CN107898716A - A kind of preparation method of nanofiber dry type facial mask - Google Patents
A kind of preparation method of nanofiber dry type facial mask Download PDFInfo
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- CN107898716A CN107898716A CN201810053724.0A CN201810053724A CN107898716A CN 107898716 A CN107898716 A CN 107898716A CN 201810053724 A CN201810053724 A CN 201810053724A CN 107898716 A CN107898716 A CN 107898716A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0212—Face masks
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/736—Chitin; Chitosan; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8129—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers or esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers, e.g. polyvinylmethylether
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0015—Electro-spinning characterised by the initial state of the material
- D01D5/003—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion
- D01D5/0038—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion the fibre formed by solvent evaporation, i.e. dry electro-spinning
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0061—Electro-spinning characterised by the electro-spinning apparatus
- D01D5/0076—Electro-spinning characterised by the electro-spinning apparatus characterised by the collecting device, e.g. drum, wheel, endless belt, plate or grid
- D01D5/0084—Coating by electro-spinning, i.e. the electro-spun fibres are not removed from the collecting device but remain integral with it, e.g. coating of prostheses
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
- D04H1/72—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged
- D04H1/728—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged by electro-spinning
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Abstract
The invention discloses a kind of preparation method based on nanofiber dry type facial mask, including polyvinyl alcohol water solution, the preparation of chitosan aqueous solution, sodium hyaluronate solution and nutrient solution；The above-mentioned product for preparing is mixed as spinning solution progress Multi needle electrostatic spinning, using facial mask by the use of non-woven fabrics base material as receiving screen, one layer of nano fibrous membrane is finally formed on mask nonwoven fabric base material, composite cellulosic membrane is made；Dried 25 minutes at 70 80 DEG C；Cut, shape, pack and sterilize, to obtain the final product.Active ingredient in facial mask liquid is mixed into polyvinyl alcohol spinning base fluid by the present invention, nanofiber will be prepared into by electrostatic spinning technique and be fixed in mask nonwoven fabric, facial mask is taken out during use, sprays suitable pure water in front, make facial mask be sufficiently humidified so as to can face apply.It is extremely low due to the use of preceding water content, and chitosan class natural antibacterial ingredient is added, the shelf-life is extended, and also allow for shipping storage.
Description
Technical field
The present invention relates to a kind of manufacture method of facial mask, more particularly to a kind of preparation side of nanofiber dry type facial mask
Method.
Background technology
Facial mask is one of the important cosmetics for nursing skin of face, its form mainly have mud cream type, tear-pull, gel-type,
Four kinds of hygenic towelette type, wherein wet tissue type facial mask are easy to operate due to easy to carry, deep to be favored by numerous women.Hygenic towelette type
Facial mask is to be aided with nutritional ingredient and medicine with non-woven fabrics base material, coated on face, utilizes the of short duration time for being covered in face, facial mask
In moisture and nutriment penetrate into the cuticula of skin epidermis, skin is become soft and high resilience, therefore be subject to vast
Women's likes.But there are problems with for facial mask now:1. facial mask is immersed in nutrient solution, take out or face apply during nutrient solution
Inevitably drippage, during particularly being applied in face, if sticky nutrient solution drops onto clothes on clothes and can produce dirt, if drop
Fall on skin, user can be very uncomfortable；2. facial mask is immersed in nutrient solution and preserves, supernutrition liquid is often stored in packaging bag
Not only waste but also increase cost.3. contain substantial amounts of nutriment in nutrient solution, liquid is even if also easily addling or grow after sterilization
Endophytic bacteria, causes security risk；4. liquid packaging needs to prevent that packaging bag from being punctured, shipping storage both it has been unfavorable for or bag can be increased
Dress up this.
In order to solve the problems, such as this, patent CN106880504A, CN1066677 and CN1067266A once disclose one kind
The production method of dry type facial mask, it, which makes core procedure, is all by face paper immersion nutrient solution and then dries that the method needs to match somebody with somebody
A large amount of nutrient solutions are put as immersion stoste, and nutrient solution is often expensive, so can both cause waste to also increase cost.
