CN107823078A

CN107823078A - A kind of functional form shampoo

Info

Publication number: CN107823078A
Application number: CN201711046601.6A
Authority: CN
Inventors: 刘蓉凤; 殷小祥; 张琳
Original assignee: Changzhou City Taeyoung Material Co Ltd
Current assignee: Changzhou City Taeyoung Material Co Ltd
Priority date: 2017-10-31
Filing date: 2017-10-31
Publication date: 2018-03-23

Abstract

A kind of functional form shampoo of disclosure of the invention, belongs to daily cosmetics technical field.Massage bead is mixed immersion with dopamine solution by the present invention, is filtered, is obtained pretreatment massage bead；20~30 parts of pretreatment massage beads, grease, lipase, keratin, keratinase are stirred, filter, produce single treatment massage bead；Single treatment massage bead and chitosan liquid are stirred, freezing, thaw cycles, filtering, produce modified massage bead；Surfactant, thickener, cosolvent, preservative, buffer, essence, pigment, water, modified massage bead, silkworm chrysalis juice are added in batch mixer, be stirred, produce functional form shampoo.Functional form shampoo provided by the invention has excellent performance, can promote natural on-off cycles of hair growth, and has antipruritic, anti-dandruff, the effect of hair care.

Description

A kind of functional form shampoo

Technical field

The invention discloses a kind of functional form shampoo, belong to daily cosmetics technical field.

Background technology

Shampoo refers to a kind of hair products with functions such as anti-dandruff function, treatment oil function and hair dyeings.In shampoo Containing Multiple components, the comprehensive function of these compositions can play the function of cleaning scalp and hair.

Most active composition is surfactant in usual shampoo, and surfactant plays cleaning hair and scalp Effect, can produce foam when shampoo and water mix, but foam number can not reflect cleaning capacity It is strong and weak.Shampoo typically uses the triethanolamine of sulphuric acid fatty alcohol and the salt-mixture of oxyammonia, dodecanoic acid isopropanol amide, first Aldehyde, polyoxyethylene, lanolin, spices, colorant and water are as raw material.

Surfactant in terms of shampoo mainly has：Sodium sulfate of polyethenoxy ether of fatty alcohol AES（Ammonium）, coconut oil Diglycollic amide, glycine betaine, quaternary amine softening agent, amino acid surfactant, SLS and some functional additives：Silicone Smooth brightener, climbazole anti-dandruff only ancient term for country school agent, pearling agent, preservative, essence, pigment etc..

The basic function of shampoo is exactly to clean, at all helpless the problems such as to pathologic dandruff, alopecia, a lot " work( Energy " the amusement that only businessman promotes.The shampoo bought at present, if it is submissive to pursue hair, be just easy to make hair it is greasy, It is dirty, collapse.Want to pursue hair it is salubrious, be easy to make again hair coarse, do, disperse, repairing performance it is poor.Both inherently lance each other Shield, it is difficult to obtain simultaneously.

When consumer selects shampoo, first have to understand the hair quality characteristic of oneself, be oiliness, neutrality or Dry Hair, The suitable shampoo of reselection；Secondly, to select to be adapted to the brand of oneself, the shampoo formula of different brands can be different, Many shampoos all do not indicate specific composition at present, and the composition marked individually may not also be present.Some shampoos are declared containing soap The traditional Chinese medicine ingredients such as angle, the tuber of multiflower knotweed, Radix Angelicae Sinensis, ginseng, expert represent, medical evidence they to scalp and hair Yellow Gentian Extract, can lead to Cross the mode of washout to scalp and hair whether Yellow Gentian Extract, be not proved also, many businessmans exaggerate this kind of shampoo The effect of.Also there is the problem of function is single in presently commercially available shampoo, can only typically play cleaning action, therefore also need to washing The feature of shampoo is studied.

The content of the invention

The present invention solves the technical problem of：For traditional shampoo function it is single the problem of, there is provided Yi Zhonggong Can type shampoo.

