CN107667139A - 多相共聚物和序列聚合 - Google Patents

多相共聚物和序列聚合 Download PDF

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Publication number
CN107667139A
CN107667139A CN201680032433.2A CN201680032433A CN107667139A CN 107667139 A CN107667139 A CN 107667139A CN 201680032433 A CN201680032433 A CN 201680032433A CN 107667139 A CN107667139 A CN 107667139A
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CN
China
Prior art keywords
catalyst
propylene
catalyst system
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Pending
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CN201680032433.2A
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English (en)
Chinese (zh)
Inventor
罗鲁斌
G·S·戴
M·W·赫尔特卡姆
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ExxonMobil Chemical Patents Inc
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Exxon Chemical Patents Inc
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Publication of CN107667139A publication Critical patent/CN107667139A/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/02—Heterophasic composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN201680032433.2A 2015-06-05 2016-04-29 多相共聚物和序列聚合 Pending CN107667139A (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201562171616P 2015-06-05 2015-06-05
US62/171,616 2015-06-05
EP15177103 2015-07-16
EP15177103.7 2015-07-16
PCT/US2016/030045 WO2016195870A1 (fr) 2015-06-05 2016-04-29 Copolymères hétérophasiques et polymérisation séquentielle

Publications (1)

Publication Number Publication Date
CN107667139A true CN107667139A (zh) 2018-02-06

Family

ID=53758014

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201680032433.2A Pending CN107667139A (zh) 2015-06-05 2016-04-29 多相共聚物和序列聚合

Country Status (3)

Country Link
EP (1) EP3303419A4 (fr)
CN (1) CN107667139A (fr)
WO (1) WO2016195870A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114269798A (zh) * 2019-07-17 2022-04-01 埃克森美孚化学专利公司 具有低玻璃化转变温度的高丙烯含量ep

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3872100A4 (fr) * 2018-10-26 2022-08-17 China Petroleum & Chemical Corporation Constituant catalyseur de polyoléfine contenant un matériau mésoporeux, son procédé de préparation et son utilisation

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1139934A (zh) * 1994-10-05 1997-01-08 蒙特尔技术有限公司 烯烃(共)聚合方法
US20050009993A1 (en) * 2001-11-09 2005-01-13 Tetsuya Morioka Propylene block copolymer
CN101146836A (zh) * 2005-03-23 2008-03-19 巴塞尔聚烯烃股份有限公司 烯烃聚合方法
CN102947385A (zh) * 2010-06-16 2013-02-27 博里利斯股份公司 具有优良的己烷可提取物含量/冲击性能平衡的丙烯聚合物组合物
CN103365559A (zh) * 2012-04-09 2013-10-23 腾讯科技（深圳）有限公司 一种绘制滑动轨迹的方法及移动终端
CN103717667A (zh) * 2011-08-19 2014-04-09 博里利斯股份公司 具有改善的表面性能的多相体系
CN103814078A (zh) * 2011-09-21 2014-05-21 博里利斯股份公司 成型组合物
US20140221514A1 (en) * 2013-02-06 2014-08-07 Exxonmobil Chemical Patents Inc. Polymerization Activators for Supported Ziegler-Natta Catalysts
US20150119537A1 (en) * 2013-10-28 2015-04-30 Exxonmobil Chemical Patents Inc. Processes Using Staged Hydrogen Addition
WO2015059229A1 (fr) * 2013-10-24 2015-04-30 Borealis Ag Homopolymère pp à bas point de fusion ayant une haute teneur en regioerreurs et un poids moléculaire élevé
WO2015065676A1 (fr) * 2013-10-28 2015-05-07 Exxonmobil Chemical Patents Inc. Procédé faisant appel à une hydrogénation par étapes

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015070360A1 (fr) * 2013-11-14 2015-05-21 Borouge Compounding Shanghai Co., Ltd. Composition de polypropylène à résistance aux rayures améliorée et propriétés mécaniques équilibrées

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1139934A (zh) * 1994-10-05 1997-01-08 蒙特尔技术有限公司 烯烃(共)聚合方法
US20050009993A1 (en) * 2001-11-09 2005-01-13 Tetsuya Morioka Propylene block copolymer
CN101146836A (zh) * 2005-03-23 2008-03-19 巴塞尔聚烯烃股份有限公司 烯烃聚合方法
CN102947385A (zh) * 2010-06-16 2013-02-27 博里利斯股份公司 具有优良的己烷可提取物含量/冲击性能平衡的丙烯聚合物组合物
CN103717667A (zh) * 2011-08-19 2014-04-09 博里利斯股份公司 具有改善的表面性能的多相体系
CN103814078A (zh) * 2011-09-21 2014-05-21 博里利斯股份公司 成型组合物
CN103365559A (zh) * 2012-04-09 2013-10-23 腾讯科技（深圳）有限公司 一种绘制滑动轨迹的方法及移动终端
US20140221514A1 (en) * 2013-02-06 2014-08-07 Exxonmobil Chemical Patents Inc. Polymerization Activators for Supported Ziegler-Natta Catalysts
WO2015059229A1 (fr) * 2013-10-24 2015-04-30 Borealis Ag Homopolymère pp à bas point de fusion ayant une haute teneur en regioerreurs et un poids moléculaire élevé
US20150119537A1 (en) * 2013-10-28 2015-04-30 Exxonmobil Chemical Patents Inc. Processes Using Staged Hydrogen Addition
WO2015065676A1 (fr) * 2013-10-28 2015-05-07 Exxonmobil Chemical Patents Inc. Procédé faisant appel à une hydrogénation par étapes

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114269798A (zh) * 2019-07-17 2022-04-01 埃克森美孚化学专利公司 具有低玻璃化转变温度的高丙烯含量ep
CN114269798B (zh) * 2019-07-17 2024-02-27 埃克森美孚化学专利公司 具有低玻璃化转变温度的高丙烯含量ep

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WO2016195870A1 (fr) 2016-12-08
EP3303419A1 (fr) 2018-04-11
EP3303419A4 (fr) 2018-06-20

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Application publication date: 20180206