CN1084342C - 单烯烃/多烯烃共聚合物、其制备方法、含该聚合物的组合物和由其生产的制品 - Google Patents
单烯烃/多烯烃共聚合物、其制备方法、含该聚合物的组合物和由其生产的制品 Download PDFInfo
- Publication number
- CN1084342C CN1084342C CN96198703A CN96198703A CN1084342C CN 1084342 C CN1084342 C CN 1084342C CN 96198703 A CN96198703 A CN 96198703A CN 96198703 A CN96198703 A CN 96198703A CN 1084342 C CN1084342 C CN 1084342C
- Authority
- CN
- China
- Prior art keywords
- polymer
- alpha
- carbon atoms
- olefin
- melt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/18—Suspension polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/565,329 US5814714A (en) | 1995-11-30 | 1995-11-30 | Mono-olefin/polyene interpolymers, method of preparation, compositions containing the same, and articles made thereof |
| US08/565,329 | 1995-11-30 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN02105397A Division CN1373144A (zh) | 1995-11-30 | 2002-02-28 | 单烯烃/多烯烃共聚合物、其制备方法、含该聚合物的组合物和由其生产的制品 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1203606A CN1203606A (zh) | 1998-12-30 |
| CN1084342C true CN1084342C (zh) | 2002-05-08 |
Family
ID=24258136
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96198703A Expired - Lifetime CN1084342C (zh) | 1995-11-30 | 1996-11-27 | 单烯烃/多烯烃共聚合物、其制备方法、含该聚合物的组合物和由其生产的制品 |
| CN02105397A Pending CN1373144A (zh) | 1995-11-30 | 2002-02-28 | 单烯烃/多烯烃共聚合物、其制备方法、含该聚合物的组合物和由其生产的制品 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN02105397A Pending CN1373144A (zh) | 1995-11-30 | 2002-02-28 | 单烯烃/多烯烃共聚合物、其制备方法、含该聚合物的组合物和由其生产的制品 |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US5814714A (enExample) |
| EP (1) | EP0863924B1 (enExample) |
| JP (1) | JP2000502117A (enExample) |
| KR (1) | KR100456710B1 (enExample) |
| CN (2) | CN1084342C (enExample) |
| AR (1) | AR012812A1 (enExample) |
| AT (1) | ATE240355T1 (enExample) |
| AU (1) | AU708722B2 (enExample) |
| BR (1) | BR9611799A (enExample) |
| DE (1) | DE69628188T2 (enExample) |
| ES (1) | ES2193276T3 (enExample) |
| MX (1) | MX9804266A (enExample) |
| NO (1) | NO982470L (enExample) |
| RU (1) | RU2167885C2 (enExample) |
| TW (1) | TW338053B (enExample) |
| WO (1) | WO1997019965A1 (enExample) |
| ZA (1) | ZA969992B (enExample) |
Families Citing this family (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE59710063D1 (de) * | 1996-02-01 | 2003-06-18 | Borealis Gmbh Schwechat Mannsw | Strukturisomere Poly(alkylethylene) |
| RU2226200C2 (ru) * | 1998-06-01 | 2004-03-27 | Дау Глобал Текнолоджиз Инк. | Способ получения моющихся, сушащихся эластичных изделий |
| US6265493B1 (en) * | 1999-07-21 | 2001-07-24 | The Penn State Research Foundation | Polyolefin graft copolymers derived from linear copolymers of alpha-olefins and divinylbenzene having narrow molecular weight and composition distributions and process for preparing same |
| US6699955B1 (en) * | 1999-11-19 | 2004-03-02 | E. I. Du Pont De Nemours And Company | Copolymerization of ethylene and dienes |