The content of the invention
In view of this, in view of the deficiencies of the prior art, it is an object of the present invention to provide a kind of nanofiber dry type facial mask
Preparation method, solve the problems, such as traditional facial mask be immersed in nutrient solution cause nutrient solution cost of idleness it is excessive reached at the same time keep away
Exempt from bacteria breed, the effect of skin care.
To reach above-mentioned purpose, the present invention uses following technical scheme：
A kind of preparation method based on nanofiber dry type facial mask, comprises the following steps：
1）By degree of polymerization 500-2500, alcoholysis degree is less than the section of 90% polyvinyl alcohol and is put into deionized water, and 0.5- is stirred at room temperature
1 is fully swollen sample when small, be then heated rapidly to more than 60 DEG C stirring 1-3 it is small when, be made 10-20% polyvinyl alcohol water
Solution；
2）Carboxymethyl chitosan is dissolved in deionized water at normal temperatures, it is water-soluble that the chitosan that mass fraction is 1- 10% is made
Liquid；
3）Sodium Hyaluronate is dissolved in the aqueous acetic acid that mass fraction is 10% and stirs 5-24h at room temperature, obtains mass fraction
For the sodium hyaluronate solution of 0.1%-1%；
4）By sericin, silk peptide or herbal raw material extracting solution it is soluble in water prepare mass fraction be 5-10% nutrient solution；
5）By step 2）、3）、4）Prepared product is added separately to step 1）In made solution, obtain polyvinyl alcohol, chitosan,
Sodium Hyaluronate, the mixed solution of nutrient solution are as spinning solution；
6）By step 5）Gained mixed solution carries out Multi needle electrostatic spinning, using facial mask by the use of non-woven fabrics base material as receiving screen,
One layer of nano fibrous membrane is finally formed on mask nonwoven fabric base material, composite cellulosic membrane is made；
7）Above-mentioned composite cellulosic membrane is dried 2-5 minutes at 70-80 DEG C；
8）Cut, shape, pack and sterilize.
Further, step 2）The carboxymethyl chitosan be carboxylation degree be 83.58%, relative molecular weight be more than 5000
Chitosan.
Further, step 5）The polyvinyl alcohol：Chitosan：Sodium Hyaluronate：Sericin weight ratio is 1:0.05-
0.1:0.01-0.05:0.1-0.5。
Further, step 4）The herbal raw material is water pears, cucumber, lemon, sweet orange, mango, carrot, Flos Chrysanthemi
Or one or more kinds of raw materials in aloe are mixed with any ratio.
The preparation method of the extracting solution is by herbal raw material cleaning, crushes to obtain fine powder, adds water to be concentrated after squeezing the juice
The solution for being 2.0-3.0g/ml for density, adds the solid-liquid ratio 1g/ml of water and the fine powder.
Further, step 6）The method of the electrostatic spinning is specifically, with 0.9mm tack pins, the voltage of 10-20kV,
The distance of 8-15cm.
The beneficial effects of the invention are as follows：
Active ingredient in facial mask liquid is mixed into polyvinyl alcohol spinning by the present invention with a kind of new approaches for being different from traditional facial mask
In base fluid, nanofiber will be prepared into by electrostatic spinning technique and be fixed in mask nonwoven fabric, when use, takes out facial mask,
Spray suitable pure water in front, make facial mask be sufficiently humidified so as to can face apply.Water-soluble nano fiber chance water speed is molten, in face paper
Top layer forms the liquid sol film rich in nutritional ingredient, both avoids nutrient solution from dripping in use, and what also increase used relaxes
Appropriateness, and nourishing maintenance effect well can be played to face.It is extremely low due to the use of preceding water content, and add chitosan class
Natural antibacterial ingredient, avoids rotten and bacteria breed, extends the shelf-life, and also allow for shipping storage.
