CN109431821A - A kind of nanofiber facial mask of the shale containing opal and preparation method thereof - Google Patents
A kind of nanofiber facial mask of the shale containing opal and preparation method thereof Download PDFInfo
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- CN109431821A CN109431821A CN201811603339.5A CN201811603339A CN109431821A CN 109431821 A CN109431821 A CN 109431821A CN 201811603339 A CN201811603339 A CN 201811603339A CN 109431821 A CN109431821 A CN 109431821A
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- opal
- shale
- facial mask
- polyethylene glycol
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0212—Face masks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8129—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers or esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers, e.g. polyvinylmethylether
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/965—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of inanimate origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/005—Antimicrobial preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0061—Electro-spinning characterised by the electro-spinning apparatus
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0061—Electro-spinning characterised by the electro-spinning apparatus
- D01D5/0092—Electro-spinning characterised by the electro-spinning apparatus characterised by the electrical field, e.g. combined with a magnetic fields, using biased or alternating fields
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
- D04H1/72—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged
- D04H1/728—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged by electro-spinning
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Engineering & Computer Science (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Textile Engineering (AREA)
- Dermatology (AREA)
- Mechanical Engineering (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a kind of nanofiber facial masks of shale containing opal, are made of the raw material of following mass fraction: polyvinyl alcohol 2%-14%, polyethylene glycol 1%-10%, sericin 1%-40%, opal shale 0.01%-1%, surplus are deionized water.Opal shale is dispersed in polyvinyl alcohol, polyethylene glycol, in sericin blend solution by ultrasonic generator, through electrostatic spinning technique, uses facial mask to use non-woven fabrics base material as receiving screen, prepares the nanofiber facial mask of the shale containing opal.Nanofiber facial mask provided by the invention has specific surface area high, and adsorption capacity is superpower, can thoroughly remove Firm deep layer dirt and grease, the effect of making skin keep sufficient clean conditions, can also skin whitening, compared with existing cleaning pack, ease of use and comfort level are greatly promoted.
Description
Technical field
The present invention relates to facial mask technical fields, and in particular to a kind of nanofiber facial mask of the shale containing opal and its preparation
Method.
Background technique
It grows to even greater heights with the improvement of people ' s living standards and to the pursuit of health, along with the high speed of dermatology is sent out
Exhibition, more and more people start skin care, and focus on the quality and functionality of cosmetics.Facial mask is the cosmetics of facial skin care,
User is attached at face, apply to face by the beautifying liquid on facial mask with special efficacy and be protected for a long time
It holds and on the face, is obtaining preferably beauty, dressing effect.
Existing cleaning pack mainly has exfoliated, smear type and three kinds of patch type.Exfoliated cleaning pack is due to shelling
From when to skin irritatin and injure it is larger, be easy to cause pore coarse and cutis laxa, should not be commonly used.Smear type clean surface
For film based on curried jelly mixing paste pureed, cleaning dynamics is stronger, but in the process of cleaning, be easy it is dry and cracked be difficult to clean, need not
It rubs disconnectedly and pulls face, long-time service be easy to cause stimulation, skin not to tolerate, phenomena such as general red dry occurs in face.Patch
Formula cleaning pack is all to allow adhere to the bamboo charcoal ingredient containing adsorptivity in woven fabric, by being attached to for a period of time based on black flour film
Face's skin permeation reaches the skin care process of adsorption function and short time, smaller to skin irritatin, but due to bamboo charcoal hole itself
Gap structure be it is grid-like, so fibre porosity is low during facial mask is made, the ability for adsorbing pore dirt is poor, cleaning
Dynamics is weaker.
Summary of the invention
For existing cleaning pack cleaning dynamics is inadequate, big to skin irritation, usage experience is poor, cleans inconvenience
Problem, the purpose of the present invention is to provide it is a kind of can thoroughly cleaning skin deep layer dirt and grease, mildly do not stimulate, it is easy to use
Nanofiber facial mask.
The present invention is realized by following technical proposals:
A kind of nanofiber facial mask of the shale containing opal, is made: polyvinyl alcohol 2%- of the raw material of following mass fraction
14%, polyethylene glycol 1%-10%, sericin 1%-40%, opal shale 0.01%-1%, surplus are deionized water.
Further, the polyvinyl alcohol is PVA1797 type, alcoholysis degree 96.0%-98.0%.
