CN108325340A - 废气中污染物的再生回收 - Google Patents
废气中污染物的再生回收 Download PDFInfo
- Publication number
- CN108325340A CN108325340A CN201810298184.2A CN201810298184A CN108325340A CN 108325340 A CN108325340 A CN 108325340A CN 201810298184 A CN201810298184 A CN 201810298184A CN 108325340 A CN108325340 A CN 108325340A
- Authority
- CN
- China
- Prior art keywords
- gas
- stripper
- sulfur dioxide
- absorption
- absorber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000008929 regeneration Effects 0.000 title claims description 13
- 238000011069 regeneration method Methods 0.000 title claims description 13
- 238000004064 recycling Methods 0.000 title claims 2
- 239000003344 environmental pollutant Substances 0.000 title description 87
- 231100000719 pollutant Toxicity 0.000 title description 87
- 238000010521 absorption reaction Methods 0.000 claims abstract description 495
- 239000007788 liquid Substances 0.000 claims abstract description 404
- 239000006096 absorbing agent Substances 0.000 claims abstract description 321
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 1117
- 238000000034 method Methods 0.000 claims description 186
- 239000002253 acid Substances 0.000 claims description 47
- 239000007791 liquid phase Substances 0.000 claims description 45
- 239000002594 sorbent Substances 0.000 claims description 37
- 239000002585 base Substances 0.000 claims description 23
- 239000003513 alkali Substances 0.000 claims description 4
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 claims 1
- 229910052815 sulfur oxide Inorganic materials 0.000 claims 1
- 239000007789 gas Substances 0.000 abstract description 715
- 239000000356 contaminant Substances 0.000 abstract description 21
- 230000008569 process Effects 0.000 description 144
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 98
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 62
- 238000012546 transfer Methods 0.000 description 56
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 51
- 238000011084 recovery Methods 0.000 description 51
- 238000001816 cooling Methods 0.000 description 48
- 239000002904 solvent Substances 0.000 description 42
- 239000003463 adsorbent Substances 0.000 description 41
- 239000001630 malic acid Substances 0.000 description 38
- 235000011090 malic acid Nutrition 0.000 description 38
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 37
- 238000006243 chemical reaction Methods 0.000 description 31
- 230000001965 increasing effect Effects 0.000 description 26
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 25
- 238000003795 desorption Methods 0.000 description 25
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 22
- 239000003518 caustics Substances 0.000 description 22
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 20
- 229910052717 sulfur Inorganic materials 0.000 description 19
- 239000011593 sulfur Substances 0.000 description 19
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 230000000694 effects Effects 0.000 description 18
- 239000003546 flue gas Substances 0.000 description 18
- 239000000243 solution Substances 0.000 description 18
- 229940049920 malate Drugs 0.000 description 17
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 description 17
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 16
- 239000002250 absorbent Substances 0.000 description 16
- 230000002745 absorbent Effects 0.000 description 16
- 238000004519 manufacturing process Methods 0.000 description 16
- 230000002829 reductive effect Effects 0.000 description 16
- 230000006835 compression Effects 0.000 description 15
- 238000007906 compression Methods 0.000 description 15
- 150000003839 salts Chemical class 0.000 description 15
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 14
- 239000003960 organic solvent Substances 0.000 description 14
- 238000012856 packing Methods 0.000 description 14
- 239000012071 phase Substances 0.000 description 14