Brief description of the drawings
Fig. 1 is the electron microscope of 1 nanofiber of the embodiment of the present invention；
Fig. 2 is the electron microscope of 2 nanofiber of the embodiment of the present invention；
Fig. 3 is the electron microscope of 3 nanofiber of the embodiment of the present invention；
Fig. 4 is the electron microscope of 4 nanofiber of the embodiment of the present invention；
Fig. 5 is the electron microscope of 5 nanofiber of the embodiment of the present invention.
Embodiment
The invention will be further described with reference to the accompanying drawings and examples.
Embodiment 1
A kind of preparation method based on nanofiber dry type facial mask, comprises the following steps：
1）By the degree of polymerization 500, alcoholysis degree is less than the section of 90% polyvinyl alcohol and is put into deionized water, be stirred at room temperature 0.5 it is small when will
Sample is fully swollen, be then heated rapidly to more than 60 DEG C stirring 1 it is small when, be made 10% polyvinyl alcohol water solution；
2）Carboxymethyl chitosan is dissolved in deionized water at normal temperatures, the chitosan aqueous solution that mass fraction is 1% is made；Institute
State carboxymethyl chitosan be carboxylation degree be 83.58%, relative molecular weight be more than 5000 chitosan；
3）The molten room temperature into the aqueous acetic acid that mass fraction is 10% of Sodium Hyaluronate is stirred into 5h, obtains mass fraction as 0.1%
Sodium hyaluronate solution；
4）By the sericin mass fraction soluble in water for preparing for 5% nutrient solution；
5）By step 2）、3）、4）Prepared product is added separately to step 1）In made solution, obtain polyvinyl alcohol, chitosan,
Sodium Hyaluronate, the mixed solution of nutrient solution are as spinning solution；The polyvinyl alcohol：Chitosan：Sodium Hyaluronate：Sericin
Weight ratio is 1:0.05:0.01:0.1；
6）By step 5）Gained mixed solution carries out Multi needle electrostatic spinning, using facial mask by the use of non-woven fabrics base material as receiving screen,
One layer of nano fibrous membrane is finally formed on mask nonwoven fabric base material, composite cellulosic membrane is made；The method tool of the electrostatic spinning
Body is, with 0.9mm tack pins, the voltage of 10kV, the distance of 8cm；Wherein, the electron microscope of nanofiber obtained by electrostatic spinning is as schemed
Shown in 1；
7）Above-mentioned composite cellulosic membrane is dried 2 minutes at 70 DEG C；
8）Cut, shape, pack and sterilize.
Embodiment 2
A kind of preparation method based on nanofiber dry type facial mask, comprises the following steps：
1）By the degree of polymerization 2500, alcoholysis degree is less than the section of 90% polyvinyl alcohol and is put into deionized water, be stirred at room temperature 1 it is small when will
Sample is fully swollen, be then heated rapidly to more than 60 DEG C stirring 3 it is small when, be made 20% polyvinyl alcohol water solution；
2）Carboxymethyl chitosan is dissolved in deionized water at normal temperatures, the chitosan aqueous solution that mass fraction is 10% is made；Institute
The carboxylation degree for stating carboxymethyl chitosan is 83.58%, chitosan of the relative molecular weight more than 5000；
3）The molten room temperature into the aqueous acetic acid that mass fraction is 10% of Sodium Hyaluronate is stirred into 24h, it is 1% to obtain mass fraction
Sodium hyaluronate solution；
4）By the silk peptide mass fraction soluble in water for preparing for 10% nutrient solution；
5）By step 2）、3）、4）Prepared product is added separately to step 1）In made solution, obtain polyvinyl alcohol, chitosan,
Sodium Hyaluronate, the mixed solution of nutrient solution are as spinning solution；The polyvinyl alcohol：Chitosan：Sodium Hyaluronate：Sericin
Weight ratio is 1: 0.1: 0.05: 0.5；
6）By step 5）Gained mixed solution carries out Multi needle electrostatic spinning, using facial mask by the use of non-woven fabrics base material as receiving screen,
One layer of nano fibrous membrane is finally formed on mask nonwoven fabric base material, composite cellulosic membrane is made；The method tool of the electrostatic spinning
Body is, with 0.9mm tack pins, the voltage of 20kV, the distance of 15cm；Wherein, the electron microscope of nanofiber obtained by electrostatic spinning is such as
Shown in Fig. 2；
7）Above-mentioned composite cellulosic membrane is dried 5 minutes at 80 DEG C；
8）Cut, shape, pack and sterilize.
