CN107383243B - 双酯化活性磺酸基蔗渣木聚糖-1,1-二茂铁双甲酸酯的制备方法 - Google Patents
双酯化活性磺酸基蔗渣木聚糖-1,1-二茂铁双甲酸酯的制备方法 Download PDFInfo
- Publication number
- CN107383243B CN107383243B CN201710830883.2A CN201710830883A CN107383243B CN 107383243 B CN107383243 B CN 107383243B CN 201710830883 A CN201710830883 A CN 201710830883A CN 107383243 B CN107383243 B CN 107383243B
- Authority
- CN
- China
- Prior art keywords
- double
- bagasse xylan
- added
- ferrocene
- formic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920001221 xylan Polymers 0.000 title claims abstract description 66
- 241000609240 Ambelania acida Species 0.000 title claims abstract description 57
- 239000010905 bagasse Substances 0.000 title claims abstract description 57
- 150000004823 xylans Chemical class 0.000 title claims abstract description 51
- BDAGIHXWWSANSR-UHFFFAOYSA-N Formic acid Chemical class OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 230000032050 esterification Effects 0.000 title claims abstract description 24
- 238000005886 esterification reaction Methods 0.000 title claims abstract description 24
- 230000000694 effects Effects 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- -1 xylan sulfate Chemical class 0.000 claims abstract description 16
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims abstract description 15
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003054 catalyst Substances 0.000 claims abstract description 10
- 235000019253 formic acid Nutrition 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 8
- ODZPKZBBUMBTMG-UHFFFAOYSA-N sodium amide Chemical compound [NH2-].[Na+] ODZPKZBBUMBTMG-UHFFFAOYSA-N 0.000 claims abstract description 8
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- 239000000243 solution Substances 0.000 claims description 26
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 24
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- 238000003756 stirring Methods 0.000 claims description 21
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 19
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 17
- 238000004458 analytical method Methods 0.000 claims description 16
- 239000012153 distilled water Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 12
- 230000001376 precipitating effect Effects 0.000 claims description 9
- 235000010288 sodium nitrite Nutrition 0.000 claims description 9
- 238000005406 washing Methods 0.000 claims description 9
- 239000008280 blood Substances 0.000 claims description 7
- 210000004369 blood Anatomy 0.000 claims description 7
- 239000000047 product Substances 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 239000012043 crude product Substances 0.000 claims description 6
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 6
- 239000012065 filter cake Substances 0.000 claims description 6
- 239000002244 precipitate Substances 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 5
- 239000011259 mixed solution Substances 0.000 claims description 4
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 230000002045 lasting effect Effects 0.000 claims description 3
- BCTWNMTZAXVEJL-UHFFFAOYSA-N phosphane;tungsten;tetracontahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.P.[W].[W].[W].[W].[W].[W].[W].[W].[W].[W].[W].[W] BCTWNMTZAXVEJL-UHFFFAOYSA-N 0.000 claims description 3
- 239000013049 sediment Substances 0.000 claims description 3
- 229940079827 sodium hydrogen sulfite Drugs 0.000 claims description 3
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 7
- 230000010100 anticoagulation Effects 0.000 abstract description 3
- 239000003814 drug Substances 0.000 abstract description 3
- 235000013305 food Nutrition 0.000 abstract description 3