- 238000004088 simulation Methods 0.000 description 14
- -1 alkanolamines Chemical class 0.000 description 12
- 238000010438 heat treatment Methods 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 12
- 239000002184 metal Substances 0.000 description 12
- 239000007787 solid Substances 0.000 description 12
- 230000008901 benefit Effects 0.000 description 11
- WPUMTJGUQUYPIV-JIZZDEOASA-L disodium (S)-malate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](O)CC([O-])=O WPUMTJGUQUYPIV-JIZZDEOASA-L 0.000 description 11
- 230000003647 oxidation Effects 0.000 description 11
- 238000007254 oxidation reaction Methods 0.000 description 11
- 235000019265 sodium DL-malate Nutrition 0.000 description 11
- 239000001394 sodium malate Substances 0.000 description 11
- 230000007423 decrease Effects 0.000 description 10
- 230000002349 favourable effect Effects 0.000 description 10
- 239000012808 vapor phase Substances 0.000 description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 9
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 9
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 9
- 238000001179 sorption measurement Methods 0.000 description 9
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 8
- 229910021529 ammonia Inorganic materials 0.000 description 8
- 230000001276 controlling effect Effects 0.000 description 8
- 239000000446 fuel Substances 0.000 description 8
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 8
- 238000011068 loading method Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 230000001172 regenerating effect Effects 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 229910052938 sodium sulfate Inorganic materials 0.000 description 8
- 235000011152 sodium sulphate Nutrition 0.000 description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 description 7
- 239000002826 coolant Substances 0.000 description 7
- 239000003112 inhibitor Substances 0.000 description 7
- 230000009467 reduction Effects 0.000 description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 230000002378 acidificating effect Effects 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000009833 condensation Methods 0.000 description 6
- 230000005494 condensation Effects 0.000 description 6
- 230000000875 corresponding effect Effects 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 235000011121 sodium hydroxide Nutrition 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 5
- 230000002411 adverse Effects 0.000 description 5
- 238000009835 boiling Methods 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000001569 carbon dioxide Substances 0.000 description 5
- 238000010276 construction Methods 0.000 description 5
- 239000012809 cooling fluid Substances 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 238000002425 crystallisation Methods 0.000 description 5
- 230000008025 crystallization Effects 0.000 description 5
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 5
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 5
- 230000036961 partial effect Effects 0.000 description 5
- 229920005646 polycarboxylate Polymers 0.000 description 5
- 238000010926 purge Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000002912 waste gas Substances 0.000 description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000010494 dissociation reaction Methods 0.000 description 4
- 230000005593 dissociations Effects 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 238000013178 mathematical model Methods 0.000 description 4
- 239000012452 mother liquor Substances 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 230000001737 promoting effect Effects 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 235000017550 sodium carbonate Nutrition 0.000 description 4
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 3
- 235000011941 Tilia x europaea Nutrition 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000006477 desulfuration reaction Methods 0.000 description 3