Further, the molecular weight of the polyethylene glycol is 2000~10000.
A kind of preparation method of the nanofiber facial mask of the shale containing opal, comprising the following steps:
Step 1: the preparation of polyvinyl alcohol, polyethylene glycol, sericin blend solution: by polyvinyl alcohol and polyethylene glycol
It is respectively dissolved in distilled water, 80 ± 5 DEG C of magnetic agitation 8h or more, is configured to solution, then two kinds of solution are mixed in proportion, it is cold
But, it is added silk gum, 4h is dissolved in 50-60 DEG C of water-bath, cooling polyvinyl alcohol, polyethylene glycol, sericin blend solution；
Step 2: the preparation of electrostatic spinning liquid: opening ultrasonic generator, polyvinyl alcohol, poly- second is added in opal shale
In glycol, sericin blend solution, power 220-260W, ultrasonic 0.5-1h keep opal Shale Dispersion uniform, obtain Static Spinning
Silk liquid；
Step 3: the preparation of the nanofiber facial mask of the shale containing opal: through electrostatic spinning technique, using facial mask nonwoven
The nanofiber facial mask of the shale containing opal is prepared as receiving screen in cloth base material.
Further, the process conditions of electrostatic spinning are electrostatic high-pressure 5-40kV, distance 5-25cm, speed 0.15ml/h-
1.5ml/h。
Opal shale is rich in a variety of benthon compositions and minerals, opal light page necessary for human skin
The distinctive nanometer cavernous structure of rock has adsorption capacity free from worldly cares, can thoroughly remove deep skin dirt and grease, protect skin
Sufficient clean conditions are held, further to absorb other nutrition skin-protection compositions.
Polyvinyl alcohol is a kind of widely used water soluble polymer, has good water solubility, film forming, sticks
The performances such as grease resistance and the solvent resistant of power and brilliance are tied, and non-toxic and tasteless, to no skin irritation, skin allergy will not be caused
Compound.
The main component of sericin is serine, and in addition there are asparatate, glutamic acid, alanine, glycine.Make
For native protein, the biocompatibility of silk gum, compatibility have gained public acceptance.Sericin has moisturizing, antibacterial, anti-oxidant, anti-
Blood coagulation and the biological natures such as promotion cell adherence and proliferation, grow with good the cell promoted at burn or traumatic wounds
Effect.Moreover, silk gum has hydrophily and degradability, is ideal bio-medical material.
It is nontoxic, nonirritant using polyethylene glycol (PEG), there is good water solubility, and have with many organic matter components
Good intermiscibility can obtain biggish enthalpy of phase change by the transformation of amorphous state to crystalline state at normal temperature, and with latent heat
Form absorb, storage, release, can be used as phase change energy storage function group.
Compared with the prior art, the invention has the following beneficial effects:
(1) the nanofiber facial mask of the shale provided by the invention containing opal has by the nanofiber that Static Spinning obtains
Have a high specific surface area, porosity is high, simultaneously because opal shale be evenly distributed on fiber surface and inside, Bu Huifa
Raw aggregation, is firmly combined with nanofiber, not easily runs off in preparation and use process, adsorption capacity is superpower, polyethylene glycol used
Compatilizer and moisturizer are served not only as, since at normal temperature biggish phase can be obtained by the transformation of amorphous state to crystalline state
Become enthalpy, when being pasted on skin, skin can be promoted to heat up, expand pore, blood circulation is accelerated, thus can adsorb deep layer dirt
Dirt and grease, blackhead, cleaning dynamics are far longer than existing patch type bamboo charcoal black flour film；
(2) sericin of the nanofiber facial mask of the shale provided by the invention containing opal, addition has excellent tune
Wet, moisture retention, biocompatibility, inoxidizability and the effect for promoting cell adherence and proliferation, additionally have natural antibacterial
Effect, so that the nanofiber facial mask of the shale containing opal can play anti-inflammatory, antianaphylactic function while deep layer cleaning
Effect has damping, moisture-keeping function, prevents dry skin, itch, inhibits dermal melanin to be formed, plays whitening function, in silk gum
Amino acid can be absorbed by the skin, supplement the nutrients, pore refining, make skin keep pale, soft, smooth, high resilience；
(3) the nanofiber facial mask of the shale provided by the invention containing opal is prepared using electrostatic spinning technique, Neng Gouyou
The fine structure of effect regulation fiber is not required to add since opal shale and sericin all have natural bacteriostasis efficacy
Adding preservative agent, it is at low cost, it does not stimulate mildly, after when use only needs cleaning skin, is sprayed on nanofiber facial mask using clear water,
It directly applies on the face, compared with existing cleaning pack, ease of use and comfort level are greatly promoted.
