RU2017131237A - Способ превращения содержащего олефин углеводородного сырья в продукт реакции олигомеризации или гидрированный продукт реакции олигомеризации - Google Patents
Способ превращения содержащего олефин углеводородного сырья в продукт реакции олигомеризации или гидрированный продукт реакции олигомеризации Download PDFInfo
- Publication number
- RU2017131237A RU2017131237A RU2017131237A RU2017131237A RU2017131237A RU 2017131237 A RU2017131237 A RU 2017131237A RU 2017131237 A RU2017131237 A RU 2017131237A RU 2017131237 A RU2017131237 A RU 2017131237A RU 2017131237 A RU2017131237 A RU 2017131237A
- Authority
- RU
- Russia
- Prior art keywords
- oligomerization
- olefin
- olefins
- reaction product
- product
- Prior art date
Links
- 238000006384 oligomerization reaction Methods 0.000 title claims 22
- 238000000034 method Methods 0.000 title claims 19
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims 16
- 239000004215 Carbon black (E152) Substances 0.000 title claims 7
- -1 OLEFIN HYDROCARBON Chemical class 0.000 title claims 7
- 229930195733 hydrocarbon Natural products 0.000 title claims 7
- 239000002994 raw material Substances 0.000 title claims 4
- 150000001336 alkenes Chemical class 0.000 claims 11
- 239000007795 chemical reaction product Substances 0.000 claims 11
- 239000003054 catalyst Substances 0.000 claims 8
- 239000000203 mixture Substances 0.000 claims 6
- 150000002430 hydrocarbons Chemical class 0.000 claims 5
- 238000009835 boiling Methods 0.000 claims 4
- 239000000047 product Substances 0.000 claims 4
- 125000004122 cyclic group Chemical group 0.000 claims 3
- 230000009849 deactivation Effects 0.000 claims 3
- 238000004821 distillation Methods 0.000 claims 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 claims 2
- 238000005984 hydrogenation reaction Methods 0.000 claims 2
- 125000004817 pentamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims 2
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims 2
- 229910021536 Zeolite Inorganic materials 0.000 claims 1
- 125000002015 acyclic group Chemical group 0.000 claims 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 150000001924 cycloalkanes Chemical class 0.000 claims 1
- 150000001925 cycloalkenes Chemical class 0.000 claims 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims 1
- 239000010457 zeolite Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7026—MFS-type, e.g. ZSM-57
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/14—Catalytic processes with inorganic acids; with salts or anhydrides of acids
- C07C2/18—Acids of phosphorus; Salts thereof; Phosphorus oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/38—Base treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7042—TON-type, e.g. Theta-1, ISI-1, KZ-2, NU-10 or ZSM-22
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/14—Phosphorus; Compounds thereof
- C07C2527/16—Phosphorus; Compounds thereof containing oxygen
- C07C2527/167—Phosphates or other compounds comprising the anion (PnO3n+1)(n+2)-
- C07C2527/173—Phosphoric acid or other acids with the formula Hn+2PnO3n+1
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP15159993.3 | 2015-03-20 | ||
| EP15159993 | 2015-03-20 | ||
| PCT/EP2015/077935 WO2016150529A1 (en) | 2015-03-20 | 2015-11-27 | Process for converting an olefin containing hydrocarbon feed into an oligomerization product or a hydrogenated oligomerization product |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2017131237A3 RU2017131237A3 (https=) | 2019-04-22 |
