CN107466908A - A kind of septum that can reduce agricultural chemicals and pesticide residues - Google Patents
A kind of septum that can reduce agricultural chemicals and pesticide residues Download PDFInfo
- Publication number
- CN107466908A CN107466908A CN201710664697.6A CN201710664697A CN107466908A CN 107466908 A CN107466908 A CN 107466908A CN 201710664697 A CN201710664697 A CN 201710664697A CN 107466908 A CN107466908 A CN 107466908A
- Authority
- CN
- China
- Prior art keywords
- septum
- beeswax
- agricultural chemicals
- pesticide residues
- activated carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003905 agrochemical Substances 0.000 title claims abstract description 16
- 239000000447 pesticide residue Substances 0.000 title claims abstract description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 50
- 235000013871 bee wax Nutrition 0.000 claims abstract description 45
- 239000012166 beeswax Substances 0.000 claims abstract description 44
- 239000000463 material Substances 0.000 claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 claims abstract description 5
- 238000004049 embossing Methods 0.000 claims description 3
- 238000010008 shearing Methods 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 claims 1
- 239000002917 insecticide Substances 0.000 abstract description 20
- 239000000575 pesticide Substances 0.000 abstract description 6
- 238000004064 recycling Methods 0.000 abstract description 4
- 238000009825 accumulation Methods 0.000 abstract description 3
- 238000011161 development Methods 0.000 abstract description 3
- 241000256844 Apis mellifera Species 0.000 description 40
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 18
- 235000009051 Ambrosia paniculata var. peruviana Nutrition 0.000 description 7
- 235000003097 Artemisia absinthium Nutrition 0.000 description 7
- 240000001851 Artemisia dracunculus Species 0.000 description 7
- 235000017731 Artemisia dracunculus ssp. dracunculus Nutrition 0.000 description 7
- 235000003261 Artemisia vulgaris Nutrition 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 238000011160 research Methods 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 238000010276 construction Methods 0.000 description 4
- 230000018109 developmental process Effects 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- MTXSIJUGVMTTMU-JTQLQIEISA-N (S)-anabasine Chemical compound N1CCCC[C@H]1C1=CC=CN=C1 MTXSIJUGVMTTMU-JTQLQIEISA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical class [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 239000004218 Orcein Substances 0.000 description 2
- 229930014345 anabasine Natural products 0.000 description 2
- 235000012907 honey Nutrition 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 235000019248 orcein Nutrition 0.000 description 2
- 230000000384 rearing effect Effects 0.000 description 2
- 230000028327 secretion Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 238000010257 thawing Methods 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 101100136092 Drosophila melanogaster peng gene Proteins 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 230000007059 acute toxicity Effects 0.000 description 1
- 231100000403 acute toxicity Toxicity 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000008450 motivation Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000019617 pupation Effects 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K47/00—Beehives
- A01K47/04—Artificial honeycombs
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K47/00—Beehives
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K47/00—Beehives
- A01K47/02—Construction or arrangement of frames for honeycombs
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K47/00—Beehives
- A01K47/06—Other details of beehives, e.g. ventilating devices, entrances to hives, guards, partitions or bee escapes
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Animal Husbandry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
Abstract
The invention discloses a kind of septum that can reduce agricultural chemicals and pesticide residues, and it is that traditionally the production method of beeswax septum is prepared after adding the sorbing materials such as activated carbon in beeswax.Gained septum of the invention can effectively adsorb agricultural chemicals and insecticide in beeswax; its Pesticides is set to be reduced with pesticide residue number; to protect the normal development of larva, moreover it is possible to the accumulation of remains of pesticide and insecticide during beeswax recycling is avoided, so as to ensure and be lifted the quality of bee product.
Description
Technical field
Present invention relates particularly to a kind of septum that can reduce agricultural chemicals and pesticide residues and the honeycomb prepared on its basis,
The bee colony feeding materials such as frame, beehive.
