CN107787335B - 制备具有改进熔融强度的乙烯类聚合物的方法 - Google Patents

制备具有改进熔融强度的乙烯类聚合物的方法 Download PDF

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CN107787335B
CN107787335B CN201680035808.0A CN201680035808A CN107787335B CN 107787335 B CN107787335 B CN 107787335B CN 201680035808 A CN201680035808 A CN 201680035808A CN 107787335 B CN107787335 B CN 107787335B
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alkyl
ethylene
comonomer
polymer
methyl
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CN107787335A (zh
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J·O·奥斯比
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Dow Global Technologies LLC
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Dow Global Technologies LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen
    • C08F4/32—Organic compounds
    • C08F4/38—Mixtures of peroxy-compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/11—Melt tension or melt strength
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
CN201680035808.0A 2015-06-24 2016-05-09 制备具有改进熔融强度的乙烯类聚合物的方法 Active CN107787335B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562183814P 2015-06-24 2015-06-24
US62/183814 2015-06-24
PCT/US2016/031410 WO2016209381A1 (en) 2015-06-24 2016-05-09 Processes to prepare ethylene-based polymers with improved melt-strength

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CN107787335A CN107787335A (zh) 2018-03-09
CN107787335B true CN107787335B (zh) 2020-12-11

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US (1) US10465023B2 (enExample)
EP (1) EP3313905B1 (enExample)
JP (1) JP6865178B2 (enExample)
KR (1) KR102575869B1 (enExample)
CN (1) CN107787335B (enExample)
BR (1) BR112017027273B1 (enExample)
ES (1) ES2799524T3 (enExample)
WO (1) WO2016209381A1 (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2717772T3 (es) 2013-12-26 2019-06-25 Dow Global Technologies Llc Procedimientos para mejorar la estabilidad del reactor para la preparación de polímeros basados en etileno utilizando polienos asimétricos
US9944733B2 (en) 2013-12-26 2018-04-17 Dow Global Technologies Llc Ethylene-based polymers formed using asymmetrical polyenes
ES2799524T3 (es) 2015-06-24 2020-12-18 Dow Global Technologies Llc Procedimientos para preparar polímeros a base de etileno con resistencia en estado fundido mejorada
KR102551637B1 (ko) 2017-06-02 2023-07-06 다우 글로벌 테크놀로지스 엘엘씨 에틸렌계 중합체 및 이의 제조
TWI805586B (zh) * 2017-06-29 2023-06-21 美商陶氏全球科技有限責任公司 可交聯組合物、製品以及導電方法
CN110945043B (zh) * 2017-07-21 2022-10-11 株式会社Jsp 苯乙烯类树脂及苯乙烯类树脂的制造方法
US11891463B2 (en) * 2018-06-28 2024-02-06 Dow Global Technologies Llc Ethylene-based polymers with improved melt strength and thermal stability
US20230365792A1 (en) * 2020-09-16 2023-11-16 Dow Global Technologies Llc Copolymers of ethylene with (meth) acrylic ester functionalized polysiloxane
KR20250119817A (ko) * 2024-02-01 2025-08-08 에스케이이노베이션 주식회사 에틸렌계 공중합체의 제조 방법

