CN108129178A - A kind of trace element fertilizer feed composition and its application - Google Patents
A kind of trace element fertilizer feed composition and its application Download PDFInfo
- Publication number
- CN108129178A CN108129178A CN201810068241.8A CN201810068241A CN108129178A CN 108129178 A CN108129178 A CN 108129178A CN 201810068241 A CN201810068241 A CN 201810068241A CN 108129178 A CN108129178 A CN 108129178A
- Authority
- CN
- China
- Prior art keywords
- zinc
- fertilizer
- parts
- molybdenum
- trace element
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 128
- 239000000203 mixture Substances 0.000 title claims abstract description 74
- 239000011573 trace mineral Substances 0.000 title claims abstract description 48
- 235000013619 trace mineral Nutrition 0.000 title claims abstract description 48
- 241000605372 Fritillaria Species 0.000 claims abstract description 71
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 43
- 229910052796 boron Inorganic materials 0.000 claims abstract description 43
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000011701 zinc Substances 0.000 claims abstract description 39
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 39
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000011733 molybdenum Substances 0.000 claims abstract description 38
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 38
- 229910021538 borax Inorganic materials 0.000 claims abstract description 14
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 14
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 14
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims abstract description 13
- 229960001763 zinc sulfate Drugs 0.000 claims abstract description 13
- 229910000368 zinc sulfate Inorganic materials 0.000 claims abstract description 13
- 239000011609 ammonium molybdate Substances 0.000 claims abstract description 12
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical group [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims abstract description 12
- 235000018660 ammonium molybdate Nutrition 0.000 claims abstract description 12
- 229940010552 ammonium molybdate Drugs 0.000 claims abstract description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 10
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims abstract description 10
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims abstract description 9
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims abstract description 9
- 229910000165 zinc phosphate Inorganic materials 0.000 claims abstract description 9
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 8
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004327 boric acid Substances 0.000 claims abstract description 8
- 239000011575 calcium Substances 0.000 claims abstract description 8
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 8
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims abstract description 8
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 7
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 claims abstract description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 7
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 claims abstract description 7
- 239000011591 potassium Substances 0.000 claims abstract description 7
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 7
- 239000011667 zinc carbonate Substances 0.000 claims abstract description 7
- 235000004416 zinc carbonate Nutrition 0.000 claims abstract description 7
- 229910000010 zinc carbonate Inorganic materials 0.000 claims abstract description 7
- BIOOACNPATUQFW-UHFFFAOYSA-N calcium;dioxido(dioxo)molybdenum Chemical compound [Ca+2].[O-][Mo]([O-])(=O)=O BIOOACNPATUQFW-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229940038879 chelated zinc Drugs 0.000 claims abstract description 5
- RLWXXXHAQBWSPA-UHFFFAOYSA-N fluoromethanol Chemical compound OCF RLWXXXHAQBWSPA-UHFFFAOYSA-N 0.000 claims abstract description 5
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims abstract description 5
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000011592 zinc chloride Substances 0.000 claims abstract description 5
- 235000005074 zinc chloride Nutrition 0.000 claims abstract description 5
- 239000011787 zinc oxide Substances 0.000 claims abstract description 5
- 239000005083 Zinc sulfide Substances 0.000 claims abstract description 4
- 239000000839 emulsion Substances 0.000 claims abstract description 4
- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 claims abstract description 4
- 229910052984 zinc sulfide Inorganic materials 0.000 claims abstract description 4
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 18
- 230000012010 growth Effects 0.000 claims description 12
- 230000008569 process Effects 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 241000698291 Rugosa Species 0.000 claims description 4
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 1
- 239000011684 sodium molybdate Substances 0.000 claims 1
- 235000015393 sodium molybdate Nutrition 0.000 claims 1
- 229930013930 alkaloid Natural products 0.000 abstract description 17
- 150000003797 alkaloid derivatives Chemical class 0.000 abstract description 10
- JZSKWOFOVWVHFZ-UHFFFAOYSA-N molybdenum phosphoric acid Chemical compound [Mo].OP(O)(O)=O JZSKWOFOVWVHFZ-UHFFFAOYSA-N 0.000 abstract description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 2
- 239000011734 sodium Substances 0.000 abstract description 2
- 229910052708 sodium Inorganic materials 0.000 abstract description 2
- VGTPKLINSHNZRD-UHFFFAOYSA-N oxoborinic acid Chemical compound OB=O VGTPKLINSHNZRD-UHFFFAOYSA-N 0.000 abstract 1
- 241000196324 Embryophyta Species 0.000 description 18
- 230000015572 biosynthetic process Effects 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 201000010099 disease Diseases 0.000 description 8
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 8
- 239000007921 spray Substances 0.000 description 8
- 238000009333 weeding Methods 0.000 description 8
- 239000011785 micronutrient Substances 0.000 description 7
- 235000013369 micronutrients Nutrition 0.000 description 7
- 239000002689 soil Substances 0.000 description 7
- 230000004584 weight gain Effects 0.000 description 7
- 235000019786 weight gain Nutrition 0.000 description 7
- 206010011224 Cough Diseases 0.000 description 6
- 241000209140 Triticum Species 0.000 description 6
- 235000021307 Triticum Nutrition 0.000 description 6
- 241000607479 Yersinia pestis Species 0.000 description 6
- YYRMJZQKEFZXMX-UHFFFAOYSA-N calcium;phosphoric acid Chemical compound [Ca+2].OP(O)(O)=O.OP(O)(O)=O YYRMJZQKEFZXMX-UHFFFAOYSA-N 0.000 description 6
- 239000003814 drug Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 239000002426 superphosphate Substances 0.000 description 6
- 229930192334 Auxin Natural products 0.000 description 5
- 239000002363 auxin Substances 0.000 description 5
- 238000003306 harvesting Methods 0.000 description 5
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 5
- 241000935235 Fritillaria meleagris Species 0.000 description 4
- 206010062717 Increased upper airway secretion Diseases 0.000 description 4
- 235000014633 carbohydrates Nutrition 0.000 description 4
- 150000001720 carbohydrates Chemical class 0.000 description 4
- 229930002875 chlorophyll Natural products 0.000 description 4
- 235000019804 chlorophyll Nutrition 0.000 description 4
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 210000003608 fece Anatomy 0.000 description 4
- 239000003864 humus Substances 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000010871 livestock manure Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 208000026435 phlegm Diseases 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 206010007247 Carbuncle Diseases 0.000 description 3