Background technology
Agricultural chemicals has resulted in global honeybee crisis of survival with insecticide.Research has shown that, is contacted in bee larva developmental process
Behavior and ability is low after causing its speed of growth and adult to insecticide, also has significant shadow even if the insecticide of denier
Ring.Dispute on larger in insecticide and be anabasine medicine by extensive concern, such medicine is systemic drug, can be in plant
Whole body spreads, the pollen and nectar that can be gathered comprising honeybee, although there are a strict keyholed back plate on usage amount and opportunity, honeybee is still organic
The food for rewinding the insecticides can be contacted and adopt, and having determined this kind of insecticides at present has stronger shadow to honeybee
Ring, except acute toxicity causes death in addition to, sublethal dose can cause behavior be immunized on influence, if bee larva is developing
Period contacts the insecticides, has the normal phenomenon of illegal act (Peng and Yang 2016) after developing adult.Separately there is research
Point out, generally existing pesticide residues in beeswax caused by bee colony, because most insecticides are that fat-soluble and heat endurance is good
It is good, it is not easy to separated from beeswax, under the circulation that beeswax constantly melts recycling, the amount and species of the agricultural chemicals remained in beeswax
Far exceed the imagination.
The basis of bee colony construction honeycomb is given when septum is raising honeybee, is to have lair bottom three through what comb foundation machine suppressed
The wax disk(-sc) of prismatic shape decorative pattern, after additional frame, bee colony can be added, honeybee can be on septum plus the beeswax of oneself secretion, gradually
Hexagon trellis lair construction is constructed out, turns into honeycomb.Although the research to honeybee and insecticide is very more, so far not
Have and remove or reduce the research of pesticide residues or method in beeswax used in building honeycomb, this causes to be permitted in bee rearing management
It is more difficult.Currently the only feasible suggestion is to abandon the honeycomb using more than the several years, allows honeybee to secrete new beeswax structure again
New honeycomb.But new frame not only increases the production cost of peasant with septum, honeybee secretion beeswax is also required to higher-energy
Consumption.There is research to point out, one kilogram of beeswax at least needs to consume more than about 8 kilograms of honey, and this allows peasant to abandon honeycomb
Motivation greatly declines.In addition, the beeswax majority for abandoning honeycomb can be reclaimed by dealer and beeswax septum is made again, or the production of other beeswaxs
Product.And pass through in new septum made of simple thawing, filtering and molding step, not any step can effectively go to kill off
Worm agent.
The content of the invention
It is an object of the invention to provide a kind of septum that can reduce agricultural chemicals and pesticide residues, and it utilizes sorbing material
The agricultural chemicals and insecticide effectively absorbed in beeswax is added, its Pesticides is reduced with pesticide residue number, to protect larva
Normal development, and it is avoided that the accumulation of remains of pesticide and insecticide during septum recycling, so as to ensure and be lifted honeybee
The quality of product.
To achieve the above object, the present invention adopts the following technical scheme that：
An object of the present invention is a kind of septum that can reduce agricultural chemicals and pesticide residues of protection, and it is to melt beeswax, is added
Enter beeswax weight 2.5-10%, the sorbing material that granular size is 1000-2000 mesh, stir until no longer occurring on sorbing material
Bubble and untill being fused in beeswax, is then cooled to 60 DEG C, is shaken up, poured into model and cool down, further in accordance with traditional beeswax
The production method of septum, it is prepared through laminated flake, embossing, shearing.
The sorbing material includes activated carbon or charcoal.
It is another object of the present invention to protect the bee colonies such as the honeycomb for preparing the above after improved, frame, beehive to raise
Material is supported, it is according to same principle, in septum and other bee larvas or adult accessible surface addition wax and adsorption material
Material, to reach the effect for reducing honeybee contact insecticide.
Research finds that the fat-soluble insecticide such as anabasine can also spread in solid-state beeswax.The present invention is by beeswax
The middle septum and other bee colony feeding materials for adding sorbing material and preparing, can utilize the suction-operated of material effectively to absorb beeswax
In agricultural chemicals and insecticide so that material Pesticides and pesticide residue number reduce.Meanwhile when beeswax recycles,
Only need to filter off the beeswax of thawing except sorbing material, it is possible to effectively by agrochemical small-molecule substance from beeswax
Remove.
The remarkable advantage of the present invention is：
Gained septum of the invention can effectively reduce agricultural chemicals and pesticide residue number in beeswax, protect the normal hair of larva
Educate, moreover it is possible to the accumulation of remains of pesticide and insecticide during beeswax recycling is avoided, so as to ensure and be lifted the product of bee product
Matter.It the experiment proved that, honeybee smoothly can build lair on septum of the present invention added with sorbing material activated carbon.
Brief description of the drawings
Fig. 1 is the sample point position view determined on septum.
Fig. 2 is velocity contrast's figure that honeybee builds lair on the septum of different activities carbon content, wherein, dotted line is trend
Line, solid line are measured data line.