| US6329454B1 (en) | 1999-12-08 | 2001-12-11 | The Dow Chemical Company | Filled propylene polymer composition |
| US6509431B1 (en) | 2000-01-18 | 2003-01-21 | Exxonmobil Oil Corporation | Terpolymers |
| CA2400665A1 (en) * | 2000-02-22 | 2001-08-30 | Univation Technologies, Llc | Process for the polymerization of ethylene and a small amount of a diene |
| US6448424B1 (en) * | 2000-05-01 | 2002-09-10 | Solvay Polyolefins Europe-Belgium (Société Anonyme) | Tetrahydrofluorenyl containing group 4 metallocenes useful as catalysts for the polymerization of olefins, process for their preparation and use of said metallocenes for the polymerization of olefins |
| US6538082B2 (en) * | 2000-12-05 | 2003-03-25 | Solvay Polyolefins Europe-Belgium | Asymmetric silicon-bridged metallocenes useful as catalysts in the polymerization of α-olefins, process for their preparation and use of said metallocenes for the polymerization of α-olefins |
| EP1366098B1 (en) * | 2000-12-20 | 2008-04-16 | Exxonmobil Chemical Patents Inc. | Olefin polymerization process to produce branched polymer compositions |
| JP2002226520A (ja) * | 2001-02-05 | 2002-08-14 | Grand Polymer Co Ltd | プロピレン・α,ω−ジエンランダム共重合体およびその製造方法 |
| JP2002256026A (ja) * | 2001-03-02 | 2002-09-11 | Idemitsu Petrochem Co Ltd | プロピレン系共重合体及びその製造方法 |
| US6709746B2 (en) * | 2002-06-05 | 2004-03-23 | Arteva North America S.á.r.l. | Reducing concentration of organic materials with substituted cyclodextrin compound in polyester packaging materials |
| KR20070067645A (ko) * | 2003-08-22 | 2007-06-28 | 사토머 테크놀로지 컴퍼니, 인코포레이티드 | Uv 계의 고온 안정화 |
| PL1695996T3 (pl) | 2005-02-28 | 2009-01-30 | Borealis Tech Oy | Kompozycje polimerowe z opóźnionym powstawaniem skaz |
| DE602005021077D1 (de) * | 2005-06-08 | 2010-06-17 | Borealis Tech Oy | Polymerzusammensetzung mit verbesserten "wet-ageing"-Eigenschaften |
| EP1844917A3 (de) | 2006-03-24 | 2008-12-03 | Entex Rust & Mitschke GmbH | Verfahren zur Verarbeitung von zu entgasenden Produkten |
| RU2008149712A (ru) * | 2006-05-17 | 2010-06-27 | Дау Глобал Текнолоджиз Инк. (Us) | Высокоэффективный способ полимеризации в растворе |
| US8225286B2 (en) * | 2006-05-23 | 2012-07-17 | Microsoft Corporation | Debugging interpreted input |
| FR2910877B1 (fr) | 2006-12-28 | 2009-09-25 | Eurocopter France | Amelioration aux rotors de giravions equipes d'amortisseurs interpales |
| WO2008082915A1 (en) * | 2006-12-29 | 2008-07-10 | Dow Global Technologies Inc. | Films, articles prepared therefrom, and methods of making the same |
| EP1997608A3 (de) | 2007-05-16 | 2009-05-27 | Entex Rust & Mitschke GmbH | Verfahren zur Verarbeitung von zu entgasenden Produkten |
| JP5226973B2 (ja) * | 2007-06-15 | 2013-07-03 | 三井化学株式会社 | エチレン系共重合体、該共重合体を含む組成物ならびにその用途 |
| WO2009056407A1 (en) * | 2007-10-31 | 2009-05-07 | Borealis Technology Oy | Silane-functionalised polyolefin compositions, products thereof and preparation processes thereof for wire and cable applications |