Detailed description of the invention
Fig. 1 is the scanning electron microscope diagram for the nanofiber facial mask that embodiment 2 prepares gained shale containing opal.
Specific embodiment
Further to illustrate technological means and its effect adopted by the present invention, below in conjunction with drawings and the specific embodiments
It is described in detail.
Embodiment 1
A kind of nanofiber facial mask of the shale containing opal, is made of the raw material of following mass fraction: polyvinyl alcohol 12%,
Polyethylene glycol 1%, sericin 25%, opal shale 0.02%, surplus are deionized water.
Further, the polyvinyl alcohol is PVA1797 type, alcoholysis degree 96.0%-98.0%.
Further, the molecular weight of the polyethylene glycol is 10000.
A kind of preparation method of the nanofiber facial mask of the shale containing opal, comprising the following steps:
Step 1: the preparation of polyvinyl alcohol, polyethylene glycol, sericin blend solution: by polyvinyl alcohol and polyethylene glycol
It is respectively dissolved in distilled water, 80 ± 5 DEG C of magnetic agitation 8h or more, is configured to solution, then two kinds of solution are mixed in proportion, it is cold
But, it is added silk gum, 4h is dissolved in 50-60 DEG C of water-bath, cooling polyvinyl alcohol, polyethylene glycol, sericin blend solution；
Step 2: the preparation of electrostatic spinning liquid: opening ultrasonic generator, polyvinyl alcohol, poly- second is added in opal shale
In glycol, sericin blend solution, power 220W, ultrasonic 1h keep opal Shale Dispersion uniform, obtain electrostatic spinning liquid；
Step 3: the preparation of the nanofiber facial mask of the shale containing opal: through electrostatic spinning technique, using facial mask nonwoven
The nanofiber facial mask of the shale containing opal is prepared as receiving screen in cloth base material.
Further, the process conditions of electrostatic spinning are electrostatic high-pressure 5-40kV, distance 5-25cm, speed 0.15ml/h-
1.5ml/h。
Embodiment 2
A kind of nanofiber facial mask of the shale containing opal, is made of the raw material of following mass fraction: polyvinyl alcohol 8%,
Polyethylene glycol 2%, sericin 30%, opal shale 0.06%, surplus are deionized water.
Further, the polyvinyl alcohol is PVA1797 type, alcoholysis degree 96.0%-98.0%.
Further, the molecular weight of the polyethylene glycol is 4000.
A kind of preparation method of the nanofiber facial mask of the shale containing opal, comprising the following steps:
Step 1: the preparation of polyvinyl alcohol, polyethylene glycol, sericin blend solution: by polyvinyl alcohol and polyethylene glycol
It is respectively dissolved in distilled water, 80 ± 5 DEG C of magnetic agitation 8h or more, is configured to solution, then two kinds of solution are mixed in proportion, it is cold
But, it is added silk gum, 4h is dissolved in 50-60 DEG C of water-bath, cooling polyvinyl alcohol, polyethylene glycol, sericin blend solution；
Step 2: the preparation of electrostatic spinning liquid: opening ultrasonic generator, polyvinyl alcohol, poly- second is added in opal shale
In glycol, sericin blend solution, power 240W, ultrasonic 0.7h keep opal Shale Dispersion uniform, obtain electrostatic spinning liquid；
Step 3: the preparation of the nanofiber facial mask of the shale containing opal: through electrostatic spinning technique, using facial mask nonwoven
The nanofiber facial mask of the shale containing opal is prepared as receiving screen in cloth base material.
Further, the process conditions of electrostatic spinning are electrostatic high-pressure 5-40kV, distance 5-25cm, speed 0.15ml/h-
1.5ml/h。
Embodiment 3
A kind of nanofiber facial mask of the shale containing opal, is made of the raw material of following mass fraction: polyvinyl alcohol 4%,
Polyethylene glycol 10%, sericin 13%, opal shale 0.8%, surplus are deionized water.