In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is：

A kind of functional form shampoo, is made up of the raw material of following parts by weight：30~40 parts of surfactants, 3~4 parts of thickenings Agent, 3~4 parts of cosolvents, 1~2 portion of preservative, 1~2 part of buffer, 1~2 part of essence, 1~2 part of pigment, 100~120 parts of water, 10~20 parts of modified massage beads, 5~6 parts of silkworm chrysalis juices；

The preparation process of the modified massage bead is：

（1）By massage bead and dopamine solution in mass ratio 1：50~1：100 mixing immersions, filtering, obtain pretreatment massage bead；

（2）Count in parts by weight, by 20~30 parts pre-process massage beads, 8~10 parts of greases, 0.1~0.2 part of lipase, 5~6 Part keratin, 0.1~0.2 part of keratinase are stirred, and are filtered, are produced single treatment massage bead；

（3）Single treatment massage bead and chitosan liquid are stirred, freezing, thaw cycles, filtering, produce modified massage bead.

The surfactant is neopelex, appointing in laureth sodium sulphate or imidazolinium betaine Meaning is a kind of.

The thickener is ammonium chloride, any one in sodium chloride or two phthalic acid amides.

The cosolvent is propane diols, any one in glycerine or 1,3-BDO.

The preservative is methyl hydroxybenzoate, any one in methylisothiazolinone or methylchloroisothiazandnone.

The buffer is citric acid, any one in tartaric acid or sulfonic acid.

The essence is lemonene, lavender is fragrant or daisy rice perfume (or spice) in any one.

The pigment is lemon yellow, any one in carmine or sunset yellow.

Step（1）The preparation process of the massage bead is：Count in parts by weight, take 20~30 parts of ferric chloride solutions successively, 10~20 parts of sponge powders, 0.1~0.2 part of hydrochloric acid, 10~20 parts of ammoniacal liquor, by ferric chloride solution, sponge powder, hydrochloric acid is stirred, Filtering, obtains filter residue, and gained filter residue is added in ammoniacal liquor, filtering, high-temperature calcination, produces massage bead；The sponge powder is by sponge powder Broken, sieving obtains.

Step（3）The preparation process of the chitosan liquid is：By chitosan and water in mass ratio 1：50~1：100 mixing are molten After swollen, heating stirring dissolving, chitosan liquid is produced.

The beneficial effects of the invention are as follows：

（1）The present invention is by adding modified massage bead, in use, firstly, since massage bead has loose structure, and table Face covers one layer of chitosan film, plays good massage effect, allows people to be comfortable on, and stimulates circulation so that hair is sent out Root absorbs more nutrients, promotes natural on-off cycles of hair growth, meanwhile, ferroso-ferric oxide has magnetic, caused magnetic field, to increase in massage bead Add internal anion, negative ions are in poised state in adjusting body, and reach active blood, promote oxygen content of blood, carry High efficacy of immunity, during hair washing is rubbed, chitosan film rupture so that lipase and keratinase in system ooze out, Grease in hair, scalp surface and hair follicle is resolved into glycerine and aliphatic acid by lipase, and glycerine has moisture-keeping function, fat Acid has an emulsification, and keratinase is by dead skin breaks down into amino acids in hair and scalp surface, on the one hand, amino acid has newborn Change acts on, and strengthens shampoo clean effect, and on the other hand, during rubbing, hair follicle expansion, amino acid penetrates into hair follicle root, Nutrient is provided for natural on-off cycles of hair growth, promotes natural on-off cycles of hair growth；

（2）The present invention is by adding silkworm chrysalis juice, during hair washing is rubbed, on the one hand, have antipruritic, anti-dandruff, the work of hair care With after the active ingredient in silkworm chrysalis juice is absorbed by hair follicle, providing nutrient for natural on-off cycles of hair growth, promote natural on-off cycles of hair growth.

