CN1077905C - 可激光标识的塑料 - Google Patents
可激光标识的塑料 Download PDFInfo
- Publication number
- CN1077905C CN1077905C CN95192924A CN95192924A CN1077905C CN 1077905 C CN1077905 C CN 1077905C CN 95192924 A CN95192924 A CN 95192924A CN 95192924 A CN95192924 A CN 95192924A CN 1077905 C CN1077905 C CN 1077905C
- Authority
- CN
- China
- Prior art keywords
- laser
- plastics
- pigment
- markable
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920003023 plastic Polymers 0.000 title claims abstract description 54
- 239000004033 plastic Substances 0.000 title claims abstract description 54
- 239000000049 pigment Substances 0.000 claims abstract description 60
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims abstract description 13
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract description 13
- 239000011248 coating agent Substances 0.000 claims description 19
- 238000000576 coating method Methods 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 15
- 239000010445 mica Substances 0.000 claims description 14
- 229910052618 mica group Inorganic materials 0.000 claims description 14
- 229920001169 thermoplastic Polymers 0.000 claims description 13
- 239000004416 thermosoftening plastic Substances 0.000 claims description 11
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 8
- 229910044991 metal oxide Inorganic materials 0.000 claims description 8
- 150000004706 metal oxides Chemical class 0.000 claims description 7
- 229920000570 polyether Polymers 0.000 claims description 7
- 229910052787 antimony Inorganic materials 0.000 claims description 6
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 6
- 239000002178 crystalline material Substances 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 3
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 3
- 229910052785 arsenic Inorganic materials 0.000 claims description 3
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 3
- 229910052797 bismuth Inorganic materials 0.000 claims description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 229910052733 gallium Inorganic materials 0.000 claims description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 229910052732 germanium Inorganic materials 0.000 claims 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims 1
- 238000000465 moulding Methods 0.000 claims 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 22
- 238000002347 injection Methods 0.000 description 18
- 239000007924 injection Substances 0.000 description 18
- 238000010330 laser marking Methods 0.000 description 17
- 239000004408 titanium dioxide Substances 0.000 description 11
- -1 metal oxide compound Chemical class 0.000 description 9
- 239000000203 mixture Substances 0.000 description 7
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 229920000909 polytetrahydrofuran Polymers 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 5
- 241001465754 Metazoa Species 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- QXYJCZRRLLQGCR-UHFFFAOYSA-N dioxomolybdenum Chemical compound O=[Mo]=O QXYJCZRRLLQGCR-UHFFFAOYSA-N 0.000 description 3
- 229920001707 polybutylene terephthalate Polymers 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- XJUNRGGMKUAPAP-UHFFFAOYSA-N dioxido(dioxo)molybdenum;lead(2+) Chemical compound [Pb+2].[O-][Mo]([O-])(=O)=O XJUNRGGMKUAPAP-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000206 moulding compound Substances 0.000 description 2