- 102000004190 Enzymes Human genes 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- 210000004072 lung Anatomy 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 102000007698 Alcohol dehydrogenase Human genes 0.000 description 2
- 108010021809 Alcohol dehydrogenase Proteins 0.000 description 2
- 239000005739 Bordeaux mixture Substances 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 2
- 241001644290 Fritillaria unibracteata Species 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- QIVBCDIJIAJPQS-VIFPVBQESA-N L-tryptophane Chemical compound C1=CC=C2C(C[C@H](N)C(O)=O)=CNC2=C1 QIVBCDIJIAJPQS-VIFPVBQESA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000005842 Thiophanate-methyl Substances 0.000 description 2
- QIVBCDIJIAJPQS-UHFFFAOYSA-N Tryptophan Natural products C1=CC=C2C(CC(N)C(O)=O)=CNC2=C1 QIVBCDIJIAJPQS-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 238000001994 activation Methods 0.000 description 2
- 238000012271 agricultural production Methods 0.000 description 2
- 238000009412 basement excavation Methods 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- BIWJNBZANLAXMG-YQELWRJZSA-N chloordaan Chemical compound ClC1=C(Cl)[C@@]2(Cl)C3CC(Cl)C(Cl)C3[C@]1(Cl)C2(Cl)Cl BIWJNBZANLAXMG-YQELWRJZSA-N 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000009264 composting Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 208000017574 dry cough Diseases 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 208000015181 infectious disease Diseases 0.000 description 2
- 230000003902 lesion Effects 0.000 description 2
- 230000004060 metabolic process Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 210000000056 organ Anatomy 0.000 description 2
- 244000052769 pathogen Species 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 230000000243 photosynthetic effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000001850 reproductive effect Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 2
- 230000000472 traumatic effect Effects 0.000 description 2
- 230000009105 vegetative growth Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004563 wettable powder Substances 0.000 description 2
- 101000950981 Bacillus subtilis (strain 168) Catabolic NAD-specific glutamate dehydrogenase RocG Proteins 0.000 description 1
- 102000003846 Carbonic anhydrases Human genes 0.000 description 1
- 108090000209 Carbonic anhydrases Proteins 0.000 description 1
- 102000004163 DNA-directed RNA polymerases Human genes 0.000 description 1
- 108090000626 DNA-directed RNA polymerases Proteins 0.000 description 1
- 240000001008 Dimocarpus longan Species 0.000 description 1
- 208000005189 Embolism Diseases 0.000 description 1
- 235000000235 Euphoria longan Nutrition 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- 102000016901 Glutamate dehydrogenase Human genes 0.000 description 1
- 102000008221 Superoxide Dismutase-1 Human genes 0.000 description 1
- 108010021188 Superoxide Dismutase-1 Proteins 0.000 description 1
- 208000031971 Yin Deficiency Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000000954 anitussive effect Effects 0.000 description 1
- 230000001088 anti-asthma Effects 0.000 description 1
- 229940124584 antitussives Drugs 0.000 description 1
- 208000024753 bloody sputum Diseases 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003172 expectorant agent Substances 0.000 description 1
- 230000003419 expectorant effect Effects 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 235000021374 legumes Nutrition 0.000 description 1
- 201000003453 lung abscess Diseases 0.000 description 1
- 201000007227 lymph node tuberculosis Diseases 0.000 description 1
- 208000004396 mastitis Diseases 0.000 description 1
- 239000002398 materia medica Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007721 medicinal effect Effects 0.000 description 1
- 230000024121 nodulation Effects 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000001243 protein synthesis Methods 0.000 description 1
- 230000002685 pulmonary effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 235000019605 sweet taste sensations Nutrition 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D3/00—Calcareous fertilisers
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01C—PLANTING; SOWING; FERTILISING
- A01C21/00—Methods of fertilising, sowing or planting
- A01C21/005—Following a specific plan, e.g. pattern
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B1/00—Superphosphates, i.e. fertilisers produced by reacting rock or bone phosphates with sulfuric or phosphoric acid in such amounts and concentrations as to yield solid products directly
- C05B1/02—Superphosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B17/00—Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Soil Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Environmental Sciences (AREA)
- Fertilizers (AREA)
Abstract
本发明公开了一种微量元素组合物,所述组合物包括下述重量份数的组分:锌肥8.0份‑11.5份、硼肥10.5份‑16.5份、钼肥0.4份‑0.7份,所述锌肥选自硫酸锌、氯化锌、氧化锌、硫化锌、磷酸锌、碳酸锌、环烷酸锌乳剂和螯合锌中一种或多种;所述硼肥选自硼砂、偏硼酸钠、二硼化铝、硼酸、硼化钙、三硼化氟甲醇络合物和螯合硼中的一种或多种;所述钼肥选自钼酸铵、硫化钼、正钼酸钠、钼酸钙、钼酸钾、硫化钼、氧化钼、钼磷酸和钼酸的一种或多种。本发明提供的微量元素组合物用可提高五年生瓦布贝母的产量并且提高其生物碱的含量。The invention discloses a trace element composition, which comprises the following components in parts by weight: 8.0-11.5 parts of zinc fertilizer, 10.5-16.5 parts of boron fertilizer, and 0.4-0.7 part of molybdenum fertilizer. Described zinc fertilizer is selected from one or more in zinc sulfate, zinc chloride, zinc oxide, zinc sulfide, zinc phosphate, zinc carbonate, zinc naphthenate emulsion and chelated zinc; Described boron fertilizer is selected from borax, metaboric acid One or more of sodium, aluminum diboride, boric acid, calcium boride, triboride fluoromethanol complex and chelated boron; the molybdenum fertilizer is selected from ammonium molybdate, molybdenum sulfide, sodium orthomolybdate , one or more of calcium molybdate, potassium molybdate, molybdenum sulfide, molybdenum oxide, molybdenum phosphoric acid and molybdic acid. The trace element composition provided by the invention can increase the output of five-year-old Fritillaria wabu and increase its alkaloid content.
Description
技术领域technical field
本发明涉及中药栽培种殖领域,具体为一种微量元素肥料组合物及其应用The invention relates to the field of traditional Chinese medicine cultivation and breeding, specifically a trace element fertilizer composition and its application
背景技术Background technique
瓦布贝母是一种具有较高药用价值的经济作物,是川贝母的栽培品,可用于肺热燥咳,干咳少痰,阴虚劳嗽,痰中带血,瘰疬,乳痈,肺痈等症。药材川贝母为止咳化痰之要药,当今社会疑难杂症成为影响人们健康的主要问题,传统医药优势凸显,川贝母市场需求量不断增加,市场缺口逐年增大。Wabu Fritillaria is an economic crop with high medicinal value. It is a cultivated product of Fritillaria sichuanensis. Carbuncle, pulmonary carbuncle embolism. The medicinal material Chuan Fritillaria is an important medicine for relieving cough and reducing phlegm. Intractable diseases in today's society have become the main problems affecting people's health. The advantages of traditional medicine are highlighted. The market demand for Chuan Fritillaria is increasing, and the market gap is increasing year by year.
川贝母主要分布在青藏高原东部地区,川西高原为其主产区,该地区气候恶劣、农业生产技术极其落后,是川贝母人工种植难以成规模的主要原因。瓦布贝母是川贝母中分布海拔最低的品种,野生资源分布区有一定的农业生产基础,是最有希望建立规模化川贝母生产基地的品种。Fritillary fritillary is mainly distributed in the eastern part of the Qinghai-Tibet Plateau, and the western Sichuan plateau is its main production area. The harsh climate and extremely backward agricultural production technology in this area are the main reasons why it is difficult to scale the fritillary fritillary artificially. Wabu Fritillaria is the variety with the lowest distribution altitude in Fritillaria sichuanensis, and the distribution area of wild resources has a certain basis for agricultural production. It is the most promising variety to establish a large-scale production base of Fritillaria sichuanensis.
