CN108409469A - A kind of special Water-retaining slow-release fertilizer of shrub althea flower - Google Patents
A kind of special Water-retaining slow-release fertilizer of shrub althea flower Download PDFInfo
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- CN108409469A CN108409469A CN201810561666.2A CN201810561666A CN108409469A CN 108409469 A CN108409469 A CN 108409469A CN 201810561666 A CN201810561666 A CN 201810561666A CN 108409469 A CN108409469 A CN 108409469A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
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- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Soil Sciences (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a kind of special Water-retaining slow-release fertilizer of shrub althea flower, raw material includes by weight:20 50 parts of bagasse, 10 27 parts of tea waste residue, 11 25 parts of seaweed, 20 37 parts of carbonization stalk, 8 13 parts of hot pepper crop, 6 14 parts of tobacco cauline leaf, 5 17 parts of composite Chinese herbal, 3 10 parts of water-holding slow-release agent, 0.1 0.5 parts of lactobacillus preparation, 15 parts of shale, 5 13 parts of shepardite, 29 parts of oyster shell whiting, 14 parts of calcium carbonate, 26 parts of fulvic acid iron, 8 15 parts of potassium fulvate, 15 parts of potassium chloride, 10 22 parts of ammonium phosphate, 9 12 parts of calcium magnesium phosphate, 1 2.3 parts of polyhydroxyalkanoates.The special Water-retaining slow-release fertilizer of shrub althea flower proposed by the present invention, nutritional ingredient is balanced, formula is reasonable, and water-holding slow-release effect is good, and fertilizer efficiency is high, can promote the growth of shrub althea flower, improve its disease and insect resistance.
Description
Technical field
The present invention relates to technical field of fertilizers more particularly to a kind of special Water-retaining slow-release fertilizers of shrub althea flower.
Background technology
Shrub althea flower is very strong to the adaptability of environment, more resistance to drying and barren, requires soil not stringent, has become one at present
The kind shrub seeds of flowering plants very common in flower garden.Fertilizer plays an important role in shrub althea flower growth course, and the fertilising of shrub althea flower is main
Based on nitrogenous fertilizer, phosphate fertilizer and potash fertilizer, in different growing stage fertilising situation different from.Although having been disclosed currently on the market more
Kind shrub althea flower fertilizer, but there are with single nutrient component, formula is unreasonable, water-holding slow-release effect for now common shrub althea flower fertilizer
The defect that fruit is not good enough, fertilizer efficiency is low.
Invention content
Technical problems based on background technology, the present invention propose a kind of special Water-retaining slow-release fertilizer of shrub althea flower,
Nutritional ingredient is balanced, formula is reasonable, and water-holding slow-release effect is good, and fertilizer efficiency is high, can promote the growth of shrub althea flower, improve its Resistant
Evil property.
The special Water-retaining slow-release fertilizer of a kind of shrub althea flower proposed by the present invention, raw material include by weight:Bagasse 20-50
Part, 11-25 parts of seaweed, 20-37 parts of carbonization stalk, 8-13 parts of hot pepper crop, 6-14 parts of tobacco cauline leaf, is answered at 10-27 parts of tea waste residue
Close 5-17 parts of Chinese herbal medicine, 3-10 parts of water-holding slow-release agent, 0.1-0.5 parts of lactobacillus preparation, 1-5 parts of shale, 5-13 parts of shepardite, shellfish
2-9 parts of shell powder, 1-4 parts of calcium carbonate, 2-6 parts of fulvic acid iron, 8-15 parts of potassium fulvate, 1-5 parts of potassium chloride, 10-22 parts of ammonium phosphate,
9-12 parts of calcium magnesium phosphate, 1-2.3 parts of polyhydroxyalkanoates.
Preferably, the tea waste residue is Ilex Latifolia Thunb waste residue.
Preferably, it is 2-10 by weight that the seaweed, which is spirulina, chlorella, seaweed, bladder-wrack,:1-5:3-11:2-7
Mixture.
Preferably, the composite Chinese herbal is a variety of in cloves, corter pseudolaricis, Chinese milk vetch, print chinaberry, tripterygium wilfordii, Chinese prickly ash mixes
Close object.