Fig. 3 is growth and breeding situation map of the honeybee on the septum of different activities carbon content.
Fig. 4 is that the parcel woods of worm containing pyrrole is cut into slices from the different septums of orchil beeswax piece.
Fig. 5 is the contrast situation of pyrrole worm woods mean concentration in the septum of charcoal containing different activities after being compared on the basis of control.
Embodiment
In order that content of the present invention easily facilitates understanding, with reference to embodiment to of the present invention
Technical scheme is described further, but the present invention is not limited only to this.
Embodiment 1
Beeswax is melted, the active carbon powder of beeswax weight 0%, 2.5%, 5% is separately added into, stirs until no longer going out on activated carbon
Untill existing bubble, 60 DEG C are then cooled to, is shaken up, pours into model and cools down, then the traditionally making of beeswax septum
Mode, laminated flake and embossing, cut into septum size.
1. the septum of different activities carbon content is put into the different bee colonies of same honeybee kind simultaneously, as shown in Figure 1 in septum
The different sample point of upper selection, record bee colony increase the speed for building lair on septum, record once within every 3 days, until lair height
Reach about 12mm or so（General lair completes height）, as a result as shown in Figure 2.Although from Figure 2 it can be seen that add the septum of activated carbon
Construction speed is slightly slow, but all bee colonies can smoothly be built into completion height, show bee colony to the septum containing activated carbon
Receive good.
Tested 2. the septum of different activities carbon content is respectively put into the different bee colonies of same honeybee kind, as a result such as
Shown in Fig. 3（Wherein A is storage honey and pollen situation on the septum containing 2.5% activated carbon, and B is on the septum containing 5% activated carbon
Food storage with feed larva situation, C be on the septum without activated carbon self-assembling formation royal cell construction, D be containing 10%
Larvae pupation and capping situation are sealed on the septum of activated carbon）.As seen from Figure 3, add activated carbon and do not add the nest of activated carbon
Plinth can be received by bee colony, and can construct royal cell, bee colony receives shape to different septums with normal storage food, rearing of larvae
Condition and service condition are without significant difference.
Embodiment 2
Each uniform beeswax piece of one layer of the cladding containing 1 ppm pyrrole worm woodss and orchil in the septum section of different activities carbon content
（It is about 5 × 5cm to coat area）（As shown in Figure 4）, it is statically placed in the growth case of simulation cellular environment（34.5 DEG C, relatively
Humidity 60-80%）, to reduce the interference that may be met with bee colony is tested with becoming because collecting surface covering respectively through 40,55 days
Beeswax piece, the concentration mensuration of measure wherein pyrrole worm woods（Each beeswax piece has two sides, can collect about 0.8-1 grams beeswax）, to comment
Estimate activated carbon septum and absorb insecticide ability, to be not added with the septum of activated carbon preparation as control.
Method for measurement of concentration is：The beeswax of collection is weighed, takes 1g to be placed in 10 mL centrifuge tubes, adds 5mL 1:1（v/
v）Acetonitrile-water mixed solution, in 80 DEG C of water-baths heat 20min after, add 1g anhydrous magnesium sulfates, vortex 1min, pipette 1mL
Supernatant adds 50mg PSA and 50mg C18 in 2mL centrifuge tubes（Impurity is absorbed, reduces interference）, 150mg anhydrous magnesium sulfates,
6000rpm centrifuges 5min after vortex 1min, and supernatant crosses 0.22um filter membranes, for liquid chromatogram measuring, as a result as shown in Figure 5.
As seen from Figure 5, the concentration of pyrrole worm woods has decline in the beeswax piece being wrapped in septum section, and display pyrrole worm woods has
Diffusion；And the concentration for being covered in the pyrrole worm woods in the beeswax piece in the section of septum containing activated carbon is being located compared with low without activated carbon
Reason is after 55 days, and the mean concentration of pyrrole worm woods reduces more than 10% in the beeswax piece containing 10% activated carbon, and this explanation contains activated carbon
Septum have absorb pyrrole worm woods ability.Because honeybee is to secrete that honeybee is cured to be fabricated to lair on septum, and the nest containing activated carbon
Insecticide is absorbed in the beeswax that plinth can cover from surface, then the chance of honeybee contact insecticide can be effectively reduced, to protect honeybee
Normal growth and development and improve the quality of bee product.
The foregoing is only presently preferred embodiments of the present invention, all equivalent changes done according to scope of the present invention patent with
Modification, it should all belong to the covering scope of the present invention.
