CN107739663A - 一种复合洗衣片及其制备方法 - Google Patents

一种复合洗衣片及其制备方法 Download PDF

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CN107739663A
CN107739663A CN201711042108.7A CN201711042108A CN107739663A CN 107739663 A CN107739663 A CN 107739663A CN 201711042108 A CN201711042108 A CN 201711042108A CN 107739663 A CN107739663 A CN 107739663A
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laundry
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laundry sheet
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钱钢
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Connaught Environmental Protection Technology (suzhou) Co Ltd
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Abstract

本发明公开了一种复合洗衣片，包括吸色布层和洗衣物质层，洗衣物质层附着在吸色布层上，吸色布层包括有纤维素纤维和粘胶纤维混纺而成的布片，布片中含有吸色剂，吸色剂包括以下组分：2,3‑环氧丙基三甲基氯化铵、氟碳表面活性剂、胶黏剂、椰子油，洗衣物质层包括以下组分：脂肪醇聚氧乙烯醚、甲基丙烯基环己烯、丙二醇甲醚醋酸酯、羟甲基壳聚糖、烷基醇酰胺、油酸甘油酯、复合酶、羟甲基淀粉钠、硬脂酸镁、乙烯脲，成膜剂、成型助剂、螯合剂、PH调节剂、柔顺剂、香精、去离子水。本发明将洗衣片和吸色片合二为一，同时兼具了洗衣片和吸色片的功能，解决了深色衣服与浅色衣服不能同洗的问题，提高了洗涤的效果。