Preferably, it is 5-9 by weight that the lactobacillus preparation, which is Lactobacillus brevis and lactobacillus plantarum,:The mixing of 2-11
Object.
Preferably, the water-holding slow-release agent is prepared according to following technique:Starch gelatinization is obtained into gelatinized starch;It will be more
The acrylic acid solution of bacterium spirit is added to the water, and is stirring evenly and then adding into methyl methacrylate, is warming up to 68-73 DEG C, is added 2,2 '-
Azo diisobutyl amidine dihydrochloride, is stirring evenly and then adding into partial gelatinization starch, reacts 5-9h under the protection of nitrogen, obtain
Material A;By acrylamide, nitric acid oxidation activated carbon, N, N '-methylene-bisacrylamides, sodium peroxydisulfate are added to the water, and are added surplus
In remaining gelatinized starch, acrylic acid is added, itaconic acid and potassium dihydrogen phosphate are uniformly mixing to obtain monomer solution, by monomer solution plus
Enter into material A, 67-75 DEG C is warming up under the protection of nitrogen, be stirred to react 2-3h, cools down after reaction, dry, powder
Broken, sieving obtains the water-holding slow-release agent.
Preferably, in the preparation process of water-holding slow-release agent, the weight of partial gelatinization starch is gelatinized starch total weight
30-38wt%;In the preparation process of material A, carbendazim, acrylic acid, methyl methacrylate, partial gelatinization starch weight
Than for 0.05-0.12:0.9-1.7:2-3:1.4-2.3;It is acrylamide, nitric acid oxidation activated carbon, remaining in monomer solution
Gelatinized starch, acrylic acid, itaconic acid, potassium dihydrogen phosphate weight ratio be 1-3:0.5-1.2:2-4:0.8-2:0.5-1.5:2-3.
Preferably, the polyhydroxyalkanoates is in poly 3-hydroxy butyrate, poly 3-hydroxy butyrate -3- hydroxycaproic esters
One or two kinds of mixture.
The special Water-retaining slow-release fertilizer of shrub althea flower of the present invention, with bagasse, tea waste residue, seaweed, carbonization stalk, capsicum
Seedling, tobacco cauline leaf, composite Chinese herbal and fulvic acid iron, potassium fulvate, potassium chloride, ammonium phosphate, calcium magnesium phosphate cooperation, are shrub althea flower
Growth provide the nutritional ingredients such as N P and K, meet the growth demand of shrub althea flower, simultaneously contain multiple nucleic acids, amino acid,
The many kinds of substance such as digestive ferment, it is therefore prevented that the chlorosis yellow of shrub althea flower blade promotes the division of cell, it is vigorous to maintain shrub althea flower
Metabolism, improve the resistance of shrub althea flower, while matching with water-holding slow-release agent, shale, shepardite, oyster shell whiting, calcium carbonate
Close, make Soil ventilation, water conservation, it is therefore prevented that soil it is hardened, promote the growth of shrub althea flower;In the preparation process of water-holding slow-release agent
In, carbendazim is dissolved in acrylic acid, after being mixed with methyl methacrylate and gelatinized starch, graft copolymerization has occurred with starch
Reaction, form microcapsule structure, part carbendazim be embedded into microcapsules, obtained material A, later by material A with
Acrylamide, nitric acid oxidation activated carbon, acrylic acid, itaconic acid and potassium dihydrogen phosphate mixing, have occurred copolyreaction and obtain again
Hydrogel coating, while nitric acid oxidation activated carbon and potassium dihydrogen phosphate being coated in hydrogel coating, it obtains
The water-holding slow-release agent, there are a large amount of COOH, CONH in structure2, the hydrophilic radicals ,-COONa therein such as-COONa exist
- COO can be ionized into water-And Na+,-the COO on chain-Between electrostatic repulsion forces so that macromolecular chain is expanded, polymer network
Expansion enters polymer network for hydrone and provides channel, and the presence of Na ions simultaneously, causes osmotic pressure inside and outside polymer
The formation of difference makes the water in medium constantly enter in polymer network, assigns its excellent water absorbing properties, be added into system
In, there is excellent water retention property, reduce the frequency of irrigation, promote the growth of shrub althea flower, simultaneously because polymer network
Water absorbing capacity difference, form one release diffusion system, as hydrone is discharged into from the polymer network of expansion
In medium, make the concentration gradient for foring carbendazim and potassium dihydrogen phosphate inside and outside polymer network, promotes the two constantly release
Into medium, on the one hand provide potash fertilizer for shrub althea flower, at the same with composite Chinese herbal, tobacco cauline leaf with insecticidal and antibacterial effect
There is synergistic effect with hot pepper crop, assign fertilizer excellent bactericidal property, improve the disease and insect resistance of shrub althea flower, while can prolong
Long flowering period promotes plant height, the stem thickness of shrub althea flower, improves the ornamental value of shrub althea flower.