Embodiment 3
A kind of preparation method based on nanofiber dry type facial mask, comprises the following steps：
1）By the degree of polymerization 1500, alcoholysis degree is less than the section of 90% polyvinyl alcohol and is put into deionized water, be stirred at room temperature 0.7 it is small when
Sample is fully swollen, be then heated rapidly to more than 60 DEG C stirring 2 it is small when, be made 15% polyvinyl alcohol water solution；
2）Carboxymethyl chitosan is dissolved in deionized water at normal temperatures, the chitosan aqueous solution that mass fraction is 5% is made；Institute
State carboxymethyl chitosan be carboxylation degree be 83.58%, relative molecular weight be more than 5000 chitosan；
3）The molten room temperature into the aqueous acetic acid that mass fraction is 10% of Sodium Hyaluronate is stirred into 15h, obtains mass fraction as 0.5%
Sodium hyaluronate solution；
4）By the herbal raw material extracting solution mass fraction soluble in water for preparing for 7% nutrient solution；The herbal raw material is water
Pears, cucumber and lemon are with 1:1:1 weight ratio；
5）By step 2）、3）、4）Prepared product is added separately in the made solution of step 1, obtain polyvinyl alcohol, chitosan,
Sodium Hyaluronate, the mixed solution of nutrient solution are as spinning solution；The polyvinyl alcohol：Chitosan：Sodium Hyaluronate：Sericin
Weight ratio is 1:0.07:0.035:0.3；
6）By step 5）Gained mixed solution carries out Multi needle electrostatic spinning, using facial mask by the use of non-woven fabrics base material as receiving screen,
One layer of nano fibrous membrane is finally formed on mask nonwoven fabric base material, composite cellulosic membrane is made；The method tool of the electrostatic spinning
Body is, with 0.9mm tack pins, the voltage of 15kV, the distance of 11cm；Wherein, the electron microscope of nanofiber obtained by electrostatic spinning is such as
Shown in Fig. 3；
7）Above-mentioned composite cellulosic membrane is dried 3 minutes at 75 DEG C；
8）Cut, shape, pack and sterilize.
Embodiment 4
A kind of preparation method based on nanofiber dry type facial mask, comprises the following steps：
1）By the degree of polymerization 2000, alcoholysis degree is less than the section of 90% polyvinyl alcohol and is put into deionized water, be stirred at room temperature 0.8 it is small when
Sample is fully swollen, be then heated rapidly to more than 60 DEG C stirring 3 it is small when, be made 20% polyvinyl alcohol water solution；
2）Carboxymethyl chitosan is dissolved in deionized water at normal temperatures, the chitosan aqueous solution that mass fraction is 8% is made；Institute
State carboxymethyl chitosan be carboxylation degree be 83.58%, relative molecular weight be more than 5000 chitosan；
3）The molten room temperature into the aqueous acetic acid that mass fraction is 10% of Sodium Hyaluronate is stirred into 22h, obtains mass fraction as 0.8%
Sodium hyaluronate solution；
4）By the herbal raw material extracting solution mass fraction soluble in water for preparing for 6% nutrient solution；The herbal raw material is water
Any of pears, cucumber, lemon, sweet orange, mango, carrot, Flos Chrysanthemi or aloe；
5）By step 2）、3）、4）Prepared product is added separately to step 1）In made solution, obtain polyvinyl alcohol, chitosan,
Sodium Hyaluronate, the mixed solution of nutrient solution are as spinning solution；The polyvinyl alcohol：Chitosan：Sodium Hyaluronate：Sericin
Weight ratio is 1:0.06:0.02:0.2；
6）By step 5）Gained mixed solution carries out Multi needle electrostatic spinning, using facial mask by the use of non-woven fabrics base material as receiving screen,
One layer of nano fibrous membrane is finally formed on mask nonwoven fabric base material, composite cellulosic membrane is made；The method tool of the electrostatic spinning
Body is, with 0.9mm tack pins, the voltage of 12kV, the distance of 12cm；Wherein, the electron microscope of nanofiber obtained by electrostatic spinning is such as
Shown in Fig. 4；
7）Above-mentioned composite cellulosic membrane is dried 4 minutes at 72 DEG C；
8）Cut, shape, pack and sterilize.
