbic acid in water, the artificial conjunction obtained by chemical synthesis is added
At Melanoidins and it is uniformly mixing to obtain hair dye 4.It is as follows that each component accounts for hair dye total weight percent：Artificial synthesized class black
Element 0.025%, sodium alginate 2%, ascorbic acid 2%, remaining is water.Hair dye 4 is uniformly applied to after white hair wash clean
Hair surface, then have hair dyed 30~50min at normal temperatures, and hair is finally cleaned drying, hair present natural brownish black and
With excellent uv absorption property, scalp is protected not injured by ultraviolet light to a certain extent.
Embodiment 5
First chitosan and sodium bicarbonate are dissolved in the water respectively, add natural black pigment and obtained by enzyme process
Artificial synthesized Melanoidins are simultaneously uniformly mixing to obtain hair dye 5.It is as follows that each component accounts for hair dye total weight percent：Natural black
Plain and artificial synthesized Melanoidins totally 0.25%, chitosan 2%, sodium bicarbonate 2%, remaining is water.It will after white hair wash clean
Hair dye 5 is uniformly applied to hair surface, and then have hair dyed 30~50min at normal temperatures, and hair is finally cleaned drying, and hair is in
Now natural brownish black and have excellent uv absorption property, protect scalp not injured by ultraviolet light to a certain extent.
Embodiment 6
First chitosan and lysine are dissolved in the water respectively, the people for adding natural black pigment and being obtained by enzyme process
Work synthesizes Melanoidins and is uniformly mixing to obtain hair dye 6.It is as follows that each component accounts for hair dye total weight percent：Natural black pigment
With artificial synthesized Melanoidins totally 0.025%, chitosan 0.2%, sodium bicarbonate 0.2%, remaining is water.After white hair wash clean
Hair dye 6 is uniformly applied to hair surface, then have hair dyed 30~50min at normal temperatures, and hair is finally cleaned drying, hair
Natural brownish black is presented and there is excellent uv absorption property, protects scalp not hindered by ultraviolet light to a certain extent
Evil.
Embodiment 7
First chitosan, sodium alginate, ascorbic acid and sodium bicarbonate are dissolved in the water respectively, add natural black pigment
And the artificial synthesized Melanoidins that are obtained by enzyme process and it is uniformly mixing to obtain hair dye 7.Each component accounts for hair dye total weight
Percentage is as follows：Natural black pigment and artificial synthesized Melanoidins totally 0.25%, chitosan and sodium alginate totally 2%, Vitamin C
Acid and sodium bicarbonate totally 2%, remaining is water.Hair dye 7 is uniformly applied to hair surface after white hair wash clean, then normal
Lower 30~the 50min that has hair dyed of temperature, finally cleans drying by hair, and hair is presented natural brownish black and has excellent UV absorption
Performance protects scalp not injured by ultraviolet light to a certain extent.
Embodiment 8
First chitosan, sodium alginate, ascorbic acid and lysine are dissolved in the water respectively, add natural black pigment with
And the artificial synthesized Melanoidins that are obtained by chemical synthesis and it is uniformly mixing to obtain hair dye 8.It is total that each component accounts for hair dye
Weight percent is as follows：Natural black pigment and artificial synthesized Melanoidins totally 0.025%, chitosan and sodium alginate totally 0.2%,
Ascorbic acid and lysine totally 0.2%, remaining is water.Hair dye 8 is uniformly applied to hair surface after white hair wash clean, is connect
30~50min of hair dyeing at normal temperatures, hair is finally cleaned into drying, hair is presented natural brownish black and has excellent purple
Outer absorbent properties, protect scalp not injured by ultraviolet light to a certain extent.
Comparative example 1
The commercially available hair dye 9 containing hydrogen peroxide is uniformly applied to hair surface after white hair wash clean, at normal temperatures
Have hair dyed 30~50min, and hair is finally cleaned drying, and sepia is presented in hair.
After the commercially available hair dye 9 containing hydrogen peroxide is had hair dyed, the hair scale piece part of hair surface is peeled off, scale layer quilt
It destroys serious.Hair, which obviously attenuates, has harsh feeling and degraded toughness, hair quality seriously to be damaged.It can be seen that this hair from attached drawing
Bright hair dye has apparent UV absorption within the scope of the ultraviolet region of 200nm~400nm, and has hair dyed containing hydrogen peroxide than commercially available
The ultraviolet absorption effect of agent is more preferable.
In conclusion compared with commercially available hair dye containing hydrogen peroxide, hair dye of the present invention is avoided using p-PDA, isophthalic
Diphenol, hydrogen peroxide and ammonium hydroxide etc. are not only natural harmless to body harmful substance, low to hair quality injury, also have excellent
Ultraviolet absorption effect, therefore hair and scalp can be protected not to be injured by ultraviolet light.Meanwhile the melanin that the present invention is prepared
Hair dye constituent is simple, and preparation method is easy, and is derived from a wealth of sources and cheap, melanin macromolecular will not be sent out with the time
Raw migration, will not more cause damages to body, natural safety.
