CN107429431A - 中间模量碳纤维的制造 - Google Patents

中间模量碳纤维的制造 Download PDF

Info

Publication number
CN107429431A
CN107429431A CN201680015296.1A CN201680015296A CN107429431A CN 107429431 A CN107429431 A CN 107429431A CN 201680015296 A CN201680015296 A CN 201680015296A CN 107429431 A CN107429431 A CN 107429431A
Authority
CN
China
Prior art keywords
carbon fiber
fibers
bath
fiber
carbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201680015296.1A
Other languages
English (en)
Chinese (zh)
Inventor
J.D.库克
T.泰勒
G.V.戴希潘德
L.唐
B.D.米斯
S.克劳福德
S.C.赵
B.D.哈蒙
A.托马斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cytec Industries Inc
Original Assignee
Cytec Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cytec Industries Inc filed Critical Cytec Industries Inc
Priority to CN202411048641.4A priority Critical patent/CN119020886A/zh
Publication of CN107429431A publication Critical patent/CN107429431A/zh
Pending legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/06Wet spinning methods
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/05Filamentary, e.g. strands
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/18Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/14Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
    • D01F9/20Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products
    • D01F9/21Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F9/22Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyacrylonitriles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2033/00Use of polymers of unsaturated acids or derivatives thereof as moulding material
    • B29K2033/18Polymers of nitriles
    • B29K2033/20PAN, i.e. polyacrylonitrile
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/731Filamentary material, i.e. comprised of a single element, e.g. filaments, strands, threads, fibres
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/28Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/38Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising unsaturated nitriles as the major constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/14Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
    • D01F9/20Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products
    • D01F9/21Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F9/22Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyacrylonitriles
    • D01F9/225Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyacrylonitriles from stabilised polyacrylonitriles

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Inorganic Fibers (AREA)
  • Artificial Filaments (AREA)
CN201680015296.1A 2015-03-12 2016-02-15 中间模量碳纤维的制造 Pending CN107429431A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202411048641.4A CN119020886A (zh) 2015-03-12 2016-02-15 中间模量碳纤维的制造

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562132137P 2015-03-12 2015-03-12
US62/132137 2015-03-12
PCT/US2016/017940 WO2016144488A1 (en) 2015-03-12 2016-02-15 Manufacture of intermediate modulus carbon fiber

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN202411048641.4A Division CN119020886A (zh) 2015-03-12 2016-02-15 中间模量碳纤维的制造

Publications (1)

Publication Number Publication Date
CN107429431A true CN107429431A (zh) 2017-12-01

Family

ID=56878943

Family Applications (2)

Application Number Title Priority Date Filing Date
CN201680015296.1A Pending CN107429431A (zh) 2015-03-12 2016-02-15 中间模量碳纤维的制造
CN202411048641.4A Pending CN119020886A (zh) 2015-03-12 2016-02-15 中间模量碳纤维的制造

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN202411048641.4A Pending CN119020886A (zh) 2015-03-12 2016-02-15 中间模量碳纤维的制造

Country Status (9)

Country Link
US (2) US20160263803A1 (enExample)
EP (1) EP3268516B1 (enExample)
JP (2) JP6817970B2 (enExample)
KR (1) KR102528151B1 (enExample)
CN (2) CN107429431A (enExample)
BR (1) BR112017019080B1 (enExample)
CA (1) CA2979199A1 (enExample)
ES (1) ES2986821T3 (enExample)
WO (1) WO2016144488A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112410891A (zh) * 2019-08-20 2021-02-26 蒙特美艾意技术有限责任公司 用于生产碳纤维的丙烯酸类纤维前体用纺丝溶液的制备优化方法,和相关碳纤维

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107429431A (zh) * 2015-03-12 2017-12-01 塞特工业公司 中间模量碳纤维的制造
KR102216640B1 (ko) * 2018-01-09 2021-02-17 주식회사 엘지화학 폴리아크릴로니트릴계 섬유의 제조방법 및 이에 이용되는 폴리아크릴로니트릴계 공중합체
KR102760710B1 (ko) * 2018-07-02 2025-02-03 사이텍 인더스트리스 인코포레이티드 탄소 섬유 제조용 중합체 및 이로부터 제조된 탄소 섬유
WO2020069195A1 (en) * 2018-09-26 2020-04-02 Cytec Industries, Inc. Controlling the degree of swelling of polymer fibers during coagulation
CN120925088A (zh) 2019-05-02 2025-11-11 塞特工业公司 用于由低多分散性聚丙烯腈制备碳纤维的方法
CN116670341A (zh) * 2020-12-23 2023-08-29 塞特工业公司 用于生产具有受控形态的基于聚丙烯腈的纤维的方法
TWI762414B (zh) 2021-08-25 2022-04-21 臺灣塑膠工業股份有限公司 碳纖維之製造方法
CN119677902A (zh) * 2022-10-24 2025-03-21 东丽株式会社 碳纤维束及使用其的碳纤维增强复合材料
WO2024186324A1 (en) * 2023-03-06 2024-09-12 Aulisio Leander F Process for preparing a carbon fiber precursor