Description

一种复合洗衣片及其制备方法
技术领域
本发明专利涉及洗化用品领域，具体涉及一种复合洗衣片及其制备方法。
背景技术
洗衣片是一种全新的洗涤产品，改变了以往洗涤产品的形态，轻便是它最大的特点，因其不含有荧光增白剂，磷等有害成分，逐渐风靡欧美市场，成为新一代洗涤产品，是一种中性的合成洗涤剂。洗衣片实现的定量洗涤，克服了传统洗衣粉、洗衣液使用中计量的繁琐，即节约了洗涤用品，其低泡超浓缩的环保特性又节约了用水，有望在国内得到推广，随着人民生活水平的提高，人们对洗衣片产品质量的要求也越来越高，洗衣片的需求量将会越来越大，质量要求也越来越高，活性物高、多功能、使用简便将是洗衣片的发展趋势。
发明内容
针对现有技术中的不足，本发明提供了一种复合洗衣片及其制备方法。
为了解决上述技术问题，本发明采用如下技术方案：
一种复合洗衣片，包括吸色布层和洗衣物质层，所述洗衣物质层附着在所述吸色布层上，所述吸色布层包括有纤维素纤维和粘胶纤维混纺而成的布片，所述布片中含有吸色剂，所述吸色剂包括以下质量份数的组分：2,3-环氧丙基三甲基氯化铵10～30份、氟碳表面活性剂10～30份、胶黏剂0.5～1份、椰子油0.5～1份，所述洗衣物质层包括以下质量份数的组分：脂肪醇聚氧乙烯醚5~10份、甲基丙烯基环己烯3~8份、丙二醇甲醚醋酸酯2~6份、羟甲基壳聚糖3～8份、烷基醇酰胺2～5份、油酸甘油酯2～5份、复合酶2～5份、羟甲基淀粉钠1~5份、硬脂酸镁0.8~2份、乙烯脲0.5~1.5份，成膜剂0.5~1.8份、成型助剂0.3~1份、螯合剂0.03~0.1份、PH调节剂0.1-1份、柔顺剂2～5份、香精0.01~0.1份、去离子水10~20份。
作为优选，所述复合酶中淀粉酶、蛋白酶、脂肪酶、纤维素酶的质量比为2～4:3～5:1～3:1～2。
作为优选，所述成膜剂为聚乙烯醇、聚乙二醇、羟丙基甲基纤维素和聚丙烯酰胺中的一种或几种。
作为优选，所述成型助剂为膨润土、滑石、云母、高岭土中的一种或几种。
作为优选，所述螯合剂为焦磷酸钠。
作为优选，所述PH调节剂为柠檬酸或柠檬酸钠。
作为优选，所述柔顺剂为氨基硅油、酰胺季铵盐、咪唑啉季铵盐、双烷基二甲基季铵盐中的一种或几种。
一种高效洗衣片的制备方法，包括以下步骤：
a）用纤维素纤维和粘胶纤维混纺的到布片；
b）将环氧丙基三甲基氯化铵、氟碳表面活性剂、胶黏、椰子油按比例混合，并加入去离子水搅拌至混合均匀得到吸色剂；
c）将布片放在吸色剂中浸泡后取出，并放入烘干装置进行烘干，制得吸色布层；
d）将成膜剂先按比例加水，加热搅拌溶解得到成膜剂溶液，备用，将脂肪醇聚氧乙烯醚、甲基丙烯基环己烯、丙二醇甲醚醋酸酯、羟甲基壳聚糖、烷基醇酰胺、油酸甘油酯、羟甲基淀粉钠、硬脂酸镁、乙烯脲加入混合机，搅拌均匀；再加入溶解好的成膜剂溶液；再依次加入螯合剂、PH调节剂、柔顺剂、香精，搅拌均匀得到洗衣物质；
e）将步骤d）制得的洗衣物质经加热烘干筒烘干，并压制成片状；
f）将复合酶与水按照不低于1:0 .5的稀释比进行稀释后加入喷洒装置内；用喷洒装置将复合酶溶液喷洒在上述步骤e）中所制得的洗衣物质片料表面上并晾干得到洗衣物质层；
g）将步骤f）制得的洗衣物质层压合在步骤c）制得的吸色布层上，经过剪切、包装得到最终产品。
作为优选, 步骤e）中用加热烘干筒烘干时，加热烘干筒的温度控制为100～120℃，转速为3～10分钟/转。
本发明的有益效果是：
本发明将洗衣片和吸色片合二为一，同时兼具了洗衣片和吸色片的功能，解决了深色衣服与浅色衣服不能同洗的问题，提高了洗涤的效果。通过添加复合酶，进一步提升洗衣片的去污能力，利用先干化后喷酶的科学工艺、有效确保了酶的活性成分不会被破坏。本发明提供的洗衣片去污功效明显优于肥皂、洗衣粉、洗衣液等洗涤用品，去污能力强、省水且不污染环境，也符合人们崇尚自然，绿色环保的理念。
具体实施方式
下面结合具体实施方式对本发明作进一步描述：
实施例1