Family Cites Families (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3300452A (en) 1963-11-06 1967-01-24 Dow Chemical Co Thermosetting ethylene copolymers
US3542749A (en) 1968-03-07 1970-11-24 Gulf Research Development Co Novel ethylene copolymers and selfsupporting film prepared therefrom
JPS52126495A (en) 1976-04-16 1977-10-24 Sumitomo Chem Co Ltd Novel ethylene copolymer and preparation thereof
US4370517A (en) 1977-12-29 1983-01-25 Hitachi Cable Limited Polyolefin compositions for electrical insulation
FR2621920B1 (fr) * 1987-10-14 1990-01-26 Charbonnages Ste Chimique Polymeres fonctionnalises de l'ethylene applicables a l'enduction d'un metal et un procede pour leur preparation
GB8925939D0 (en) 1989-11-16 1990-01-04 Exxon Chemical Patents Inc Cable coating compositions and cables made therefrom
FI90986C (fi) 1991-10-15 1994-04-25 Neste Oy Ekstrudoitavan eteeni-hydroksiakrylaatti-sekapolymeerin käyttö
SE9103077D0 (sv) 1991-10-22 1991-10-22 Neste Oy Omaettad etensampolymer och saett foer framstaellning daerav
JP3157163B2 (ja) 1991-12-30 2001-04-16 ザ・ダウ・ケミカル・カンパニー エチレンインターポリマーの重合
US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
JPH0641238A (ja) * 1992-07-21 1994-02-15 Tosoh Corp 押出コ−ティング用エチレン重合体の製造方法
HU225374B1 (en) 1993-01-29 2006-10-28 Dow Global Technologies Inc Process for producing ethylene/alfa-olefin interpolymer composition
US6448341B1 (en) 1993-01-29 2002-09-10 The Dow Chemical Company Ethylene interpolymer blend compositions
US5869575A (en) 1995-08-02 1999-02-09 The Dow Chemical Company Ethylene interpolymerizations
SE507045C2 (sv) 1996-05-31 1998-03-23 Borealis As Etensampolymer med förhöjd omättnadsgrad och sätt för framställning därav
FR2756829A1 (fr) 1996-12-11 1998-06-12 Atochem Elf Sa Copolymere ethylene/ester (meth)acrylique de polyalkyleneglycol(ether) et film imperrespirant obtenu a partir de celui-ci
JP2003527474A (ja) 2000-03-16 2003-09-16 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング ポリエチレンの製造方法
ATE280785T1 (de) 2000-08-15 2004-11-15 Akzo Nobel Nv Verwendung von trioxepanen zur herstellung von acrylharzen mit hohem feststoffgehalt, styrolharzen und polyethylenharzen mit niedriger dichte
CN101137681B (zh) * 2005-03-09 2011-04-13 沙特基础工业公司 在管式反应器中制备乙烯共聚物的方法
JP5296668B2 (ja) 2006-03-24 2013-09-25 サウディ ベーシック インダストリーズ コーポレイション 押出コーティング組成物
US20090253878A1 (en) 2008-02-29 2009-10-08 Zhibin Ye Branched polyolefin polymer tethered with polymerizable methacryloyl groups and process for preparing same
EP2462192A1 (en) 2009-08-03 2012-06-13 E. I. du Pont de Nemours and Company Energy absorbing copolyetherester resin compositions
KR20120081136A (ko) 2009-09-14 2012-07-18 다우 글로벌 테크놀로지스 엘엘씨 에틸렌 및 폴리(알콕시드)로부터 유도된 단위를 포함하는 중합체
US9150681B2 (en) 2010-10-29 2015-10-06 Dow Global Technologies Llc Ethylene-based polymers and processes for the same
WO2012084787A1 (en) 2010-12-22 2012-06-28 Basell Polyolefine Gmbh Process for the preparation of ethylene copolymers in the presence of free-radical polymerization initiator by copolymerizing ethylene, a bi- or multifunctional comonomer and optionally further comonomers
JP5709131B2 (ja) 2011-05-11 2015-04-30 国立大学法人東京工業大学 画像処理システム
JP2013062068A (ja) 2011-09-12 2013-04-04 Denso Corp 車両用灯具
CN104053671A (zh) 2011-11-01 2014-09-17 生态学有限公司 治疗癌症的抗体和方法
MX360854B (es) 2011-12-22 2018-11-20 Dow Global Technologies Llc Polímeros basados en etileno con una resistencia a la fusión mejorada, y procesos para lo mismo.
JP6339565B2 (ja) * 2012-06-27 2018-06-06 ダウ グローバル テクノロジーズ エルエルシー エチレン系ポリマーおよびそのプロセス
KR102023511B1 (ko) 2012-09-07 2019-09-30 삼성전자주식회사 엑스선 영상 생성 방법 및 장치
US8897459B2 (en) 2012-09-12 2014-11-25 Bose Corporation Two-way audio communication system with reduced ground noise
US9944733B2 (en) 2013-12-26 2018-04-17 Dow Global Technologies Llc Ethylene-based polymers formed using asymmetrical polyenes
WO2015100318A1 (en) 2013-12-26 2015-07-02 Dow Global Technologies Llc Processes to form ethylene-based polymers using asymmetrical polyenes
ES2717772T3 (es) 2013-12-26 2019-06-25 Dow Global Technologies Llc Procedimientos para mejorar la estabilidad del reactor para la preparación de polímeros basados en etileno utilizando polienos asimétricos
US9856338B2 (en) 2014-06-27 2018-01-02 Dow Global Technologies Llc Processes to prepare ethylene-based polymers using a distribution of carbon monoxide
KR102359175B1 (ko) 2014-06-27 2022-02-08 다우 글로벌 테크놀로지스 엘엘씨 일산화탄소 및 레올로지 개질제로부터 유도된 단위를 포함하는 에틸렌계 폴리머
ES2799524T3 (es) 2015-06-24 2020-12-18 Dow Global Technologies Llc Procedimientos para preparar polímeros a base de etileno con resistencia en estado fundido mejorada

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Publication number Publication date
BR112017027273B1 (pt) 2022-01-25
KR102575869B1 (ko) 2023-09-08
US20180134825A1 (en) 2018-05-17
BR112017027273A2 (pt) 2018-09-04
WO2016209381A1 (en) 2016-12-29
JP6865178B2 (ja) 2021-04-28
CN107787335A (zh) 2018-03-09
US10465023B2 (en) 2019-11-05
ES2799524T3 (es) 2020-12-18
EP3313905B1 (en) 2020-05-20
EP3313905A1 (en) 2018-05-02
JP2018518576A (ja) 2018-07-12
KR20180022790A (ko) 2018-03-06

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