Embodiment 5
A kind of preparation method based on nanofiber dry type facial mask, comprises the following steps：
1）By the degree of polymerization 1000, alcoholysis degree is less than the section of 90% polyvinyl alcohol and is put into deionized water, be stirred at room temperature 0.9 it is small when
Sample is fully swollen, be then heated rapidly to more than 60 DEG C stirring 1.5 it is small when, be made 13% polyvinyl alcohol water solution；
2）Carboxymethyl chitosan is dissolved in deionized water at normal temperatures, it is water-soluble that the chitosan that mass fraction is 1- 10% is made
Liquid；The carboxymethyl chitosan be carboxylation degree be 83.58%, relative molecular weight be more than 5000 chitosan；
3）The molten room temperature into the aqueous acetic acid that mass fraction is 10% of Sodium Hyaluronate is stirred into 20h, obtains mass fraction as 0.6%
Sodium hyaluronate solution；
4）By herbal raw material extracting solution it is soluble in water prepare mass fraction be 5-10% nutrient solution；The herbal raw material is
Water pears, cucumber, lemon, sweet orange, mango, carrot, Flos Chrysanthemi and aloe are using proportion as 1:1:1:1:1:1:1:1 mixing；
5）By step 2）、3）、4）Prepared product is added separately to step 1）In made solution, obtain polyvinyl alcohol, chitosan,
Sodium Hyaluronate, the mixed solution of nutrient solution are as spinning solution；The polyvinyl alcohol：Chitosan：Sodium Hyaluronate：Sericin
Weight ratio is 1:0.09:0.04:0.2；
6）By step 5）Gained mixed solution carries out Multi needle electrostatic spinning, using facial mask by the use of non-woven fabrics base material as receiving screen,
One layer of nano fibrous membrane is finally formed on mask nonwoven fabric base material, composite cellulosic membrane is made；The method tool of the electrostatic spinning
Body is, with 0.9mm tack pins, the voltage of 18kV, the distance of 14cm；Wherein, the electron microscope of nanofiber obtained by electrostatic spinning is such as
Shown in Fig. 5；
7）Above-mentioned composite cellulosic membrane is dried 5 minutes at 77 DEG C；
8）Cut, shape, pack and sterilize.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, this area is common
Other modifications or equivalent substitution that technical staff makes technical scheme, without departing from technical solution of the present invention
Spirit and scope, should all cover among scope of the presently claimed invention.