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- AVFBYUADVDVJQL-UHFFFAOYSA-N phosphoric acid;trioxotungsten;hydrate Chemical compound O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.OP(O)(O)=O AVFBYUADVDVJQL-UHFFFAOYSA-N 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000007858 starting material Substances 0.000 abstract description 2
- 238000003786 synthesis reaction Methods 0.000 abstract description 2
- 150000002148 esters Chemical class 0.000 description 6
- 239000012086 standard solution Substances 0.000 description 6
- 238000006467 substitution reaction Methods 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 4
- 230000019635 sulfation Effects 0.000 description 4
- 238000005670 sulfation reaction Methods 0.000 description 4
- 241000725303 Human immunodeficiency virus Species 0.000 description 3
- 238000004448 titration Methods 0.000 description 3
- 150000004676 glycans Chemical class 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000000542 sulfonic acid group Chemical group 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 125000000969 xylosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)CO1)* 0.000 description 2
- 235000018185 Betula X alpestris Nutrition 0.000 description 1
- 235000018212 Betula X uliginosa Nutrition 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- 240000000731 Fagus sylvatica Species 0.000 description 1
- 235000010099 Fagus sylvatica Nutrition 0.000 description 1
- 241000713772 Human immunodeficiency virus 1 Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 208000007536 Thrombosis Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000002479 acid--base titration Methods 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 230000004931 aggregating effect Effects 0.000 description 1
- 230000003172 anti-dna Effects 0.000 description 1
- 230000000078 anti-malarial effect Effects 0.000 description 1
- 230000002785 anti-thrombosis Effects 0.000 description 1
- 239000003146 anticoagulant agent Substances 0.000 description 1
- 239000003430 antimalarial agent Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000000975 bioactive effect Effects 0.000 description 1
- 230000007910 cell fusion Effects 0.000 description 1
- 230000009514 concussion Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000003013 cytotoxicity Effects 0.000 description 1
- 231100000135 cytotoxicity Toxicity 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 150000004804 polysaccharides Chemical class 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000002798 spectrophotometry method Methods 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
- C08B37/0057—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid beta-D-Xylans, i.e. xylosaccharide, e.g. arabinoxylan, arabinofuronan, pentosans; (beta-1,3)(beta-1,4)-D-Xylans, e.g. rhodymenans; Hemicellulose; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Abstract
Description
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710830883.2A CN107383243B (zh) | 2017-09-15 | 2017-09-15 | 双酯化活性磺酸基蔗渣木聚糖-1,1-二茂铁双甲酸酯的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710830883.2A CN107383243B (zh) | 2017-09-15 | 2017-09-15 | 双酯化活性磺酸基蔗渣木聚糖-1,1-二茂铁双甲酸酯的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN107383243A CN107383243A (zh) | 2017-11-24 |
CN107383243B true CN107383243B (zh) | 2019-06-07 |
Family
ID=60350386
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710830883.2A Active CN107383243B (zh) | 2017-09-15 | 2017-09-15 | 双酯化活性磺酸基蔗渣木聚糖-1,1-二茂铁双甲酸酯的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN107383243B (zh) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114380393B (zh) * | 2022-01-25 | 2022-12-09 | 南京大学 | 一种负载二茂铁的耦合反硝化脱氮生物填料及其制备方法和应用 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106366215A (zh) * | 2016-10-26 | 2017-02-01 | 桂林理工大学 | 双酯化活性磺酸基蔗渣木聚糖对羟基苯甲酸酯的制备方法 |