Further, the polyvinyl alcohol is PVA1797 type, alcoholysis degree 96.0%-98.0%.
Further, the molecular weight of the polyethylene glycol is 2000.
A kind of preparation method of the nanofiber facial mask of the shale containing opal, comprising the following steps:
Step 1: the preparation of polyvinyl alcohol, polyethylene glycol, sericin blend solution: by polyvinyl alcohol and polyethylene glycol
It is respectively dissolved in distilled water, 80 ± 5 DEG C of magnetic agitation 8h or more, is configured to solution, then two kinds of solution are mixed in proportion, it is cold
But, it is added silk gum, 4h is dissolved in 50-60 DEG C of water-bath, cooling polyvinyl alcohol, polyethylene glycol, sericin blend solution；
Step 2: the preparation of electrostatic spinning liquid: opening ultrasonic generator, polyvinyl alcohol, poly- second is added in opal shale
In glycol, sericin blend solution, power 260W, ultrasonic 0.5h keep opal Shale Dispersion uniform, obtain electrostatic spinning liquid；
Step 3: the preparation of the nanofiber facial mask of the shale containing opal: through electrostatic spinning technique, using facial mask nonwoven
The nanofiber facial mask of the shale containing opal is prepared as receiving screen in cloth base material.
Further, the process conditions of electrostatic spinning are electrostatic high-pressure 5-40kV, distance 5-25cm, speed 0.15ml/h-
1.5ml/h。
Fig. 1 is the scanning electron microscope diagram of the nanofiber facial mask of 2 gained shale containing opal of embodiment, can be seen
Out, opal shale nano particle is uniformly distributed in fiber surface and inside, fiber surface smoother, without beading phenomenon,
Diameter distribution is also very uniform.
Comparative example 1
In addition to without opal shale, remaining is the same as embodiment 2.
Comparative example 2
In addition to without polyethylene glycol, remaining is the same as embodiment 2.
Comparative example 3
In addition to without sericin, remaining is the same as embodiment 2.
Clinical test
1 object and method
1.1 research objects: be included in standard: 1. 18~35 years old skin of face has phenomena such as fuel-displaced, pigmentation, the colour of skin is gloomy
Female subjects；2. this research of voluntary participation simultaneously signs informed consent form.Exclusion criteria: 1. have to ingredient any in this product
Allergies person；2. gestation or breast feeding women；3. using (for oral administration or external application) steroid drugs or antihistaminic medicine in the recent period
Object person；4. having systemic disease or skin patient；5. this product person cannot be used as required；6. cannot follow-up person on time.
1.2 research method
1.2.1 skin care item source and type: the commercially available bamboo charcoal black flour film with cleaning function；The embodiment of the present invention 1~3 is made
The nanofiber facial mask of the standby obtained shale containing opal；The nanofiber facial mask that comparative example 1~3 is prepared.
1.2.2 all subjects subject's group technology: are randomly divided into 7 groups, i.e. control group, test by table of random number
Group 1~3, contrast groups 1~3.Control group number 30,1 number 29 of test group, 2 number 30 of test group, 3 number 29 of test group, comparison
1 number 32 of group, 2 number 29 of contrast groups, 3 number 28 of contrast groups, selecting grease gland forehead abundant is recipient site, and three groups tested
Forehead applies corresponding facial mask to person after face cleaning before sleeping daily, and control group uses the commercially available bamboo charcoal black flour with cleaning function
Film, the nanofiber facial mask for the shale containing opal that test group is prepared using the embodiment of the present invention 1~3, contrast groups use
The nanofiber facial mask that comparative example 1~3 is prepared.Entire research continues 12 weeks, and during which forehead is without using other cleanings and beauty
White product.
1.2.3 cleanliness testing and photo are left and taken: the moisture of (W0) test subject's forehead skin respectively contains before test
Amount, fat content, sophistication, smoothness, harmful bacteria content, (W2) after 2 weeks, (W4) after 4 weeks, (W8) after 8 weeks, after 12 weeks
(W12) test above-mentioned items respectively again, and by each group test before be compared on the basis of (W0) test result, indicate to mention with "+"
Height, "-" indicate reduce, " 0 " indicates no significant change, every time test before use digital camera (Coolpix 5700, Nikon,
Japan) leave and take the photo of subject's forehead normotopia.