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920006324 polyoxymethylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- ZEHOVWPIGREOPO-UHFFFAOYSA-N 4,5,6,7-tetrachloro-2-[2-(4,5,6,7-tetrachloro-1,3-dioxoinden-2-yl)quinolin-8-yl]isoindole-1,3-dione Chemical compound O=C1C(C(=C(Cl)C(Cl)=C2Cl)Cl)=C2C(=O)N1C(C1=N2)=CC=CC1=CC=C2C1C(=O)C2=C(Cl)C(Cl)=C(Cl)C(Cl)=C2C1=O ZEHOVWPIGREOPO-UHFFFAOYSA-N 0.000 description 1
- 241000931526 Acer campestre Species 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 241001005836 Euchloe ausonia Species 0.000 description 1
- 229920005176 Hostaform® Polymers 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 229920006097 Ultramide® Polymers 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001495 arsenic compounds Chemical class 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002872 contrast media Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- UVOOBSVIDMVALT-UHFFFAOYSA-L copper hydrogen phosphate hydrate Chemical compound P(=O)(O)([O-])[O-].[Cu+2].O UVOOBSVIDMVALT-UHFFFAOYSA-L 0.000 description 1
- 229960004643 cupric oxide Drugs 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- SVTBMSDMJJWYQN-UHFFFAOYSA-N hexylene glycol Natural products CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 229910052615 phyllosilicate Inorganic materials 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920001643 poly(ether ketone) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 229920006352 transparent thermoplastic Polymers 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/26—Printing on other surfaces than ordinary paper
- B41M1/30—Printing on other surfaces than ordinary paper on organic plastics, horn or similar materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/267—Marking of plastic artifacts, e.g. with laser
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/24—Ablative recording, e.g. by burning marks; Spark recording
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/22—Removing surface-material, e.g. by engraving, by etching
- B44C1/228—Removing surface-material, e.g. by engraving, by etching by laser radiation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Description
抗拉强度/MPa | 断裂伸长率/% | 肖氏A硬度 | 磨损/mm3 |
DIN 53504 | DIN 53504 | DIN53505 | DIN53516 |
50 | 650 | 85 | 30 |
Claims (11)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4415802.5 | 1994-05-05 | ||
DE4415802A DE4415802A1 (de) | 1994-05-05 | 1994-05-05 | Lasermarkierbare Kunststoffe |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1147227A CN1147227A (zh) | 1997-04-09 |
CN1077905C true CN1077905C (zh) | 2002-01-16 |
Family
ID=6517323
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN95192924A Expired - Lifetime CN1077905C (zh) | 1994-05-05 | 1995-05-03 | 可激光标识的塑料 |
Country Status (12)
Country | Link |
---|---|
US (1) | US6214917B1 (zh) |
EP (1) | EP0797511B1 (zh) |
JP (1) | JP3591654B2 (zh) |
KR (1) | KR100347466B1 (zh) |
CN (1) | CN1077905C (zh) |
AT (1) | ATE183142T1 (zh) |
AU (1) | AU690993B2 (zh) |
BR (1) | BR9507704A (zh) |
DE (2) | DE4415802A1 (zh) |
ES (1) | ES2138737T3 (zh) |
WO (1) | WO1995030546A1 (zh) |
ZA (1) | ZA953604B (zh) |
Families Citing this family (94)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6521688B1 (en) * | 1994-05-05 | 2003-02-18 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Laser-markable plastics |
DE19629675A1 (de) | 1996-07-23 | 1998-01-29 | Merck Patent Gmbh | Lasermarkierbare Kunststoffe |