- 230000023556 desulfurization Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000004571 lime Substances 0.000 description 3
- BJEPYKJPYRNKOW-UWTATZPHSA-M malate ion Chemical compound [O-]C(=O)[C@H](O)CC(O)=O BJEPYKJPYRNKOW-UWTATZPHSA-M 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 238000005457 optimization Methods 0.000 description 3
- 238000010979 pH adjustment Methods 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000011112 process operation Methods 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 238000007086 side reaction Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- 238000011144 upstream manufacturing Methods 0.000 description 3
- JPGXOMADPRULAC-UHFFFAOYSA-N 1-[butoxy(butyl)phosphoryl]oxybutane Chemical compound CCCCOP(=O)(CCCC)OCCCC JPGXOMADPRULAC-UHFFFAOYSA-N 0.000 description 2
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 2
- 229910002089 NOx Inorganic materials 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 239000003125 aqueous solvent Substances 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- 229960005070 ascorbic acid Drugs 0.000 description 2
- 239000011668 ascorbic acid Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 239000011151 fibre-reinforced plastic Substances 0.000 description 2
- 229940093915 gynecological organic acid Drugs 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000010446 mirabilite Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 235000011118 potassium hydroxide Nutrition 0.000 description 2
- 238000004886 process control Methods 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 2
- 235000010265 sodium sulphite Nutrition 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229940123457 Free radical scavenger Drugs 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229940123973 Oxygen scavenger Drugs 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- HIVLDXAAFGCOFU-UHFFFAOYSA-N ammonium hydrosulfide Chemical compound [NH4+].[SH-] HIVLDXAAFGCOFU-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 239000012062 aqueous buffer Substances 0.000 description 1
- 239000012223 aqueous fraction Substances 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000005203 dry scrubbing Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
- 230000001976 improved effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 230000004941 influx Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-L malate(2-) Chemical compound [O-]C(=O)C(O)CC([O-])=O BJEPYKJPYRNKOW-UHFFFAOYSA-L 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 150000004701 malic acid derivatives Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000013028 medium composition Substances 0.000 description 1
- 238000010310 metallurgical process Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- 239000012038 nucleophile Substances 0.000 description 1
- 230000000269 nucleophilic effect Effects 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- 229960002635 potassium citrate Drugs 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- 235000011082 potassium citrates Nutrition 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000005588 protonation Effects 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- HIFJUMGIHIZEPX-UHFFFAOYSA-N sulfuric acid;sulfur trioxide Chemical compound O=S(=O)=O.OS(O)(=O)=O HIFJUMGIHIZEPX-UHFFFAOYSA-N 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000005200 wet scrubbing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1406—Multiple stage absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1425—Regeneration of liquid absorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1481—Removing sulfur dioxide or sulfur trioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/507—Sulfur oxides by treating the gases with other liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/75—Multi-step processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/205—Other organic compounds not covered by B01D2252/00 - B01D2252/20494