Claims (5)
1. a kind of preparation method based on nanofiber dry type facial mask, it is characterised in that comprise the following steps：
1）By degree of polymerization 500-2500, alcoholysis degree is less than the section of 90% polyvinyl alcohol and is put into deionized water, and 0.5- is stirred at room temperature
1 is fully swollen sample when small, be then heated rapidly to more than 60 DEG C stirring 1-3 it is small when, be made 10-20% polyvinyl alcohol water
Solution；
2）Carboxymethyl chitosan is dissolved in deionized water at normal temperatures, it is water-soluble that the chitosan that mass fraction is 1- 10% is made
Liquid；
3）Sodium Hyaluronate is dissolved in the aqueous acetic acid that mass fraction is 10% and stirs 5-24h at room temperature, obtains mass fraction
For the sodium hyaluronate solution of 0.1%-1%；
4）By sericin, silk peptide or herbal raw material extracting solution it is soluble in water prepare mass fraction be 5-10% nutrient solution；
5）By step 2）、3）、4）Prepared product is added separately to step 1）In made solution, obtain polyvinyl alcohol, chitosan,
Sodium Hyaluronate, the mixed solution of nutrient solution are as spinning solution；
6）By step 5）Gained mixed solution carries out Multi needle electrostatic spinning, using facial mask by the use of non-woven fabrics base material as receiving screen,
One layer of nano fibrous membrane is finally formed on mask nonwoven fabric base material, composite cellulosic membrane is made；
7）Above-mentioned composite cellulosic membrane is dried 2-5 minutes at 70-80 DEG C；
8）Cut, shape, pack and sterilize.
2. preparation method according to claim 1, it is characterised in that step 2）The carboxymethyl chitosan is that carboxylation degree is
83.58%th, relative molecular weight is more than 5000 chitosan.
3. preparation method according to claim 1, it is characterised in that step 4）The herbal raw material for water pears, cucumber,
One or more kinds of raw materials in lemon, sweet orange, mango, carrot, Flos Chrysanthemi or aloe are with any than mixing.
4. preparation method according to claim 1, it is characterised in that step 5）The polyvinyl alcohol：Chitosan：Hyalomitome
Sour sodium：Sericin weight ratio is 1:0.05-0.1:0.01-0.05:0.1-0.5.
5. preparation method according to claim 1, it is characterised in that step 6）The method of the electrostatic spinning specifically,
With 0.9mm tack pins, the voltage of 10-20kV, the distance of 8-15cm.
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Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108685722A (en) * | 2018-07-06 | 2018-10-23 | 佛山皖阳生物科技有限公司 | A kind of preparation method of face mask substrate material |
| CN109234827A (en) * | 2018-09-26 | 2019-01-18 | 冷秀红 | A kind of preparation method of the face paper using the siliceous binding material of rose-red |
| CN109431821A (en) * | 2018-12-26 | 2019-03-08 | 河南工程学院 | A kind of nanofiber facial mask of the shale containing opal and preparation method thereof |
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| CN109234827A (en) * | 2018-09-26 | 2019-01-18 | 冷秀红 | A kind of preparation method of the face paper using the siliceous binding material of rose-red |
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| CN109431821B (en) * | 2018-12-26 | 2021-07-16 | 河南工程学院 | Nano-fiber mask containing opal shale and preparation method thereof |
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| CN112626712A (en) * | 2019-10-08 | 2021-04-09 | 轴心纤维有限公司 | Polysaccharide and protein nanofiber matrices with functional ingredients for skin care products |
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| CN113930897A (en) * | 2021-04-02 | 2022-01-14 | 武汉纺织大学 | Water-soluble non-woven fabric mask and preparation method thereof |
| CN113679618A (en) * | 2021-08-04 | 2021-11-23 | 长春工业大学 | Preparation method of gelatinized modified fiber electrostatic spinning mask |
| CN113882088A (en) * | 2021-09-28 | 2022-01-04 | 盐城工业职业技术学院 | Method for preparing functional facial mask material by extracting sericin from castor silkworm silk gland |
| CN114481441A (en) * | 2021-12-16 | 2022-05-13 | 西安工程大学 | Nano-fiber mask base cloth containing fibroin, functional mask and preparation method of functional mask |
| CN115252518A (en) * | 2022-07-28 | 2022-11-01 | 上海应用技术大学 | Instant plant extract/polymer composite fiber membrane and preparation thereof |
| CN115607458A (en) * | 2022-10-13 | 2023-01-17 | 厦门净境新材料科技有限公司 | Preparation method of efficient moisturizing invisible mask |
| CN115569083A (en) * | 2022-10-21 | 2023-01-06 | 浙江凯燕护理用品科技有限公司 | High-water-content antibacterial sanitary wet tissue and preparation method thereof |
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