CN107934937B - 一种碳材料-黑磷烯复合气凝胶及其制备方法 - Google Patents
一种碳材料-黑磷烯复合气凝胶及其制备方法 Download PDFInfo
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- CN107934937B CN107934937B CN201711192107.0A CN201711192107A CN107934937B CN 107934937 B CN107934937 B CN 107934937B CN 201711192107 A CN201711192107 A CN 201711192107A CN 107934937 B CN107934937 B CN 107934937B
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- black phosphorus
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- phosphorus alkene
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 69
- 239000002131 composite material Substances 0.000 title claims abstract description 60
- 239000004964 aerogel Substances 0.000 title claims abstract description 56
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 239000003575 carbonaceous material Substances 0.000 claims abstract description 31
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910021389 graphene Inorganic materials 0.000 claims description 32
- 238000001035 drying Methods 0.000 claims description 15
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 9
- 239000002048 multi walled nanotube Substances 0.000 claims description 9
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 8
- 239000011259 mixed solution Substances 0.000 claims description 7
- 239000002109 single walled nanotube Substances 0.000 claims description 7
- 239000013049 sediment Substances 0.000 claims description 6
- 230000001476 alcoholic effect Effects 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 238000004108 freeze drying Methods 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 4
- 238000002604 ultrasonography Methods 0.000 claims description 4
- 238000010907 mechanical stirring Methods 0.000 claims description 3
- -1 black phosphorus alkene Chemical class 0.000 abstract description 38
- 239000000463 material Substances 0.000 abstract description 17
- 238000000034 method Methods 0.000 abstract description 17
- 238000006243 chemical reaction Methods 0.000 abstract description 12
- 239000000126 substance Substances 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 238000004026 adhesive bonding Methods 0.000 abstract description 2
- 238000010382 chemical cross-linking Methods 0.000 abstract description 2
- 239000003431 cross linking reagent Substances 0.000 abstract description 2
- 239000007787 solid Substances 0.000 abstract 1
- 238000007710 freezing Methods 0.000 description 10
- 230000008014 freezing Effects 0.000 description 10
- 239000007788 liquid Substances 0.000 description 9
- 238000004146 energy storage Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 238000000859 sublimation Methods 0.000 description 5
- 230000008022 sublimation Effects 0.000 description 5
- 238000000926 separation method Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 241000209094 Oryza Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 239000002041 carbon nanotube Substances 0.000 description 3
- 229910021393 carbon nanotube Inorganic materials 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000002096 quantum dot Substances 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 241000446313 Lamella Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- 229960000907 methylthioninium chloride Drugs 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000011232 storage material Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 239000012620 biological material Substances 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
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- 239000007772 electrode material Substances 0.000 description 1
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- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 206010016256 fatigue Diseases 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
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- 230000031700 light absorption Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000007626 photothermal therapy Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
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- 238000001338 self-assembly Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000011540 sensing material Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 238000002371 ultraviolet--visible spectrum Methods 0.000 description 1
- 239000011240 wet gel Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/003—Phosphorus
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/06—Multi-walled nanotubes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/10—Solid density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Carbon And Carbon Compounds (AREA)
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Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108529578B (zh) * | 2018-04-26 | 2021-09-14 | 昆明理工大学 | 一种高稳定纳米黑磷/三维石墨烯复合材料的制备方法 |
CN108940141B (zh) * | 2018-08-10 | 2020-09-08 | 太原理工大学 | 一种石墨烯复合气凝胶的制备方法 |
CN109152113B (zh) * | 2018-09-20 | 2022-02-01 | 广东烯创科技有限公司 | 基于石墨烯的电热膜及其制备方法、电暖片和电暖设备 |
CN109592962B (zh) * | 2019-01-28 | 2020-08-04 | 北京航空航天大学 | 一种仿生三元体系石墨烯-黑磷纳米复合材料薄膜制备方法 |
CN110498404B (zh) * | 2019-07-22 | 2021-01-22 | 山东玥能新材料科技有限公司 | 一种原位制备黑磷-碳纳米管复合材料的方法 |
CN110498464B (zh) * | 2019-08-07 | 2021-10-26 | 桂林电子科技大学 | 一种碳纳米管气凝胶木片双层结构光热转化材料 |
CN110482529B (zh) * | 2019-08-27 | 2021-03-09 | 深圳市德方纳米科技股份有限公司 | 黑磷碳纳米管复合材料及其制备方法 |
CN111394152B (zh) * | 2020-03-26 | 2021-11-23 | 西安建筑科技大学 | 一种含有纳米氧化石墨烯/黑磷纳米片的复合润滑剂及其制备方法 |
CN113603101A (zh) * | 2021-09-02 | 2021-11-05 | 中建材科创新技术研究院(山东)有限公司 | 一种柔性气凝胶透明片及其制备方法 |
CN114852995B (zh) * | 2022-03-31 | 2024-03-22 | 海南师范大学 | 黑磷基复合材料构建辣根过氧化物酶传感器的电催化应用 |
Citations (4)
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KR20160096374A (ko) * | 2015-02-05 | 2016-08-16 | 이성균 | 층상구조의 액상 펄스 레이저 어블레이션 - 그래핀, 포스포린 제조방법. |
CN106711408A (zh) * | 2015-11-13 | 2017-05-24 | 中国科学院金属研究所 | 柔性锂离子电池黑磷纳米片-石墨烯复合薄膜负极及制备 |
CN106744853A (zh) * | 2016-12-29 | 2017-05-31 | 深圳大学 | 一种石墨烯/黑磷纳米片/含氮离子液体复合气凝胶及其制备方法 |
CN106990144A (zh) * | 2017-03-24 | 2017-07-28 | 福州大学 | 黑磷纳米片与半解开碳纳米纤维复合材料的制备方法 |
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Patent Citations (4)
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KR20160096374A (ko) * | 2015-02-05 | 2016-08-16 | 이성균 | 층상구조의 액상 펄스 레이저 어블레이션 - 그래핀, 포스포린 제조방법. |
CN106711408A (zh) * | 2015-11-13 | 2017-05-24 | 中国科学院金属研究所 | 柔性锂离子电池黑磷纳米片-石墨烯复合薄膜负极及制备 |
CN106744853A (zh) * | 2016-12-29 | 2017-05-31 | 深圳大学 | 一种石墨烯/黑磷纳米片/含氮离子液体复合气凝胶及其制备方法 |
CN106990144A (zh) * | 2017-03-24 | 2017-07-28 | 福州大学 | 黑磷纳米片与半解开碳纳米纤维复合材料的制备方法 |
Non-Patent Citations (1)
Title |
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Graphene oxide/black phosphorus nanoflake aerogels with robust thermo-stability and significantly enhanced photothermal properties in air;Chenyang Xing et al.;《Nanoscale》;20170412;第9卷;第8096页左栏第1段、第8097页左栏第3段和右栏倒数第2段 * |
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