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101760791A (zh) * 2009-11-24 2010-06-30 中复神鹰碳纤维有限责任公司 一种干喷湿纺制备高性能聚丙烯腈基碳纤维原丝的方法
US20120088104A1 (en) * 2009-06-10 2012-04-12 Mitsubishi Rayon Co., Ltd. Acrylonitrile swollen fiber for carbon fiber, precursor fiber bundle, stabilized fiber bundle, carbon fiber bundle and production methods thereof
CN102766989A (zh) * 2012-07-25 2012-11-07 北京化工大学 一种具有中模量的高强度聚丙烯腈基碳纤维及其制备方法
US20130101494A1 (en) * 2011-10-21 2013-04-25 Wacker Chemical Corporation Hydrophilic Silicone Copolymers Useful In Carbon Fiber Production
CN103184590A (zh) * 2013-04-15 2013-07-03 西安康本材料有限公司 一种强度为4800~5000MPa碳纤维的制备方法
CN103334180A (zh) * 2013-06-26 2013-10-02 中简科技发展有限公司 一种三角形截面聚丙烯腈炭纤维的制备方法
CN103409854A (zh) * 2013-08-28 2013-11-27 西安元创化工科技股份有限公司 一种碳纤维的生产方法

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4078034A (en) * 1976-12-21 1978-03-07 E. I. Du Pont De Nemours And Company Air gage spinning process
DE3621257A1 (de) * 1986-06-25 1988-01-07 Akzo Gmbh Verfahren zur herstellung poren aufweisender kohlenstoffmembranen
JPH0397918A (ja) * 1989-09-05 1991-04-23 Toray Ind Inc 異形断面炭素繊維の製造法
JP3223452B2 (ja) * 1991-02-08 2001-10-29 三菱レイヨン株式会社 炭素繊維前駆体繊維の製造方法
DE19651440A1 (de) * 1996-12-11 1998-06-18 Hoechst Ag Hochfeste Polyacrylnitrilfasern hohen Moduls, Verfahren zu deren Herstellung und deren Verwendung
CN1105793C (zh) * 1997-08-27 2003-04-16 三菱丽阳株式会社 用于形成碳纤维的丙烯腈-基前体纤维、及其制备方法以及由该前体纤维得到的碳纤维
JP4975217B2 (ja) * 2001-03-06 2012-07-11 三菱レイヨン株式会社 炭素繊維とその製造方法、炭素繊維用前駆体繊維の製造方法並びにプリプレグ
JP4243141B2 (ja) * 2002-12-24 2009-03-25 昭和電工株式会社 硬化性組成物、その硬化物およびその成形体
US7941903B2 (en) 2004-02-13 2011-05-17 Mitsubishi Rayon Co., Ltd. Carbon fiber precursor fiber bundle, production method and production device therefor, and carbon fiber and production method therefor
US20060197244A1 (en) * 2005-03-07 2006-09-07 Honeywell International Inc. Mold fixture to densify composite beam key using resin transfer molding
US7749479B2 (en) * 2006-11-22 2010-07-06 Hexcel Corporation Carbon fibers having improved strength and modulus and an associated method and apparatus for preparing same
ES2389832T3 (es) 2007-12-30 2012-11-02 Toho Tenax Co., Ltd. Procedimiento de producción de fibras ignífugas y fibra de carbono
US8372323B2 (en) 2009-09-10 2013-02-12 International Fibers, Ltd. Process of making polyacrylonitrile fibers
JP5151809B2 (ja) * 2008-08-27 2013-02-27 東レ株式会社 炭素繊維前駆体繊維の製造方法
JP5109936B2 (ja) * 2008-11-10 2012-12-26 東レ株式会社 炭素繊維前駆体繊維と炭素繊維の製造方法
JP5169939B2 (ja) * 2009-03-26 2013-03-27 東レ株式会社 炭素繊維前駆体繊維と炭素繊維の製造方法
KR101578985B1 (ko) * 2011-01-21 2015-12-18 미쯔비시 레이온 가부시끼가이샤 다공질 전극 기재, 그 제조 방법, 막-전극 접합체, 고체 고분자형 연료 전지, 전구체 시트, 및 피브릴상 섬유
US9096955B2 (en) * 2011-09-30 2015-08-04 Ut-Battelle, Llc Method for the preparation of carbon fiber from polyolefin fiber precursor, and carbon fibers made thereby
US9409823B2 (en) * 2013-02-15 2016-08-09 Deborah D. L. Chung Microstructured high-temperature hybrid material, its composite material and method of making
WO2014138807A1 (en) * 2013-03-15 2014-09-18 Commonwealth Scientific And Industrial Research Organisation Polymer derived from acrylonitrile
KR102189516B1 (ko) 2013-07-30 2020-12-11 도레이 카부시키가이샤 탄소 섬유 다발 및 내염화 섬유 다발
US20160326672A1 (en) * 2014-01-08 2016-11-10 The University Of Tokyo Pan-based carbon fiber and production method therefor
US20170233897A1 (en) * 2014-08-27 2017-08-17 Mitsubishi Rayon Co., Ltd. Glossy pilling-resistant acrylic fiber, method for producing same, and spun yarn and knitted fabric containing said acrylic fiber
CN107429431A (zh) 2015-03-12 2017-12-01 塞特工业公司 中间模量碳纤维的制造