Claims (4)
- A kind of 1. septum that can reduce agricultural chemicals and pesticide residues, it is characterised in that：Beeswax is melted, adds a certain amount of absorption Material, is stirred untill no longer there is bubble on sorbing material, is then cooled to 60 DEG C, shaken up, and is poured into cold in model But, further in accordance with the production method of traditional beeswax septum, through laminated flake, embossing, shearing, the septum is made.
- 2. the septum of low agricultural chemicals and pesticide residues can be reduced according to claim 1, it is characterised in that：The sorbing material Addition be beeswax weight 2.5-10%, its granular size is 1000-2000 mesh.
- 3. the septum of low agricultural chemicals and pesticide residues can be reduced according to claim 1, it is characterised in that：The sorbing material Including activated carbon or charcoal.
- It is 4. a kind of in the bee colony feeding materials prepared described in claim 1 on septum, it is characterised in that：The bee colony feeding materials Including any one in honeycomb, frame, beehive and artificial royal cell.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710664697.6A CN107466908A (en) | 2017-08-07 | 2017-08-07 | A kind of septum that can reduce agricultural chemicals and pesticide residues |
| PCT/CN2017/097574 WO2019028929A1 (en) | 2017-08-07 | 2017-08-16 | Comb foundation for reducing pesticide and insecticide residue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710664697.6A CN107466908A (en) | 2017-08-07 | 2017-08-07 | A kind of septum that can reduce agricultural chemicals and pesticide residues |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107466908A true CN107466908A (en) | 2017-12-15 |
Family
ID=60597017
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710664697.6A Pending CN107466908A (en) | 2017-08-07 | 2017-08-07 | A kind of septum that can reduce agricultural chemicals and pesticide residues |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN107466908A (en) |
| WO (1) | WO2019028929A1 (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1069619A (en) * | 1991-08-22 | 1993-03-10 | 陈信洁 | Anti-beemite is prevented the foulbrood beehive base |
| CN1596625A (en) * | 2004-09-06 | 2005-03-23 | 赵振峰 | Biological disease prevention honeycomb matrix and its production method |
| KR100748895B1 (en) * | 2006-05-30 | 2007-08-17 | 유호창 | Beehive and behive manufacturing method using propolis |
| CN201630124U (en) * | 2010-03-26 | 2010-11-17 | 北京绿纯有机生物科技开发中心 | Artificial honeycomb with septum shared by two sides |
| CN106172085A (en) * | 2016-07-09 | 2016-12-07 | 慈溪市亿园蜜蜂授粉专业合作社 | A kind of manufacture method of propolis septum |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201536552U (en) * | 2009-11-26 | 2010-08-04 | 丁巨国 | Paper wax foundation |
| CN101810201A (en) * | 2010-04-16 | 2010-08-25 | 中国农业科学院蜜蜂研究所 | Biological preparation for preventing and treating nest insects |
| CN105454316A (en) * | 2015-12-20 | 2016-04-06 | 欧必煜 | Formula of Chinese bee Chinese herbal medicine comb foundation and making method |
-
2017
- 2017-08-07 CN CN201710664697.6A patent/CN107466908A/en active Pending
- 2017-08-16 WO PCT/CN2017/097574 patent/WO2019028929A1/en active Application Filing
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1069619A (en) * | 1991-08-22 | 1993-03-10 | 陈信洁 | Anti-beemite is prevented the foulbrood beehive base |
| CN1596625A (en) * | 2004-09-06 | 2005-03-23 | 赵振峰 | Biological disease prevention honeycomb matrix and its production method |
| KR100748895B1 (en) * | 2006-05-30 | 2007-08-17 | 유호창 | Beehive and behive manufacturing method using propolis |
| CN201630124U (en) * | 2010-03-26 | 2010-11-17 | 北京绿纯有机生物科技开发中心 | Artificial honeycomb with septum shared by two sides |
| CN106172085A (en) * | 2016-07-09 | 2016-12-07 | 慈溪市亿园蜜蜂授粉专业合作社 | A kind of manufacture method of propolis septum |
Non-Patent Citations (2)
| Title |
|---|
| 王永刚等: "《煤化工工艺学》", 30 September 2014, 中国矿业大学出版社 * |
| 薛慧文等: "《蜜蜂无公害饲养综合技术》", 31 January 2003, 中国农业出版社 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2019028929A1 (en) | 2019-02-14 |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171215 |
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