Specific implementation mode
In the following, technical scheme of the present invention is described in detail by specific embodiment.
Embodiment 1
The special Water-retaining slow-release fertilizer of a kind of shrub althea flower proposed by the present invention, raw material include by weight:50 parts of bagasse,
10 parts of tea waste residue, 25 parts of seaweed, 20 parts of carbonization stalk, 13 parts of hot pepper crop, 6 parts of tobacco cauline leaf, 17 parts of composite Chinese herbal, water conservation
3 parts of sustained release agent, 0.5 part of lactobacillus preparation, 1 part of shale, 13 parts of shepardite, 2 parts of oyster shell whiting, 4 parts of calcium carbonate, 2 parts of fulvic acid iron,
15 parts of potassium fulvate, 1 part of potassium chloride, 22 parts of ammonium phosphate, 9 parts of calcium magnesium phosphate, 2.3 parts of polyhydroxyalkanoates.
Embodiment 2
The special Water-retaining slow-release fertilizer of a kind of shrub althea flower proposed by the present invention, raw material include by weight:20 parts of bagasse,
27 parts of tea waste residue, 11 parts of seaweed, 37 parts of carbonization stalk, 8 parts of hot pepper crop, 14 parts of tobacco cauline leaf, 5 parts of composite Chinese herbal, water conservation
10 parts of sustained release agent, 0.1 part of lactobacillus preparation, 5 parts of shale, 5 parts of shepardite, 9 parts of oyster shell whiting, 1 part of calcium carbonate, 6 parts of fulvic acid iron,
8 parts of potassium fulvate, 5 parts of potassium chloride, 10 parts of ammonium phosphate, 12 parts of calcium magnesium phosphate, 1 part of polyhydroxyalkanoates.
Embodiment 3
The special Water-retaining slow-release fertilizer of a kind of shrub althea flower proposed by the present invention, raw material include by weight:43 parts of bagasse,
14 parts of tea waste residue, 24 parts of seaweed, carbonization stalk 24,11 parts of hot pepper crop, 8 parts of tobacco cauline leaf, 15 parts of composite Chinese herbal, water conservation are slow
Release 7 parts of agent, 0.4 part of lactobacillus preparation, 2 parts of shale, 12 parts of shepardite, 3 parts of oyster shell whiting, 3 parts of calcium carbonate, 3 parts of fulvic acid iron, Huang
Rotten 14 parts of potassium of acid, 2 parts of potassium chloride, 21 parts of ammonium phosphate, 10 parts of calcium magnesium phosphate, 2 parts of polyhydroxyalkanoates;
Wherein, the tea waste residue is Ilex Latifolia Thunb waste residue;
The seaweed is that spirulina, chlorella, seaweed, bladder-wrack are 2 by weight:5:3:7 mixture;
The composite Chinese herbal be cloves, Chinese milk vetch mixture, and cloves, Chinese milk vetch weight ratio be 3:5;
The lactobacillus preparation is that Lactobacillus brevis and lactobacillus plantarum are 5 by weight:11 mixture;
The water-holding slow-release agent is prepared according to following technique:Starch gelatinization is obtained into gelatinized starch;By carbendazim
Acrylic acid solution is added to the water, and is stirring evenly and then adding into methyl methacrylate, is warming up to 68 DEG C, and it is different that 2,2 '-azos two are added
Butyl amidine dihydrochloride, is stirring evenly and then adding into partial gelatinization starch, reacts 9h under the protection of nitrogen, obtains material A;By third
Acrylamide, nitric acid oxidation activated carbon, N, N '-methylene-bisacrylamides, sodium peroxydisulfate are added to the water, and remaining gelatinization is added and forms sediment
In powder, acrylic acid, itaconic acid and potassium dihydrogen phosphate is added and is uniformly mixing to obtain monomer solution, monomer solution is added to material A
In, 67 DEG C are warming up under the protection of nitrogen, is stirred to react 3h, cool down after reaction, be dry, crushing, sieving obtain it is described
Water-holding slow-release agent;
In the preparation process of water-holding slow-release agent, the weight of partial gelatinization starch is the 30wt% of gelatinized starch total weight;
In the preparation process of material A, carbendazim, acrylic acid, methyl methacrylate, partial gelatinization starch weight ratio be 0.12:
0.9:3:1.4;In monomer solution, acrylamide, nitric acid oxidation activated carbon, remaining gelatinized starch, acrylic acid, itaconic acid,
The weight ratio of potassium dihydrogen phosphate is 1:1.2:2:2:0.5:3;
The polyhydroxyalkanoates is poly 3-hydroxy butyrate.