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120088104A1 (en) * 2009-06-10 2012-04-12 Mitsubishi Rayon Co., Ltd. Acrylonitrile swollen fiber for carbon fiber, precursor fiber bundle, stabilized fiber bundle, carbon fiber bundle and production methods thereof
CN102459722A (zh) * 2009-06-10 2012-05-16 三菱丽阳株式会社 碳纤维用丙烯腈溶胀丝、前驱体纤维束、耐火化纤维束、碳纤维束以及它们的制造方法
CN101760791A (zh) * 2009-11-24 2010-06-30 中复神鹰碳纤维有限责任公司 一种干喷湿纺制备高性能聚丙烯腈基碳纤维原丝的方法
US20130101494A1 (en) * 2011-10-21 2013-04-25 Wacker Chemical Corporation Hydrophilic Silicone Copolymers Useful In Carbon Fiber Production
CN102766989A (zh) * 2012-07-25 2012-11-07 北京化工大学 一种具有中模量的高强度聚丙烯腈基碳纤维及其制备方法
CN103184590A (zh) * 2013-04-15 2013-07-03 西安康本材料有限公司 一种强度为4800~5000MPa碳纤维的制备方法
CN103334180A (zh) * 2013-06-26 2013-10-02 中简科技发展有限公司 一种三角形截面聚丙烯腈炭纤维的制备方法
CN103409854A (zh) * 2013-08-28 2013-11-27 西安元创化工科技股份有限公司 一种碳纤维的生产方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112410891A (zh) * 2019-08-20 2021-02-26 蒙特美艾意技术有限责任公司 用于生产碳纤维的丙烯酸类纤维前体用纺丝溶液的制备优化方法,和相关碳纤维

Also Published As

Publication number Publication date
CN119020886A (zh) 2024-11-26
JP2018508667A (ja) 2018-03-29
BR112017019080A2 (pt) 2018-04-17
JP2021004437A (ja) 2021-01-14
BR112017019080B1 (pt) 2022-03-29
KR20170122785A (ko) 2017-11-06
US20160263803A1 (en) 2016-09-15
EP3268516A1 (en) 2018-01-17
EP3268516B1 (en) 2024-06-12
US20170362742A1 (en) 2017-12-21
ES2986821T3 (es) 2024-11-12
WO2016144488A1 (en) 2016-09-15
CA2979199A1 (en) 2016-09-15
KR102528151B1 (ko) 2023-05-03
JP7225173B2 (ja) 2023-02-20
JP6817970B2 (ja) 2021-01-20
US11479881B2 (en) 2022-10-25

Similar Documents

Publication Publication Date Title
JP7225173B2 (ja) 中間弾性率炭素繊維の製造
CN107208324B (zh) 聚丙烯腈纤维的致密化
US10647844B2 (en) Polyacrylonitrile (PAN) polymers with low polydispersity index (PDI) and carbon fibers made therefrom
EP2735575A1 (en) Polyacrylonitrile-based copolymer, polyacrylonitrile-based precursor fiber for carbon fiber, carbon fiber bundles, process for producing flameproofed fiber bundles, and process for producing carbon fiber bundles
Yi et al. Study on optimum coagulation conditions of high molecular weight PAN fiber in wet spinning by orthogonal experimental design
US12129575B2 (en) Controlling the degree of swelling of polymer fibers during coagulation

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20171201

RJ01 Rejection of invention patent application after publication