1.2.4 skin-whitening is assessed
In the dermatologist that W2, W4, W8, W12 do not participate in this test by one according to photo to subject's forehead skin
The improvement degree of color is evaluated, and is divided into and is obviously improved, moderate improvement, slightly improves and without four grades of improvement.
3 results
3.2 skin cleanliness testings the results are shown in Table 1.
1 three groups of subject's forehead skin test result statistics of table
3.3 skin-whitening assessment results are shown in Table 2.
2 three groups of subject's forehead skin color improvement statistics of table
This test discovery test group and skin test result and color the improvement statistics of control group have statistics poor
Different (P < 0.05), and have different degrees of improvement using experimenter's skin of the application test group 1~3, illustrate that the application provides
The shale containing opal nanofiber facial mask can thorough cleaning skin, reduce fat secretion, have moisturizing, whitening, antibacterial function
Effect, and with using the time to extend, effect increases, and skin sophistication and smoothness are improved.
From the number in the skin test result table 1 and skin colour improvement table 2 of test group 1~3 and contrast groups 1~3
According to it is found that the every test result and skin colour improvement of test group 1~3 are superior to contrast groups, contrast groups 1 are free of albumen
The cleaning effect of stone shale, facial mask substantially reduces, and antibiotic property also weakens, and since cleaning is not thorough, skin is inhaled from sericin
The nutrition of receipts is few, and color improvement is also poor；Contrast groups 2 are free of polyethylene glycol, and the compatibility of facial mask declines, hair when use
Hole is not easy to open, and cleaning, moisturizing and color improvement is caused to be deteriorated；Contrast groups 3 are free of sericin, and cleaning efficacy declines not
Obviously, but antibacterial effect is poor, and moisturizing and white-skinned face function cannot achieve.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, ability
Other modifications or equivalent replacement that domain those of ordinary skill makes technical solution of the present invention, without departing from skill of the present invention
The spirit and scope of art scheme, are intended to be within the scope of the claims of the invention.
Claims (5)
1. a kind of nanofiber facial mask of shale containing opal, which is characterized in that be made of the raw material of following mass fraction: poly- second
Enol 2%-14%, polyethylene glycol 1%-10%, sericin 1%-40%, opal shale 0.01%-1%, surplus are deionized water.
2. the nanofiber facial mask of the shale according to claim 1 containing opal, which is characterized in that the polyvinyl alcohol is
PVA1797 type, alcoholysis degree 96.0%-98.0%.
3. the nanofiber facial mask of the shale according to claim 1 containing opal, which is characterized in that the polyethylene glycol
Molecular weight is 2000-10000.
4. a kind of preparation method of the nanofiber facial mask of the shale according to claim 1 containing opal, which is characterized in that
The following steps are included:
Step 1: the preparation of polyvinyl alcohol, polyethylene glycol, sericin blend solution: respectively by polyvinyl alcohol and polyethylene glycol
It is dissolved in distilled water, 80 ± 5 DEG C of 8 h or more of magnetic agitation, is configured to solution, then two kinds of solution are mixed in proportion, it is cold
But, it is added silk gum, 4 h are dissolved in 50-60 DEG C of water-bath, cooling polyvinyl alcohol, polyethylene glycol, sericin blend solution；
Step 2: the preparation of electrostatic spinning liquid: open ultrasonic generator, by opal shale be added polyvinyl alcohol, polyethylene glycol,
In sericin blend solution, power 220-260 W, ultrasonic 0.5-1 h keep opal Shale Dispersion uniform, obtain electrostatic spinning
Liquid；
Step 3: the preparation of the nanofiber facial mask of the shale containing opal: through electrostatic spinning technique, using facial mask nonwoven fabric base
The nanofiber facial mask of the shale containing opal is prepared as receiving screen in material.