Claims (10)
1. a kind of melanin hair dye, which is characterized in that including melanin, thickener, pH adjusting agent and water；The melanin
It is 0.01%~20% to account for hair dye total weight percent, and it is 0.2%~2%, pH that thickener, which accounts for hair dye total weight percent,
It is 0.2%~10% that value conditioning agent, which accounts for hair dye total weight percent, remaining is water.
2. melanin hair dye as described in claim 1, which is characterized in that the melanin accounts for hair dye total weight percent
It is 0.025%~0.25%, it is 0.2%~2% that thickener, which accounts for hair dye total weight percent, and it is total that pH adjusting agent accounts for hair dye
Weight percent is 0.2%~2%.
3. melanin hair dye as claimed in claim 1 or 2, which is characterized in that the melanin include natural black pigment or
One or both of artificial synthesized Melanoidins mix.
4. melanin hair dye as claimed in claim 1 or 2, which is characterized in that the thickener includes chitosan, crust
It is element, sodium alginate, glucan, hyaluronic acid, sodium carboxymethylcellulose, carboxymethyl chitin, carboxymethyl chitosan, starch, bright
One or more of glue, guar gum, agar, soybean protein glue, hyaluronic acid sodium, xanthans mix.
5. melanin hair dye as claimed in claim 3, which is characterized in that the thickener includes chitosan, chitin, sea
Mosanom, glucan, hyaluronic acid, sodium carboxymethylcellulose, carboxymethyl chitin, carboxymethyl chitosan, starch, gelatin, melon
The mixing of one or more of your glue, agar, soybean protein glue, hyaluronic acid sodium, xanthans.
6. the melanin hair dye as described in claim 1,2 or 5, which is characterized in that the pH adjusting agent includes Vitamin C
One or more of acid, lysine, arginine, sodium bicarbonate mix.
7. melanin hair dye as claimed in claim 3, which is characterized in that the pH adjusting agent includes ascorbic acid, relies
One or more of propylhomoserin, arginine, sodium bicarbonate mix.
8. melanin hair dye as claimed in claim 4, which is characterized in that the pH adjusting agent includes ascorbic acid, relies
One or more of propylhomoserin, arginine, sodium bicarbonate mix.
9. a kind of preparation method of melanin hair dye described in claim 1-8, which is characterized in that respectively by pH adjusting agent and
Thickener is dissolved in the water, and adds melanin and is uniformly mixed.
10. preparation method as claimed in claim 9, which is characterized in that the source of the natural black pigment includes from various dynamic
It is extracted in plant, the source of artificial synthesized Melanoidins includes enzymatic clarification and chemical synthesis.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810385629.0A CN108670879B (en) | 2018-04-24 | 2018-04-24 | Melanin hair dye and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810385629.0A CN108670879B (en) | 2018-04-24 | 2018-04-24 | Melanin hair dye and preparation method thereof |
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| Publication Number | Publication Date |
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| CN108670879A true CN108670879A (en) | 2018-10-19 |
| CN108670879B CN108670879B (en) | 2020-05-12 |
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| CN201810385629.0A Active CN108670879B (en) | 2018-04-24 | 2018-04-24 | Melanin hair dye and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112641645A (en) * | 2020-12-29 | 2021-04-13 | 江南大学 | Safe and nontoxic dyeing and scalding agent, preparation method and application |
| CN114831907A (en) * | 2022-06-22 | 2022-08-02 | 华南农业大学 | Boletus melanin hair dye and preparation method and use method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1116088A (en) * | 1992-11-19 | 1996-02-07 | 布里斯托尔-米尔斯·斯奎布公司 | Compositions and methods for temporarily coloring hair using chemically synthesized or biosythetic water-soluble melanin |
| CN102743306A (en) * | 2011-04-20 | 2012-10-24 | 浙江医药股份有限公司新昌制药厂 | Natural hair dye adopting water-soluble plant melanin, preparation method thereof and hair dyeing method thereof |
| CN107903655A (en) * | 2017-10-18 | 2018-04-13 | 湖北科技学院 | The method and its application of melanin are extracted in a kind of pericarp from sweet osmanthus |
-
2018
- 2018-04-24 CN CN201810385629.0A patent/CN108670879B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1116088A (en) * | 1992-11-19 | 1996-02-07 | 布里斯托尔-米尔斯·斯奎布公司 | Compositions and methods for temporarily coloring hair using chemically synthesized or biosythetic water-soluble melanin |
| CN102743306A (en) * | 2011-04-20 | 2012-10-24 | 浙江医药股份有限公司新昌制药厂 | Natural hair dye adopting water-soluble plant melanin, preparation method thereof and hair dyeing method thereof |
| CN107903655A (en) * | 2017-10-18 | 2018-04-13 | 湖北科技学院 | The method and its application of melanin are extracted in a kind of pericarp from sweet osmanthus |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112641645A (en) * | 2020-12-29 | 2021-04-13 | 江南大学 | Safe and nontoxic dyeing and scalding agent, preparation method and application |
| CN112641645B (en) * | 2020-12-29 | 2021-12-03 | 江南大学 | Safe and nontoxic dyeing and scalding agent, preparation method and application |
| CN114831907A (en) * | 2022-06-22 | 2022-08-02 | 华南农业大学 | Boletus melanin hair dye and preparation method and use method thereof |
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| Publication number | Publication date |
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| CN108670879B (en) | 2020-05-12 |
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