DE19652242A1 (de) | 1996-12-16 | 1998-06-18 | Basf Ag | Verwendung von hydridhaltigem Aluminiumoxid zur Erzeugung von optisch erkennbaren Markierungen und Beschriftungen |
DE19920627A1 (de) * | 1998-05-28 | 1999-12-02 | Merck Patent Gmbh | Pigmentmischung |
US20040056006A1 (en) * | 1998-10-01 | 2004-03-25 | The Welding Institute | Welding method |
CN1257896A (zh) * | 1998-12-23 | 2000-06-28 | 默克专利股份有限公司 | 颜料混合物 |
DE19905415A1 (de) * | 1999-02-10 | 2000-08-17 | Hoechst Trespaphan Gmbh | Transparente biaxial orientierte Polyolefinfolie |
US6710284B1 (en) * | 1999-02-26 | 2004-03-23 | Micron Technology, Inc. | Laser marking techniques for bare semiconductor die |
DE19916467C5 (de) * | 1999-04-12 | 2007-05-16 | Ticona Gmbh | Verfahren zur Herstellung von elektrisch leitenden Schichten an der Oberfläche von Kunststoff-Formteilen durch Laserenergie und damit hergestellter Gegenstand |
US6706785B1 (en) * | 2000-02-18 | 2004-03-16 | Rona/Emi Industries, Inc. | Methods and compositions related to laser sensitive pigments for laser marking of plastics |
DE10018600A1 (de) * | 2000-04-14 | 2001-10-25 | Merck Patent Gmbh | Lasermarkierbare Kunststoffe |
US6371548B1 (en) * | 2000-07-25 | 2002-04-16 | Textron Automotive Company Inc. | Automotive trim panel with electrical wiring incorporated therein |
DE10053639B4 (de) * | 2000-10-28 | 2007-04-12 | Chemische Fabrik Budenheim Kg | Verwendung von Eisen-, Cobalt-, Nickel- oder Molybdänsalzen |
WO2002038677A2 (en) * | 2000-11-10 | 2002-05-16 | Gentex Corporation | Visibly transparent dyes for through-transmission laser welding |
US20050269304A1 (en) * | 2001-02-28 | 2005-12-08 | Nazir Khan | Laser coding |
WO2002068205A1 (en) | 2001-02-28 | 2002-09-06 | Sherwood Technology Ltd. | Laser coding |
GB0104959D0 (en) * | 2001-02-28 | 2001-04-18 | Sherwood Technology Ltd | Laser coding |
EP1657072B3 (en) | 2001-03-16 | 2016-08-31 | DataLase Ltd | Laser-imaging method |
US6693657B2 (en) * | 2001-04-12 | 2004-02-17 | Engelhard Corporation | Additive for YAG laser marking |
DE10136479A1 (de) * | 2001-07-27 | 2003-02-06 | Merck Patent Gmbh | Farbige Beschriftung und Markierung von Kunststoffen und Lacken |
FR2833518B1 (fr) * | 2001-12-14 | 2004-06-25 | Gemplus Card Int | Support d'information marquee par laser |
US7694887B2 (en) | 2001-12-24 | 2010-04-13 | L-1 Secure Credentialing, Inc. | Optically variable personalized indicia for identification documents |
AU2002364036A1 (en) | 2001-12-24 | 2003-07-15 | Digimarc Id Systems, Llc | Laser etched security features for identification documents and methods of making same |
WO2003055684A2 (en) * | 2001-12-24 | 2003-07-10 | Digimarc Id Systems, Llc | Laser engraving methods and compositions |
US7793846B2 (en) | 2001-12-24 | 2010-09-14 | L-1 Secure Credentialing, Inc. | Systems, compositions, and methods for full color laser engraving of ID documents |
AU2002364255A1 (en) | 2001-12-24 | 2003-07-15 | Digimarc Id Systems, Llc | Covert variable information on id documents and methods of making same |
US7728048B2 (en) | 2002-12-20 | 2010-06-01 | L-1 Secure Credentialing, Inc. | Increasing thermal conductivity of host polymer used with laser engraving methods and compositions |
US7201963B2 (en) * | 2002-01-15 | 2007-04-10 | Gentex Corporation | Pre-processed workpiece having a surface deposition of absorber dye rendering the workpiece weld-enabled |