Embodiment

Sponge is placed in sponge pulverizer and crushed, the sieve of 40~50 mesh is crossed, obtains sponge powder；By silkworm chrysalis and water in mass ratio 1：10~1：20 are placed in juice extractor, squeeze the juice, and obtain silkworm chrysalis juice；Count in parts by weight, it is 20 to take 20~30 parts of mass fractions successively ~30% ferric chloride solution, 10~20 parts of sponge powders, the hydrochloric acid that 0.1~0.2 part of mass fraction is 8~10%, 10~20 parts of matter The ammoniacal liquor that fraction is 20~30% is measured, by the ferric chloride solution that mass fraction is 20~30%, sponge powder, mass fraction is 8~10% Hydrochloric acid be placed in No. 1 beaker, in rotating speed be 300~400r/min under the conditions of, after being stirred 20~30min, mixed liquor, then Mixed liquor is filtered, obtains filter residue, then gained filter residue is placed in the ammoniacal liquor that mass fraction is 20~30%, in rotating speed be 300~ Under the conditions of 400r/min, 20~30min is stirred, is filtered, is obtained reaction solution, then by reacting liquid filtering, obtain filter cake, then will Filter cake is placed in Muffle furnace, and 500~650 DEG C are warming up to 4~6 DEG C/min heating rate, in 500~650 DEG C of conditions of temperature Under, 40~60min of high-temperature calcination, room temperature is down to stove, produces massage bead；By chitosan and water in mass ratio 1：50~1：100 Add in No. 2 beakers, after being stirred 20~30min with glass bar, stand 3~4h of swelling, then No. 2 beakers are moved into digital display and surveyed Fast constant temperature blender with magnetic force, in temperature be 95~100 DEG C, rotating speed be 400~500r/min under the conditions of, heating stirring dissolving 40~ 60min, produce chitosan liquid；Dopamine solution in mass ratio 1 by massage bead with mass concentration for 2g/L：50~1：100 put In No. 3 beakers, under the conditions of rotating speed is 300~400r/min, 40~60min of immersion is stirred, obtains soak, then will leaching Liquid filtering is steeped, obtains pretreatment massage bead；Count in parts by weight, by 20~30 parts pre-process massage beads, 8~10 parts of greases, 0.1~ 0.2 part of lipase, 5~6 parts of keratin, 0.1~0.2 part of keratinase are placed in No. 4 beakers, in rotating speed be 300~400r/ Under the conditions of min, 40~60min of immersion is stirred, after being stirred, filtering, produces single treatment massage bead；By single treatment Massage bead is placed in No. 5 beakers with chitosan liquid, under the conditions of rotating speed is 300~400r/min, is stirred 30~50min, Mixed slurry is obtained, then mixed slurry is placed in refrigerator, under the conditions of temperature is -10~-20 DEG C, 2~3h is freezed, must freeze Block, frozen block is then placed in naturally to thaw under room temperature condition, so freezing, thaw cycles 8~10 times, obtains thawing solution, and will Thawing solution filters, and produces modified massage bead；Count in parts by weight, by 30~40 parts of surfactants, 3~4 parts of thickeners, 3~4 Part cosolvent, 1~2 portion of preservative, 1~2 part of buffer, 1~2 part of essence, 1~2 part of pigment, 100~120 parts of water, 10~20 The modified massage bead of part, 5~6 parts of silkworm chrysalis juices are added in batch mixers, under the conditions of rotating speed is 1000~1200r/min, high-speed stirring 30~50min of mixing is mixed, produces functional form shampoo.The surfactant is neopelex, laureth Any one in sodium sulphate or imidazolinium betaine.The thickener is ammonium chloride, sodium chloride or two phthalic acid amides In any one.The cosolvent is propane diols, any one in glycerine or 1,3-BDO.The preservative is Ni Bo Any one in tortoise beetle ester, methylisothiazolinone or methylchloroisothiazandnone.The buffer is citric acid, tartaric acid Or any one in sulfonic acid.The essence is lemonene, lavender is fragrant or daisy rice perfume (or spice) in any one.The pigment is Lemon yellow, any one in carmine or sunset yellow.