五年生瓦布贝母,既是贝母种子培育的关键年,又是产量形成的最后一年,贝母在这一年若无法获得合理组分与配比的微肥,将会导致药材产量下降、药材中药效组分如生物碱比例降低,从而影响其药效。The five-year-old Wabu Fritillaria is not only the key year for the seed cultivation of Fritillaria, but also the last year of yield formation. If Fritillaria cannot obtain a reasonable composition and ratio of micronutrient fertilizers in this year, it will lead to a decline in the production of medicinal materials 1. The proportion of effective components in medicinal materials such as alkaloids is reduced, thereby affecting its efficacy.
发明内容Contents of the invention
本发明提供一种针对五年生瓦布贝母栽培的微量元素肥料组合物及其应用,本发明提供的组合物具有经济高效的特点,可提高瓦布贝母产量,提高瓦布贝母中药效成分的含量,适用于高海拔地区的五年生瓦布贝母的种植与栽培。The invention provides a trace element fertilizer composition and its application for the cultivation of five-year-old Fritillaria rugosa. The composition provided by the invention has the characteristics of economy and high efficiency, which can increase the yield of Fritillaria rugosa and improve the traditional Chinese medicine of Fritillaria rugosa. The content of active ingredients is suitable for the planting and cultivation of five-year-old Wabu Fritillaria in high altitude areas.
为解决上述问题,本发明提供一种微量元素组合物,其特征在于,所述组合物包括下述重量份数的组分:锌肥8.0份-11.5份、硼肥10.5份-16.5份、钼肥0.4份-0.7份,所述锌肥选自硫酸锌、氯化锌、氧化锌、硫化锌、磷酸锌、碳酸锌、环烷酸锌乳剂和螯合锌中一种或多种;所述硼肥选自硼砂、偏硼酸钠、二硼化铝、硼酸、硼化钙、三硼化氟甲醇络合物和螯合硼中的一种或多种;所述钼肥选自钼酸铵、硫化钼、正钼酸钠、钼酸钙、钼酸钾、硫化钼、氧化钼、钼磷酸和钼酸的一种或多种。In order to solve the above problems, the present invention provides a trace element composition, characterized in that the composition comprises the following components in parts by weight: 8.0-11.5 parts of zinc fertilizer, 10.5-16.5 parts of boron fertilizer, molybdenum 0.4 part-0.7 part of fertilizer, the zinc fertilizer is selected from one or more of zinc sulfate, zinc chloride, zinc oxide, zinc sulfide, zinc phosphate, zinc carbonate, zinc naphthenate emulsion and chelated zinc; The boron fertilizer is selected from one or more of borax, sodium metaborate, aluminum diboride, boric acid, calcium boride, triboride fluoromethanol complex and chelated boron; the molybdenum fertilizer is selected from ammonium molybdate , one or more of molybdenum sulfide, sodium orthomolybdate, calcium molybdate, potassium molybdate, molybdenum sulfide, molybdenum oxide, molybdenum phosphoric acid and molybdic acid.
优选的,所述组合物包括下述重量份数的组分:8.21份-11.49份,硼肥10.86份-16.42份,钼肥0.47份-0.66份。Preferably, the composition includes the following components in parts by weight: 8.21-11.49 parts, 10.86-16.42 parts of boron fertilizer, and 0.47-0.66 part of molybdenum fertilizer.
优选的,所述锌肥选自硫酸锌、磷酸锌、碳酸锌中的一种或多种。Preferably, the zinc fertilizer is selected from one or more of zinc sulfate, zinc phosphate, and zinc carbonate.
优选的,所述锌肥为硫酸锌。Preferably, the zinc fertilizer is zinc sulfate.
优选的,所述硼肥选自硼酸、硼砂和硼化钙中的一种或多种。Preferably, the boron fertilizer is selected from one or more of boric acid, borax and calcium boride.
优选的,所述硼肥为硼砂。Preferably, the boron fertilizer is borax.
优选的,所述钼肥选自钼酸铵、正钼酸钠和钼酸的一种或多种。Preferably, the molybdenum fertilizer is selected from one or more of ammonium molybdate, sodium orthomolybdate and molybdic acid.
优选的,所述钼肥为钼酸铵。Preferably, the molybdenum fertilizer is ammonium molybdate.
本发明还提供一种上述微量元素组合物在瓦布贝母栽培过程中的应用。The present invention also provides an application of the above-mentioned trace element composition in the cultivation process of Fritillaria wabu.
优选的,所述瓦布贝母为五年生瓦布贝母。Preferably, the Wabu Fritillaria is five-year-old Wabu Fritillaria.
优选的,所述微量元素组合物的施用方法为在瓦布贝母生长第五年5月初至6月底施用,分4次施用,15天1次;所述微量元素组合物总用量包括下述用量组分:锌肥8.21kg/hm2-11.49kg/hm2,硼肥10.86kg/hm2-16.42kg/hm2,钼肥0.47kg/hm2-0.66kg/hm2。Preferably, the application method of the trace element composition is from the beginning of May to the end of June in the fifth year of the growth of Fritillaria wabu, divided into 4 applications, once every 15 days; the total amount of the trace element composition includes the following Dosage components: zinc fertilizer 8.21kg/hm 2 -11.49kg/hm 2 , boron fertilizer 10.86kg/hm 2 -16.42kg/hm 2 , molybdenum fertilizer 0.47kg/hm 2 -0.66kg/hm 2 .
优选的,所述4次施用,第一次施用微量元素组合物总用量的20%;第二次施用微量元素组合物总用量的30%;第三次施用微量元素组合物总用量的30%;第四次施用微量元素组合物总用量的20%。Preferably, for the 4 applications, 20% of the total amount of the trace element composition is applied for the first time; 30% of the total amount of the trace element composition is applied for the second time; 30% of the total amount of the trace element composition is applied for the third time ; The fourth application of 20% of the total consumption of the trace element composition.
更为优选的,所述4次施用为将微量元素组合物配成1升的水溶液喷施。More preferably, the 4 applications are the spraying of the trace element composition formulated into 1 liter of aqueous solution.
瓦布贝母:瓦布贝母(Fritillaria unibracteata Hsiao et K.C.Hsiavar.wabuensis(S.Y.Tang et S.C.Yue)Z.D.Liu,S.Wang et S.C.Chen)为药材川贝母的基源种之一,为名贵中药材,一般在7月下旬至8月上旬地上部分完全枯萎后采挖,除去须根及泥沙,晒干。具有清热润肺,化痰止咳,散结消痈功效。广泛用于肺热燥咳,干咳少痰,阴虚劳嗽,痰中带血,瘰疬,乳痈,肺痈等症。Wabu Fritillaria: Wabu Fritillaria (Fritillaria unibracteata Hsiao et K.C.Hsiavar.wabuensis (S.Y.Tang et S.C.Yue) Z.D.Liu, S.Wang et S.C.Chen) is one of the source species of the medicinal material Chuan Fritillaria, and is a precious traditional Chinese medicine The wood is generally excavated after the aboveground part is completely withered from late July to early August, and the fibrous roots and silt are removed, and dried in the sun. It has the functions of clearing heat and moistening lung, resolving phlegm and relieving cough, dispelling stagnation and eliminating carbuncle. It is widely used in dry cough due to lung heat, dry cough with little phlegm, overworked cough due to yin deficiency, bloody sputum, scrofula, mastitis, lung abscess and other diseases.
