CN107406340A - 将含烯烃的烃进料转化为低聚产物或氢化低聚产物的方法 - Google Patents

将含烯烃的烃进料转化为低聚产物或氢化低聚产物的方法 Download PDF

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Publication number
CN107406340A
CN107406340A CN201580077735.7A CN201580077735A CN107406340A CN 107406340 A CN107406340 A CN 107406340A CN 201580077735 A CN201580077735 A CN 201580077735A CN 107406340 A CN107406340 A CN 107406340A
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Prior art keywords
oligomerization
olefins
olefin
feed
content
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CN201580077735.7A
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English (en)
Chinese (zh)
Inventor
E·德斯米特
M·詹森
M·普特曼斯
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ExxonMobil Chemical Patents Inc
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Exxon Chemical Patents Inc
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Publication of CN107406340A publication Critical patent/CN107406340A/zh
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08Catalytic processes
    • C07C2/12Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7026MFS-type, e.g. ZSM-57
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08Catalytic processes
    • C07C2/14Catalytic processes with inorganic acids; with salts or anhydrides of acids
    • C07C2/18Acids of phosphorus; Salts thereof; Phosphorus oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/32Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/38Base treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7042TON-type, e.g. Theta-1, ISI-1, KZ-2, NU-10 or ZSM-22
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14Phosphorus; Compounds thereof
    • C07C2527/16Phosphorus; Compounds thereof containing oxygen
    • C07C2527/167Phosphates or other compounds comprising the anion (PnO3n+1)(n+2)-
    • C07C2527/173Phosphoric acid or other acids with the formula Hn+2PnO3n+1
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN201580077735.7A 2015-03-20 2015-11-27 将含烯烃的烃进料转化为低聚产物或氢化低聚产物的方法 Pending CN107406340A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP15159993 2015-03-20
EP15159993.3 2015-03-20
PCT/EP2015/077935 WO2016150529A1 (en) 2015-03-20 2015-11-27 Process for converting an olefin containing hydrocarbon feed into an oligomerization product or a hydrogenated oligomerization product

Publications (1)

Publication Number Publication Date
CN107406340A true CN107406340A (zh) 2017-11-28

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CN201580077735.7A Pending CN107406340A (zh) 2015-03-20 2015-11-27 将含烯烃的烃进料转化为低聚产物或氢化低聚产物的方法

Country Status (7)

Country Link
US (1) US10508063B2 (https=)
EP (1) EP3271315A1 (https=)
JP (1) JP2018508557A (https=)
CN (1) CN107406340A (https=)
AU (1) AU2015387361B2 (https=)
RU (1) RU2017131237A (https=)
WO (1) WO2016150529A1 (https=)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112867701A (zh) * 2018-10-17 2021-05-28 埃克森美孚化学专利公司 烯烃的低聚
CN112867700A (zh) * 2018-10-17 2021-05-28 埃克森美孚化学专利公司 烯烃的低聚
CN119110841A (zh) * 2022-04-06 2024-12-10 埃克森美孚技术与工程公司 用于将c2+烯烃转化为可用于产生异链烷烃煤油组合物的更高碳数烯烃的方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8969259B2 (en) 2013-04-05 2015-03-03 Reg Synthetic Fuels, Llc Bio-based synthetic fluids

Citations (4)

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US5177282A (en) * 1989-05-05 1993-01-05 Huels Aktiengesellschaft Oligomerization of olefins
US20030171632A1 (en) * 2000-07-10 2003-09-11 Du Toit Francois Benjamin Process and apparatus for the production of diesel fuels by oligomerisation of olefinic feed streams
CN1220658C (zh) * 2000-04-28 2005-09-28 埃克森美孚化学专利公司 烯烃低聚方法
CN1960955A (zh) * 2004-06-01 2007-05-09 埃克森美孚化学专利公司 烯烃低聚反应方法

