CN108440739A - 一种超支化抗流挂剂及在单组分聚氨酯防水涂料中的应用 - Google Patents
一种超支化抗流挂剂及在单组分聚氨酯防水涂料中的应用 Download PDFInfo
- Publication number
- CN108440739A CN108440739A CN201810222770.9A CN201810222770A CN108440739A CN 108440739 A CN108440739 A CN 108440739A CN 201810222770 A CN201810222770 A CN 201810222770A CN 108440739 A CN108440739 A CN 108440739A
- Authority
- CN
- China
- Prior art keywords
- hyperbranched
- sag agent
- polymer
- carbamate
- mono
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 50
- 239000003973 paint Substances 0.000 title claims description 20
- 239000000203 mixture Substances 0.000 title claims description 17
- 238000006243 chemical reaction Methods 0.000 claims abstract description 33
- 229920000642 polymer Polymers 0.000 claims abstract description 28
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims abstract description 22
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 14
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 12
- 229920000587 hyperbranched polymer Polymers 0.000 claims abstract description 6
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000006116 polymerization reaction Methods 0.000 claims abstract 2
- 239000012948 isocyanate Substances 0.000 claims description 24
- 150000002513 isocyanates Chemical class 0.000 claims description 19
- 239000000178 monomer Substances 0.000 claims description 15
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 13
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 13
- 239000004814 polyurethane Substances 0.000 claims description 11
- 229920002635 polyurethane Polymers 0.000 claims description 11
- 229910052710 silicon Inorganic materials 0.000 claims description 10
- 239000010703 silicon Substances 0.000 claims description 10
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 8
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 claims description 8
- 239000002002 slurry Substances 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 238000000518 rheometry Methods 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 3
- 230000009471 action Effects 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 239000003063 flame retardant Substances 0.000 claims 1
- 239000005056 polyisocyanate Substances 0.000 claims 1
- 229920001228 polyisocyanate Polymers 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 9
- 239000000654 additive Substances 0.000 abstract description 6
- 230000000996 additive effect Effects 0.000 abstract description 6
- 238000010276 construction Methods 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
- 239000011248 coating agent Substances 0.000 description 15
- 238000000576 coating method Methods 0.000 description 15
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 12
- 238000003756 stirring Methods 0.000 description 12
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- 239000003054 catalyst Substances 0.000 description 8
- 238000010992 reflux Methods 0.000 description 8
- 229920000768 polyamine Polymers 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- 238000005292 vacuum distillation Methods 0.000 description 5
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000007665 sagging Methods 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 238000005267 amalgamation Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 239000003937 drug carrier Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- -1 isocyanates Methyl esters Chemical class 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/83—Chemically modified polymers
- C08G18/837—Chemically modified polymers by silicon containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3271—Hydroxyamines
- C08G18/329—Hydroxyamines containing aromatic groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810222770.9A CN108440739B (zh) | 2018-03-19 | 2018-03-19 | 一种超支化抗流挂剂及在单组份聚氨酯防水涂料中的应用 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810222770.9A CN108440739B (zh) | 2018-03-19 | 2018-03-19 | 一种超支化抗流挂剂及在单组份聚氨酯防水涂料中的应用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN108440739A true CN108440739A (zh) | 2018-08-24 |
CN108440739B CN108440739B (zh) | 2020-07-28 |
Family
ID=63194987
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810222770.9A Active CN108440739B (zh) | 2018-03-19 | 2018-03-19 | 一种超支化抗流挂剂及在单组份聚氨酯防水涂料中的应用 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN108440739B (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111138974A (zh) * | 2020-01-06 | 2020-05-12 | 浙江大学衢州研究院 | 超支化硅烷改性聚氨酯复合聚硅氧烷防污涂料及制备方法 |