瓦布贝母属多年生草本植物,生长缓慢。在种子繁殖生长过程中,种子萌发后依序通过实生苗、营养生长更新、生殖生长更新而发育成熟。种子播种第一年只生长一枚针状叶(习称“一根针”),第二年发育为一枚较宽的子叶(习称“鸡舌头”),此两年为贝母实生苗阶段,鳞茎生长较为缓慢;第三年地上部分为1-2片较宽叶片(习称“一匹叶”),第四年开始抽茎(习称“树儿子”),但一般不开花,此两年地下鳞茎生长迅速,为贝母营养生长更新阶段;第五年开始发育花茎和花(习称“灯笼花”)并结实,进行生殖生长更新。瓦布贝母鳞茎质量大,药用成分含量高,生长海拔低的特性,为人工栽培川贝母类药材提供了最经济有效的品种选择。Wabu Fritillaria is a perennial herb that grows slowly. In the process of seed reproduction and growth, after germination, seeds develop and mature through seedlings, vegetative growth renewal, and reproductive growth renewal in sequence. In the first year of seed sowing, only one needle-shaped leaf (commonly known as "a needle") grows, and in the second year it develops into a wider cotyledon (commonly known as "chicken tongue"). These two years are the seedlings of Fritillaria stage, the bulbs grow slowly; in the third year, the aboveground part has 1-2 wide leaves (commonly known as "one leaf"), and in the fourth year, the stems begin to pump (commonly known as "tree son"), but generally do not bloom. In the past two years, the underground bulbs grow rapidly, which is the vegetative growth and renewal stage of Fritillaria; in the fifth year, flower stems and flowers (commonly known as "lantern flowers") begin to develop and bear fruit, and undergo reproductive growth and renewal. The bulbs of Fritillaria wabu have high quality, high content of medicinal ingredients, and low growth altitude, which provides the most economical and effective variety selection for artificial cultivation of Fritillaria sichuanensis medicinal materials.
本发明提供的微量元素肥料组合物为特定重量份数的锌肥、硼肥、钼肥组成。其中锌在参与叶绿素生成、防止叶绿素的降解和形成碳水化合物等光合作用过程具有重要作用,锌可以参加某些酶如谷氨酸脱氢酶、乙醇脱氢酶的活化过程。并且色氨酸合成也需要锌,而色氨酸是合成生长素(IAA)的前体,生长素对植物农作物药物亦具有重要的作用。锌还是多种酶的组成成分,乙醇脱氢酶、Cu-Zn超氧物歧化酶、碳酸酐酶和RNA聚合酶中都有锌存在。含钼元素的蛋白具有硝酸还原作用和固氮作用,能提高蛋白质质量,钼还能促进光合作用并去除土壤中由于活性铝在作物体内积累而产生的毒害作用,钼还在植物对铁的吸收和运输中起着不可替代的重要作用。硼参与作物体内碳水化合物的代谢,参与体内生长素的合成和利用,参与豆科植物的的根瘤和固氮作用,参与植物花器官的形成和伸长,植物种子的形成。The trace element fertilizer composition provided by the invention is composed of zinc fertilizer, boron fertilizer and molybdenum fertilizer in specific parts by weight. Among them, zinc plays an important role in photosynthetic processes such as participating in chlorophyll formation, preventing chlorophyll degradation and forming carbohydrates. Zinc can participate in the activation process of certain enzymes such as glutamate dehydrogenase and alcohol dehydrogenase. And the synthesis of tryptophan also needs zinc, and tryptophan is the precursor of synthetic auxin (IAA), and auxin also plays an important role in plant crop medicine. Zinc is also a component of many enzymes, including zinc in alcohol dehydrogenase, Cu-Zn superoxide dismutase, carbonic anhydrase and RNA polymerase. Molybdenum-containing protein has nitric acid reduction and nitrogen fixation, which can improve protein quality. Molybdenum can also promote photosynthesis and remove the poisonous effect caused by the accumulation of active aluminum in crops in the soil. Molybdenum also plays a role in the absorption of iron by plants and Transportation plays an irreplaceable important role. Boron participates in the metabolism of carbohydrates in crops, in the synthesis and utilization of auxin in the body, in the nodulation and nitrogen fixation of legumes, in the formation and elongation of plant flower organs, and in the formation of plant seeds.
综上所述,本发明提供的微量元素组合物通过协同作用,参与作物蛋白质合成、酶活化、参与硝酸还原与固氮作用,参与作物体内碳水化合物、生长素的合成和利用,去除活性铝在作物内的毒害作用等等,三种组合物协同作用,共同影响瓦布贝母的鳞茎重量的积累、影响瓦布贝母的产量,还影响了瓦布贝母中生物碱的含量。本发明提供的组合物用于五年生瓦布贝母的栽培,使获得的瓦布贝母自身鳞茎增重率达到113.75%,与未施用微量元素肥的瓦布贝母相比,单位面积增产率与单株鳞茎增重率达到95.45%,生物碱含量(以西贝碱计)提高了87.12%。In summary, the trace element composition provided by the present invention participates in crop protein synthesis, enzyme activation, nitric acid reduction and nitrogen fixation, participates in the synthesis and utilization of carbohydrates and auxin in crops, and removes active aluminum in crops through synergistic effects. Toxic effects in the fritillaria, etc., the three compositions act synergistically to jointly affect the accumulation of the bulb weight of the fritillaria wabu, affect the yield of the fritillaria wabu, and also affect the content of alkaloids in the fritillaria wabu. The composition provided by the present invention is used for the cultivation of five-year-old Fritillaria wabu, so that the bulb weight gain rate of the obtained Fritillaria wabu can reach 113.75%, and compared with the Fritillaria wabu that has not been applied with trace element fertilizers, the yield per unit area is increased The rate and the weight gain rate of a single bulb reached 95.45%, and the alkaloid content (calculated as sibetine) increased by 87.12%.
具体实施方式Detailed ways
为了使本领域的技术人员更好地理解发明的技术方案,下面结合具体实施方式对本发明作进一步的详细说明。In order to enable those skilled in the art to better understand the technical solution of the invention, the present invention will be further described in detail below in conjunction with specific embodiments.
瓦布贝母习称“栽培品”,为百合科植物瓦布贝母Fritillaria unibracteataHsiao et K.C.Hsia var.wabuensis(S.Y.Tang et S.C.Yue)Z.D.Liu,S.Wang etS.C.chen的干燥鳞茎部分,为2010年版《中国药典》川贝母项下新收载的资源品种。瓦布贝母主要分布于四川岷江上游山区的茂县、北川、松潘、黑水县境内,主要生长在海拔2500-3000m的灌木林、小乔木林下。Wabu Fritillaria, commonly known as "cultivated products", is the dried bulb part of Fritillaria unibracteataHsiao et K.C.Hsia var.wabuensis (S.Y.Tang et S.C.Yue) Z.D.Liu, S.Wang etS.C.chen, It is a newly recorded resource variety under the Fritillaria sichuanensis in the 2010 edition of "Chinese Pharmacopoeia". Wabu fritillary is mainly distributed in Maoxian, Beichuan, Songpan, and Heishui counties in the upper mountainous area of the Minjiang River in Sichuan. It mainly grows under shrubs and small trees at an altitude of 2500-3000m.