Example 1

Sponge is placed in sponge pulverizer and crushed, the sieve of 50 mesh is crossed, obtains sponge powder；By silkworm chrysalis and water in mass ratio 1：20 are placed in Juice extractor, squeeze the juice, obtain silkworm chrysalis juice；Count in parts by weight, take successively 30 parts of mass fractions be 30% ferric chloride solution, 20 parts Sponge powder, the hydrochloric acid that 0.2 part of mass fraction is 10%, the ammoniacal liquor that 20 parts of mass fractions are 30%, by the chlorination that mass fraction is 30% Ferrous solution, sponge powder, the hydrochloric acid that mass fraction is 10% are placed in No. 1 beaker, and under the conditions of rotating speed is 400r/min, stirring is mixed After closing 30min, mixed liquor, then mixed liquor is filtered, filter residue is obtained, then gained filter residue is placed in the ammoniacal liquor that mass fraction is 30%, Under the conditions of rotating speed is 400r/min, 30min is stirred, is filtered, is obtained reaction solution, then by reacting liquid filtering, obtain filter cake, with Filter cake is placed in Muffle furnace afterwards, 650 DEG C are warming up to 6 DEG C/min heating rate, under the conditions of 650 DEG C of temperature, high temperature is forged 60min is burnt, room temperature is down to stove, produces massage bead；By chitosan and water in mass ratio 1：100 add in No. 2 beakers, use glass After rod is stirred 30min, swelling 4h is stood, then No. 2 beakers are moved into digital displays and tested the speed constant temperature blender with magnetic force, be in temperature 100 DEG C, under the conditions of rotating speed is 500r/min, heating stirring dissolving 60min, produce chitosan liquid；By massage bead and mass concentration For 2g/L dopamine solution in mass ratio 1：100 are placed in No. 3 beakers, under the conditions of rotating speed is 400r/min, are stirred 60min is soaked, obtains soak, then soak is filtered, obtains pretreatment massage bead；Count in parts by weight, 30 parts of pretreatments are pressed Rubbed pearl, 10 parts of greases, 0.2 part of lipase, 6 parts of keratin, and 0.2 part of keratinase is placed in No. 4 beakers, in rotating speed be 400r/ Under the conditions of min, immersion 60min is stirred, after being stirred, filtering, produces single treatment massage bead；Single treatment is massaged Pearl is placed in No. 5 beakers with chitosan liquid, under the conditions of rotating speed is 400r/min, is stirred 50min, is obtained mixed slurry, with Mixed slurry is placed in refrigerator afterwards, under the conditions of temperature is -20 DEG C, 3h is freezed, obtains frozen block, frozen block is then placed in room Naturally to thaw under the conditions of temperature, so freezing, thaw cycles 10 times, obtain thawing solution, and thawing solution is filtered, and produce modified massage Pearl；Count in parts by weight, by 40 parts of surfactants, 4 parts of thickeners, 4 parts of cosolvents, 2 portions of preservatives, 2 parts of buffers, 2 parts Essence, 2 parts of pigments, 120 parts of water, 20 parts of modified massage beads, 6 parts of silkworm chrysalis juices are added in batch mixers, in rotating speed be 1200r/min Under the conditions of, high-speed stirred mixing 50min, produce functional form shampoo.The surfactant is neopelex.Institute It is ammonium chloride to state thickener.The cosolvent is propane diols.The preservative is methyl hydroxybenzoate.The buffer is lemon Acid.The essence is lemonene.The pigment is lemon yellow.