Embodiment 4
The special Water-retaining slow-release fertilizer of a kind of shrub althea flower proposed by the present invention, raw material include by weight:28 parts of bagasse,
25 parts of tea waste residue, 16 parts of seaweed, 35 parts of carbonization stalk, 9 parts of hot pepper crop, 13 parts of tobacco cauline leaf, 8 parts of composite Chinese herbal, water conservation
8 parts of sustained release agent, 0.3 part of lactobacillus preparation, 4.3 parts of shale, 7 parts of shepardite, 8 parts of oyster shell whiting, 2 parts of calcium carbonate, fulvic acid iron 5
Part, 9 parts of potassium fulvate, 4 parts of potassium chloride, 15 parts of ammonium phosphate, 11 parts of calcium magnesium phosphate, 1.3 parts of polyhydroxyalkanoates;
Wherein, the tea waste residue is Ilex Latifolia Thunb waste residue;
The seaweed is that spirulina, chlorella, seaweed, bladder-wrack are 10 by weight:1:11:2 mixture;
The composite Chinese herbal be corter pseudolaricis, print chinaberry, Chinese prickly ash mixture, and corter pseudolaricis, print chinaberry, Chinese prickly ash weight ratio be
3:6:2;
The lactobacillus preparation is that Lactobacillus brevis and lactobacillus plantarum are 9 by weight:2 mixture;
The water-holding slow-release agent is prepared according to following technique:Starch gelatinization is obtained into gelatinized starch;By carbendazim
Acrylic acid solution is added to the water, and is stirring evenly and then adding into methyl methacrylate, is warming up to 73 DEG C, and it is different that 2,2 '-azos two are added
Butyl amidine dihydrochloride, is stirring evenly and then adding into partial gelatinization starch, reacts 5h under the protection of nitrogen, obtains material A;By third
Acrylamide, nitric acid oxidation activated carbon, N, N '-methylene-bisacrylamides, sodium peroxydisulfate are added to the water, and remaining gelatinization is added and forms sediment
In powder, acrylic acid, itaconic acid and potassium dihydrogen phosphate is added and is uniformly mixing to obtain monomer solution, monomer solution is added to material A
In, 75 DEG C are warming up under the protection of nitrogen, is stirred to react 2h, cool down after reaction, be dry, crushing, sieving obtain it is described
Water-holding slow-release agent;
In the preparation process of water-holding slow-release agent, the weight of partial gelatinization starch is the 38wt% of gelatinized starch total weight;
In the preparation process of material A, carbendazim, acrylic acid, methyl methacrylate, partial gelatinization starch weight ratio be 0.05:
1.7:2:2.3;In monomer solution, acrylamide, nitric acid oxidation activated carbon, remaining gelatinized starch, acrylic acid, itaconic acid,
The weight ratio of potassium dihydrogen phosphate is 3:0.5:4:0.8:1.5:2;
The polyhydroxyalkanoates is poly 3-hydroxy butyrate -3- hydroxycaproic esters.