| BRPI0818125A2 (pt) * | 2007-10-31 | 2015-03-31 | Borealis Tech Oy | Composições de poliolefina funcionalizada por silano, produtos das mesmas e processos de preparação das mesmas para aplicações de fio e cabo |
| EP2130865B1 (en) * | 2008-06-06 | 2010-11-17 | Borealis AG | Extrusion coating polyethylene composition |
| EP2130860A1 (en) | 2008-06-06 | 2009-12-09 | Borealis Technology Oy | Polymer |
| KR101167082B1 (ko) * | 2008-11-05 | 2012-07-20 | 에스케이이노베이션 주식회사 | 에틸렌과 α-올레핀의 탄성 공중합체 제조방법 |
| EP2348057A1 (en) | 2010-01-21 | 2011-07-27 | INEOS Manufacturing Belgium NV | Novel polymers |
| US9388254B2 (en) | 2010-12-21 | 2016-07-12 | Dow Global Technologies Llc | Olefin-based polymers and dispersion polymerizations |
| DE102011112081A1 (de) | 2011-05-11 | 2015-08-20 | Entex Rust & Mitschke Gmbh | Verfahren zur Verarbeitung von Elasten |
| WO2013040519A2 (en) * | 2011-09-14 | 2013-03-21 | Materia, Inc. | Improved electrolytic cell covers comprising a resin composition polymerized with a group 8 olefin metathesis catalyst |
| US20160272798A1 (en) | 2011-09-23 | 2016-09-22 | Exxonmobil Chemical Patents Inc. | Modified Polyethylene Compositions with Enhanced Melt Strength |
| WO2013043796A2 (en) | 2011-09-23 | 2013-03-28 | Exxonmobil Chemical Patents Inc. | Modified polyethylene compositions |
| KR20140107260A (ko) * | 2011-12-19 | 2014-09-04 | 다우 글로벌 테크놀로지스 엘엘씨 | 분산 중합에 의해 제조된 에틸렌 기재 중합체 |
| WO2014056553A1 (de) | 2012-10-11 | 2014-04-17 | Entex Gmbh Rust & Mitschke Gmbh | Extruder zur verarbeitung von kunststoffen, die zum kleben neigen |
| DE102017001093A1 (de) | 2016-04-07 | 2017-10-26 | Entex Rust & Mitschke Gmbh | Entgasen bei der Extrusion von Kunststoffen mit Filterscheiben aus Sintermetall |
| DE102015001167A1 (de) | 2015-02-02 | 2016-08-04 | Entex Rust & Mitschke Gmbh | Entgasen bei der Extrusion von Kunststoffen |
| WO2016191076A1 (en) * | 2015-05-28 | 2016-12-01 | Dow Global Technologies Llc | Process to form ethylene/alpha-olefin interpolymers |
| DE102015008406A1 (de) | 2015-07-02 | 2017-04-13 | Entex Rust & Mitschke Gmbh | Verfahren zur Bearbeitung von Produkten im Extruder |
| DE102016002143A1 (de) | 2016-02-25 | 2017-08-31 | Entex Rust & Mitschke Gmbh | Füllteilmodul in Planetwalzenextruderbauweise |
| DE102017006638A1 (de) | 2017-07-13 | 2019-01-17 | Entex Rust & Mitschke Gmbh | Füllteilmodul in Planetwalzenextruderbauweise |
| CN111148641B (zh) | 2017-08-24 | 2023-03-31 | 陶氏环球技术有限责任公司 | 乙烯/C5-C10α-烯烃/多烯互聚物 |
| WO2019121731A1 (en) * | 2017-12-18 | 2019-06-27 | Borealis Ag | A polyethylene with a high vinyl content and beneficial rheological properties |
| BR112021012845A2 (pt) * | 2018-12-28 | 2021-09-28 | Dow Global Technologies Llc | Composição curável, e, artigo |
| JP7609783B2 (ja) | 2018-12-28 | 2025-01-07 | ダウ グローバル テクノロジーズ エルエルシー | 不飽和ポリオレフィンを含む硬化性組成物 |
| JP7610511B2 (ja) | 2018-12-28 | 2025-01-08 | ダウ グローバル テクノロジーズ エルエルシー | テレケリックポリオレフィンおよびこれを調製するための方法 |