CN113897129A (zh) * | 2021-11-26 | 2022-01-07 | 国网河南省电力公司桐柏县供电公司 | 一种电缆接头防水密封材料 |
CN114561811A (zh) * | 2022-03-02 | 2022-05-31 | 安徽弋尚纺织科技有限公司 | 一种耐磨布料及其制备方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030069370A1 (en) * | 2001-03-26 | 2003-04-10 | Dvornic Petar R. | Hyperbranched polyureas, polyurethanes, polyamidoamines, polyamides and polyesters |
CN101709039A (zh) * | 2009-07-07 | 2010-05-19 | 济南大学 | 用于双组份聚氨酯防水涂料的超支化型固化剂及制备方法 |
CN105431482A (zh) * | 2013-05-24 | 2016-03-23 | 比克化学股份有限公司 | 用于抗污表面涂层的超支化聚烷氧基硅氧烷添加剂 |
WO2016185007A1 (de) * | 2015-05-21 | 2016-11-24 | Hilti Aktiengesellschaft | Schäumbare, dämmschichtbildende mehrkomponenten-zusammensetzung und deren verwendung |
CN106634534A (zh) * | 2016-12-27 | 2017-05-10 | 苏州中材非金属矿工业设计研究院有限公司 | 一种抗流挂单组份聚氨酯防水涂料及其制备方法 |
CN107189035A (zh) * | 2017-07-01 | 2017-09-22 | 杭州美高华颐化工有限公司 | 一种无溶剂超支化有机硅柔软剂及其制备方法 |
CN107428881A (zh) * | 2015-03-27 | 2017-12-01 | Ppg工业俄亥俄公司 | 耐久性防指纹聚合物和涂料组合物 |
-
2018
- 2018-03-19 CN CN201810222770.9A patent/CN108440739B/zh active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030069370A1 (en) * | 2001-03-26 | 2003-04-10 | Dvornic Petar R. | Hyperbranched polyureas, polyurethanes, polyamidoamines, polyamides and polyesters |
CN101709039A (zh) * | 2009-07-07 | 2010-05-19 | 济南大学 | 用于双组份聚氨酯防水涂料的超支化型固化剂及制备方法 |
CN105431482A (zh) * | 2013-05-24 | 2016-03-23 | 比克化学股份有限公司 | 用于抗污表面涂层的超支化聚烷氧基硅氧烷添加剂 |
CN107428881A (zh) * | 2015-03-27 | 2017-12-01 | Ppg工业俄亥俄公司 | 耐久性防指纹聚合物和涂料组合物 |
WO2016185007A1 (de) * | 2015-05-21 | 2016-11-24 | Hilti Aktiengesellschaft | Schäumbare, dämmschichtbildende mehrkomponenten-zusammensetzung und deren verwendung |
CN106634534A (zh) * | 2016-12-27 | 2017-05-10 | 苏州中材非金属矿工业设计研究院有限公司 | 一种抗流挂单组份聚氨酯防水涂料及其制备方法 |
CN107189035A (zh) * | 2017-07-01 | 2017-09-22 | 杭州美高华颐化工有限公司 | 一种无溶剂超支化有机硅柔软剂及其制备方法 |
Non-Patent Citations (1)
Title |
---|
龚跃法: "《有机化学(上册)》", 31 July 2009, 华东理工大学出版社 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111138974A (zh) * | 2020-01-06 | 2020-05-12 | 浙江大学衢州研究院 | 超支化硅烷改性聚氨酯复合聚硅氧烷防污涂料及制备方法 |
CN113897129A (zh) * | 2021-11-26 | 2022-01-07 | 国网河南省电力公司桐柏县供电公司 | 一种电缆接头防水密封材料 |
CN113897129B (zh) * | 2021-11-26 | 2023-07-04 | 国网河南省电力公司桐柏县供电公司 | 一种电缆接头防水密封材料 |
CN114561811A (zh) * | 2022-03-02 | 2022-05-31 | 安徽弋尚纺织科技有限公司 | 一种耐磨布料及其制备方法 |
CN114561811B (zh) * | 2022-03-02 | 2023-09-08 | 安徽弋尚纺织科技有限公司 | 一种耐磨布料及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN108440739B (zh) | 2020-07-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101580688B (zh) | 一种双组分建筑用硅酮密封胶配方与制备 | |
CN102827340B (zh) | 有机硅改性水性聚氨酯复合材料及其应用 | |
CN101348611B (zh) | 丙烯酸改性聚硅氧烷树脂及其涂料 | |
CN106634534B (zh) | 一种抗流挂单组份聚氨酯防水涂料及其制备方法 | |
CN108440739A (zh) | 一种超支化抗流挂剂及在单组分聚氨酯防水涂料中的应用 | |
CN103910847A (zh) | 一种硅烷封端聚氨酯低聚物及其制备方法 | |
JPS6157616A (ja) | 水分遮断下に貯蔵安定な合成樹脂材料の製法 | |
CN102070874B (zh) | 一种高渗透性高强度环氧灌浆材料及其制备方法与应用 | |
CN102925041A (zh) | 一种地坪涂料及其制备方法 | |
CN101280061A (zh) | 有机硅-聚氨酯-丙烯酸酯三元复合离聚物乳液的合成方法 | |
CN103450797A (zh) | 一种可常温固化的环氧聚硅氧烷树脂 | |
CN107033827A (zh) | 一种建筑用单组分硅烷改性聚醚密封胶及其制备方法 | |
CN103224751A (zh) | 一种耐酸碱腐蚀耐水耐磨地坪涂料及其制备方法 | |
CN103923557A (zh) | 一种喷涂聚脲弹性体专用底涂及其制备方法 | |
CN109988538A (zh) | 无溶剂型聚氨酯胶粘剂的制备方法 | |
CN106281199A (zh) | 一种耐化学稳定性单组分聚氨酯胶粘剂及其制备方法 | |
CN109134839B (zh) | 一种超支化型石蜡的制备及其在人造板中的应用 | |
JPS61228015A (ja) | エポキシ樹脂組成物 | |
CN108384022A (zh) | 一种提高非固化橡胶沥青耐高温性能超支化树脂的制备 | |
Huang et al. | New hybrid materials incorporating tetrabutyl titanate and tetraethoxysilane with functional SEBS elastomer via the sol‐gel process: Synthesis and characterization | |
CN107090263A (zh) | 一种光伏切割用环氧树脂胶及其制备方法 | |
CN110498933A (zh) | 一种自乳化型水性环氧乳液及其制备方法 | |
CN109609078A (zh) | 湿固化型有机硅改性阻燃聚氨酯热熔胶及其制备方法 | |
CN113004481B (zh) | 一种反应型聚氨酯乳化剂及其制备方法 | |
CN109852323A (zh) | 有机硅改性单组份反应型聚氨酯热熔胶及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20201209 Address after: 271000 west house, 2 / F, Tower B, Taishan science and Technology City, hi tech Zone, Tai'an City, Shandong Province Patentee after: SHANDONG BAOSHENG NEW MATERIAL TECHNOLOGY Co.,Ltd. Address before: 250022 No. 336, South Xin Zhuang West Road, Shizhong District, Ji'nan, Shandong Patentee before: University of Jinan |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A hyperbranched anti sagging agent and its application in single component polyurethane waterproof coatings Granted publication date: 20200728 Pledgee: Taian Bank Co.,Ltd. Daizong sub branch Pledgor: SHANDONG BAOSHENG NEW MATERIAL TECHNOLOGY Co.,Ltd. Registration number: Y2024980016804 |