AU2003221894A1 (en) | 2002-04-09 | 2003-10-27 | Digimarc Id Systems, Llc | Image processing techniques for printing identification cards and documents |
US7824029B2 (en) | 2002-05-10 | 2010-11-02 | L-1 Secure Credentialing, Inc. | Identification card printer-assembler for over the counter card issuing |
DE10235018A1 (de) * | 2002-07-31 | 2004-02-12 | Merck Patent Gmbh | Lasermarkierbare flexible Trägereinheit |
DE10252007A1 (de) * | 2002-11-06 | 2004-05-27 | Merck Patent Gmbh | Lasermarkierbare Pigmente |
GB0226597D0 (en) | 2002-11-14 | 2002-12-24 | Sun Chemical Bv | Laser marking process |
US7804982B2 (en) | 2002-11-26 | 2010-09-28 | L-1 Secure Credentialing, Inc. | Systems and methods for managing and detecting fraud in image databases used with identification documents |
US7169471B1 (en) | 2003-02-06 | 2007-01-30 | Emd Chemicals, Inc. | Laser-marking additive |
US7763179B2 (en) * | 2003-03-21 | 2010-07-27 | Digimarc Corporation | Color laser engraving and digital watermarking |
EP1614064B1 (en) | 2003-04-16 | 2010-12-08 | L-1 Secure Credentialing, Inc. | Three dimensional data storage |
US7187396B2 (en) * | 2003-11-07 | 2007-03-06 | Engelhard Corporation | Low visibility laser marking additive |
DE102004010504B4 (de) * | 2004-03-04 | 2006-05-04 | Degussa Ag | Hochtransparente lasermarkierbare und laserschweißbare Kunststoffmaterialien, deren Verwendung und Herstellung sowie Verwendung von Metallmischoxiden und Verfahren zur Kennzeichnung von Produktionsgütern |
CA2558151C (en) * | 2004-03-04 | 2011-01-04 | Degussa Ag | Laser-weldable transparent, translucent, or opaque plastic materials that are tinted by colorants |
DE102004012335A1 (de) * | 2004-03-11 | 2005-09-22 | Basf Ag | Thermoplastische Polyurethane enthaltend Edelmetallsalze |
US7459259B2 (en) * | 2004-09-29 | 2008-12-02 | Sabic Innovative Plastics Ip B.V. | Marked article and method of making the same |
DE102004050478A1 (de) * | 2004-10-15 | 2006-04-27 | Chemische Fabrik Budenheim Kg | Formmasse für die Herstellung schwer entflammbarer Gegenstände, Pigment hierfür und dessen Verwendung |
DE102004050557B4 (de) | 2004-10-15 | 2010-08-12 | Ticona Gmbh | Lasermarkierbare Formmassen und daraus erhältliche Produkte und Verfahren zur Lasermarkierung |
US20070098900A1 (en) * | 2004-11-05 | 2007-05-03 | Fuji Hunt Photographic Chemicals, Inc. | Media providing non-contacting formation of high contrast marks and method of using same, composition for forming a laser-markable coating, a laser-markable material and process of forming a marking |
WO2006065611A1 (en) | 2004-12-14 | 2006-06-22 | Polyone Corporation | Use of bismuth oxides for laser markings in thermoplastic polyurethane compounds |
US7704586B2 (en) * | 2005-03-09 | 2010-04-27 | Degussa Ag | Plastic molded bodies having two-dimensional and three-dimensional image structures produced through laser subsurface engraving |
JP2007031491A (ja) * | 2005-07-22 | 2007-02-08 | Dainichiseika Color & Chem Mfg Co Ltd | レーザー溶着用樹脂組成物 |
DE102005035914A1 (de) * | 2005-07-28 | 2007-02-01 | Chemische Fabrik Budenheim Kg | Laserschweißverfahren und -material |
DE102005038774A1 (de) * | 2005-08-15 | 2007-02-22 | Merck Patent Gmbh | Polymere mit hoher IR-Absorption |
KR100697977B1 (ko) * | 2005-12-30 | 2007-03-23 | 삼성토탈 주식회사 | 레이저 마킹이 가능한 열가소성 수지 조성물 |
DE102007021199B4 (de) * | 2006-07-17 | 2016-02-11 | Evonik Degussa Gmbh | Zusammensetzungen aus organischem Polymer als Matrix und anorganischen Partikeln als Füllstoff, Verfahren zu deren Herstellung sowie deren Verwendung und damit hergestellte Formkörper |