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US4021502A (en) 1975-02-24 1977-05-03 Mobil Oil Corporation Converting low molecular weight olefins over zeolites
US4016218A (en) 1975-05-29 1977-04-05 Mobil Oil Corporation Alkylation in presence of thermally modified crystalline aluminosilicate catalyst
US4381255A (en) 1981-01-14 1983-04-26 W. R. Grace & Co. Binderless zeolite extrudates and method of producing
US4560536A (en) 1983-08-26 1985-12-24 Mobil Oil Corporation Catalytic conversion with catalyst regeneration sequence
DE3867245D1 (de) * 1987-01-23 1992-02-13 Mobil Oil Corp Verbesserung von diolefine enthaltenden kohlenwasserstoffen.
US5026933A (en) 1987-10-07 1991-06-25 Mobil Oil Corporation Olefin oligomerization with surface modified zeolite catalyst
US4919896A (en) 1987-12-28 1990-04-24 Mobil Oil Corporation Multistage catalytic reactor system for production of heavy hydrocarbons
US4973790A (en) 1989-11-16 1990-11-27 Mobil Oil Corporation Process for upgrading light olefinic streams
CA2128624C (en) 1992-01-30 2001-11-20 Georges M. K. Mathys Alkene oligomerization
GB9225183D0 (en) 1992-12-02 1993-01-20 British Petroleum Co Plc Process for the production of branched olefins
US6143942A (en) 1994-02-22 2000-11-07 Exxon Chemical Patents Inc. Oligomerization and catalysts therefor
US5446222A (en) 1994-06-17 1995-08-29 Mobil Oil Corporation Oligomers of cyclopentadiene and process for making them
GB9502342D0 (en) 1995-02-07 1995-03-29 Exxon Chemical Patents Inc Hydrocarbon treatment and catalyst therefor
DE19654166A1 (de) * 1996-12-23 1998-06-25 Basf Ag Von Cyclopenten abgeleitete Oligomerengemische, Verfahren zu ihrer Herstellung und ihre Verwendung
ATE240266T1 (de) 1998-09-22 2003-05-15 Exxonmobil Chem Patents Inc Verfahren zur herstellung von durch zeolith gebundenen zeolithen mit hohem sio2-gehalt und ihre verwendung
US6875899B2 (en) 2001-02-01 2005-04-05 Exxonmobil Chemical Patents Inc. Production of higher olefins
WO2005058777A1 (en) 2003-12-18 2005-06-30 Exxonmobil Chemical Patents Inc. Improvements in or relating to catalysed reactions
GB0412151D0 (en) 2004-06-01 2004-06-30 Exxonmobil Chem Patents Inc Olefin oligomerization process
US7678953B2 (en) 2005-01-31 2010-03-16 Exxonmobil Chemical Patents Inc. Olefin oligomerization
JP5102943B2 (ja) * 2005-05-25 2012-12-19 Jx日鉱日石エネルギー株式会社 固体リン酸触媒およびそれを用いたオレフィンの二量化反応方法
GB0512377D0 (en) 2005-06-17 2005-07-27 Exxonmobil Chem Patents Inc Oligomerisation of olefins with zeolite catalyst
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WO2012033562A1 (en) 2010-09-07 2012-03-15 Exxonmobil Chemical Patents Inc. Extrudates including zeolite catalysts and their use in oligomerization processes
EP2649160B1 (en) 2010-12-07 2022-03-16 ExxonMobil Chemical Patents Inc. Processes utilizing solvent extraction
EP2736632B1 (en) 2011-07-25 2017-02-01 ExxonMobil Chemical Patents Inc. Integrated nitrile poison adsorption and desorption system
US9550705B2 (en) 2011-07-25 2017-01-24 Exxonmobill Chemical Patents Inc. Olefin oligomerization process
WO2013013887A2 (en) 2011-07-25 2013-01-31 Exxonmobil Chemical Patents Inc. Olefin oligomerization process
WO2013013888A2 (en) 2011-07-25 2013-01-31 Exxonmobil Chemical Patents Inc. Olefin oligomerization process
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* Cited by examiner, † Cited by third party
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US5177282A (en) * 1989-05-05 1993-01-05 Huels Aktiengesellschaft Oligomerization of olefins
CN1220658C (zh) * 2000-04-28 2005-09-28 埃克森美孚化学专利公司 烯烃低聚方法
US20030171632A1 (en) * 2000-07-10 2003-09-11 Du Toit Francois Benjamin Process and apparatus for the production of diesel fuels by oligomerisation of olefinic feed streams
CN1960955A (zh) * 2004-06-01 2007-05-09 埃克森美孚化学专利公司 烯烃低聚反应方法

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112867701A (zh) * 2018-10-17 2021-05-28 埃克森美孚化学专利公司 烯烃的低聚
CN112867700A (zh) * 2018-10-17 2021-05-28 埃克森美孚化学专利公司 烯烃的低聚
CN119110841A (zh) * 2022-04-06 2024-12-10 埃克森美孚技术与工程公司 用于将c2+烯烃转化为可用于产生异链烷烃煤油组合物的更高碳数烯烃的方法

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Publication number Publication date
RU2017131237A3 (https=) 2019-04-22
EP3271315A1 (en) 2018-01-24
US20180037520A1 (en) 2018-02-08
JP2018508557A (ja) 2018-03-29
WO2016150529A1 (en) 2016-09-29
RU2017131237A (ru) 2019-04-22
AU2015387361A1 (en) 2017-11-02
US10508063B2 (en) 2019-12-17
AU2015387361B2 (en) 2019-10-31

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Application publication date: 20171128