| RU2017131237A true RU2017131237A (ru) | 2019-04-22 |
Family
ID=52692530
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2017131237A RU2017131237A (ru) | 2015-03-20 | 2015-11-27 | Способ превращения содержащего олефин углеводородного сырья в продукт реакции олигомеризации или гидрированный продукт реакции олигомеризации |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US10508063B2 (https=) |
| EP (1) | EP3271315A1 (https=) |
| JP (1) | JP2018508557A (https=) |
| CN (1) | CN107406340A (https=) |
| AU (1) | AU2015387361B2 (https=) |
| RU (1) | RU2017131237A (https=) |
| WO (1) | WO2016150529A1 (https=) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8969259B2 (en) | 2013-04-05 | 2015-03-03 | Reg Synthetic Fuels, Llc | Bio-based synthetic fluids |
| CN112867700A (zh) * | 2018-10-17 | 2021-05-28 | 埃克森美孚化学专利公司 | 烯烃的低聚 |
| EP3867212A4 (en) * | 2018-10-17 | 2022-08-31 | ExxonMobil Chemical Patents Inc. | OLEFIN OLIGOMERIZATION |
| US12012561B2 (en) * | 2022-04-06 | 2024-06-18 | ExxonMobil Technology and Engineering Company | Methods for converting C2+ olefins to higher carbon number olefins |
Family Cites Families (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3960978A (en) | 1974-09-05 | 1976-06-01 | Mobil Oil Corporation | Converting low molecular weight olefins over zeolites |
| US4021502A (en) | 1975-02-24 | 1977-05-03 | Mobil Oil Corporation | Converting low molecular weight olefins over zeolites |
| US4016218A (en) | 1975-05-29 | 1977-04-05 | Mobil Oil Corporation | Alkylation in presence of thermally modified crystalline aluminosilicate catalyst |
| US4381255A (en) | 1981-01-14 | 1983-04-26 | W. R. Grace & Co. | Binderless zeolite extrudates and method of producing |
| US4560536A (en) | 1983-08-26 | 1985-12-24 | Mobil Oil Corporation | Catalytic conversion with catalyst regeneration sequence |
| EP0275930B1 (en) * | 1987-01-23 | 1992-01-02 | Mobil Oil Corporation | Upgrading diene-containing hydrocarbons |
| US5026933A (en) | 1987-10-07 | 1991-06-25 | Mobil Oil Corporation | Olefin oligomerization with surface modified zeolite catalyst |
| US4919896A (en) | 1987-12-28 | 1990-04-24 | Mobil Oil Corporation | Multistage catalytic reactor system for production of heavy hydrocarbons |
| DE3914817C2 (de) | 1989-05-05 | 1995-09-07 | Huels Chemische Werke Ag | Verfahren zur Oligomerisierung von Olefinen |
| US4973790A (en) | 1989-11-16 | 1990-11-27 | Mobil Oil Corporation | Process for upgrading light olefinic streams |
| ZA93594B (en) | 1992-01-30 | 1993-08-31 | Exxon Chemical Patents Inc | Alkene oligomerisation. |
| GB9225183D0 (en) | 1992-12-02 | 1993-01-20 | British Petroleum Co Plc | Process for the production of branched olefins |
| AU681948B2 (en) | 1994-02-22 | 1997-09-11 | Exxon Chemical Patents Inc. | Oligomerization and catalysts therefor |
| US5446222A (en) | 1994-06-17 | 1995-08-29 | Mobil Oil Corporation | Oligomers of cyclopentadiene and process for making them |
| GB9502342D0 (en) | 1995-02-07 | 1995-03-29 | Exxon Chemical Patents Inc | Hydrocarbon treatment and catalyst therefor |
| DE19654166A1 (de) * | 1996-12-23 | 1998-06-25 | Basf Ag | Von Cyclopenten abgeleitete Oligomerengemische, Verfahren zu ihrer Herstellung und ihre Verwendung |