5. the preparation method of the nanofiber facial mask of the shale according to claim 4 containing opal, which is characterized in that electrostatic
The process conditions of spinning are electrostatic high-pressure 5-40kV, distance 5-25cm, speed 0.15ml/h-1.5ml/h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811603339.5A CN109431821B (en) | 2018-12-26 | 2018-12-26 | Nano-fiber mask containing opal shale and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811603339.5A CN109431821B (en) | 2018-12-26 | 2018-12-26 | Nano-fiber mask containing opal shale and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109431821A true CN109431821A (en) | 2019-03-08 |
| CN109431821B CN109431821B (en) | 2021-07-16 |
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ID=65537598
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811603339.5A Active CN109431821B (en) | 2018-12-26 | 2018-12-26 | Nano-fiber mask containing opal shale and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113558998A (en) * | 2021-09-01 | 2021-10-29 | 浙江理工大学绍兴柯桥研究院有限公司 | Nanofiber mask and preparation method thereof |
| CN115025005A (en) * | 2022-06-01 | 2022-09-09 | 佛山拜澳生物科技有限公司 | Electrostatic spinning nanofiber mask capable of reducing skin residues and preparation method thereof |
| CN115670966A (en) * | 2022-11-09 | 2023-02-03 | 余姚市龙翔水刺热轧无纺有限公司 | Moisturizing mask base cloth and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101268989A (en) * | 2007-03-22 | 2008-09-24 | 姚璐佳 | Health skin-care agent of opal light shale powder |
| JP2010100577A (en) * | 2008-10-24 | 2010-05-06 | Beanz Kenkyusho:Kk | Warmth-providing cosmetic |
| KR20140039370A (en) * | 2012-09-20 | 2014-04-02 | 대한민국(농촌진흥청장) | Cosmetic composition including hydrolysate from silkworm gland |
| CN105504884A (en) * | 2014-07-21 | 2016-04-20 | 北京依依星科技有限公司 | Method of preparing TiO2/opal composite powder |
| CN106726628A (en) * | 2016-11-22 | 2017-05-31 | 惠州市申天地生物科技有限公司 | Negative ion far-infrared multifunctional nano material |
| CN107898716A (en) * | 2018-01-19 | 2018-04-13 | 河南工程学院 | A kind of preparation method of nanofiber dry type facial mask |
| CN108339516A (en) * | 2018-01-27 | 2018-07-31 | 中国矿业大学(北京) | A kind of iron-removal and whitening method of opoka |
-
2018
- 2018-12-26 CN CN201811603339.5A patent/CN109431821B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101268989A (en) * | 2007-03-22 | 2008-09-24 | 姚璐佳 | Health skin-care agent of opal light shale powder |
| JP2010100577A (en) * | 2008-10-24 | 2010-05-06 | Beanz Kenkyusho:Kk | Warmth-providing cosmetic |
| KR20140039370A (en) * | 2012-09-20 | 2014-04-02 | 대한민국(농촌진흥청장) | Cosmetic composition including hydrolysate from silkworm gland |
| CN105504884A (en) * | 2014-07-21 | 2016-04-20 | 北京依依星科技有限公司 | Method of preparing TiO2/opal composite powder |
| CN106726628A (en) * | 2016-11-22 | 2017-05-31 | 惠州市申天地生物科技有限公司 | Negative ion far-infrared multifunctional nano material |
| CN107898716A (en) * | 2018-01-19 | 2018-04-13 | 河南工程学院 | A kind of preparation method of nanofiber dry type facial mask |
| CN108339516A (en) * | 2018-01-27 | 2018-07-31 | 中国矿业大学(北京) | A kind of iron-removal and whitening method of opoka |
Non-Patent Citations (3)
| Title |
|---|
| 吴赞敏: "《纺织品清洁染整加工技术》", 31 January 2007 * |
| 广州市白云区美莲葆化妆品厂: "粤G妆网备字2015053399 天姿曼蓝魅之夜滋养修护面膜", 《国产非特殊用途化妆品备案信息服务平台》 * |
| 杨力等: "《组织修复生物力学》", 31 December 2017 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113558998A (en) * | 2021-09-01 | 2021-10-29 | 浙江理工大学绍兴柯桥研究院有限公司 | Nanofiber mask and preparation method thereof |
| CN115025005A (en) * | 2022-06-01 | 2022-09-09 | 佛山拜澳生物科技有限公司 | Electrostatic spinning nanofiber mask capable of reducing skin residues and preparation method thereof |
| CN115670966A (en) * | 2022-11-09 | 2023-02-03 | 余姚市龙翔水刺热轧无纺有限公司 | Moisturizing mask base cloth and preparation method thereof |
| CN115670966B (en) * | 2022-11-09 | 2023-10-03 | 余姚市龙翔水刺热轧无纺有限公司 | Moisturizing facial mask base cloth and preparation method thereof |
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