Example 2

Sponge is placed in sponge pulverizer and crushed, the sieve of 50 mesh is crossed, obtains sponge powder；By silkworm chrysalis and water in mass ratio 1：20 are placed in Juice extractor, squeeze the juice, obtain silkworm chrysalis juice；Count in parts by weight, take successively 30 parts of mass fractions be 30% ferric chloride solution, 20 parts Sponge powder, the hydrochloric acid that 0.2 part of mass fraction is 10%, the ammoniacal liquor that 20 parts of mass fractions are 30%, by the chlorination that mass fraction is 30% Ferrous solution, sponge powder, the hydrochloric acid that mass fraction is 10% are placed in No. 1 beaker, and under the conditions of rotating speed is 400r/min, stirring is mixed After closing 30min, mixed liquor, then mixed liquor is filtered, filter residue is obtained, then gained filter residue is placed in the ammoniacal liquor that mass fraction is 30%, Under the conditions of rotating speed is 400r/min, 30min is stirred, is filtered, is obtained reaction solution, then by reacting liquid filtering, obtain filter cake, with Filter cake is placed in Muffle furnace afterwards, 650 DEG C are warming up to 6 DEG C/min heating rate, under the conditions of 650 DEG C of temperature, high temperature is forged 60min is burnt, room temperature is down to stove, produces massage bead；By chitosan and water in mass ratio 1：100 add in No. 2 beakers, use glass After rod is stirred 30min, swelling 4h is stood, then No. 2 beakers are moved into digital displays and tested the speed constant temperature blender with magnetic force, be in temperature 100 DEG C, under the conditions of rotating speed is 500r/min, heating stirring dissolving 60min, produce chitosan liquid；Count in parts by weight, by 40 parts Surfactant, 4 parts of thickeners, 4 parts of cosolvents, 2 portions of preservatives, 2 parts of buffers, 2 parts of essence, 2 parts of pigments, 120 parts of water, 20 Part massage bead, 6 parts of silkworm chrysalis juices are added in batch mixers, under the conditions of rotating speed is 1200r/min, high-speed stirred mixing 50min, i.e., Obtain functional form shampoo.The surfactant is neopelex.The thickener is ammonium chloride.The cosolvent For propane diols.The preservative is methyl hydroxybenzoate.The buffer is citric acid.The essence is lemonene.The pigment For lemon yellow.

Example 3

Count in parts by weight, take the ferric chloride solution that 30 parts of mass fractions are 30%, 20 parts of sponge powders, 0.2 part of mass fraction successively For 10% hydrochloric acid, the ammoniacal liquor that 20 parts of mass fractions are 30%, by the ferric chloride solution that mass fraction is 30%, sponge powder, quality point Number is placed in No. 1 beaker for 10% hydrochloric acid, under the conditions of rotating speed is 400r/min, after being stirred 30min, and mixed liquor, then will Mixed liquor is filtered, and obtains filter residue, then gained filter residue is placed in the ammoniacal liquor that mass fraction is 30%, in rotating speed be 400r/min conditions Under, 30min is stirred, is filtered, is obtained reaction solution, then by reacting liquid filtering, obtain filter cake, filter cake is then placed in Muffle furnace In, 650 DEG C are warming up to 6 DEG C/min heating rate, under the conditions of 650 DEG C of temperature, high-temperature calcination 60min, room is down to stove Temperature, produce massage bead；By chitosan and water in mass ratio 1：100 add in No. 2 beakers, after being stirred 30min with glass bar, Stand swelling 4h, then No. 2 beakers moved into digital displays and tested the speed constant temperature blender with magnetic force, in temperature be 100 DEG C, rotating speed 500r/min Under the conditions of, heating stirring dissolving 60min, produce chitosan liquid；Massage bead is pressed with mass concentration for 2g/L dopamine solution Mass ratio 1：100 are placed in No. 3 beakers, under the conditions of rotating speed is 400r/min, is stirred immersion 60min, obtains soak, then Soak is filtered, obtains pretreatment massage bead；Count in parts by weight, massage bead, 10 parts of greases, 0.2 part of fat are pre-processed by 30 parts Fat enzyme, 6 parts of keratin, 0.2 part of keratinase are placed in No. 4 beakers, under the conditions of rotating speed is 400r/min, are stirred immersion 60min, after being stirred, filtering, produce single treatment massage bead；Single treatment massage bead and chitosan liquid are placed in No. 5 burnings In cup, under the conditions of rotating speed is 400r/min, 50min is stirred, mixed slurry is obtained, mixed slurry is then placed in refrigerator In, under the conditions of temperature is -20 DEG C, 3h is freezed, frozen block is obtained, frozen block is then placed in naturally to thaw under room temperature condition, such as This freezing, thaw cycles 10 times, obtain thawing solution, and thawing solution is filtered, and produce modified massage bead；Count in parts by weight, by 40 Part surfactant, 4 parts of thickeners, 4 parts of cosolvents, 2 portions of preservatives, 2 parts of buffers, 2 parts of essence, 2 parts of pigments, 120 parts of water, 20 parts of modified massage beads are added in batch mixer, under the conditions of rotating speed is 1200r/min, high-speed stirred mixing 50min, produce function Type shampoo.The surfactant is neopelex.The thickener is ammonium chloride.The cosolvent is the third two Alcohol.The preservative is methyl hydroxybenzoate.The buffer is citric acid.The essence is lemonene.The pigment is lemon It is yellow.