-
2017
- 2017-09-15 CN CN201710830883.2A patent/CN107383243B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106366215A (zh) * | 2016-10-26 | 2017-02-01 | 桂林理工大学 | 双酯化活性磺酸基蔗渣木聚糖对羟基苯甲酸酯的制备方法 |
Non-Patent Citations (1)
Title |
---|
"Synthesis, crystal structure, electronic spectroscopy, electrochemistry and biological studies of carbohydrate containing ferrocene amides";Rajiv Trivedi et;《Applied Organometallic Chemistry》;20121231;第369-376页 |
Also Published As
Publication number | Publication date |
---|---|
CN107383243A (zh) | 2017-11-24 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104628882B (zh) | 一种磺酸基蔗渣木聚糖邻苯二甲酸酯的合成方法 | |
CN100595225C (zh) | 分子印迹聚合物微球的制备方法及其分离恩诺沙星的方法 | |
CN102964539B (zh) | 多孔磁性聚苯乙烯微球的制备方法 | |
CN107417857A (zh) | 抗癌活性衍生物蔗渣木聚糖丁香酸酯‑g‑AM/MMA的合成方法 | |
CN101942041B (zh) | 一种硫酸酯化蔗渣木聚糖的制备方法 | |
CN104927063B (zh) | 一种吸附回收工业废水中酚类化合物的方法及吸附材料的制备方法 | |
CN102344527A (zh) | 利用分子印迹聚合物净化磺胺类药物的方法 | |
CN102068965A (zh) | 一种适于蛋白纯化的壳聚糖分离介质的制备方法 | |
CN101985493B (zh) | 三氟氯氰菊酯分子印迹聚合物的制备方法及其用途 | |
CN108101996A (zh) | 利用纤维素生产纤维素质子型离子液体的方法 | |
CN107383243B (zh) | 双酯化活性磺酸基蔗渣木聚糖-1,1-二茂铁双甲酸酯的制备方法 | |
CN107722533A (zh) | 磁性交联aa/am接枝酯化氰乙基木薯淀粉微球的制备方法 | |
CN105153367A (zh) | 一种双氰胺介孔表面分子印迹聚合物微球的制备方法 | |
CN101250827B (zh) | 双醛羧甲基纤维素的制备及其醛基含量的检测方法 | |
CN102101683A (zh) | 碘化钾的制备方法 | |
CN106366215A (zh) | 双酯化活性磺酸基蔗渣木聚糖对羟基苯甲酸酯的制备方法 | |
CN104448057B (zh) | 一种纳米级阿魏酸蔗渣木聚糖酯的制备方法 | |
CN105363417A (zh) | 一种交联羧甲基化琼脂糖基凝胶微球的制备方法 | |
CN106519079A (zh) | 抗hiv活性磺酸基蔗渣木聚糖对苯二甲酸酯的合成方法 | |
CN105884608B (zh) | 一种从木质纤维素水解液中分离乙酰丙酸的方法 | |
CN104803845B (zh) | 一种药用柠檬酸酯的合成方法 | |
CN104774575A (zh) | 一种水溶性生物基硫酸酯/磺酸盐的制备工艺及作为绿色环保粘胶剂的用途 | |
CN102863646A (zh) | 一种松香基多孔聚合物微球的制备方法 | |
CN106565857A (zh) | 一种双活性磺酸基蔗渣木聚糖间苯二甲酸酯的合成方法 | |
CN107722142A (zh) | 一种抗hiv活性磺酸基蔗渣木聚糖对二茂铁苯甲酸酯的合成方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract | ||
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20171124 Assignee: GUANGXI AGLYCONE PLANT PRODUCTS Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980044210 Denomination of invention: Preparation method of 1,1-diferrocene dicarboxylic acid ester of double esterified active sulfonic acid bagasse xylan Granted publication date: 20190607 License type: Common License Record date: 20231025 |
|
EE01 | Entry into force of recordation of patent licensing contract | ||
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20171124 Assignee: Guangxi Guiren Energy Saving Technology Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980045083 Denomination of invention: Preparation method of 1,1-diferrocene dicarboxylic acid ester of double esterified active sulfonic acid bagasse xylan Granted publication date: 20190607 License type: Common License Record date: 20231103 Application publication date: 20171124 Assignee: GUANGXI CHAOXING SOLAR ENERGY TECHNOLOGY Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980045079 Denomination of invention: Preparation method of 1,1-diferrocene dicarboxylic acid ester of double esterified active sulfonic acid bagasse xylan Granted publication date: 20190607 License type: Common License Record date: 20231030 |
|
EE01 | Entry into force of recordation of patent licensing contract | ||
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20171124 Assignee: Guilin Yifen Food Technology Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980046005 Denomination of invention: Preparation method of 1,1-diferrocene dicarboxylic acid ester of double esterified active sulfonic acid bagasse xylan Granted publication date: 20190607 License type: Common License Record date: 20231106 |