Embodiment 5
The special Water-retaining slow-release fertilizer of a kind of shrub althea flower proposed by the present invention, raw material include by weight:37 parts of bagasse,
18 parts of tea waste residue, 17 parts of seaweed, 29 parts of carbonization stalk, 9 parts of hot pepper crop, 11 parts of tobacco cauline leaf, 12 parts of composite Chinese herbal, water conservation
7 parts of sustained release agent, 0.32 part of lactobacillus preparation, 3 parts of shale, 9 parts of shepardite, 7 parts of oyster shell whiting, 3 parts of calcium carbonate, 5 parts of fulvic acid iron,
11 parts of potassium fulvate, 3 parts of potassium chloride, 18 parts of ammonium phosphate, 10 parts of calcium magnesium phosphate, 1.7 parts of polyhydroxyalkanoates;
Wherein, the tea waste residue is Ilex Latifolia Thunb waste residue;
The seaweed is that spirulina, chlorella, seaweed, bladder-wrack are 7 by weight:3:8:5 mixture;
The composite Chinese herbal be cloves, corter pseudolaricis, Chinese milk vetch, print chinaberry, tripterygium wilfordii, Chinese prickly ash mixture, and cloves, soil
Rose of Sharon skin, Chinese milk vetch, print chinaberry, tripterygium wilfordii, Chinese prickly ash weight ratio be 3:8:2:3:4:1;
The lactobacillus preparation is that Lactobacillus brevis and lactobacillus plantarum are 8 by weight:7 mixture;
The water-holding slow-release agent is prepared according to following technique:Starch gelatinization is obtained into gelatinized starch;By carbendazim
Acrylic acid solution is added to the water, and is stirring evenly and then adding into methyl methacrylate, is warming up to 70 DEG C, and it is different that 2,2 '-azos two are added
Butyl amidine dihydrochloride, is stirring evenly and then adding into partial gelatinization starch, reacts 7h under the protection of nitrogen, obtains material A;By third
Acrylamide, nitric acid oxidation activated carbon, N, N '-methylene-bisacrylamides, sodium peroxydisulfate are added to the water, and remaining gelatinization is added and forms sediment
In powder, acrylic acid, itaconic acid and potassium dihydrogen phosphate is added and is uniformly mixing to obtain monomer solution, monomer solution is added to material A
In, it is warming up to 72 DEG C under the protection of nitrogen, is stirred to react 2.5h, cools down after reaction, is dry, crushing, sieving obtains institute
State water-holding slow-release agent;
In the preparation process of water-holding slow-release agent, the weight of partial gelatinization starch is the 35wt% of gelatinized starch total weight;
In the preparation process of material A, carbendazim, acrylic acid, methyl methacrylate, partial gelatinization starch weight ratio be 0.1:
1.3:2.6:2;In monomer solution, acrylamide, nitric acid oxidation activated carbon, remaining gelatinized starch, acrylic acid, itaconic acid,
The weight ratio of potassium dihydrogen phosphate is 2:1:3:1:1:2.6;
The polyhydroxyalkanoates is the mixture of poly 3-hydroxy butyrate, poly 3-hydroxy butyrate -3- hydroxycaproic esters,
And the weight ratio of poly 3-hydroxy butyrate, poly 3-hydroxy butyrate -3- hydroxycaproic esters is 4:7.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (8)
1. a kind of special Water-retaining slow-release fertilizer of shrub althea flower, which is characterized in that its raw material includes by weight:20-50 parts of bagasse,
It is 10-27 parts of tea waste residue, 11-25 parts of seaweed, 20-37 parts of carbonization stalk, 8-13 parts of hot pepper crop, 6-14 parts of tobacco cauline leaf, compound
5-17 parts of Chinese herbal medicine, 3-10 parts of water-holding slow-release agent, 0.1-0.5 parts of lactobacillus preparation, 1-5 parts of shale, 5-13 parts of shepardite, shell
2-9 parts of powder, 1-4 parts of calcium carbonate, 2-6 parts of fulvic acid iron, 8-15 parts of potassium fulvate, 1-5 parts of potassium chloride, 10-22 parts of ammonium phosphate, calcium
9-12 parts of magnesium-phosphorus fertilizer, 1-2.3 parts of polyhydroxyalkanoates.