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/20—Halogens or halogen compounds
- B01D2257/204—Inorganic halogen compounds
- B01D2257/2045—Hydrochloric acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/302—Sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/304—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/404—Nitrogen oxides other than dinitrogen oxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/406—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361793571P | 2013-03-15 | 2013-03-15 | |
| US61/793,571 | 2013-03-15 | ||
| CN201480027375.5A CN105209157B (zh) | 2013-03-15 | 2014-03-14 | 废气中污染物的再生回收 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480027375.5A Division CN105209157B (zh) | 2013-03-15 | 2014-03-14 | 废气中污染物的再生回收 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108325340A true CN108325340A (zh) | 2018-07-27 |
Family
ID=51537743
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810298184.2A Pending CN108325340A (zh) | 2013-03-15 | 2014-03-14 | 废气中污染物的再生回收 |
| CN201480027375.5A Active CN105209157B (zh) | 2013-03-15 | 2014-03-14 | 废气中污染物的再生回收 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480027375.5A Active CN105209157B (zh) | 2013-03-15 | 2014-03-14 | 废气中污染物的再生回收 |
Country Status (16)
| Country | Link |
|---|---|
| US (2) | US9266059B2 (https=) |
| EP (1) | EP2969136B1 (https=) |
| JP (2) | JP6912197B2 (https=) |
| KR (1) | KR102180252B1 (https=) |
| CN (2) | CN108325340A (https=) |
| AU (1) | AU2014228907B2 (https=) |
| BR (1) | BR112015022004B8 (https=) |
| CA (2) | CA2902732C (https=) |
| CL (2) | CL2015002727A1 (https=) |
| EA (1) | EA038815B1 (https=) |
| ES (1) | ES2898386T3 (https=) |
| MX (1) | MX382558B (https=) |
| MY (1) | MY183705A (https=) |
| SA (1) | SA515361089B1 (https=) |
| WO (1) | WO2014144618A1 (https=) |
| ZA (1) | ZA201506906B (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI795750B (zh) * | 2020-03-27 | 2023-03-11 | 日商三菱動力股份有限公司 | 燃燒排氣淨化處理相關裝置及方法 |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3031511B1 (en) * | 2014-12-11 | 2018-03-07 | Union Engineering A/S | Method for energy efficient recovery of carbon dioxide from an absorbent |
| ITUB20154126A1 (it) * | 2015-10-06 | 2017-04-06 | Giammarco Vetrocoke S R L | Procedimento perfezionato di rimozione selettiva di gas da miscele gassose che li contengono mediante l'impiego di soluzioni di lavaggio funzionanti con un ciclo chimico-fisico di assorbimento e rigenerazione ed impianto per attuare il procedimento |
| LU93014B1 (en) * | 2016-04-04 | 2017-10-05 | Ajo Ind S A R L | Catalyst mixture for the treatment of waste gas |
| EP3445475B1 (en) * | 2016-04-18 | 2022-09-07 | MECS, Inc. | Removal of sulfate from solvent solutions using an anion exchange resin |
| CN105964110A (zh) * | 2016-06-27 | 2016-09-28 | 成都市新都化工股份有限公司 | 一种水溶性聚磷酸铵生产中的尾气吸收装置 |
| US10458685B2 (en) * | 2016-11-08 | 2019-10-29 | Heatcraft Refrigeration Products Llc | Absorption subcooler for a refrigeration system |
| US10688435B2 (en) * | 2017-02-27 | 2020-06-23 | Honeywell International Inc. | Dual stripper with water sweep gas |
| US10941497B2 (en) | 2017-02-27 | 2021-03-09 | Honeywell International Inc. | Electrochemical carbon dioxide converter and liquid regenerator |
| CN108097001A (zh) * | 2018-01-11 | 2018-06-01 | 中石化南京工程有限公司 | 一种用于吸收氨氮混合气中氨气的系统和方法 |
| KR102250566B1 (ko) * | 2018-12-14 | 2021-05-10 | 한양대학교 에리카산학협력단 | 수처리 장치 및 수처리 방법 |
| US10589223B1 (en) | 2019-04-18 | 2020-03-17 | Saudi Arabian Oil Company | Method and apparatus for treating a sulfur dioxide containing stream by hydrogen sulfide in aqueous conditions |
| KR102586512B1 (ko) | 2020-06-23 | 2023-10-06 | 주식회사 엘지화학 | 이소프로필 알코올 제조방법 |
| TWI854155B (zh) * | 2020-11-03 | 2024-09-01 | 財團法人工業技術研究院 | 去除煙道氣中的二氧化硫的方法與裝置 |
| IT202100005585A1 (it) * | 2021-03-10 | 2022-09-10 | Nuovo Pignone Tecnologie Srl | Sistema di abbattimento di biossido di carbonio a base di ammoniaca con sezioni sovrapposte |