一种复合洗衣片，包括吸色布层和洗衣物质层，洗衣物质层附着在吸色布层上，吸色布层包括有纤维素纤维和粘胶纤维混纺而成的布片，布片中含有吸色剂，吸色剂包括以下质量份数的组分：2,3-环氧丙基三甲基氯化铵10份、氟碳表面活性剂30份、胶黏剂0.5份、椰子油1份，洗衣物质层包括以下质量份数的组分：脂肪醇聚氧乙烯醚10份、甲基丙烯基环己烯3份、丙二醇甲醚醋酸酯6份、羟甲基壳聚糖3份、烷基醇酰胺5份、油酸甘油酯5份、复合酶2份、羟甲基淀粉钠1份、硬脂酸镁2份、乙烯脲1.5份，成膜剂0.5份、成型助剂1份、螯合剂0.1份、PH调节剂0.1份、柔顺剂2份、香精0.1份、去离子水20份。
其中，复合酶为淀粉酶、蛋白酶、脂肪酶、纤维素酶按照质量比为2: 5:1: 2混合而成；成膜剂为聚乙烯醇；成型助剂为膨润土；螯合剂为焦磷酸钠；PH调节剂为柠檬酸；柔顺剂为氨基硅油。
一种高效洗衣片的制备方法，包括以下步骤：
a）用纤维素纤维和粘胶纤维混纺的到布片；
b）将环氧丙基三甲基氯化铵、氟碳表面活性剂、胶黏、椰子油按比例混合，并加入去离子水搅拌至混合均匀得到吸色剂；
c）将布片放在吸色剂中浸泡后取出，并放入烘干装置进行烘干，制得吸色布层；
d）将成膜剂先按比例加水，加热搅拌溶解得到成膜剂溶液，备用，将脂肪醇聚氧乙烯醚、甲基丙烯基环己烯、丙二醇甲醚醋酸酯、羟甲基壳聚糖、烷基醇酰胺、油酸甘油酯、羟甲基淀粉钠、硬脂酸镁、乙烯脲加入混合机，搅拌均匀；再加入溶解好的成膜剂溶液；再依次加入螯合剂、PH调节剂、柔顺剂、香精，搅拌均匀得到洗衣物质；
e）将步骤d）制得的洗衣物质经加热烘干筒烘干，加热烘干筒的温度控制在100～120℃，转速为3～10分钟/转，并压制成片状；
f）将复合酶与水按照不低于1:0 .5的稀释比进行稀释后加入喷洒装置内；用喷洒装置将复合酶溶液喷洒在上述步骤e）中所制得的洗衣物质片料表面上并晾干得到洗衣物质层；
g）将步骤f）制得的洗衣物质层压合在步骤c）制得的吸色布层上，经过剪切、包装得到最终产品。
实施例2
本实施例与实施例1基本相同，区别在于：2,3-环氧丙基三甲基氯化铵30份、氟碳表面活性剂10份、胶黏剂1份、椰子油0.5份，洗衣物质层包括以下质量份数的组分：脂肪醇聚氧乙烯醚5份、甲基丙烯基环己烯8份、丙二醇甲醚醋酸酯2份、羟甲基壳聚糖8份、烷基醇酰胺2份、油酸甘油酯2份、复合酶5份、羟甲基淀粉钠5份、硬脂酸镁0.8份、乙烯脲0.5份，成膜剂1.8份、成型助剂0.3份、螯合剂0.03份、PH调节剂1份、柔顺剂5份、香精0.01份、去离子水10份。
其中，复合酶为淀粉酶、蛋白酶、脂肪酶、纤维素酶按照质量比为4:3: 3:1混合而成；成膜剂为聚乙二醇；成型助剂为云母；螯合剂为焦磷酸钠；PH调节剂为柠檬酸钠；柔顺剂为酰胺季铵盐。
实施例3
本实施例与实施例1基本相同，区别在于：2,3-环氧丙基三甲基氯化铵20份、氟碳表面活性剂20份、胶黏剂0.8份、椰子油0.7份，洗衣物质层包括以下质量份数的组分：脂肪醇聚氧乙烯醚8份、甲基丙烯基环己烯6份、丙二醇甲醚醋酸酯4份、羟甲基壳聚糖5份、烷基醇酰胺3份、油酸甘油酯4份、复合酶3份、羟甲基淀粉钠3份、硬脂酸镁1.2份、乙烯脲1份，成膜剂1.1份、成型助剂0.7份、螯合剂0.06份、PH调节剂0.5份、柔顺剂3份、香精0.05份、去离子水15份。
其中，复合酶为淀粉酶、蛋白酶、脂肪酶、纤维素酶按照质量比为3:4:2:1.5混合而成；成膜剂为羟丙基甲基纤维素和聚丙烯酰胺的等质量混合物；成型助剂为滑石和高岭土的等质量混合物；螯合剂为焦磷酸钠；PH调节剂为柠檬酸；柔顺剂为咪唑啉季铵盐和双烷基二甲基季铵盐的等质量混合物。
本发明方案所公开的技术手段不仅限于上述实施方式所公开的技术手段，还包括由以上技术特征任意组合所组成的技术方案。应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也视为本发明的保护范围。