| WO2020140064A1 (en) | 2018-12-28 | 2020-07-02 | Dow Global Technologies Llc | Organometallic chain transfer agents |
| WO2021188361A1 (en) * | 2020-03-20 | 2021-09-23 | Exxonmobil Chemical Patents Inc. | Linear alpha-olefin copolymers and impact copolymers thereof |
| CN115298236B (zh) * | 2020-03-27 | 2024-05-28 | 陶氏环球技术有限责任公司 | 长链支化的基于乙烯的聚合物 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3984610A (en) * | 1971-04-16 | 1976-10-05 | Du Pont Of Canada Limited | Ethylene polymers with long chain branching |
| CN1070651A (zh) * | 1991-08-14 | 1993-04-07 | 三井石油化学工业株式会社 | 用于烯烃聚合的催化剂和烯烃聚合物 |
| US5229478A (en) * | 1988-06-16 | 1993-07-20 | Exxon Chemical Patents Inc. | Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3291780A (en) * | 1960-10-05 | 1966-12-13 | Du Pont | Slurry process for the preparation of hydrocarbon interpolymers |
| US3819591A (en) * | 1970-05-19 | 1974-06-25 | J Campbell | Branched-chain hydrocarbon elastomers |
| US3764589A (en) * | 1970-12-30 | 1973-10-09 | Copolymer Rubber & Chem Corp | Alpha-olefin interpolymers formed with unsaturated organo silanes |
| NL8502747A (nl) * | 1985-10-09 | 1987-05-04 | Stamicarbon | Gemodificeerd polyetheen, werkwijze voor het bereiden van gemodificeerd polyetheen, en produkten vervaardigd uit gemodificeerd polyetheen. |
| US4668834B1 (en) * | 1985-10-16 | 1996-05-07 | Uniroyal Chem Co Inc | Low molecular weight ethylene-alphaolefin copolymer intermediates |
| IL84642A0 (en) * | 1986-12-19 | 1988-04-29 | Exxon Chemical Patents Inc | Ethylene copolymers and their preparation |
| JP2538625B2 (ja) * | 1987-11-13 | 1996-09-25 | 三井石油化学工業株式会社 | 分枝α−オレフイン系ランダム共重合体およびその製法 |
| CA1327673C (en) * | 1988-06-16 | 1994-03-08 | Sigmund Floyd | Process for production of high molecular weight epdm elastomers using a metallocene-alumoxane catalyst system |
| JP2835729B2 (ja) * | 1988-10-24 | 1998-12-14 | チッソ株式会社 | オレフィン重合体の製造方法 |
| NZ235032A (en) * | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| US5272236A (en) * | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| US5721185A (en) * | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
| US5278272A (en) * | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
| SE9103077D0 (sv) * | 1991-10-22 | 1991-10-22 | Neste Oy | Omaettad etensampolymer och saett foer framstaellning daerav |
| RU95110681A (ru) * | 1992-09-29 | 1997-01-10 | Эксон Кемикэл Пейтентс Инк. (US) | Разветвленные длинноцепочечные полимеры и способ получения разветвленных длинноцепочечных полимеров |
| WO1994010216A1 (fr) * | 1992-10-28 | 1994-05-11 | Idemitsu Kosan Co., Ltd. | Copolymeres d'olefines et procede pour leur production |
| SE501577C2 (sv) * | 1992-12-07 | 1995-03-20 | Borealis Holding As | Omättad etensampolymer och sätt för framställning därav |
| US5470993A (en) * | 1993-06-24 | 1995-11-28 | The Dow Chemical Company | Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom |
| CN1111551C (zh) * | 1994-04-20 | 2003-06-18 | 陶氏化学公司 | 硅烷可交联的基本线型乙烯聚合物及其用途 |