2. the special Water-retaining slow-release fertilizer of shrub althea flower according to claim 1, which is characterized in that the tea waste residue is Ilex Latifolia Thunb
Waste residue.
3. the special Water-retaining slow-release fertilizer of shrub althea flower according to claim 1 or claim 2, which is characterized in that the seaweed be spirulina,
Chlorella, seaweed, bladder-wrack are 2-10 by weight:1-5:3-11:The mixture of 2-7.
4. according to the special Water-retaining slow-release fertilizer of any one of the claim 1-3 shrub althea flowers, which is characterized in that it is described it is compound in
Herbal medicine is cloves, corter pseudolaricis, Chinese milk vetch, prints mixture a variety of in chinaberry, tripterygium wilfordii, Chinese prickly ash.
5. according to the special Water-retaining slow-release fertilizer of any one of the claim 1-4 shrub althea flowers, which is characterized in that the lactic acid bacteria
Preparation is that Lactobacillus brevis and lactobacillus plantarum are 5-9 by weight:The mixture of 2-11.
6. according to the special Water-retaining slow-release fertilizer of any one of the claim 1-5 shrub althea flowers, which is characterized in that the water conservation is slow
Agent is released to be prepared according to following technique:Starch gelatinization is obtained into gelatinized starch;The acrylic acid solution of carbendazim is added to the water,
It is stirring evenly and then adding into methyl methacrylate, is warming up to 68-73 DEG C, 2,2 '-azo diisobutyl amidine dihydrochlorides are added, stir
Partial gelatinization starch is added after mixing uniformly, reacts 5-9h under the protection of nitrogen, obtains material A;By acrylamide, nitric acid oxidation
Activated carbon, N, N '-methylene-bisacrylamides, sodium peroxydisulfate are added to the water, and are added in remaining gelatinized starch, and propylene is added
Acid, itaconic acid and potassium dihydrogen phosphate are uniformly mixing to obtain monomer solution, monomer solution are added into material A, in the guarantor of nitrogen
It is warming up to 67-75 DEG C under shield, is stirred to react 2-3h, cools down after reaction, is dry, crushing, sieving obtains the water-holding slow-release
Agent.
7. the special Water-retaining slow-release fertilizer of shrub althea flower according to claim 6, which is characterized in that in the preparation of water-holding slow-release agent
Cheng Zhong, the weight of partial gelatinization starch are the 30-38wt% of gelatinized starch total weight;In the preparation process of material A, more bacterium
Spirit, acrylic acid, methyl methacrylate, partial gelatinization starch weight ratio be 0.05-0.12:0.9-1.7:2-3:1.4-2.3;
In monomer solution, acrylamide, nitric acid oxidation activated carbon, remaining gelatinized starch, acrylic acid, itaconic acid, potassium dihydrogen phosphate
Weight ratio be 1-3:0.5-1.2:2-4:0.8-2:0.5-1.5:2-3.
8. according to the special Water-retaining slow-release fertilizer of any one of the claim 1-7 shrub althea flowers, which is characterized in that the poly- hydroxyl
Alkanoic acid ester is one or two kinds of mixture in poly 3-hydroxy butyrate, poly 3-hydroxy butyrate -3- hydroxycaproic esters.
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CN106259320A (en) * | 2016-07-21 | 2017-01-04 | 河南师范大学 | A kind of water-absorbing-retaining sustained-release pesticides and preparation method thereof |
CN107162828A (en) * | 2017-07-27 | 2017-09-15 | 芜湖晋诚农业科技有限公司 | A kind of the fertilizer of retaining water and releasing nutrients slowly for improving Chinese cabbage disease resistance |
CN107188738A (en) * | 2017-07-27 | 2017-09-22 | 芜湖晋诚农业科技有限公司 | A kind of special Water-retaining slow-release fertilizer of Chinese cabbage |
CN107216219A (en) * | 2017-07-27 | 2017-09-29 | 芜湖晋诚农业科技有限公司 | A kind of fertilizer for improving Chinese cabbage quality |
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Application publication date: 20180817 |