DE102006038043A1 (de) | 2006-08-14 | 2008-02-21 | Chemische Fabrik Budenheim Kg | Laserbeschriftbares Polymermaterial |
JP5300844B2 (ja) * | 2007-06-29 | 2013-09-25 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング | ポリマーコア、シェルおよび吸収材を含むマイクロスフィア |
DE102007037165A1 (de) | 2007-08-07 | 2009-02-12 | Mühlbauer Ag | Verfahren und Vorrichtung zum Verlegen von dünnem Draht |
DE102007038578A1 (de) | 2007-08-16 | 2009-02-19 | Evonik Degussa Gmbh | Verfahren zur Dekorierung von Oberflächen |
JP5409045B2 (ja) * | 2008-02-29 | 2014-02-05 | 富士フイルム株式会社 | レーザー彫刻用樹脂組成物、レーザー彫刻用樹脂印刷版原版、レリーフ印刷版およびレリーフ印刷版の製造方法 |
CN101423653B (zh) * | 2008-12-01 | 2011-08-17 | 上海金发科技发展有限公司 | 具有激光打印标记功能的玻纤增强聚对苯二甲酸丁二醇酯树脂组合物及其制备方法 |
KR101096886B1 (ko) | 2009-05-08 | 2011-12-22 | 삼성토탈 주식회사 | 흑색 레이저 마킹 특성이 우수한 폴리올레핀계 수지 조성물 |
DE102009033762A1 (de) | 2009-07-17 | 2011-01-27 | Leonhard Kurz Stiftung & Co. Kg | Verfahren zur Herstellung eines Mehrschichtkörpers sowie Mehrschichtkörper |
WO2011083100A1 (de) | 2010-01-05 | 2011-07-14 | Basf Se | Transparentes, laserbeschriftbares polyurethan |
US8790769B2 (en) | 2010-01-05 | 2014-07-29 | Basf Se | Transparent, laser-inscribable polyurethane |
KR20140009985A (ko) * | 2010-10-26 | 2014-01-23 | 사빅 이노베이티브 플라스틱스 아이피 비.브이. | 모든 색상 성능을 가진 레이저 직접 스트럭쳐링 물질 |
WO2012104006A1 (en) | 2011-02-03 | 2012-08-09 | Merck Patent Gmbh | Laser-markable and laser-weldable polymers |
JP5912704B2 (ja) * | 2011-03-18 | 2016-04-27 | 三菱エンジニアリングプラスチックス株式会社 | 熱可塑性樹脂組成物、樹脂成形品、及びメッキ層付樹脂成形品の製造方法 |
CN102751568A (zh) * | 2011-04-22 | 2012-10-24 | 深圳富泰宏精密工业有限公司 | 天线及该天线的制造方法 |
DE102011101579B4 (de) * | 2011-05-12 | 2015-03-05 | Otto Bock Healthcare Gmbh | Verwendung eines leitfähigen Polymermaterials für medizinische und orthopädietechnische Anwendungen |
US9187221B2 (en) | 2011-09-27 | 2015-11-17 | Crown Packaging Technology, Inc. | Can ends having machine readable information |
ES2642166T3 (es) | 2011-09-27 | 2017-11-15 | Crown Packaging Technology, Inc. | Extremos de lata que tienen información legible por máquina |
EP2711399B1 (en) | 2012-03-23 | 2014-12-31 | Mitsubishi Engineering-Plastics Corporation | Thermoplastic resin composition, resin article, and method of manufacturing resin article with plated layer |
CN104395092A (zh) | 2012-06-21 | 2015-03-04 | 3M创新有限公司 | 静电耗散可激光雕刻膜 |
CN104619783B (zh) | 2012-09-14 | 2017-06-16 | 三菱工程塑料株式会社 | 热塑性树脂组合物、树脂成型品和带镀层的树脂成型品的制造方法 |
JP5675920B2 (ja) | 2012-09-14 | 2015-02-25 | 三菱エンジニアリングプラスチックス株式会社 | レーザーダイレクトストラクチャリング用樹脂組成物、樹脂成形品、およびメッキ層付樹脂成形品の製造方法 |
US20150353714A1 (en) * | 2012-09-14 | 2015-12-10 | Mitsubishi Engineering-Plastics Corporation | Thermoplastic resin composition, resin molded article, and method for manufacturing resin molded article having a plated layer |
CN104583330B (zh) | 2012-09-14 | 2016-09-21 | 三菱工程塑料株式会社 | 热塑性树脂组合物、树脂成型品和带镀层的树脂成型品的制造方法 |
US9944778B2 (en) | 2012-10-19 | 2018-04-17 | Merck Patent Gmbh | Microspheres |
WO2014188828A1 (ja) | 2013-05-20 | 2014-11-27 | 東罐マテリアル・テクノロジー株式会社 | 酸化ビスマス系レーザーマーキング用添加剤 |
DE102013010703A1 (de) | 2013-06-27 | 2014-12-31 | Merck Patent Gmbh | Mikrokugeln |
JP5766864B2 (ja) * | 2013-10-24 | 2015-08-19 | 三菱エンジニアリングプラスチックス株式会社 | 樹脂組成物、樹脂成形品、および樹脂成形品の製造方法 |
US9676927B2 (en) | 2014-04-09 | 2017-06-13 | The Shepherd Color Company | Core-shell composite inorganic metal oxides and method of preparing for prevention of thermal oxidative degradation in polymer and resin compositions |