Comparative example：Certain commercially available brand shampoo.

The gained of example 1 to 3 shampoo and comparative example product are subjected to performance detection, specific detection method is as follows：

Volunteer is used, every group of 5 people, the natural on-off cycles of hair growth length of measurement one month, take its average value.And root Its cardability, flexibility, moisture retention are tested according to GB11432, properties are set to 6 grades, specific as follows：6：Pole It is good；5：It is good；4：Preferably；3：Typically；2：It is poor；1：Difference.

Specific testing result is as shown in table 1：

Table 1

Detection content	Example 1	Example 2	Example 3	Comparative example
					Growth length/cm	5.3	2.5	2.8	1.1
Cardability	5.5	4.5	4.5	3.5
					Flexibility	5.5	4	5	3
Moisture retention	5	4	4	3

From the testing result of table 1, present invention gained feature shampoo can accelerate natural on-off cycles of hair growth, and hair soft can be made suitable It is sliding easily to comb.

Claims

A kind of 1. functional form shampoo, it is characterised in that：It is made up of the raw material of following parts by weight：30~40 parts of surface-actives Agent, 3~4 parts of thickeners, 3~4 parts of cosolvents, 1~2 portion of preservative, 1~2 part of buffer, 1~2 part of essence, 1~2 part of pigment, 100~120 parts of water, 10~20 parts of modified massage beads, 5~6 parts of silkworm chrysalis juices；

The preparation process of the modified massage bead is：

（1）By massage bead and dopamine solution in mass ratio 1：50~1：100 mixing immersions, filtering, obtain pretreatment massage bead；

（2）Count in parts by weight, by 20~30 parts pre-process massage beads, 8~10 parts of greases, 0.1~0.2 part of lipase, 5~6 Part keratin, 0.1~0.2 part of keratinase are stirred, and are filtered, are produced single treatment massage bead；

（3）Single treatment massage bead and chitosan liquid are stirred, freezing, thaw cycles, filtering, produce modified massage bead.
A kind of 2. functional form shampoo according to claim 1, it is characterised in that：The surfactant is detergent alkylate Sodium sulfonate, any one in laureth sodium sulphate or imidazolinium betaine.
A kind of 3. functional form shampoo according to claim 1, it is characterised in that：The thickener is ammonium chloride, sodium chloride Or two any one in phthalic acid amide.
A kind of 4. functional form shampoo according to claim 1, it is characterised in that：The cosolvent is propane diols, glycerine or Any one in 1,3 butylene glycol.
A kind of 5. functional form shampoo according to claim 1, it is characterised in that：The preservative is methyl hydroxybenzoate, first Any one in base OIT or methylchloroisothiazandnone.
A kind of 6. functional form shampoo according to claim 1, it is characterised in that：The buffer is citric acid, tartaric acid Or any one in sulfonic acid.
A kind of 7. functional form shampoo according to claim 1, it is characterised in that：The essence is lemonene, and lavender is fragrant Or any one in daisy rice perfume (or spice).
A kind of 8. functional form shampoo according to claim 1, it is characterised in that：The pigment is lemon yellow, it is carmine or Any one in sunset yellow.
A kind of 9. functional form shampoo according to claim 1, it is characterised in that：Step（1）The preparation of the massage bead Cheng Wei：Count in parts by weight, take 20~30 parts of ferric chloride solutions successively, 10~20 parts of sponge powders, 0.1~0.2 part of hydrochloric acid, 10~ 20 parts of ammoniacal liquor, by ferric chloride solution, sponge powder, hydrochloric acid is stirred, and filtering, obtains filter residue, gained filter residue is added in ammoniacal liquor, mistake Filter, high-temperature calcination, produces massage bead；The sponge powder is crushed by sponge, sieving obtains.
A kind of 10. functional form shampoo according to claim 1, it is characterised in that：Step（3）The preparation of the chitosan liquid Process is：By chitosan and water in mass ratio 1：50~1：After 100 mixing swellings, heating stirring dissolving, chitosan liquid is produced.