瓦布贝母当做川贝母使用,最早记载于《本草纲目拾遗》,言之“大如钱,皮细白而带黄斑,味甘、出龙安,乃川贝中第一,不可多得”。瓦布贝母一直为当地乡医所器重,认为其清热润肺、化痰止咳的功效比暗紫贝母(F.unibracteata Hsiao etK.C.Hsia)好,但由于开发早,野生资源不多,野生瓦布贝母处于濒危状态。Wabu Fritillaria was used as Chuanbeimu, which was first recorded in "Compendium of Materia Medica Supplements". It was said that "it is as big as money, with thin white skin and yellow spots, sweet taste, and longan. It is the first among Chuanbei and rare." . Wabu Fritillaria has always been valued by the local medical institutes. It is believed that its effect of clearing away heat and nourishing the lungs, reducing phlegm and relieving cough is better than that of Dark Purple Fritillaria (F.unibracteata Hsiao et K.C.Hsia), but due to early development, there are not many wild resources , the wild Wabu Fritillaria is endangered.
现有研究表明,瓦布贝母中含有至少7种以上生物碱,且各生物碱极性差异不大,但含量差别较多。目前从瓦布贝母中分离得到并且化学结构已知的生物碱成分主要有:西贝碱、贝母辛、鄂贝乙素、异浙贝甲素、西贝素-β-氮氧化物、异浙贝甲素氮氧化物。并且栽培瓦布贝母中的总生物碱含量高于野生瓦布贝母和暗紫贝母中的含量,并且栽培瓦布贝母中的总生物碱含量随着生长年限的增长而增加,因此栽培瓦布贝母的采收年限应以5年生的为主。Existing studies have shown that there are at least 7 kinds of alkaloids in Fritillaria wabu, and the polarity of each alkaloid is not much different, but the content is quite different. At present, the alkaloid components isolated from Fritillaria wabu and whose chemical structure is known mainly include: sibetin, fritillary, obetine, isobexin, sibetin-β-nitrogen oxide, Isofibaricin Nitrogen Oxide. And the total alkaloid content in cultivated Fritillaria wabu is higher than that in wild Fritillaria wabu and Fritillaria dark purple, and the content of total alkaloids in cultivated Fritillaria wabu increases with the growth of growth years, so The harvest period of cultivated Wabu Fritillaria should be mainly 5 years old.
本发明提供一种微量元素组合物,所述组合物包括下述重量份数的组分:锌肥8.0份-11.5份,优选为8.21份-11.49份;硼肥10.5份-16.5份,优选为硼肥10.86份-16.42份;钼肥0.4份-0.7份,优选为钼肥0.47份-0.66份。The present invention provides a kind of trace element composition, and described composition comprises the component of following parts by weight: zinc fertilizer 8.0 parts-11.5 parts, preferably 8.21 parts-11.49 parts; Boron fertilizer 10.5 parts-16.5 parts, preferably 10.86-16.42 parts of boron fertilizer; 0.4-0.7 part of molybdenum fertilizer, preferably 0.47-0.66 part of molybdenum fertilizer.
所述锌肥选自硫酸锌、氯化锌、氧化锌、硫化锌、磷酸锌、碳酸锌、环烷酸锌乳剂和螯合锌中一种或多种,优选为硫酸锌、磷酸锌、碳酸锌中的一种或多种,更为优选为硫酸锌。The zinc fertilizer is selected from one or more of zinc sulfate, zinc chloride, zinc oxide, zinc sulfide, zinc phosphate, zinc carbonate, zinc naphthenate emulsion and chelated zinc, preferably zinc sulfate, zinc phosphate, carbonic acid One or more of zinc, more preferably zinc sulfate.
所述硼肥选自硼砂、偏硼酸钠、二硼化铝、硼酸、硼化钙、三硼化氟甲醇络合物和螯合硼中的一种或多种;优选为硼酸、硼砂和硼化钙中的一种或多种;更为优选为硼砂。The boron fertilizer is selected from one or more of borax, sodium metaborate, aluminum diboride, boric acid, calcium boride, triboride fluoromethanol complex and chelated boron; preferably boric acid, borax and boron One or more of calcium oxide; more preferably borax.
所述钼肥选自钼酸铵、硫化钼、正钼酸钠、钼酸钙、钼酸钾、硫化钼、氧化钼、钼磷酸和钼酸的一种或多种;优选为钼酸铵、正钼酸钠和钼酸的一种或多种;更为优选为钼酸铵。The molybdenum fertilizer is selected from one or more of ammonium molybdate, molybdenum sulfide, sodium orthomolybdate, calcium molybdate, potassium molybdate, molybdenum sulfide, molybdenum oxide, molybdenum phosphoric acid and molybdic acid; preferably ammonium molybdate, One or more of sodium orthomolybdate and molybdic acid; more preferably ammonium molybdate.
本发明还提供一种上述微量元素组合物在五年生瓦布贝母栽培过程中的应用。The present invention also provides an application of the above-mentioned trace element composition in the cultivation process of five-year-old Wabu Fritillaria.
施用方法为在瓦布贝母生长第五年5月初至6月底施用,分4次施用,15天1次;微量元素组合物总用量包括下述用量组分:锌肥8.21kg/hm2-11.49kg/hm2,硼肥10.86kg/hm2-16.42kg/hm2,钼肥0.47kg/hm2-0.66kg/hm2。第一次施用微量元素组合物总用量的20%;第二次施用微量元素组合物总用量的30%;第三次施用微量元素组合物总用量的30%;第四次施用微量元素组合物总用量的20%。每次施用均将微量元素组合物配成1升的水溶液喷施。The application method is from the beginning of May to the end of June in the fifth year of the growth of Fritillaria wabu, divided into 4 applications, once every 15 days; the total amount of trace element composition includes the following components: zinc fertilizer 8.21kg/hm 2 - 11.49kg/hm 2 , boron fertilizer 10.86kg/hm 2 -16.42kg/hm 2 , molybdenum fertilizer 0.47kg/hm 2 -0.66kg/hm 2 . Apply 20% of the total amount of the trace element composition for the first time; apply 30% of the total amount of the trace element composition for the second time; apply 30% of the total amount of the trace element composition for the third time; apply the trace element composition for the fourth time 20% of the total usage. For each application, the trace element composition was formulated into 1 liter of aqueous solution and sprayed.
本发明提供的微量元素肥料组合物由锌硼钼三种微肥构成。锌参与叶绿素生成、防止叶绿素的降解和形成碳水化合物等光合作用过程。硼参与体内生长素的合成和利用,参与植物花器官的形成和伸长。钼肥参与植物的氮代谢作用,三种微量元素肥料协同作用,提高瓦布贝母产量,提高瓦布贝母中生物碱含量,提高其药效。The trace element fertilizer composition provided by the invention is composed of three kinds of micro fertilizers of zinc, boron and molybdenum. Zinc participates in photosynthetic processes such as chlorophyll production, prevention of chlorophyll degradation and formation of carbohydrates. Boron participates in the synthesis and utilization of auxin in the body, and participates in the formation and elongation of plant floral organs. Molybdenum fertilizer participates in the nitrogen metabolism of plants, and the synergistic effect of the three trace element fertilizers increases the yield of Fritillaria wabu, increases the content of alkaloids in Fritillaria wabu, and improves its efficacy.