| WO2023154232A1 (en) * | 2022-02-10 | 2023-08-17 | Eig, Inc. | High efficiency utilization of heat in co2 stripper |
| US20240109077A1 (en) * | 2022-09-30 | 2024-04-04 | Harrison Zack Rice | System and method for capturing carbon to remove carbon dioxide from the atmosphere |
| CN115957597B (zh) * | 2022-11-25 | 2024-05-10 | 新疆敦华绿碳技术股份有限公司 | 一种解吸装置及二氧化碳生产系统 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52146773A (en) * | 1976-05-28 | 1977-12-06 | Bayer Ag | Method of removing sulfur dioxide from exhaust air |
| CN1780678A (zh) * | 2003-08-13 | 2006-05-31 | 坎索尔夫科技公司 | 低能耗so2洗涤方法 |
| CN101185838A (zh) * | 2007-08-24 | 2008-05-28 | 中国石油化工集团公司 | 一种可再生湿法烟气脱硫工艺 |
| CN102015068A (zh) * | 2008-04-02 | 2011-04-13 | 康宁股份有限公司 | 管理用于从流体流中吸着痕量污染物的流通式整体型吸着剂的使用的方法 |
| CN102292139A (zh) * | 2009-01-29 | 2011-12-21 | 巴斯夫欧洲公司 | 用于除去酸性气体的包含氨基酸和酸性促进剂的吸收剂 |
| US20120107209A1 (en) * | 2010-10-29 | 2012-05-03 | Mecs Inc | Regenerative recovery of sulfur dioxide from effluent gases |
Family Cites Families (65)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB371888A (en) | 1931-01-29 | 1932-04-29 | John Stanley Dunn | Improved process for the recovery of sulphur dioxide from gas mixtures containing it |
| US2031802A (en) | 1932-05-06 | 1936-02-25 | Ici Ltd | Recovery of sulphur dioxide from gas mixtures |
| GB400998A (en) | 1932-05-06 | 1933-11-06 | Daniel Tyrer | Improvements in or relating to the recovery of sulphur dioxide from gas mixtures |
| US2295587A (en) | 1939-11-25 | 1942-09-15 | American Smelting Refining | Recovery of sulphur dioxide from gas mixtures |
| US2368595A (en) | 1941-08-29 | 1945-01-30 | Shell Dev | Process for the separation of acidic gases from fluids |
| US2399013A (en) | 1944-09-12 | 1946-04-23 | American Smelting Refining | Process for the recovery of sulphur dioxide from gas mixtures |
| US2615787A (en) | 1949-08-27 | 1952-10-28 | Shell Dev | Purification and separation of gaseous mixtures |
| US2729543A (en) | 1950-12-12 | 1956-01-03 | Union Oil Co | Removal of sulfur dioxide from gases containing the same |
| BE547385A (https=) * | 1955-04-28 | |||
| US2878099A (en) | 1955-07-22 | 1959-03-17 | Ruhrstahl Ag Fa | Method of deacidifying gases |
| US3272885A (en) * | 1962-10-01 | 1966-09-13 | Phillips Petroleum Co | Separation of ethylene from acetylene |
| US3687624A (en) | 1970-09-11 | 1972-08-29 | Wellman Lord Inc | Process for recovering sulfur dioxide from a gas containing same |
| US3833508A (en) | 1971-04-27 | 1974-09-03 | Itt | Gas removal method and composition |
| US3911093A (en) | 1971-10-18 | 1975-10-07 | Stauffer Chemical Co | Recovery of SO{HD 2 {B from waste gas emissions |
| NO133546C (https=) | 1972-11-24 | 1976-05-19 | Sintef | |
| GB1482643A (en) | 1973-10-31 | 1977-08-10 | Kureha Chemical Ind Co Ltd | Method for removing oxides of nitrogen from a gas |
| JPS5096478A (https=) | 1973-12-27 | 1975-07-31 | ||
| GB1501702A (en) | 1974-01-21 | 1978-02-22 | Kureha Chemical Ind Co Ltd | Method of removing nitrogen oxides from a gas containing them |
| US4222993A (en) | 1974-09-19 | 1980-09-16 | Heinz Holter | Removal of noxious contaminants from gas |
| JPS5288268A (en) * | 1976-01-20 | 1977-07-23 | Chiyoda Chem Eng & Constr Co Ltd | Desulfurization of exhaust flue gas |
| US4083944A (en) | 1976-12-17 | 1978-04-11 | Arthur G. Mckee & Company | Regenerative process for flue gas desulfurization |
| JPS53106382A (en) * | 1977-02-28 | 1978-09-16 | Chiyoda Chem Eng & Constr Co Ltd | Simultaneous desulfurization and denitration method for exhaust gas |
| US4140751A (en) * | 1977-03-04 | 1979-02-20 | Peabody Process Systems, Inc. | Process for pressure stripping of sulfur dioxide from buffered solutions |
| CA1106576A (en) | 1977-03-25 | 1981-08-11 | Alexander J. Kosseim | Process for removing so.sub.2 from effluent gases and for removing heat stable salts from systems in which they accumulate using an anion exchange resin |