Claims (9)

1.一种复合洗衣片，其特征在于，包括吸色布层和洗衣物质层，所述洗衣物质层附着在所述吸色布层上，所述吸色布层包括有纤维素纤维和粘胶纤维混纺而成的布片，所述布片中含有吸色剂，所述吸色剂包括以下质量份数的组分：2,3-环氧丙基三甲基氯化铵10～30份、氟碳表面活性剂10～30份、胶黏剂0.5～1份、椰子油0.5～1份，所述洗衣物质层包括以下质量份数的组分：脂肪醇聚氧乙烯醚5~10份、甲基丙烯基环己烯3~8份、丙二醇甲醚醋酸酯2~6份、羟甲基壳聚糖3～8份、烷基醇酰胺2～5份、油酸甘油酯2～5份、复合酶2～5份、羟甲基淀粉钠1~5份、硬脂酸镁0.8~2份、乙烯脲0.5~1.5份，成膜剂0.5~1.8份、成型助剂0.3~1份、螯合剂0.03~0.1份、PH调节剂0.1-1份、柔顺剂2～5份、香精0.01~0.1份、去离子水10~20份。
2.如权利要求1所述的复合洗衣片，其特征在于，所述复合酶中淀粉酶、蛋白酶、脂肪酶、纤维素酶的质量比为2～4:3～5:1～3:1～2。
3.如权利要求1所述的复合洗衣片，其特征在于，所述成膜剂为聚乙烯醇、聚乙二醇、羟丙基甲基纤维素和聚丙烯酰胺中的一种或几种。
4.如权利要求1所述的复合洗衣片，其特征在于，所述成型助剂为膨润土、滑石、云母、高岭土中的一种或几种。
5.如权利要求1所述的复合洗衣片，其特征在于，所述螯合剂为焦磷酸钠。
6.如权利要求1所述的复合洗衣片，其特征在于，所述PH调节剂为柠檬酸或柠檬酸钠。
7.如权利要求1所述的复合洗衣片，其特征在于，所述柔顺剂为氨基硅油、酰胺季铵盐、咪唑啉季铵盐、双烷基二甲基季铵盐中的一种或几种。
8.一种高效洗衣片的制备方法，其特征在于，包括以下步骤：
a）用纤维素纤维和粘胶纤维混纺的到布片；
b）将环氧丙基三甲基氯化铵、氟碳表面活性剂、胶黏、椰子油按比例混合，并加入去离子水搅拌至混合均匀得到吸色剂；
c）将布片放在吸色剂中浸泡后取出，并放入烘干装置进行烘干，制得吸色布层；
d）将成膜剂先按比例加水，加热搅拌溶解得到成膜剂溶液，备用，将脂肪醇聚氧乙烯醚、甲基丙烯基环己烯、丙二醇甲醚醋酸酯、羟甲基壳聚糖、烷基醇酰胺、油酸甘油酯、羟甲基淀粉钠、硬脂酸镁、乙烯脲加入混合机，搅拌均匀；再加入溶解好的成膜剂溶液；再依次加入螯合剂、PH调节剂、柔顺剂、香精，搅拌均匀得到洗衣物质；
e）将步骤d）制得的洗衣物质经加热烘干筒烘干，并压制成片状；
f）将复合酶与水按照不低于1:0 .5的稀释比进行稀释后加入喷洒装置内；用喷洒装置将复合酶溶液喷洒在上述步骤e）中所制得的洗衣物质片料表面上并晾干得到洗衣物质层；
g）将步骤f）制得的洗衣物质层压合在步骤c）制得的吸色布层上，经过剪切、包装得到最终产品。
9.如权利要求8所述的高效洗衣片的制备方法，其特征在于, 步骤e）中用加热烘干筒烘干时，加热烘干筒的温度控制为100～120℃，转速为3～10分钟/转。
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