| EP1115657B1 (en) | 1998-09-22 | 2003-05-14 | ExxonMobil Chemical Patents Inc. | Preparation of high silica zeolites bound by zeolite and use thereof |
| GB0010433D0 (en) * | 2000-04-28 | 2000-06-14 | Exxon Chemical Patents Inc | Alkene oligomerization process |
| AU8141301A (en) * | 2000-07-10 | 2002-01-21 | Sasol Tech Pty Ltd | Process and apparatus for the production of diesel fuels by oligomerisation of olefinic feed streams |
| US6875899B2 (en) * | 2001-02-01 | 2005-04-05 | Exxonmobil Chemical Patents Inc. | Production of higher olefins |
| US20070255081A1 (en) | 2003-12-18 | 2007-11-01 | Exxonmobil Chemical Company | Catalysed Reactions |
| GB0412139D0 (en) * | 2004-06-01 | 2004-06-30 | Exxonmobil Chem Patents Inc | Olefin oligomerization process |
| GB0412151D0 (en) | 2004-06-01 | 2004-06-30 | Exxonmobil Chem Patents Inc | Olefin oligomerization process |
| US7678953B2 (en) | 2005-01-31 | 2010-03-16 | Exxonmobil Chemical Patents Inc. | Olefin oligomerization |
| JP5102943B2 (ja) * | 2005-05-25 | 2012-12-19 | Ｊｘ日鉱日石エネルギー株式会社 | 固体リン酸触媒およびそれを用いたオレフィンの二量化反応方法 |
| GB0512377D0 (en) | 2005-06-17 | 2005-07-27 | Exxonmobil Chem Patents Inc | Oligomerisation of olefins with zeolite catalyst |
| US7825204B2 (en) | 2006-12-19 | 2010-11-02 | Lyondell Chemical Technology, L.P. | Inorganic oxide extrudates |
| US20120022224A1 (en) | 2010-07-22 | 2012-01-26 | Geraldine Tosin | Particles Including Zeolite Catalysts And Their Use In Oligomerization Processes |
| WO2012033562A1 (en) | 2010-09-07 | 2012-03-15 | Exxonmobil Chemical Patents Inc. | Extrudates including zeolite catalysts and their use in oligomerization processes |
| EP2649160B1 (en) | 2010-12-07 | 2022-03-16 | ExxonMobil Chemical Patents Inc. | Processes utilizing solvent extraction |
| US9550705B2 (en) | 2011-07-25 | 2017-01-24 | Exxonmobill Chemical Patents Inc. | Olefin oligomerization process |
| US9776937B2 (en) | 2011-07-25 | 2017-10-03 | Exxonmobil Chemical Patents Inc. | Integrated nitrile poison adsorption and desorption system |
| WO2013013884A2 (en) | 2011-07-25 | 2013-01-31 | Exxonmobil Chemical Patents Inc. | Process for nitrile removal from hydrocarbon feeds |
| US9505685B2 (en) | 2011-07-25 | 2016-11-29 | Exxonmobil Chemical Patents Inc. | Olefin oligomerization process |
| US9573861B2 (en) | 2011-07-25 | 2017-02-21 | Exxonmobil Chemical Patents Inc. | Olefin oligomerization process |
-
2015
- 2015-11-27 JP JP2017549218A patent/JP2018508557A/ja active Pending
- 2015-11-27 CN CN201580077735.7A patent/CN107406340A/zh active Pending
- 2015-11-27 RU RU2017131237A patent/RU2017131237A/ru not_active Application Discontinuation
- 2015-11-27 WO PCT/EP2015/077935 patent/WO2016150529A1/en not_active Ceased
- 2015-11-27 EP EP15804369.5A patent/EP3271315A1/en not_active Withdrawn
- 2015-11-27 AU AU2015387361A patent/AU2015387361B2/en not_active Ceased
- 2015-11-27 US US15/550,700 patent/US10508063B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| AU2015387361A1 (en) | 2017-11-02 |
| US20180037520A1 (en) | 2018-02-08 |
| US10508063B2 (en) | 2019-12-17 |
| AU2015387361B2 (en) | 2019-10-31 |
| JP2018508557A (ja) | 2018-03-29 |
| CN107406340A (zh) | 2017-11-28 |
| RU2017131237A3 (https=) | 2019-04-22 |
| EP3271315A1 (en) | 2018-01-24 |
| WO2016150529A1 (en) | 2016-09-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA92 | Acknowledgement of application withdrawn (lack of supplementary materials submitted) |
Effective date: 20200423 |