| US4122149A (en) | 1977-03-25 | 1978-10-24 | Union Carbide Corporation | Process for removing SO2 from effluent gases and for removing heat stable salts from systems in which they accumulate |
| SE405109B (sv) | 1977-04-12 | 1978-11-20 | Svenska Flaektfabriken Ab | Forfarande for utvinning av koncentrerad svaveldioxid ur avgaser innehallande svaveldioxid |
| UST970008I4 (en) * | 1977-05-05 | 1978-05-02 | Tennessee Valley Authority | Removal and recovery of sulfur oxides from gas streams with melamine |
| SE429200B (sv) | 1978-10-31 | 1983-08-22 | Flaekt Ab | Forfarande for atervinning av natriumcitrat fran vattenlosningar som anvents i ett absorptions/avdrivningsforfarande for so?712-atervinning |
| JPS5584519A (en) * | 1978-12-20 | 1980-06-25 | Chiyoda Chem Eng & Constr Co Ltd | Wet type smoke desulfurization using pottasium tartrate as absorbent |
| US4277268A (en) | 1979-10-17 | 1981-07-07 | Conoco, Inc. | Heat pump fractionation process |
| US4366134A (en) | 1979-11-14 | 1982-12-28 | Pfizer Inc. | Flue gas desulfurization process |
| US4444571A (en) | 1983-03-07 | 1984-04-24 | Bend Research, Inc. | Energy-efficient process for the stripping of gases from liquids |
| US4670242A (en) | 1984-11-09 | 1987-06-02 | Monsanto Company | Heat recovery from concentrated sulfuric acid |
| US4996038A (en) | 1983-07-05 | 1991-02-26 | Monsanto Company | Heat recovery from concentrated sulfuric acid |
| US4576813A (en) | 1983-07-05 | 1986-03-18 | Monsanto Company | Heat recovery from concentrated sulfuric acid |
| CA1228324A (en) | 1984-03-07 | 1987-10-20 | Hans Becker | Process and apparatus for distillation and/or stripping |
| DE3578133D1 (de) | 1984-03-07 | 1990-07-19 | Linde Ag | Verfahren und vorrichtung zur rektifikation und/oder strippung. |
| DD252978A5 (de) | 1985-09-16 | 1988-01-06 | K | Verfahren zur reinigung von schwefeldioxid enthaltenden gasen |
| US5068419A (en) | 1986-12-18 | 1991-11-26 | Uop | Separation of an organic acid from a fermentation broth with an anionic polymeric adsorbent |
| US4968501A (en) | 1988-02-01 | 1990-11-06 | Mason James A | Use of chlorous acid for removing sulfur dioxide from combustion gases |
| US5130112A (en) | 1990-03-23 | 1992-07-14 | Monsanto Company | Method for recovering high grade process energy from a contact sulfuric acid process |
| GB9103382D0 (en) | 1991-02-19 | 1991-04-03 | Boc Group Plc | Treatment of gases |
| US5538707A (en) | 1994-03-01 | 1996-07-23 | Monsanto Company | Acid concentration control in SO3 absorption |
| US5785888A (en) | 1995-03-24 | 1998-07-28 | Milmac Operating Company | Method for removal of sulfur dioxide |
| US6174348B1 (en) | 1999-08-17 | 2001-01-16 | Praxair Technology, Inc. | Nitrogen system for regenerating chemical solvent |
| US7056482B2 (en) * | 2003-06-12 | 2006-06-06 | Cansolv Technologies Inc. | Method for recovery of CO2 from gas streams |
| UA93541C2 (ru) * | 2006-02-14 | 2011-02-25 | Басф Ce | Способ удаления кислых газов из потока текучей среды и способ переоборудования установки для удаления кислых газов из потока текучей среды |
| US7901488B2 (en) * | 2006-10-04 | 2011-03-08 | Board Of Regents, The University Of Texas System | Regeneration of an aqueous solution from an acid gas absorption process by matrix stripping |
| US7981196B2 (en) | 2007-06-04 | 2011-07-19 | Posco | Apparatus and method for recovering carbon dioxide from flue gas using ammonia water |
| US8182577B2 (en) | 2007-10-22 | 2012-05-22 | Alstom Technology Ltd | Multi-stage CO2 removal system and method for processing a flue gas stream |
| DE102008058143B4 (de) * | 2008-11-20 | 2012-04-12 | Lurgi Gmbh | Verfahren und Anlage zur Gewinnung von NH3 aus einem NH3 und Sauergase enthaltenden Gemisch |
| US8063112B2 (en) | 2008-12-08 | 2011-11-22 | Cansolv Technologies Inc. | Process for the regeneration of an ion exchange resin using sulfurous acid |
| CN101481095A (zh) | 2009-02-05 | 2009-07-15 | 中国石化集团南京设计院 | 硫酸生产能量回收及利用工艺 |