上述为本发明的详细阐述,下面为本发明实施例。The foregoing is a detailed description of the present invention, and the following are examples of the present invention.
下述实施例中组合物的各组分均为市售肥料,质量标准为优级纯。Each component of the composition in the following examples is a commercially available fertilizer, and the quality standard is superior grade pure.
实施例一Embodiment one
微量元素肥料组合物Micronutrient fertilizer composition
锌肥8.0份、硼肥10.5份、钼肥0.4份,锌肥为氯化锌4份、氧化锌4份;硼肥为螯合硼8份、偏硼酸钠0.5份、二硼化铝2份;钼肥为硫化钼0.2份、钼酸钙0.2份。8.0 parts of zinc fertilizer, 10.5 parts of boron fertilizer, 0.4 parts of molybdenum fertilizer, zinc fertilizer is 4 parts of zinc chloride, 4 parts of zinc oxide; boron fertilizer is 8 parts of chelated boron, 0.5 parts of sodium metaborate, 2 parts of aluminum diboride ; The molybdenum fertilizer is 0.2 parts of molybdenum sulfide and 0.2 parts of calcium molybdate.
实施例二Embodiment two
微量元素肥料组合物Micronutrient fertilizer composition
锌肥11.5份、硼肥16.5份、钼肥0.7份,锌肥为螯合锌5份、磷酸锌5份、硫酸锌1.5份;硼肥为三硼化氟甲醇络合物8、硼化钙0.5份、硼砂8份;钼肥为钼酸钾0.2份、氧化钼0.2份、钼磷酸0.3份。11.5 parts of zinc fertilizer, 16.5 parts of boron fertilizer, 0.7 part of molybdenum fertilizer, zinc fertilizer is 5 parts of chelated zinc, 5 parts of zinc phosphate, 1.5 parts of zinc sulfate; boron fertilizer is triboride fluoromethanol complex 8, calcium boride 0.5 parts, 8 parts of borax; molybdenum fertilizer is 0.2 parts of potassium molybdate, 0.2 parts of molybdenum oxide, and 0.3 parts of molybdenum phosphoric acid.
实施例三Embodiment three
微量元素肥料组合物Micronutrient fertilizer composition
锌肥8.21份,硼肥10.86份,钼肥0.47份,锌肥为磷酸锌4.21份、硫酸锌4.00份;硼肥为硼砂5.43份、硼酸5.43份;钼肥为钼酸0.23份,正钼酸钠0.24份。8.21 parts of zinc fertilizer, 10.86 parts of boron fertilizer, 0.47 parts of molybdenum fertilizer, zinc fertilizer is 4.21 parts of zinc phosphate, 4.00 parts of zinc sulfate; boron fertilizer is 5.43 parts of borax, 5.43 parts of boric acid; Sodium 0.24 parts.
实施例四Embodiment four
微量元素肥料组合物Micronutrient fertilizer composition
锌肥11.49份,硼肥16.42份,钼肥0.66份,锌肥为碳酸锌;硼肥为硼化钙10.21份、硼砂6.21份;钼肥为正钼酸钠0.33份、钼酸铵0.33份。11.49 parts of zinc fertilizer, 16.42 parts of boron fertilizer, 0.66 parts of molybdenum fertilizer, the zinc fertilizer is zinc carbonate; the boron fertilizer is 10.21 parts of calcium boride, 6.21 parts of borax; the molybdenum fertilizer is 0.33 parts of sodium orthomolybdate and 0.33 parts of ammonium molybdate.
实施例五Embodiment five
微量元素肥料组合物Micronutrient fertilizer composition
锌肥9.05份,硼肥11.88份,钼肥0.56份,锌肥为硫酸锌,硼肥为硼砂,钼肥为钼酸铵。9.05 parts of zinc fertilizer, 11.88 parts of boron fertilizer, 0.56 parts of molybdenum fertilizer, the zinc fertilizer is zinc sulfate, the boron fertilizer is borax, and the molybdenum fertilizer is ammonium molybdate.
实施例六Embodiment six
微量元素肥料组合物Micronutrient fertilizer composition
锌肥10.16份,硼肥14.24份,钼肥0.62份,锌肥为硫酸锌,硼肥为硼砂,钼肥为钼酸铵。10.16 parts of zinc fertilizer, 14.24 parts of boron fertilizer, 0.62 parts of molybdenum fertilizer, the zinc fertilizer is zinc sulfate, the boron fertilizer is borax, and the molybdenum fertilizer is ammonium molybdate.
实施例七Embodiment seven
贝母栽培Fritillaria cultivation
1选地、整地、栽种1Site selection, preparation, and planting
选择背风的坡地作为栽培地点,且要求坡度处于半阴半阳的坡面。并远离麦类作物,防止锈病感染;以疏松、富含腐殖质的镶上为好,粘土、沙土均不适宜。Choose a leeward slope as the cultivation site, and the slope is required to be half shade and half sun. And stay away from wheat crops to prevent rust infection; it is better to inlay loose and rich in humus, clay and sand are not suitable.
结冻前整地,清除地面杂草,深耕细耙,作1.3m宽的畦。每亩用厩肥1500kg、过磷酸钙50kg、油饼100kg,堆沤腐熟后撤于畦面并浅翻;畦面作成弓形。Before freezing, prepare the land, clear the weeds on the ground, plow and rake deeply, and make a 1.3m wide furrow. Use 1500kg of manure, 50kg of superphosphate, and 100kg of oil cake per mu. After the composting is mature, remove it to the furrow surface and turn it shallowly; the furrow surface is made into a bow shape.
7-9月间收获时,选择无创伤病斑的鳞茎作种。用条栽法,按行距15cm开沟,株距10cm,栽后覆土5-6cm。或在栽时分瓣,斜栽于穴内,栽后覆盖细土、灰肥3-5cm厚,压紧镇平。When harvesting between July and September, choose bulbs without traumatic lesions as seeds. With the strip planting method, the row spacing is 15cm, the plant spacing is 10cm, and the soil is 5-6cm after planting. Or divide the petals when planting, plant obliquely in the hole, cover with fine soil, gray fertilizer 3-5cm thick after planting, compact and flatten.
2追肥2 top dressing
使用的肥料包括腐殖土,农家肥和过磷酸钙等,过磷酸钙亩使用25kg,先将各种肥料混匀再将其撒至田中。The fertilizers used include humus, farmyard manure and superphosphate, etc. The superphosphate is 25kg per mu. Mix all kinds of fertilizers and then spread them in the field.
