CN1079218A - 水包油型β-胡萝卜素的制作工艺 - Google Patents
水包油型β-胡萝卜素的制作工艺 Download PDFInfo
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Abstract
一种水包油型β-胡萝卜素的制作工艺，主要是
经复合乳化剂：吐温类、司盘类和亲水性胶体，以一定
的比例和β-胡萝卜素的油溶液及水进行乳化，可得
乳化粒径小于1μm的稳定的乳状液，然后加入β-环
状糊精或蔗糖作防止β-胡萝卜素氧化的保护剂，上
述乳状液再经造粒、干燥，即可得含一定量的β-胡萝
卜素的水包油颗粒。
Description
本发明是一种生产水包油型β-胡萝卜素固体颗粒的方法。
β-胡萝卜素是一种维生素A源，在医药界和饮食界具有广泛的用途，β-胡萝卜素是难溶于水的，而且其色素很不稳定，见光易分解，这给β-胡萝卜素的使用带来诸多不便。在此发明以前，水溶性β-胡萝卜素制作工艺复杂，制作程序要求严格，需人为添加化学合成的抗氧化剂。
本发明的目的是为食品业和医药业提供一种以食用油乳化液为基质的高稳定性的β-胡萝卜素的水溶性干粉。其制作工艺简单，无需添加专一的抗氧化剂，产品稳定性好，能抗紫外照射，乳化粒径小于1um.
本发明的方法为将一定含量的β-胡萝卜素油溶液，加入HLB较低的乳化剂1，同时加入水溶性的胶体和HLB较高的乳化剂2及水，其比例为油∶乳化剂1∶胶∶乳化剂2∶水＝20∶3-8∶20∶5-8∶50-150将其混合物用乳匀器充分乳化10-15min，乳化过程可以是20℃-100℃，然后将上述乳状液或β-环糊精与糖类混合，充分混匀后其软材经造粒机造粒成形、干燥，即可制成高稳定性的含β-胡萝卜素的水包油型颗粒。
上述的乳化剂1可以是食品工业中常用的亲油性乳化剂，如分子蒸馏单甘酯，司盘80，司盘60，月桂酸丙二醇酯。
上述的乳化剂2为食品工业中常用的亲水性乳化剂，如乳化剂OP，吐温80，吐温20，蔗糖脂肪酸酯类。
上述的水溶性胶体可以为CMC-Na，海藻胶、黄芪胶、阿拉伯树胶等植物多糖胶。
本发明所涉及的生产工艺为将β-胡萝卜素的油溶液、乳化剂，亲水胶体、水按上述比例混合，用高压匀浆泵或胶体磨充分乳化再用兼作保护剂和分散剂的β-糊精或糖与上述乳状胶体充分混匀，所得软材，经制颗粒的筛网筛过，造粒，经烘房50-60℃干燥，即得合β-胡萝卜素的水溶性小颗粒，此颗粒能在常温下溶于水，其稳定性好，乳化粒径小于1um。
操作例1、CMC-Na20份、加吐温80 5份、加水150份、加热至60-80℃溶解，置于乳匀机上搅拌均匀，后加20份含20% β-胡萝卜素的油溶液，同时加8份司盘80，上述混合液经市售DJM立式胶体磨充分乳化，再用上述乳状液以1∶1与市售蔗糖混合。即可得含5% β-胡罗卜素的水包油型颗粒。
操作例2，阿拉伯胶20份加吐温20 5份，加水50份，溶解混匀后加20份含2.78%的β-胡萝卜素油溶液，5份司盘20，经市售GYB高压匀浆泵充分乳化，所得乳化液与25份β-环糊精，混合，再经造粒、干燥，即可得0.5-0.8%的β-胡萝卜素的水包油型固体颗粒。
操作例3，黄芪胶20份，吐温60 5份，水100份，分子蒸馏单甘酯8份，25-30% β-胡萝卜素的油溶液20份，蔗糖30份充分混匀，经高压匀浆泵充分乳化。所得乳状胶体经造粒、干燥，即可得5-7% β-胡萝卜素的水溶性干粉。
Claims (7)
1、一种生产水包油型β-胡萝卜素的制作工艺。乳状液配方为20-25份β-胡萝卜素的油溶液；3-8份HLB较高的亲水性乳化剂，20-30份水溶性胶体，5-8份HLB较低的亲油性乳化剂，50-150份水，40-50份糖将上述组分按比例混合，置20℃-100℃经胶体磨或高压匀浆泵充分乳化，再经干燥、造粒即可得含β-胡萝卜素0.5-10%的水包油(O/W)型固体颗粒。此颗粒为红中略有黄色，能快速溶于水，稳定性好。
2、根据权利要求1的方法，β-胡萝卜素的油溶液可以是市售的或自配的各种含β-胡萝卜素的油溶液或油悬液。
3、根据权利要求1的方法，其HLB较低的亲油性乳化剂可以是司盘80，司盘60，司盘83，分子蒸馏单甘酯，月桂酸丙二醇酯等亲油性乳化剂。
4、根据权利要求1的方法，其HLB较高的亲水性乳化剂，可以是吐温20、乳化剂OP，吐温30、蔗糖脂肪酸酯等亲水性乳化剂。
5、根据权利要求1的方法，水溶性胶体可以是羧甲基纤维素钠简称（CMC-Na），海藻胶（或称藻朊酸钠）黄芪胶、阿拉伯树胶等易溶于水，能增加水的粘度的高分子化合物。
6、根据权利要求1的方法，乳化机械可以是胶体磨，高压匀浆泵高速搅拌机，乳化温度为20-100℃。
7、根据权利要求1的方法，作保护剂和分散剂的可以是β-环糊精、蔗糖或其它单糖或双糖类。
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN93110751A CN1038220C (zh) | 1993-04-08 | 1993-04-08 | 水包油型β-胡萝卜素的制作工艺 |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN93110751A CN1038220C (zh) | 1993-04-08 | 1993-04-08 | 水包油型β-胡萝卜素的制作工艺 |
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| Publication Number | Publication Date |
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| CN1079218A true CN1079218A (zh) | 1993-12-08 |