DE102014008962A1 (de) | 2014-06-23 | 2016-01-07 | Merck Patent Gmbh | Mikrokugeln |
DE102014016286A1 (de) * | 2014-11-05 | 2016-05-12 | Merck Patent Gmbh | Lasermarkierbare und laserschweißbare polymere Materialien |
EA201891847A1 (ru) * | 2016-02-22 | 2019-03-29 | Басф Се | Зародышеобразователь для твердых термопластичных полиуретанов |
DE102016210160A1 (de) | 2016-06-08 | 2017-12-14 | Weilburger Coatings Gmbh | Wässrige Zusammensetzung zur Erzeugung einer lasermarkierbaren Beschichtung und lasermarkierte Beschichtung |
DE102016219858A1 (de) | 2016-10-12 | 2018-04-12 | Weilburger Coatings Gmbh | Verfahren zur Herstellung einer Beschichtung mit Markierungen auf einer Oberfläche oder einem Teil einer Oberfläche eines Gegenstandes |
WO2018117834A1 (en) | 2016-12-22 | 2018-06-28 | Dsm Ip Assets B.V. | Improved heat and electrically resistive thermoplastic resin compositions |
CN110300778A (zh) | 2017-01-11 | 2019-10-01 | 沙特基础工业全球技术公司 | 通过芯-壳结构lds添加剂与涂覆在矿物填料表面上的金属化合物而具有导热性和激光电镀性能的组合物 |
EP3363649A1 (en) | 2017-02-20 | 2018-08-22 | Clariant Plastics & Coatings Ltd | Antimony free composition for laser marking thermoplastic compounds |
CN106957522A (zh) * | 2017-03-17 | 2017-07-18 | 姜有为 | 牲畜专用可视耳标材料及其制备方法和耳标 |
DE102017011800A1 (de) | 2017-12-20 | 2019-06-27 | Merck Patent Gmbh | Effektpigmente |
DE102019131305B3 (de) * | 2019-11-20 | 2020-12-10 | Dr. Ing. H.C. F. Porsche Aktiengesellschaft | Verfahren zum Herstellen einer Verbundscheibe eines Kraftfahrzeugs und Verbundscheibe |
DE102019131303B3 (de) * | 2019-11-20 | 2020-12-31 | Dr. Ing. H.C. F. Porsche Aktiengesellschaft | Verfahren zum Herstellen einer thermoplastischen Folie, die für ein Verbundglas vorgesehen ist |
DE102020105077A1 (de) | 2020-02-26 | 2021-08-26 | Treffert GmbH & Co. KG | Polymer mit Zusatzstoffen für das Selektive Lasersintern |
US20240002621A1 (en) | 2020-10-01 | 2024-01-04 | Basf Se | eTPE Laser Marking |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0447032A2 (en) * | 1990-03-15 | 1991-09-18 | British Aerospace Public Limited Company | A laser markable white pigment composition |
JPH03249214A (ja) * | 1990-02-23 | 1991-11-07 | Unitika Ltd | 白色系繊維および布帛 |
EP0459552A1 (de) * | 1990-05-26 | 1991-12-04 | METALLGESELLSCHAFT Aktiengesellschaft | Elektrisch leitfähiges Bariumsulfat und Verfahren zu seiner Herstellung |
JPH04257308A (ja) * | 1991-02-08 | 1992-09-11 | Unitika Ltd | 白色系軽量保温性中空繊維 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6050813A (ja) | 1983-08-31 | 1985-03-20 | 触媒化成工業株式会社 | プラスチック又は塗料配合用透光性導電性粉末素材 |
JP3444919B2 (ja) * | 1992-04-18 | 2003-09-08 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング | 導電性顔料 |
DE59304334D1 (de) * | 1992-04-25 | 1996-12-05 | Merck Patent Gmbh | Elektrisch leitfähiges Pigment |
JP3102822B2 (ja) | 1992-05-29 | 2000-10-23 | 日本ジーイープラスチックス株式会社 | レーザーマーキング用樹脂組成物 |
US5422383A (en) | 1993-04-22 | 1995-06-06 | Somar Corporation | Laser beam absorbing resin composition, coloring material therefor and laser beam marking method |
DE4436897A1 (de) | 1994-10-15 | 1996-04-18 | Elastogran Gmbh | Verfahren zur Beschriftung von Formkörpern |
-
1994
- 1994-05-05 DE DE4415802A patent/DE4415802A1/de not_active Withdrawn
-
1995
- 1995-05-03 EP EP95919380A patent/EP0797511B1/de not_active Expired - Lifetime
- 1995-05-03 BR BR9507704A patent/BR9507704A/pt active Search and Examination