微量元素肥料组合物采用实施例一至实施例六所提供的组合物,在瓦布贝母生长第五年5月初至6月底施用,分4次施用,15天1次;微量元素组合物总用量包括下述用量组分:锌肥8.21kg/hm2-11.49kg/hm2,硼肥10.86kg/hm2-16.42kg/hm2,钼肥0.47kg/hm2-0.66kg/hm2。第一次施用微量元素组合物总用量的20%;第二次施用微量元素组合物总用量的30%;第三次施用微量元素组合物总用量的30%;第四次施用微量元素组合物总用量的20%。每次施用均将微量元素组合物配成1升的水溶液喷施。The trace element fertilizer composition adopts the composition provided in Embodiment 1 to Embodiment 6, and is applied at the beginning of May to the end of June in the fifth year of the growth of Wabu Fritillaria, and is applied in 4 times, once every 15 days; the total amount of trace element composition Including the following dosage components: zinc fertilizer 8.21kg/hm 2 -11.49kg/hm 2 , boron fertilizer 10.86kg/hm 2 -16.42kg/hm 2 , molybdenum fertilizer 0.47kg/hm 2 -0.66kg/hm 2 . Apply 20% of the total amount of the trace element composition for the first time; apply 30% of the total amount of the trace element composition for the second time; apply 30% of the total amount of the trace element composition for the third time; apply the trace element composition for the fourth time 20% of the total usage. For each application, the trace element composition was formulated into 1 liter of aqueous solution and sprayed.
3除草、病虫害防治3 Weeding, pest control
3.1除草3.1 Weeding
瓦布贝母杂草较多,应及时除草,春季出苗前用草宁除草1次。There are many weeds in Wabu Fritillaria, weeding should be done in time, and weeding should be done once with grass ning before emergence in spring.
3.2病虫害防治3.2 Pest control
锈病:为川贝母主要病害,病源多来自麦类作物,多发生于5-6月。防治方法:选远离麦类作物的地种植;整地时清除病残组织,减少越冬病原;增施磷、钾肥,降低田间湿度;发病初期喷甲基托布津可湿性粉剂800-1000倍液或粉锈宁1000倍液,7-10天喷1次,连喷3-4次。Rust: It is the main disease of Fritillaria sichuanensis. The source of the disease mostly comes from wheat crops, and it mostly occurs in May-June. Control methods: choose a place far away from wheat crops; remove diseased and disabled tissues during site preparation to reduce overwintering pathogens; increase phosphorus and potassium fertilizers to reduce field humidity; spray thiophanate-methyl wettable powder 800-1000 times liquid or tributinin at the beginning of the disease 1000 times liquid, spray once every 7-10 days, and spray 3-4 times continuously.
立枯病:为害幼苗,发生于夏季多雨季节。防治方法:注意排水、调节郁闭度,以及阴雨天揭棚盖;发病前后用1∶1∶100的波尔多液喷洒。Blight: Harms seedlings and occurs in the rainy summer season. Control methods: pay attention to drainage, adjust canopy density, and uncover the canopy in rainy days; spray with 1:1:100 Bordeaux mixture before and after the onset.
虫害以金针虫和蛴螬为主,4-6月为害植株。防治方法:每亩用50%氯丹乳油0.5-1kg,于整地时拌上或出苗后掺水500kg灌水防治。Insect pests are mainly needleworms and grubs, which damage plants from April to June. Control method: Use 0.5-1kg of 50% chlordane EC per mu, mix it with soil preparation or mix with 500kg of water after emergence for control.
4收获4 harvest
瓦布贝母于7月下旬至8月上旬采挖,选晴天采挖,采挖后计算瓦布贝母单株鳞茎增重率,计算方法为:((第五年单株鳞茎重量-第四年单株鳞茎重量)/第四年单株鳞茎重量)*100%。Wabu Fritillaria is excavated from late July to early August, and excavated on sunny days. After excavation, the weight gain rate of a single bulb of Wabu Fritillaria is calculated. The calculation method is: ((the weight of a single bulb in the fifth year - the first Four-year single bulb weight)/fourth year single bulb weight)*100%.
5结果5 results
上述结果表明,本发明提供的实施例一至实施例六均能起到增加瓦布贝母鳞茎重量,增产的作用,其中实施例三至实施例六为本发明的优选方式,实施例五与实施例六为更为优选的方式。The above-mentioned results show that embodiment one to embodiment six provided by the present invention can all play the effect of increasing the weight of the bulb of Fritillaria wabu, increasing production, wherein embodiment three to embodiment six are preferred forms of the present invention, embodiment five and implementation Example 6 is a more preferred way.
实施例八Embodiment eight
贝母栽培Fritillaria cultivation
1选地、整地、栽种1Site selection, preparation, and planting
选择背风的坡地作为栽培地点,且要求坡度处于半阴半阳的坡面。并远离麦类作物,防止锈病感染;以疏松、富含腐殖质的镶上为好,粘土、沙土均不适宜。Choose a leeward slope as the cultivation site, and the slope is required to be half shade and half sun. And stay away from wheat crops to prevent rust infection; it is better to inlay loose and rich in humus, clay and sand are not suitable.
结冻前整地,清除地面杂草,深耕细耙,作1.3m宽的畦。每亩用厩肥1500kg、过磷酸钙50kg、油饼100kg,堆沤腐熟后撤于畦面并浅翻;畦面作成弓形。Before freezing, prepare the land, clear the weeds on the ground, plow and rake deeply, and make a 1.3m wide furrow. Use 1500kg of manure, 50kg of superphosphate, and 100kg of oil cake per mu. After the composting is mature, remove it to the furrow surface and turn it shallowly; the furrow surface is made into a bow shape.
7-9月间收获时,选择无创伤病斑的鳞茎作种。用条栽法,按行距15cm开沟,株距10cm,栽后覆土5-6cm。或在栽时分瓣,斜栽于穴内,栽后覆盖细土、灰肥3-5cm厚,压紧镇平。When harvesting between July and September, choose bulbs without traumatic lesions as seeds. With the strip planting method, the row spacing is 15cm, the plant spacing is 10cm, and the soil is 5-6cm after planting. Or divide the petals when planting, plant obliquely in the hole, cover with fine soil, gray fertilizer 3-5cm thick after planting, compact and flatten.
2追肥2 top dressing
使用的肥料包括腐殖土,农家肥和过磷酸钙等,过磷酸钙亩使用25kg,先将各种肥料混匀再将其撒至田中。The fertilizers used include humus, farmyard manure and superphosphate, etc. The superphosphate is 25kg per mu. Mix all kinds of fertilizers and then spread them in the field.
根据微量元素施用与否分为实验组与对照组Divided into experimental group and control group according to whether trace elements were administered or not
实验组为施用微量元素肥料组合物的组,采用实施例七所提供的组合物;施用量为锌肥8.21kg/hm2-11.49kg/hm2,硼肥10.86kg/hm2-16.42kg/hm2,钼肥0.47kg/hm2-0.66kg/hm2。The experimental group is the group applying trace element fertilizer composition, using the composition provided in Example 7; the application rate is zinc fertilizer 8.21kg/hm 2 -11.49kg/hm 2 , boron fertilizer 10.86kg/hm 2 -16.42kg/ hm 2 , molybdenum fertilizer 0.47kg/hm 2 -0.66kg/hm 2 .
对照组1为不施用微量元素肥料组合物的组;Control group 1 is the group that does not apply trace element fertilizer composition;
对照组2为只施用锌肥组,施用量为8.21kg/hm2-11.49kg/hm2。The control group 2 is the group applying only zinc fertilizer, and the application rate is 8.21kg/hm 2 -11.49kg/hm 2 .
对照组3为只施用硼肥组,施用量为10.86kg/hm2-16.42kg/hm2。Control group 3 is a group that only applies boron fertilizer, and the application rate is 10.86kg/hm 2 -16.42kg/hm 2 .