| CN1038220C CN1038220C (zh) | 1998-05-06 |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999007238A2 (en) * | 1997-08-08 | 1999-02-18 | The Procter & Gamble Company | Oil-in-water dispersions of carotenoids stable against oxidation prepared from water-dispersible beadlets |
| CN101112359B (zh) * | 2007-07-31 | 2010-09-15 | 中国农业大学 | 一种透明水分散型β-胡萝卜素浓缩液的制备方法 |
| CN101269310B (zh) * | 2008-05-06 | 2010-12-22 | 大连赛诺微囊技术有限公司 | 冷水分散型微囊粉的制备方法 |
| WO2012159446A1 (zh) * | 2011-05-20 | 2012-11-29 | 浙江医药股份有限公司新昌制药厂 | 一种发酵法生产天然β-胡萝卜素的方法和应用 |
| CN106617085A (zh) * | 2016-12-01 | 2017-05-10 | 浙江工业大学 | 一种裂片石莼多糖‑吐温20复配β‑胡萝卜素乳液的制备方法 |
| CN108433013A (zh) * | 2018-03-06 | 2018-08-24 | 珠海雅富兴源食品工业有限公司 | 一种天然胡萝卜素制剂的制备方法 |
| CN109280685A (zh) * | 2017-07-21 | 2019-01-29 | 浙江医药股份有限公司新昌制药厂 | 通过增加天然类胡萝卜素发酵过程中溶氧生产天然类胡萝卜素的方法 |
| CN113068778A (zh) * | 2021-05-12 | 2021-07-06 | 合肥工业大学 | 一种含环糊精包埋胡萝卜素的芋头浆体饮料的制作方法 |
-
1993
- 1993-04-08 CN CN93110751A patent/CN1038220C/zh not_active Expired - Fee Related
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999007238A2 (en) * | 1997-08-08 | 1999-02-18 | The Procter & Gamble Company | Oil-in-water dispersions of carotenoids stable against oxidation prepared from water-dispersible beadlets |
| WO1999007238A3 (en) * | 1997-08-08 | 1999-04-29 | Procter & Gamble | Oil-in-water dispersions of carotenoids stable against oxidation prepared from water-dispersible beadlets |
| US6007856A (en) * | 1997-08-08 | 1999-12-28 | The Procter & Gamble Company | Oil-in-water dispersions of β-carotene and other carotenoids stable against oxidation prepared from water-dispersible beadlets having high concentrations of carotenoid |
| CN101112359B (zh) * | 2007-07-31 | 2010-09-15 | 中国农业大学 | 一种透明水分散型β-胡萝卜素浓缩液的制备方法 |
| CN101269310B (zh) * | 2008-05-06 | 2010-12-22 | 大连赛诺微囊技术有限公司 | 冷水分散型微囊粉的制备方法 |
| WO2012159446A1 (zh) * | 2011-05-20 | 2012-11-29 | 浙江医药股份有限公司新昌制药厂 | 一种发酵法生产天然β-胡萝卜素的方法和应用 |
| CN106617085A (zh) * | 2016-12-01 | 2017-05-10 | 浙江工业大学 | 一种裂片石莼多糖‑吐温20复配β‑胡萝卜素乳液的制备方法 |
| CN106617085B (zh) * | 2016-12-01 | 2020-08-21 | 浙江工业大学 | 一种裂片石莼多糖-吐温20复配β-胡萝卜素乳液的制备方法 |
| CN109280685A (zh) * | 2017-07-21 | 2019-01-29 | 浙江医药股份有限公司新昌制药厂 | 通过增加天然类胡萝卜素发酵过程中溶氧生产天然类胡萝卜素的方法 |
| CN108433013A (zh) * | 2018-03-06 | 2018-08-24 | 珠海雅富兴源食品工业有限公司 | 一种天然胡萝卜素制剂的制备方法 |
| CN108433013B (zh) * | 2018-03-06 | 2021-04-27 | 珠海雅富兴源食品工业有限公司 | 一种天然胡萝卜素制剂的制备方法 |
| CN113068778A (zh) * | 2021-05-12 | 2021-07-06 | 合肥工业大学 | 一种含环糊精包埋胡萝卜素的芋头浆体饮料的制作方法 |
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| Publication number | Publication date |
|---|---|
| CN1038220C (zh) | 1998-05-06 |
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