| NL9400758A (nl) * | 1994-05-06 | 1995-12-01 | Dsm Nv | Werkwijze voor de bereiding van een hoogmoleculair polymeer uit etheen, alfa-olefine en eventueel dieen. |
| US6300451B1 (en) * | 1994-10-24 | 2001-10-09 | Exxon Chemical Patents Inc. | Long-chain branched polymers and their production |
-
1995
- 1995-11-30 US US08/565,329 patent/US5814714A/en not_active Expired - Lifetime
-
1996
- 1996-11-27 ES ES96940613T patent/ES2193276T3/es not_active Expired - Lifetime
- 1996-11-27 DE DE69628188T patent/DE69628188T2/de not_active Expired - Lifetime
- 1996-11-27 BR BR9611799A patent/BR9611799A/pt not_active IP Right Cessation
- 1996-11-27 AT AT96940613T patent/ATE240355T1/de not_active IP Right Cessation
- 1996-11-27 JP JP9517667A patent/JP2000502117A/ja active Pending
- 1996-11-27 RU RU98112006/04A patent/RU2167885C2/ru not_active IP Right Cessation
- 1996-11-27 AU AU10248/97A patent/AU708722B2/en not_active Ceased
- 1996-11-27 EP EP96940613A patent/EP0863924B1/en not_active Expired - Lifetime
- 1996-11-27 KR KR10-1998-0704036A patent/KR100456710B1/ko not_active Expired - Lifetime
- 1996-11-27 WO PCT/US1996/018922 patent/WO1997019965A1/en not_active Ceased
- 1996-11-27 CN CN96198703A patent/CN1084342C/zh not_active Expired - Lifetime
- 1996-11-28 AR ARP960105386A patent/AR012812A1/es not_active Application Discontinuation
- 1996-11-28 ZA ZA9609992A patent/ZA969992B/xx unknown
-
1997
- 1997-02-15 TW TW086101792A patent/TW338053B/zh active
-
1998
- 1998-05-28 MX MX9804266A patent/MX9804266A/es unknown
- 1998-05-29 NO NO982470A patent/NO982470L/no not_active Application Discontinuation
-
2002
- 2002-02-28 CN CN02105397A patent/CN1373144A/zh active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3984610A (en) * | 1971-04-16 | 1976-10-05 | Du Pont Of Canada Limited | Ethylene polymers with long chain branching |
| US5229478A (en) * | 1988-06-16 | 1993-07-20 | Exxon Chemical Patents Inc. | Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system |
| CN1070651A (zh) * | 1991-08-14 | 1993-04-07 | 三井石油化学工业株式会社 | 用于烯烃聚合的催化剂和烯烃聚合物 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0863924B1 (en) | 2003-05-14 |
| NO982470L (no) | 1998-07-29 |
| TW338053B (en) | 1998-08-11 |
| KR19990071758A (ko) | 1999-09-27 |
| CN1203606A (zh) | 1998-12-30 |
| EP0863924A1 (en) | 1998-09-16 |
| US5814714A (en) | 1998-09-29 |
| CN1373144A (zh) | 2002-10-09 |
| KR100456710B1 (ko) | 2005-04-08 |
| AR012812A1 (es) | 2000-11-22 |
| ES2193276T3 (es) | 2003-11-01 |
| ZA969992B (en) | 1998-05-28 |
| BR9611799A (pt) | 1999-07-13 |
| AU708722B2 (en) | 1999-08-12 |
| WO1997019965A1 (en) | 1997-06-05 |
| AU1024897A (en) | 1997-06-19 |
| MX9804266A (es) | 1998-09-30 |
| ATE240355T1 (de) | 2003-05-15 |
| JP2000502117A (ja) | 2000-02-22 |
| RU2167885C2 (ru) | 2001-05-27 |
| NO982470D0 (no) | 1998-05-29 |
| DE69628188T2 (de) | 2004-04-01 |
| DE69628188D1 (de) | 2003-06-18 |
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