对照组4为只施用钼肥组,施用量为0.47kg/hm2-0.66kg/hm2。The control group 4 is the group applying only molybdenum fertilizer, and the application rate is 0.47kg/hm 2 -0.66kg/hm 2 .
在瓦布贝母生长第五年5月初至6月底施用,分4次施用,15天1次;第一次施用总用量的20%;第二次施用总用量的30%;第三次施用总用量的30%;第四次施用总用量的20%。每次施用均将微量元素组合物配成1升的水溶液喷施。Apply from the beginning of May to the end of June in the fifth year of Wabu Fritillaria growth, divide into 4 applications, once every 15 days; the first application is 20% of the total amount; the second application is 30% of the total amount; the third application 30% of the total dosage; 20% of the total dosage for the fourth application. For each application, the trace element composition was formulated into 1 liter of aqueous solution and sprayed.
3除草、病虫害防治3 Weeding, pest control
3.1除草3.1 Weeding
瓦布贝母杂草较多,应及时除草,春季出苗前用草宁除草1次。There are many weeds in Wabu Fritillaria, weeding should be done in time, and weeding should be done once with grass ning before emergence in spring.
3.2病虫害防治3.2 Pest control
锈病:为川贝母主要病害,病源多来自麦类作物,多发生于5-6月。防治方法:选远离麦类作物的地种植;整地时清除病残组织,减少越冬病原;增施磷、钾肥,降低田间湿度;发病初期喷甲基托布津可湿性粉剂800-1000倍液或粉锈宁1000倍液,7-10天喷1次,连喷3-4次。Rust: It is the main disease of Fritillaria sichuanensis. The source of the disease mostly comes from wheat crops, and it mostly occurs in May-June. Control methods: choose a place far away from wheat crops; remove diseased and disabled tissues during site preparation to reduce overwintering pathogens; increase phosphorus and potassium fertilizers to reduce field humidity; spray thiophanate-methyl wettable powder 800-1000 times liquid or tributinin at the beginning of the disease 1000 times liquid, spray once every 7-10 days, and spray 3-4 times continuously.
立枯病:为害幼苗,发生于夏季多雨季节。防治方法:注意排水、调节郁闭度,以及阴雨天揭棚盖;发病前后用1∶1∶100的波尔多液喷洒。Blight: Harms seedlings and occurs in the rainy summer season. Control methods: pay attention to drainage, adjust canopy density, and uncover the canopy in rainy days; spray with 1:1:100 Bordeaux mixture before and after the onset.
虫害以金针虫和蛴螬为主,4-6月为害植株。防治方法:每亩用50%氯丹乳油0.5-1kg,于整地时拌上或出苗后掺水500kg灌水防治。Insect pests are mainly needleworms and grubs, which damage plants from April to June. Control method: Use 0.5-1kg of 50% chlordane EC per mu, mix it with soil preparation or mix with 500kg of water after emergence for control.
4收获4 harvest
瓦布贝母于7月下旬至8月上旬采挖,选晴天采挖,采挖后计算各组的单位面积鲜产量、单株鳞茎鲜重以及总生物碱含量(以西贝碱计),并将实验组与对照组对比,计算出增产率与增重率。Wabu Fritillaria was excavated from late July to early August, and excavated on sunny days. After excavation, the fresh yield per unit area, fresh weight of bulbs per plant and total alkaloid content (calculated as sibidine) of each group were calculated, and Comparing the experimental group with the control group, the yield increase rate and weight gain rate were calculated.
5结果5 results
实验组与对照组单位面积鲜产量、单株鳞茎鲜重以及总生物碱含量(以西贝碱计)测定结果如下表所示:Experimental group and control group fresh yield per unit area, single bulb fresh weight and total alkaloid content (calculated in siebeline) measurement results are shown in the following table:
施用微肥组合物的实验组,相较于各对照组的增产率与增重率以及生物碱含量的增加率如下表所示:For the experimental group using the micro-fertilizer composition, compared with the increase rate of each control group, the increase rate and weight gain rate and the increase rate of alkaloid content are shown in the following table:
上述结果表明,本发明相较于对照组而言,单位面积鲜产量、单株鳞茎鲜重以及总生物碱含量(以西贝碱计)均有明显提高,其中相对于不施微肥组,增产率达到95.45%,单株鳞茎增重率达到95.45%,生物碱含量提高87.12%,具有非常明显的增产增效作用,相较于单独施用锌肥、硼肥以及钼肥,具有明显的协同增效作用。其中生物碱含量可直接影响瓦布贝母的药效,影响其镇咳、祛痰、平喘的效用,故本发明提供的微量元素肥料组合物不仅仅提高了瓦布贝母的产量,还极大的提高了其生物碱的含量,提高了药用效果。The above results show that, compared with the control group, the present invention has significantly improved fresh yield per unit area, fresh bulb per plant and total alkaloid content (calculated in terms of sibetine). The weight gain rate of a single bulb reached 95.45%, and the alkaloid content increased by 87.12%, which has a very obvious effect of increasing production and efficiency. Compared with the single application of zinc fertilizer, boron fertilizer and molybdenum fertilizer, it has obvious synergistic growth effect. Wherein the content of alkaloids can directly affect the efficacy of Fritillaria wabu, and affect its antitussive, expectorant, and antiasthmatic effects, so the trace element fertilizer composition provided by the invention not only improves the output of Fritillaria wabu, but also improves the yield of Fritillaria wabu. The content of its alkaloids has been greatly improved, and the medicinal effect has been improved.
以上仅是本发明的优选实施方式,应当指出的是,上述优选实施方式不应视为对本发明的限制,本发明的保护范围应当以权利要求所限定的范围为准。对于本技术领域的普通技术人员来说,在不脱离本发明的精神和范围内,还可以做出若干改进和润饰,这些改进和润饰也应视为本发明的保护范围。The above are only preferred implementations of the present invention. It should be noted that the above preferred implementations should not be regarded as limiting the present invention, and the scope of protection of the present invention should be based on the scope defined in the claims. For those skilled in the art, without departing from the spirit and scope of the present invention, some improvements and modifications can also be made, and these improvements and modifications should also be regarded as the protection scope of the present invention.
Claims (10)
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CN104058816A (en) * | 2014-07-03 | 2014-09-24 | 四川农业大学 | Fertilizer for Bupleurum chinense and application method thereof |
CN106386138A (en) * | 2016-09-23 | 2017-02-15 | 四川农业大学 | An angelica dahurica planting method |
US20170297961A1 (en) * | 2014-02-24 | 2017-10-19 | Thomas T. Yamashita | Fertilizer Compositions Comprising a Cellulose Nutrient Component and Methods for Using Same |
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US20170297961A1 (en) * | 2014-02-24 | 2017-10-19 | Thomas T. Yamashita | Fertilizer Compositions Comprising a Cellulose Nutrient Component and Methods for Using Same |
CN104058816A (en) * | 2014-07-03 | 2014-09-24 | 四川农业大学 | Fertilizer for Bupleurum chinense and application method thereof |
CN106386138A (en) * | 2016-09-23 | 2017-02-15 | 四川农业大学 | An angelica dahurica planting method |
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