| JP2010207727A (ja) * | 2009-03-10 | 2010-09-24 | Mitsubishi Heavy Industries Mechatronics Systems Ltd | ガス精製装置及びガス精製方法 |
| US8309047B2 (en) | 2009-09-15 | 2012-11-13 | Alstom Technology Ltd | Method and system for removal of carbon dioxide from a process gas |
| JP5665022B2 (ja) | 2010-03-31 | 2015-02-04 | 新日鉄住金エンジニアリング株式会社 | 二酸化炭素ガス回収装置 |
| JP5402842B2 (ja) | 2010-06-14 | 2014-01-29 | 株式会社Ihi | 二酸化炭素の回収方法及び回収装置 |
| US8647421B2 (en) * | 2011-03-17 | 2014-02-11 | Mitsubishi Heavy Industries, Ltd. | CO2 recovery apparatus |
| CN102895840B (zh) | 2011-07-27 | 2015-06-03 | 中国石油化工股份有限公司 | 一种可再生湿法烟气脱硫工艺 |
| JP2013059726A (ja) * | 2011-09-13 | 2013-04-04 | Mitsubishi Heavy Ind Ltd | Co2回収装置およびco2回収方法 |
| EP2768601B1 (en) * | 2011-09-26 | 2020-09-09 | EIG Inc. | Simultaneous high efficiency capture of co2 and h2s from pressurized gas |
| DE112011105958B4 (de) * | 2011-12-16 | 2023-01-26 | Dge Dr.-Ing. Günther Engineering Gmbh | Verfahren und Anlage zur Abtrennung von Kohlendioxid aus methan- und schwefelwasserstoffhaltigen Biogasen |
| MA37598B1 (fr) | 2012-05-02 | 2016-05-31 | Mecs Inc | Récupération régénérative de contaminants à partir de gaz d'effluent |
| CN102659568B (zh) | 2012-05-03 | 2015-03-18 | 中粮生物化学(安徽)股份有限公司 | 一种连续脱除含柠檬酸的溶液中的阳离子的方法 |
| MA40600B1 (fr) * | 2014-12-19 | 2018-11-30 | Outotec Finland Oy | Procédé et installation pour une production énergétiquement efficace, améliorée d'acide sulfurique |
-
2014
- 2014-03-14 CA CA2902732A patent/CA2902732C/en active Active
- 2014-03-14 CN CN201810298184.2A patent/CN108325340A/zh active Pending
- 2014-03-14 ES ES14765162T patent/ES2898386T3/es active Active
- 2014-03-14 MY MYPI2015703065A patent/MY183705A/en unknown
- 2014-03-14 JP JP2016502982A patent/JP6912197B2/ja not_active Expired - Fee Related
- 2014-03-14 BR BR112015022004A patent/BR112015022004B8/pt not_active IP Right Cessation
- 2014-03-14 WO PCT/US2014/029103 patent/WO2014144618A1/en not_active Ceased
- 2014-03-14 MX MX2015012112A patent/MX382558B/es unknown
- 2014-03-14 AU AU2014228907A patent/AU2014228907B2/en not_active Ceased
- 2014-03-14 EP EP14765162.4A patent/EP2969136B1/en not_active Not-in-force
- 2014-03-14 EA EA201591811A patent/EA038815B1/ru unknown
- 2014-03-14 KR KR1020157028408A patent/KR102180252B1/ko not_active Expired - Fee Related
- 2014-03-14 CA CA3126768A patent/CA3126768C/en active Active
- 2014-03-14 CN CN201480027375.5A patent/CN105209157B/zh active Active
- 2014-03-17 US US14/216,077 patent/US9266059B2/en active Active
-
2015
- 2015-09-14 SA SA515361089A patent/SA515361089B1/ar unknown
- 2015-09-15 CL CL2015002727A patent/CL2015002727A1/es unknown
- 2015-09-17 ZA ZA2015/06906A patent/ZA201506906B/en unknown
-
2016
- 2016-01-14 US US14/995,885 patent/US9884289B2/en active Active
-
2018
- 2018-06-07 CL CL2018001526A patent/CL2018001526A1/es unknown
-
2019
- 2019-03-05 JP JP2019039633A patent/JP7174651B2/ja active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52146773A (en) * | 1976-05-28 | 1977-12-06 | Bayer Ag | Method of removing sulfur dioxide from exhaust air |
| CN1780678A (zh) * | 2003-08-13 | 2006-05-31 | 坎索尔夫科技公司 | 低能耗so2洗涤方法 |
| CN101185838A (zh) * | 2007-08-24 | 2008-05-28 | 中国石油化工集团公司 | 一种可再生湿法烟气脱硫工艺 |
| CN102015068A (zh) * | 2008-04-02 | 2011-04-13 | 康宁股份有限公司 | 管理用于从流体流中吸着痕量污染物的流通式整体型吸着剂的使用的方法 |
| CN102292139A (zh) * | 2009-01-29 | 2011-12-21 | 巴斯夫欧洲公司 | 用于除去酸性气体的包含氨基酸和酸性促进剂的吸收剂 |
| US20120107209A1 (en) * | 2010-10-29 | 2012-05-03 | Mecs Inc | Regenerative recovery of sulfur dioxide from effluent gases |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI795750B (zh) * | 2020-03-27 | 2023-03-11 | 日商三菱動力股份有限公司 | 燃燒排氣淨化處理相關裝置及方法 |
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105209157B (zh) | 废气中污染物的再生回收 | |
| CA2871987C (en) | Regenerative recovery of contaminants from effluent gases | |
| CN103249465B (zh) | 排放气体中二氧化硫的再生回收 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180727 |