- 1995-05-03 DE DE59506606T patent/DE59506606D1/de not_active Expired - Lifetime
- 1995-05-03 KR KR1019960706241A patent/KR100347466B1/ko not_active IP Right Cessation
- 1995-05-03 AT AT95919380T patent/ATE183142T1/de not_active IP Right Cessation
- 1995-05-03 JP JP52866795A patent/JP3591654B2/ja not_active Expired - Lifetime
- 1995-05-03 ES ES95919380T patent/ES2138737T3/es not_active Expired - Lifetime
- 1995-05-03 WO PCT/EP1995/001672 patent/WO1995030546A1/de active IP Right Grant
- 1995-05-03 CN CN95192924A patent/CN1077905C/zh not_active Expired - Lifetime
- 1995-05-03 AU AU25239/95A patent/AU690993B2/en not_active Ceased
- 1995-05-04 ZA ZA953604A patent/ZA953604B/xx unknown
-
1999
- 1999-12-15 US US09/461,032 patent/US6214917B1/en not_active Expired - Lifetime
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03249214A (ja) * | 1990-02-23 | 1991-11-07 | Unitika Ltd | 白色系繊維および布帛 |
EP0447032A2 (en) * | 1990-03-15 | 1991-09-18 | British Aerospace Public Limited Company | A laser markable white pigment composition |
EP0459552A1 (de) * | 1990-05-26 | 1991-12-04 | METALLGESELLSCHAFT Aktiengesellschaft | Elektrisch leitfähiges Bariumsulfat und Verfahren zu seiner Herstellung |
JPH04257308A (ja) * | 1991-02-08 | 1992-09-11 | Unitika Ltd | 白色系軽量保温性中空繊維 |
Also Published As
Publication number | Publication date |
---|---|
ATE183142T1 (de) | 1999-08-15 |
DE59506606D1 (de) | 1999-09-16 |
BR9507704A (pt) | 1997-08-19 |
AU2523995A (en) | 1995-11-29 |
JPH10500149A (ja) | 1998-01-06 |
WO1995030546A1 (de) | 1995-11-16 |
KR100347466B1 (ko) | 2002-12-18 |
ES2138737T3 (es) | 2000-01-16 |
ZA953604B (en) | 1995-12-05 |
CN1147227A (zh) | 1997-04-09 |
EP0797511A1 (de) | 1997-10-01 |
AU690993B2 (en) | 1998-05-07 |
DE4415802A1 (de) | 1995-11-09 |
US6214917B1 (en) | 2001-04-10 |
EP0797511B1 (de) | 1999-08-11 |
KR970702790A (ko) | 1997-06-10 |
JP3591654B2 (ja) | 2004-11-24 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1077905C (zh) | 可激光标识的塑料 | |
US6521688B1 (en) | Laser-markable plastics | |
US6545065B2 (en) | Laser-markable plastics | |
EP1145864B1 (de) | Lasermarkierbare Kunststoffe | |
CN1144230A (zh) | 可激光标记塑料 | |
US6924077B2 (en) | Colored inscription and marking of plastics and surface coatings | |
EP0739933B1 (en) | Polyester resin composition | |
US6291551B1 (en) | Laser-markable plastics | |
CN109963702B (zh) | 用于激光可标记及激光可焊接的聚合物材料的添加剂 | |
EP1998962A1 (de) | Nanopartikuläre metallboridzusammensetzung und deren verwendung zum kennzeichnen von kunststoffteilen | |
EP2052032B1 (de) | Laserbeschriftbares polymermaterial | |
CN107849290B (zh) | 可激光标记的聚合物和涂料 | |
CA2294235A1 (en) | Plastics which can be laser-marked | |
WO2015051868A1 (de) | Pigmente basierend auf bismuthverbindungen | |
CN110337463B (zh) | 用于激光标记热塑性配混物的无锑组合物 | |
DE102004045305A1 (de) | Lasermarkierbare und laserschweißbare polymere Materialien | |
CN112119128B (zh) | 激光添加剂及其在聚合物材料中的用途 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Free format text: FORMER OWNER: BASF AG Effective date: 20140912 Owner name: BASF AG Free format text: FORMER OWNER: MERCK PATENT GMBH Effective date: 20140912 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20140912 Address after: Ludwigshafen, Germany Patentee after: Basf AG Address before: Darmstadt Patentee before: Merck Patent GmbH Patentee before: Basf AG |
|
C17 | Cessation of patent right | ||
CX01 | Expiry of patent term |
Expiration termination date: 20150503 Granted publication date: 20020116 |